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Solar Energy: Organic Photovoltaics Courtney Klosterman Case Western Reserve University Physics Department REU Summer Program
Outline of Presentation Big Picture Problem Background: Silicon/Organic Solar Cells What I’m looking at: Structures and Calculations Goal Matching Calculations Future Work
Big  Picture Problem ,[object Object]
Prevents their widespread use to generate electricity
Most solar cells today are made of silicon in different states: crystalline, multicrystalline or amorphoushttp://www.devicedaily.com
Silicon  Solar Cells ,[object Object]
Recombination at the junction creates a depletion region with a large built-in electric field
  Electrons/holes are created when a photon is absorbed, and if in the depletion region, will be pushed in opposite directions by the electric field.,[object Object]
The polymers poly-3-hexylthiophene (P3HT) and Phenyl-C61-butyric acid methyl ester (PCBM) are mixed together to form an interpenetrating network of p and n type material called a bulk heterojunction. http://www.livescience.com http://riekemetals.thomasnet.com http://www.phys.tue.
Organic Solar Cells ,[object Object]
When the exciton reaches an interface between the p and n-type materials, charge is transferred which breaks the exciton and allows charge to be extracted to the electrodes.
    In a bulk heterojunction the distance the electron-hole pair has to travel to an interface is minimized, which optimizes the absorbance and minimizes recombination of electrons and holes,[object Object]
Structures ,[object Object]
 The absorption peak would be optimized around 50nm layer thickness of the polymer photovoltaic.
Similar to a laser cavity effect called frequency pullingITO, PV, Al ITO, PV, no cavity effect
Structures ,[object Object],[object Object]
How we make slides Use commercial ITO glass, or Sputter-coat ITO Mix Polymers together, dissolve well Spin coat polymers at various speeds Evaporate Aluminum or Sputter-coat Silver Sputter-coater		Some finished Samples		Evaporator

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Courtney Klosterman Presentation

  • 1. Solar Energy: Organic Photovoltaics Courtney Klosterman Case Western Reserve University Physics Department REU Summer Program
  • 2. Outline of Presentation Big Picture Problem Background: Silicon/Organic Solar Cells What I’m looking at: Structures and Calculations Goal Matching Calculations Future Work
  • 3.
  • 4. Prevents their widespread use to generate electricity
  • 5. Most solar cells today are made of silicon in different states: crystalline, multicrystalline or amorphoushttp://www.devicedaily.com
  • 6.
  • 7. Recombination at the junction creates a depletion region with a large built-in electric field
  • 8.
  • 9. The polymers poly-3-hexylthiophene (P3HT) and Phenyl-C61-butyric acid methyl ester (PCBM) are mixed together to form an interpenetrating network of p and n type material called a bulk heterojunction. http://www.livescience.com http://riekemetals.thomasnet.com http://www.phys.tue.
  • 10.
  • 11. When the exciton reaches an interface between the p and n-type materials, charge is transferred which breaks the exciton and allows charge to be extracted to the electrodes.
  • 12.
  • 13.
  • 14. The absorption peak would be optimized around 50nm layer thickness of the polymer photovoltaic.
  • 15. Similar to a laser cavity effect called frequency pullingITO, PV, Al ITO, PV, no cavity effect
  • 16.
  • 17. How we make slides Use commercial ITO glass, or Sputter-coat ITO Mix Polymers together, dissolve well Spin coat polymers at various speeds Evaporate Aluminum or Sputter-coat Silver Sputter-coater Some finished Samples Evaporator
  • 18.
  • 19.
  • 20.
  • 21.
  • 22.
  • 24. Look at electrical properties
  • 25. Find parameters that give good absorption and electrical propertiesGlove Box System at Ohio State Organic Solar Cell IV Curve http://deibel.files.wordpress.com
  • 26. Acknowledgements Kenneth D. Singer Brent Valle National Science Foundation Clips/SOURCE QUESTIONS?