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International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 06 Issue: 06 | June 2019 www.irjet.net p-ISSN: 2395-0072
© 2019, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 371
Treatment of Dairy Waste Water by using Groundnut Shell as Low Cost
Adsorbent
Deepika Dinakar1, Aswathi Mithran2
1M.Tech student, Environmental Engineering in the Department of Civil Engineering
2M-Dasan Institute of Technology Ulliyeri, Kerala, India
3Assistant Professor, Department of Civil Engineering, M-Dasan Institite of Technology Ulliyeri, Kerala, India
---------------------------------------------------------------------***----------------------------------------------------------------------
Abstract - Milk has important place in human life. The dairy
industry involves processing of raw milk into products like
consumer milk, butter, cheese etc. The quantity of water
required in a milk processing plantdependsuponthesizeofthe
plant, generally expressed in terms of the maximum weight of
milk handled in a single day, and the processes involved. The
dairy industry is generally considered to be the largest source
of food processing wastewater in many countries. With
increase in demand for milk and milk products,manydairiesof
different sizes have come up in different places. These dairies
collect the milk from the produces, and then either simply
bottle it for marketing, or produce different milk foods
according to their capacities. In this paper the waste water
from dairy is passing through the grounut shell medium
particle size retained on 4.75 mm IS sieve. By using low cost
adsorbent minimize the hazardous effect which is harmful to
the environment to considerable extent
Key Words: Dairy waste water, Groundnut shell, Column
Chromotography, pH, BOD, COD, etc
1. INTRODUCTION
The dairy industry is generally considered to be the largest
source of food processing wastewater in many countries.
With increase in demand for milk and milk products, many
dairies of different sizes have come up in different places.
These dairies collect the milk from the produces, and then
either simply bottle it for marketing, or produce different
milk foods according to their capacities. Present study
focuses on using groundnut shells, which are basically the
waste usually fed to cattle’s, as absorbents fordairyindustry
effluent. Water is one of the universal substances, which is
used alike by all the living species to sustain life. Clean and
plentiful water provides the foundation for prosperous life
and communities. We rely on cleanwatertosurvive, butnow
we are heading towards a water crisis. The changes in
climatic patterns are threatening lakes and rivers, and also
the key sources that we tap for drinking water, which are
being overdrawn or tainted with pollution.
The main characteristics of waste from dairy industy
i)High dissolved solids
ii) High suspended solids
iii) High BOD
iv) Phosphorus
v) Nitrogen
vi) Oil and
1.1 Need of Study
Management of the quality of thispreciousresource
is, therefore, of special importance.Disposingdifferentkinds
of wastewater such as domestic, industrial and agricultural
effluent into environment, especially to surface water, can
cause heavy pollution of this body sources. With regard to
increasing wastewater disposed standards to the
environment, high considerations should be made when
selecting proper treatment processes. . It should be kept in
mind that economical aspectsareimportant,too.Inaddition,
employing environment friendly methods for treatment is
emphasized much more these days . In this study, dairy
effluent is collected and analyzed for different parameters
such as pH, TSS, BOD and COD. After checking such
parameters groundnut shells are use for reduce their
concentration andpurification,whichhaspropertytoreduce
or to absorb the impurities.
1.2 Objectives of study
 To check the feasibility of use of groundnut husk as
adsorbent for dairy wastewater.
 To determine various parameter of treated &
untreated dairy wastewater as pH, B.O.D, C.O.D,
T.S.S.
 To study Environmental pollution control due to
dairy waste water.
 Removing of organic matter by adsorption
techniques & reduction of B.O.D, C.O.D,andincrease
of pH of natural water.
 To achieve the sustainable development of
environment by avoiding pollution of streams.
 To reuse the wastewater for various quality.eg.
Gardening, flushing sewer, cleaning, farming.
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 06 Issue: 06 | June 2019 www.irjet.net p-ISSN: 2395-0072
© 2019, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 372
1.3 DAIRY WASTE SOURCES
Each unit operation generates dairy waste water
like wash water from cleaning of milk cans, process
equipment’s, tankers, pipelines floorsandportionsofspilled
milk, spoiled milk and milk leakage from milk pumps and
pipelines. There are different categories.
