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Dr. Hassan Z. Harraz
hharraz2006@yahoo.com
Autum 2023
“Iron Ore is more Integral to the Global
Economy than any Other Commodity,
Except Perhaps Oil”.
Christopher LaFemina, mining analyst at Barclays Capital
(In 2011 the Financial Times quoted)
@Hassan Harraz 2023
IRONMAKING
IRON PRODUCTION
(IRONWORKS)
DOI: 10.13140/RG.2.2.32002.45767
Keywords:
• Blast Furnace
• Direct Reduction Furnace
@Hassan Harraz 2023
IRONMAKING
2
1. INTRODUCTION
2. IRONMAKING ROUTES
Figure 1: Prominent Routes for Steelmaking
Table 1: Ironmaking Processes
IRON
PRODUCTION
(IRONWORKS)
Smelting
• Blast Furnace (produces Pig Iron)
o Cold blast
o Hot blast
o Anthracite iron
• Direct Reduction Furnace (produces DRI)
• Bloomery (produces Sponge Iron)
Secondary
• Wrought Iron (via Finery Forge or
Reverberatory Puddling Furnace)
• Cast Iron (via Cupola Furnace or Induction
Furnace)
@Hassan Harraz 2023
IRONMAKING
6
2.1. Blast Furnace (produces Pig Iron)
2.1.1. Carica
2.1.2. Operating Conditions in Large Blast Furnace (BF)
Blast Furnace
2.1.3. Reactions in BF
2.1.3. Reactions in BF (cont.)
2.1.4.Trace Elements
2.2. Direct Reduction Furnace (produces DRI)
2.2. Direct Reduction Furnace (produces DRI)
Reforming natural gas has a H2/CO ratio of 1.6, the temperature is 900 C. Part of the exhaust gas is mixed
with natural gas and reformed, and the remainder is used as the fuel for the reformer furnace. Higher
furnace temperatures result in higher productivity, because the metal is reduced by an endothermic
reaction. However, an excessive furnace temperature will cause the pellets and lump ore to melt during
reduction and agglomeration. The maximum reduction rate is about 95%, and the carbon content is limited
to about 2.5%.
Example of Direct Reduction Process
@Hassan Harraz 2023
IRONMAKING
16
Table 2: Comparison of Pig Iron and DRI
References
1. "What is direct reduced iron (DRI)? definition and meaning". Businessdictionary.com.
Retrieved 2011-07-11.
2. "Direct reduced iron (DRI)". International Iron Metallics Association. 14 November 2019.
3. R. J. Fruehan, et al. (2000). Theoretical Minimum Energies to Produce Steel (for
Selected Conditions)
4. "2020 World Direct Reduction Statistics" (PDF). Midrex Technologies. 2020. Retrieved 25
January 2020.
5. "Steel making today and tomorrow". Archived from the original on 20 December 2020.
6. Direct Reduced Iron (DRI) - Cargo Handbook - the world's largest cargo transport
guidelines website". www.cargohandbook.com. Retrieved 2022-06-18.
7. Hattwig, Martin; Steen, Henrikus (2004), Handbook of explosion prevention and
protection, Wiley-VCH, pp. 269–270, ISBN 978-3-527-30718-0. (dead link 24
October 2019).
8. "MIDREX" (PDF).
9. Zimmermann, Michael B.; Winichagoon, Pattanee; Gowachirapant, Sueppong; Hess,
Sonja Y.; Harrington, Mary; Chavasit, Visith; Lynch, Sean R.; Hurrell, Richard F.
(2005). "Comparison of the efficacy of wheat-based snacks fortified with ferrous
sulfate, electrolytic iron, or hydrogen-reduced elemental iron: Randomized, double-
blind, controlled trial in Thai women". The American Journal of Clinical
Nutrition. 82 (6): 1276–1282. doi:10.1093/ajcn/82.6.1276. PMID 16332661.
10. Shah, Bhagwan G.; Giroux, Alexandre; Belonje, Bartholomeus (1977). "Specifications
for reduced iron as a food additive". Journal of Agricultural and Food
Chemistry. 25 (3): 592–594. doi:10.1021/jf60211a044. PMID 858856.
