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WHAT IS A CHEMICAL BOND? 
‡ A chemical bond holds two atoms together. 
‡ It is formed by the attraction of a positive and a 
negative ion or by the attraction of a positive 
nucleus to negative electrons. 
‡ Atoms form chemical bonds to get eight valence 
electrons, to complete the octet rule and to 
become stable.
THERE ARE 3 TYPES OF 
CHEMICAL BONDS 
• Ionic 
• Covalent 
• Metallic
• Ionic bonds form between cations (metals) 
and anions (nonmetals). 
• The metal transfers its valence electron to 
the nonmetal. The nonmetal accepts the 
valence electrons and turns into a negative 
ion, while the metal becomes a positive ion. 
• Arranged in a pattern of a crystal lattice 
• High melting and boiling points 
• Hard, rigid, and brittle
IONIC BONDS: ENERGY 
• The formation of ionic compounds is exothermic. 
• The energy required to separate ions is called the lattice energy. 
The more negative the lattice energy, the stronger the force of 
attraction. 
• Lattice energy of smaller compounds is more negative than that of 
larger compounds because the nucleus holds the valence electrons 
more closely together.
• Instead of transferring electrons, atoms share electrons. 
• If one pair of electrons are shared, a single bond is formed 
(Group 17 elements form single bonds). 
• If multiple pairs of electrons are shared, double and triple 
bonds can be formed (carbon, nitrogen, oxygen, and 
sulfur usually form multiple bonds).
COVALENT BONDS: SIGMA VS. PI 
• Single covalent bonds are called sigma bonds. Occurs 
when the electron pair is shared in an area centered 
between the two atoms. A sigma bond results if the 
valence atomic orbitals overlap end to end. 
• A pi bond is formed when parallel orbitals overlap to 
share electrons. The shared electron pair occupies the 
space above and below the place where the atoms are 
joined. 
• A double bond has one sigma and one pi bond. A 
triple bond has one sigma bond and two pi bonds.
COVALENT BONDS: ENERGY 
• Bond length: Distance between the atoms 
• Bond dissociation energy: Amount of energy required to bread a 
covalent bond 
• The smaller the bond length, the greater the bond dissociation 
energy, and vice versa.
COVALENT VS. IONIC
• When metals bond together to 
complete the octet rule. 
• All metal atoms contribute their 
valence electrons to form a sea of 
electrons. Electrons are free to 
move b/w the atoms.
METALLIC BONDING: ALLOYS 
• An alloy is a mixture of elements that has metallic properties. 
• Properties of alloys are different from those of the elements in it. 
• Alloys most commonly forms when elements involved are similar 
in size or the atoms of one element are considerably smaller than 
the atoms of the other. 
• There are two types of alloys, substitutional and interstitial.
METALLIC BONDS: ENERGY 
• Metallic bonds are weak and little 
energy is needed to break the bonds. 
Therefore, they have high melting 
points 
• Because the electrons are mobile, 
they transfer heat more efficiently 
and, therefore, are better 
conductors.
CONCLUSION 
• Elements bond to become stable. 
• Elements bond to have 8 valence electrons. 
• 3 types of bonds: Ionic, Covalent, Metallic 
• In ionic bonds, one element gives its electrons to another element. 
• Covalent bonds are the strongest bonds. Elements share electrons. 
• Metallic bonds are the weakest bonds. Elements are in a sea of 
electrons
Chemical bonding

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Chemical bonding

  • 1.
  • 2. WHAT IS A CHEMICAL BOND? ‡ A chemical bond holds two atoms together. ‡ It is formed by the attraction of a positive and a negative ion or by the attraction of a positive nucleus to negative electrons. ‡ Atoms form chemical bonds to get eight valence electrons, to complete the octet rule and to become stable.
  • 3. THERE ARE 3 TYPES OF CHEMICAL BONDS • Ionic • Covalent • Metallic
  • 4. • Ionic bonds form between cations (metals) and anions (nonmetals). • The metal transfers its valence electron to the nonmetal. The nonmetal accepts the valence electrons and turns into a negative ion, while the metal becomes a positive ion. • Arranged in a pattern of a crystal lattice • High melting and boiling points • Hard, rigid, and brittle
  • 5. IONIC BONDS: ENERGY • The formation of ionic compounds is exothermic. • The energy required to separate ions is called the lattice energy. The more negative the lattice energy, the stronger the force of attraction. • Lattice energy of smaller compounds is more negative than that of larger compounds because the nucleus holds the valence electrons more closely together.
  • 6. • Instead of transferring electrons, atoms share electrons. • If one pair of electrons are shared, a single bond is formed (Group 17 elements form single bonds). • If multiple pairs of electrons are shared, double and triple bonds can be formed (carbon, nitrogen, oxygen, and sulfur usually form multiple bonds).
  • 7. COVALENT BONDS: SIGMA VS. PI • Single covalent bonds are called sigma bonds. Occurs when the electron pair is shared in an area centered between the two atoms. A sigma bond results if the valence atomic orbitals overlap end to end. • A pi bond is formed when parallel orbitals overlap to share electrons. The shared electron pair occupies the space above and below the place where the atoms are joined. • A double bond has one sigma and one pi bond. A triple bond has one sigma bond and two pi bonds.
  • 8. COVALENT BONDS: ENERGY • Bond length: Distance between the atoms • Bond dissociation energy: Amount of energy required to bread a covalent bond • The smaller the bond length, the greater the bond dissociation energy, and vice versa.
  • 10. • When metals bond together to complete the octet rule. • All metal atoms contribute their valence electrons to form a sea of electrons. Electrons are free to move b/w the atoms.
  • 11. METALLIC BONDING: ALLOYS • An alloy is a mixture of elements that has metallic properties. • Properties of alloys are different from those of the elements in it. • Alloys most commonly forms when elements involved are similar in size or the atoms of one element are considerably smaller than the atoms of the other. • There are two types of alloys, substitutional and interstitial.
  • 12. METALLIC BONDS: ENERGY • Metallic bonds are weak and little energy is needed to break the bonds. Therefore, they have high melting points • Because the electrons are mobile, they transfer heat more efficiently and, therefore, are better conductors.
  • 13. CONCLUSION • Elements bond to become stable. • Elements bond to have 8 valence electrons. • 3 types of bonds: Ionic, Covalent, Metallic • In ionic bonds, one element gives its electrons to another element. • Covalent bonds are the strongest bonds. Elements share electrons. • Metallic bonds are the weakest bonds. Elements are in a sea of electrons