 Cooling water
 Sanitary waste water
 3Industrial waste water
2. METHODOLOGY
Step 1- Fabrication of Experimental Setup
The experimental setupforconductingthestudyhas
been fabricated. Column chromatography is adopted for
conducting the experiment. The material used for the
fabrication of column will be PVC pipe.
Step 2- Collection of Adsorbent
The groundnut shell medium retained on 4.75mm IS sieve is
used as absorbent. Sieve analysis is carried out for the
preparation of groundnut shell rusk. Groundnut is generally
the seeds that ripen underground, of the following plants, all
in the Faboideae subfamily of the legumes
Step3- Collection of Dairy Waste Water Sample
The source for the collection of waste water sample
throughout the present study was Milma peringolam near
kunnamangalam Calicut. The methodology involved in
collection of samples at different units
Step4- Selection of Water Quality Parameters and its
determination
This project includes the study of removal efficiencyofwater
quality parameters such as pH, BOD, COD, Total suspended
and total dissolved solids
Step5- Determination of Initial Characteristics of Waste
Water
For the determination of initial characteristic ofwastewater
testing the untreated dairy waste water for the parametes
such as ph, colour, turbidity, total solids, BOD, COD.
Step6- Compare the actual result with permissible
parameter
The actual result obtained after conducting the initial
characteristic determination will be compared with the
permissible limits of parameter. For that an effluent
standard for dairy industry has been used
Step7- Treat a dairy waste water with groundnutshellsrusk
The waste water from the dairy is passing through
the groundnut shell medium through each of the column
having diameter 2 inch, 2.5 inch and 3 inch. Primarily the
waste water is passed through 20 cm height of groundnut
shell medium in each of the three column. The contact time
adopted for conducting the experiment are 2 hour, 6 hour,
24 hour. After 2 hour, 6 hour and 24 hour and the treated
water is tested. Similarly the waste water is passed through
40 cm and 60 cm height of the groundnut shell medium.
Step8- Testing of treated dairy waste water for various
quality parameters
The treated water after passing through the groundnutshell
medium are collected from the bottom of the column
through the collecting pipe. The treated dairy waste water is
tested for various water quality parameters
Step9- Compare the treated waste water readings with
untreated waste water parameter
Comparison can be carried out between the treated waste
water and untreated waste water. The comparison can be
analyzed through the graphical representation
Step10- Checking the removal efficieny
The removal efficiency is found by comparing the
various parameters such as pH, turbidity,TDS, suspended
solids, BOD and COD before and after the treatment.
Fig- 1: Experimental Setup
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 06 Issue: 06 | June 2019 www.irjet.net p-ISSN: 2395-0072
© 2019, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 373
3. RESULT AND DISCUSSION
Chart- 1: Variation of parameters with time in 20 cm
height of material in 2 inch pipe
Chart- 2: Variation of parameters with time in 20 cm
height of material in 2.5 inch pipe
Chart- 3: Variation of parameters with time in 20 cm
height of material 3 inch pipe
Chart- 4: Variation of parameters with time in 40 cm
height of material 2 inch pipe
Chart- 5: Variation of parameters with time in 40 cm
height of material 2.5 inch pipe
Chart- 6: Variation of parameters with time in 40 cm
height of material 3 inch pipe
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 06 Issue: 06 | June 2019 www.irjet.net p-ISSN: 2395-0072
© 2019, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 374
Chart- 7: Variation of parameters with time in 60 cm
height of material 2 inch pipe
Chart- 8: Variation of parameters with time in 60 cm
height of material 2.5 inch pipe
Chart- 9: Variation of parameters with time in 60 cm
height of material in 3 inch pipel
Effect on pH: As from the above study it has been
seen that pH of dairy waste water sample after passing
through 3 inch diameter pipe in which the height of ground
nut shell is 60cm is found to be more feasible as compare to
other pipe having diameter 2, 2.5 inch and heightofmaterial
20, 40, 60 cm.