@Hassan Harraz 2023
IRONMAKING
18

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IRONWORKS.pdf

  • 1. Dr. Hassan Z. Harraz hharraz2006@yahoo.com Autum 2023 “Iron Ore is more Integral to the Global Economy than any Other Commodity, Except Perhaps Oil”. Christopher LaFemina, mining analyst at Barclays Capital (In 2011 the Financial Times quoted) @Hassan Harraz 2023 IRONMAKING IRON PRODUCTION (IRONWORKS) DOI: 10.13140/RG.2.2.32002.45767
  • 2. Keywords: • Blast Furnace • Direct Reduction Furnace @Hassan Harraz 2023 IRONMAKING 2
  • 5. Figure 1: Prominent Routes for Steelmaking
  • 6. Table 1: Ironmaking Processes IRON PRODUCTION (IRONWORKS) Smelting • Blast Furnace (produces Pig Iron) o Cold blast o Hot blast o Anthracite iron • Direct Reduction Furnace (produces DRI) • Bloomery (produces Sponge Iron) Secondary • Wrought Iron (via Finery Forge or Reverberatory Puddling Furnace) • Cast Iron (via Cupola Furnace or Induction Furnace) @Hassan Harraz 2023 IRONMAKING 6
  • 7. 2.1. Blast Furnace (produces Pig Iron)
  • 9. 2.1.2. Operating Conditions in Large Blast Furnace (BF)
  • 12. 2.1.3. Reactions in BF (cont.)
  • 14. 2.2. Direct Reduction Furnace (produces DRI)
  • 15. 2.2. Direct Reduction Furnace (produces DRI)
  • 16. Reforming natural gas has a H2/CO ratio of 1.6, the temperature is 900 C. Part of the exhaust gas is mixed with natural gas and reformed, and the remainder is used as the fuel for the reformer furnace. Higher furnace temperatures result in higher productivity, because the metal is reduced by an endothermic reaction. However, an excessive furnace temperature will cause the pellets and lump ore to melt during reduction and agglomeration. The maximum reduction rate is about 95%, and the carbon content is limited to about 2.5%. Example of Direct Reduction Process @Hassan Harraz 2023 IRONMAKING 16
  • 17. Table 2: Comparison of Pig Iron and DRI
  • 18. References 1. "What is direct reduced iron (DRI)? definition and meaning". Businessdictionary.com. Retrieved 2011-07-11. 2. "Direct reduced iron (DRI)". International Iron Metallics Association. 14 November 2019. 3. R. J. Fruehan, et al. (2000). Theoretical Minimum Energies to Produce Steel (for Selected Conditions) 4. "2020 World Direct Reduction Statistics" (PDF). Midrex Technologies. 2020. Retrieved 25 January 2020. 5. "Steel making today and tomorrow". Archived from the original on 20 December 2020. 6. Direct Reduced Iron (DRI) - Cargo Handbook - the world's largest cargo transport guidelines website". www.cargohandbook.com. Retrieved 2022-06-18. 7. Hattwig, Martin; Steen, Henrikus (2004), Handbook of explosion prevention and protection, Wiley-VCH, pp. 269–270, ISBN 978-3-527-30718-0. (dead link 24 October 2019). 8. "MIDREX" (PDF). 9. Zimmermann, Michael B.; Winichagoon, Pattanee; Gowachirapant, Sueppong; Hess, Sonja Y.; Harrington, Mary; Chavasit, Visith; Lynch, Sean R.; Hurrell, Richard F. (2005). "Comparison of the efficacy of wheat-based snacks fortified with ferrous sulfate, electrolytic iron, or hydrogen-reduced elemental iron: Randomized, double- blind, controlled trial in Thai women". The American Journal of Clinical Nutrition. 82 (6): 1276–1282. doi:10.1093/ajcn/82.6.1276. PMID 16332661. 10. Shah, Bhagwan G.; Giroux, Alexandre; Belonje, Bartholomeus (1977). "Specifications for reduced iron as a food additive". Journal of Agricultural and Food Chemistry. 25 (3): 592–594. doi:10.1021/jf60211a044. PMID 858856. @Hassan Harraz 2023 IRONMAKING 18