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Warm Up:
• Show me the electron transfer
between magnesium and chlorine
• What would the formula be?
• What is the name of this compound?
Covalent Bonding
• Covalent Bond: Valence electrons shared
between two atoms.
• Molecule – a group of covalently bonded
atoms.
– Molecules usually consist of a nonmetal bonded
to a nonmetal or a metalloid bonded to
nonmetal.
• Example: H2
• s-orbital of one hydrogen atom overlaps with the s-
orbital of an other hydrogen atom.
• A dash is used to represent a shared pair of
electrons.
• Example: Cl2
• Single covalent bond – share one pair of electrons
between two atoms.
Drawing Molecules
• We can use electron dot notation to help
show how the atoms in a molecule are held
together.
• These drawings are known as Lewis
structures.
• All atoms seek to fill their outer energy shell,
most follow the Octet rule, where they will
have 8 electrons on their outer level.
– Hydrogen only wants 2, as it’s in the 1s energy
level.
Multiple Covalent Bonds
• Sometimes it is possible to form more than
one covalent bond between two atoms.
• Example: O2
• Double covalent bond – share two pairs of
electrons between the same two atoms.
• Example: N2
• Triple covalent bond – share three pairs of
electrons between the same two atoms.
• Double and triple covalent bonds are
referred to as multiple covalent bonds.
LEWIS STRUCTURES WITH MULTIPLE
COVALENT BONDS
• Example: CH2O
• If all electrons have been used and the
central atom is not stable, then consider a
multiple bond.
• Convert two dots to a dash.
• Example: CO2
Polyatomic Ions
•Group of covalently bonded atoms that has a charge.
(a charged molecule)
•Example: SO4
-2
(sulfate ion)
•These bond ionically with cations
Multiple Covalent Bonds
• Sometimes it is possible to form more than
one covalent bond between two atoms.
• Example: O2
• Double covalent bond – share two pairs of
electrons between the same two atoms.
• Example: N2
• Triple covalent bond – share three pairs of
electrons between the same two atoms.
• Double and triple covalent bonds are
referred to as multiple covalent bonds.
LEWIS STRUCTURES WITH MULTIPLE
COVALENT BONDS
• Example: CH2O
• If all electrons have been used and the
central atom is not stable, then consider a
multiple bond.
• Convert two dots to a dash.
• Example: CO2
Naming Binary Molecular Compounds
• Unlike ionic compounds, molecular compounds
are composed of individual covalently bonded
units, or molecules.
• The old system (prefix system) of naming
molecular compounds is based on the use of
prefixes.
– examples: CCl4 — carbon tetrachloride (tetra- = 4)
CO — carbon monoxide (mon- = 1)
CO2 — carbon dioxide (di- = 2)
Prefixes for Naming Covalent Compounds
Independent Practice
a. Give the name for As2O5.
b. Write the formula for oxygen difluoride.
Polar and Nonpolar Covalent Bonds
• Covalent bonding involves sharing
electrons between atoms.
• Nonpolar covalent bond – equal sharing of
electrons between two atoms.
– Both atoms have same attraction for shared pair.
– Example: H – H
• Polar covalent bond – unequal sharing of
electrons between atoms.
– One atom has greater attraction for shared pair.
(Electronegativity Tug – of – War)
– Example: H – Cl
• This creates partial (δ) charges on each
atom in the bond.
• The atom that has a greater attraction for
shared electrons takes on a partial negative
charge. The atom with a weaker attraction
takes on a partial positive charge.
– How can you determine which atom has greater
attraction for electrons?
– ELECTRONEGATIVITY

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Ch. 7.4 Molecular Geometry

  • 1. Warm Up: • Show me the electron transfer between magnesium and chlorine • What would the formula be? • What is the name of this compound?
  • 2. Covalent Bonding • Covalent Bond: Valence electrons shared between two atoms. • Molecule – a group of covalently bonded atoms. – Molecules usually consist of a nonmetal bonded to a nonmetal or a metalloid bonded to nonmetal.
  • 3. • Example: H2 • s-orbital of one hydrogen atom overlaps with the s- orbital of an other hydrogen atom. • A dash is used to represent a shared pair of electrons. • Example: Cl2 • Single covalent bond – share one pair of electrons between two atoms.
  • 4. Drawing Molecules • We can use electron dot notation to help show how the atoms in a molecule are held together. • These drawings are known as Lewis structures. • All atoms seek to fill their outer energy shell, most follow the Octet rule, where they will have 8 electrons on their outer level. – Hydrogen only wants 2, as it’s in the 1s energy level.
  • 5. Multiple Covalent Bonds • Sometimes it is possible to form more than one covalent bond between two atoms. • Example: O2 • Double covalent bond – share two pairs of electrons between the same two atoms.
  • 6. • Example: N2 • Triple covalent bond – share three pairs of electrons between the same two atoms. • Double and triple covalent bonds are referred to as multiple covalent bonds.
  • 7. LEWIS STRUCTURES WITH MULTIPLE COVALENT BONDS • Example: CH2O • If all electrons have been used and the central atom is not stable, then consider a multiple bond. • Convert two dots to a dash. • Example: CO2
  • 8. Polyatomic Ions •Group of covalently bonded atoms that has a charge. (a charged molecule) •Example: SO4 -2 (sulfate ion) •These bond ionically with cations
  • 9. Multiple Covalent Bonds • Sometimes it is possible to form more than one covalent bond between two atoms. • Example: O2 • Double covalent bond – share two pairs of electrons between the same two atoms.
  • 10. • Example: N2 • Triple covalent bond – share three pairs of electrons between the same two atoms. • Double and triple covalent bonds are referred to as multiple covalent bonds.
  • 11. LEWIS STRUCTURES WITH MULTIPLE COVALENT BONDS • Example: CH2O • If all electrons have been used and the central atom is not stable, then consider a multiple bond. • Convert two dots to a dash. • Example: CO2
  • 12. Naming Binary Molecular Compounds • Unlike ionic compounds, molecular compounds are composed of individual covalently bonded units, or molecules. • The old system (prefix system) of naming molecular compounds is based on the use of prefixes. – examples: CCl4 — carbon tetrachloride (tetra- = 4) CO — carbon monoxide (mon- = 1) CO2 — carbon dioxide (di- = 2)
  • 13. Prefixes for Naming Covalent Compounds
  • 14. Independent Practice a. Give the name for As2O5. b. Write the formula for oxygen difluoride.
  • 15. Polar and Nonpolar Covalent Bonds • Covalent bonding involves sharing electrons between atoms. • Nonpolar covalent bond – equal sharing of electrons between two atoms. – Both atoms have same attraction for shared pair. – Example: H – H
  • 16. • Polar covalent bond – unequal sharing of electrons between atoms. – One atom has greater attraction for shared pair. (Electronegativity Tug – of – War) – Example: H – Cl • This creates partial (δ) charges on each atom in the bond.
  • 17. • The atom that has a greater attraction for shared electrons takes on a partial negative charge. The atom with a weaker attraction takes on a partial positive charge. – How can you determine which atom has greater attraction for electrons? – ELECTRONEGATIVITY