Effect on total solid: TS of dairy waste water sample
after passing through 3inch diameter pipe in which the
height of ground nut shell is 60cm is found to be more
feasible as compare to other pipe having diameter 2 and 2.5
inch and height of material 20, 40, 60 cm.
Effect on BOD: As from the above chart it has been seen that
BOD of dairy waste water sample after passing through 3
inch diameter pipe in which the height of ground nut shell is
60cm is found to be more feasible as compare to other pipe
having diameter 2 and 2.5 inch and height of material 20, 40,
60 cm.
Effect on COD: As from the above chart it has been
seen that COD of dairy waste water sample after passing
through 3 inch diameter pipe in which the height of ground
nut shell is 60cm is found to be more feasible as compare to
other pipe having diameter 2 and 2.5 inch and height of
material 20, 40, 60 cm.
Beacuse of large diameter and the height ground
nut shell material, hence the large vol. of material in these
pipe and the large surface area of material which coming in
contact with the dairy waste water which adsorb the
impurities present in the dairy waste water.
3. CONCLUSION
Wastewater treatment is a process used to remove
contaminants from wastewaterorsewageandconvertitinto
an effluent that can be returned to the water cycle with
minimum impact on the environment, or directly reused.
The treatment of wastewater is part of the overarching field
of sanitation. Sanitation also includes the management of
human waste and solid waste as well as stormwater
(drainage) management. By-products from wastewater
treatment plants, such as screenings, grit and sewagesludge
may also be treated in a wastewater treatment plant.
Biological processes can be employed in the treatment of
wastewater and these processes may include, for example,
aerated lagoons, activated sludge or slow sand filters. To be
effective, sewage must be conveyed to a treatment plant by
appropriate pipes and infrastructure and the process itself
must be subject to regulation and controls. Present study
focuses on using groundnut shells, which are basically the
waste usually fed to cattle’s, as absorbents fordairyindustry
effluent. Water is one of the universal substances, which is
used alike by all the living species to sustain life. Clean and
plentiful water provides the foundation for prosperous life
and communities. We rely on cleanwatertosurvive, butnow
we are heading towards a water crisis. Industrialization
activities for the development of nation contribute to global
environmental deterioration as these activities caused
depletion, degradation and deterioration of natural
resources and biodiversity. Additionally, these industrial
activities indirectly overload water body with thousands of
water pollutantandsubsequentlypollutingthe environment.
From the above study it has been seen that the parameters
such as pH, total solid, BOD and COD of dairy waste water
sample after passing through 3 inch diameter pipe in which
the height of ground nut shell is 60cm is found to be more
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 06 Issue: 06 | June 2019 www.irjet.net p-ISSN: 2395-0072
© 2019, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 375
feasible as compare to other pipe having diameter2,2.5inch
and height of material 20, 40, 60cm IRJET.
REFERENCES
[1] Ashutosh Tripathi and Manju Rawat Ranjan, (2013),
“Heavy Metal Removal from WastewaterUsingLowCost
Adsorbents”, International Research Journal of
Engineering and Technology, Volume 6, Issue 6.
[2] Prof. Chidanand Patil, Ms. Manika Hugar, (2015),
“Treatment of dairy wastewater by natural coagulants”-
International Research Journal of Engineering and
Technology (IRJET), Volume 2, Issue 4.
[3] S. Idris1, Y. A. Iyaka, B. E. N. Dauda, M. M. NdamitsandM.
T. Umar, (2012), “Kinetic Study of Utilizing Groundnut
Shell as an Adsorbent in Removing Chromium and
Nickel from Dye Effluent”, American Chemical Science
Journal, 12-24.
[4] Isah U. A. and Yusuf A.I, (2012), “Adsorption Of Lead
Ions On Groundnut Shell Activated Carbon”,
www.pelagiaresearchlibrary.com, 1511-1515.
[5] Mohammad Ajmal, R. A. K. Rao, Jameel Ahmad And Rais
Ahmad, (2006), “The Use of Testa of Groundnut Shell
(Arachis hypogea) for the Adsorption of Ni(II) from the
Aqueous System”, International Research Journal of
Engineering and Technology.

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IRJET- Treatment of Dairy Waste Water by using Groundnut Shell as Low Cost Adsorbent

  • 1. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 06 Issue: 06 | June 2019 www.irjet.net p-ISSN: 2395-0072 © 2019, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 371 Treatment of Dairy Waste Water by using Groundnut Shell as Low Cost Adsorbent Deepika Dinakar1, Aswathi Mithran2 1M.Tech student, Environmental Engineering in the Department of Civil Engineering 2M-Dasan Institute of Technology Ulliyeri, Kerala, India 3Assistant Professor, Department of Civil Engineering, M-Dasan Institite of Technology Ulliyeri, Kerala, India ---------------------------------------------------------------------***---------------------------------------------------------------------- Abstract - Milk has important place in human life. The dairy industry involves processing of raw milk into products like consumer milk, butter, cheese etc. The quantity of water required in a milk processing plantdependsuponthesizeofthe plant, generally expressed in terms of the maximum weight of milk handled in a single day, and the processes involved. The dairy industry is generally considered to be the largest source of food processing wastewater in many countries. With increase in demand for milk and milk products,manydairiesof different sizes have come up in different places. These dairies collect the milk from the produces, and then either simply bottle it for marketing, or produce different milk foods according to their capacities. In this paper the waste water from dairy is passing through the grounut shell medium particle size retained on 4.75 mm IS sieve. By using low cost adsorbent minimize the hazardous effect which is harmful to the environment to considerable extent Key Words: Dairy waste water, Groundnut shell, Column Chromotography, pH, BOD, COD, etc 1. INTRODUCTION The dairy industry is generally considered to be the largest source of food processing wastewater in many countries. With increase in demand for milk and milk products, many dairies of different sizes have come up in different places. These dairies collect the milk from the produces, and then either simply bottle it for marketing, or produce different milk foods according to their capacities. Present study focuses on using groundnut shells, which are basically the waste usually fed to cattle’s, as absorbents fordairyindustry effluent. Water is one of the universal substances, which is used alike by all the living species to sustain life. Clean and plentiful water provides the foundation for prosperous life and communities. We rely on cleanwatertosurvive, butnow we are heading towards a water crisis. The changes in climatic patterns are threatening lakes and rivers, and also the key sources that we tap for drinking water, which are being overdrawn or tainted with pollution. The main characteristics of waste from dairy industy i)High dissolved solids ii) High suspended solids iii) High BOD iv) Phosphorus v) Nitrogen vi) Oil and 1.1 Need of Study Management of the quality of thispreciousresource is, therefore, of special importance.Disposingdifferentkinds of wastewater such as domestic, industrial and agricultural effluent into environment, especially to surface water, can cause heavy pollution of this body sources. With regard to increasing wastewater disposed standards to the environment, high considerations should be made when selecting proper treatment processes. . It should be kept in mind that economical aspectsareimportant,too.Inaddition, employing environment friendly methods for treatment is emphasized much more these days . In this study, dairy effluent is collected and analyzed for different parameters such as pH, TSS, BOD and COD. After checking such parameters groundnut shells are use for reduce their concentration andpurification,whichhaspropertytoreduce or to absorb the impurities. 1.2 Objectives of study  To check the feasibility of use of groundnut husk as adsorbent for dairy wastewater.  To determine various parameter of treated & untreated dairy wastewater as pH, B.O.D, C.O.D, T.S.S.  To study Environmental pollution control due to dairy waste water.  Removing of organic matter by adsorption techniques & reduction of B.O.D, C.O.D,andincrease of pH of natural water.  To achieve the sustainable development of environment by avoiding pollution of streams.  To reuse the wastewater for various quality.eg. Gardening, flushing sewer, cleaning, farming.
  • 2. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 06 Issue: 06 | June 2019 www.irjet.net p-ISSN: 2395-0072 © 2019, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 372 1.3 DAIRY WASTE SOURCES Each unit operation generates dairy waste water like wash water from cleaning of milk cans, process equipment’s, tankers, pipelines floorsandportionsofspilled milk, spoiled milk and milk leakage from milk pumps and pipelines. There are different categories.  Cooling water  Sanitary waste water  3Industrial waste water 2. METHODOLOGY Step 1- Fabrication of Experimental Setup The experimental setupforconductingthestudyhas been fabricated. Column chromatography is adopted for conducting the experiment. The material used for the fabrication of column will be PVC pipe. Step 2- Collection of Adsorbent The groundnut shell medium retained on 4.75mm IS sieve is used as absorbent. Sieve analysis is carried out for the preparation of groundnut shell rusk. Groundnut is generally the seeds that ripen underground, of the following plants, all in the Faboideae subfamily of the legumes Step3- Collection of Dairy Waste Water Sample The source for the collection of waste water sample throughout the present study was Milma peringolam near kunnamangalam Calicut. The methodology involved in collection of samples at different units Step4- Selection of Water Quality Parameters and its determination This project includes the study of removal efficiencyofwater quality parameters such as pH, BOD, COD, Total suspended and total dissolved solids Step5- Determination of Initial Characteristics of Waste Water For the determination of initial characteristic ofwastewater testing the untreated dairy waste water for the parametes such as ph, colour, turbidity, total solids, BOD, COD. Step6- Compare the actual result with permissible parameter The actual result obtained after conducting the initial characteristic determination will be compared with the permissible limits of parameter. For that an effluent standard for dairy industry has been used Step7- Treat a dairy waste water with groundnutshellsrusk The waste water from the dairy is passing through the groundnut shell medium through each of the column having diameter 2 inch, 2.5 inch and 3 inch. Primarily the waste water is passed through 20 cm height of groundnut shell medium in each of the three column. The contact time adopted for conducting the experiment are 2 hour, 6 hour, 24 hour. After 2 hour, 6 hour and 24 hour and the treated water is tested. Similarly the waste water is passed through 40 cm and 60 cm height of the groundnut shell medium. Step8- Testing of treated dairy waste water for various quality parameters The treated water after passing through the groundnutshell medium are collected from the bottom of the column through the collecting pipe. The treated dairy waste water is tested for various water quality parameters Step9- Compare the treated waste water readings with untreated waste water parameter Comparison can be carried out between the treated waste water and untreated waste water. The comparison can be analyzed through the graphical representation Step10- Checking the removal efficieny The removal efficiency is found by comparing the various parameters such as pH, turbidity,TDS, suspended solids, BOD and COD before and after the treatment. Fig- 1: Experimental Setup
  • 3. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 06 Issue: 06 | June 2019 www.irjet.net p-ISSN: 2395-0072 © 2019, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 373 3. RESULT AND DISCUSSION Chart- 1: Variation of parameters with time in 20 cm height of material in 2 inch pipe Chart- 2: Variation of parameters with time in 20 cm height of material in 2.5 inch pipe Chart- 3: Variation of parameters with time in 20 cm height of material 3 inch pipe Chart- 4: Variation of parameters with time in 40 cm height of material 2 inch pipe Chart- 5: Variation of parameters with time in 40 cm height of material 2.5 inch pipe Chart- 6: Variation of parameters with time in 40 cm height of material 3 inch pipe
  • 4. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 06 Issue: 06 | June 2019 www.irjet.net p-ISSN: 2395-0072 © 2019, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 374 Chart- 7: Variation of parameters with time in 60 cm height of material 2 inch pipe Chart- 8: Variation of parameters with time in 60 cm height of material 2.5 inch pipe Chart- 9: Variation of parameters with time in 60 cm height of material in 3 inch pipel Effect on pH: As from the above study it has been seen that pH of dairy waste water sample after passing through 3 inch diameter pipe in which the height of ground nut shell is 60cm is found to be more feasible as compare to other pipe having diameter 2, 2.5 inch and heightofmaterial 20, 40, 60 cm. Effect on total solid: TS of dairy waste water sample after passing through 3inch diameter pipe in which the height of ground nut shell is 60cm is found to be more feasible as compare to other pipe having diameter 2 and 2.5 inch and height of material 20, 40, 60 cm. Effect on BOD: As from the above chart it has been seen that BOD of dairy waste water sample after passing through 3 inch diameter pipe in which the height of ground nut shell is 60cm is found to be more feasible as compare to other pipe having diameter 2 and 2.5 inch and height of material 20, 40, 60 cm. Effect on COD: As from the above chart it has been seen that COD of dairy waste water sample after passing through 3 inch diameter pipe in which the height of ground nut shell is 60cm is found to be more feasible as compare to other pipe having diameter 2 and 2.5 inch and height of material 20, 40, 60 cm. Beacuse of large diameter and the height ground nut shell material, hence the large vol. of material in these pipe and the large surface area of material which coming in contact with the dairy waste water which adsorb the impurities present in the dairy waste water. 3. CONCLUSION Wastewater treatment is a process used to remove contaminants from wastewaterorsewageandconvertitinto an effluent that can be returned to the water cycle with minimum impact on the environment, or directly reused. The treatment of wastewater is part of the overarching field of sanitation. Sanitation also includes the management of human waste and solid waste as well as stormwater (drainage) management. By-products from wastewater treatment plants, such as screenings, grit and sewagesludge may also be treated in a wastewater treatment plant. Biological processes can be employed in the treatment of wastewater and these processes may include, for example, aerated lagoons, activated sludge or slow sand filters. To be effective, sewage must be conveyed to a treatment plant by appropriate pipes and infrastructure and the process itself must be subject to regulation and controls. Present study focuses on using groundnut shells, which are basically the waste usually fed to cattle’s, as absorbents fordairyindustry effluent. Water is one of the universal substances, which is used alike by all the living species to sustain life. Clean and plentiful water provides the foundation for prosperous life and communities. We rely on cleanwatertosurvive, butnow we are heading towards a water crisis. Industrialization activities for the development of nation contribute to global environmental deterioration as these activities caused depletion, degradation and deterioration of natural resources and biodiversity. Additionally, these industrial activities indirectly overload water body with thousands of water pollutantandsubsequentlypollutingthe environment. From the above study it has been seen that the parameters such as pH, total solid, BOD and COD of dairy waste water sample after passing through 3 inch diameter pipe in which the height of ground nut shell is 60cm is found to be more
  • 5. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 06 Issue: 06 | June 2019 www.irjet.net p-ISSN: 2395-0072 © 2019, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 375 feasible as compare to other pipe having diameter2,2.5inch and height of material 20, 40, 60cm IRJET. REFERENCES [1] Ashutosh Tripathi and Manju Rawat Ranjan, (2013), “Heavy Metal Removal from WastewaterUsingLowCost Adsorbents”, International Research Journal of Engineering and Technology, Volume 6, Issue 6. [2] Prof. Chidanand Patil, Ms. Manika Hugar, (2015), “Treatment of dairy wastewater by natural coagulants”- International Research Journal of Engineering and Technology (IRJET), Volume 2, Issue 4. [3] S. Idris1, Y. A. Iyaka, B. E. N. Dauda, M. M. NdamitsandM. T. Umar, (2012), “Kinetic Study of Utilizing Groundnut Shell as an Adsorbent in Removing Chromium and Nickel from Dye Effluent”, American Chemical Science Journal, 12-24. [4] Isah U. A. and Yusuf A.I, (2012), “Adsorption Of Lead Ions On Groundnut Shell Activated Carbon”, www.pelagiaresearchlibrary.com, 1511-1515. [5] Mohammad Ajmal, R. A. K. Rao, Jameel Ahmad And Rais Ahmad, (2006), “The Use of Testa of Groundnut Shell (Arachis hypogea) for the Adsorption of Ni(II) from the Aqueous System”, International Research Journal of Engineering and Technology.