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Cement ProductionCement Production
Source: PCA, 2003
Raw Materials Necessary forRaw Materials Necessary for
Portland Cement ManufacturePortland Cement Manufacture
Must Provide the FollowingMust Provide the Following
CalciumCalcium
SilicaSilica
AluminaAlumina
IronIron
CalciumCalcium IronIron SilicaSilica AluminaAlumina SulfateSulfate
Alkali wasteAlkali waste
AragoniteAragonite
CalciteCalcite
Cement-kilnCement-kiln
dustdust
Cement rockCement rock
ChalkChalk
ClayClay
Fuller’s earthFuller’s earth
LimestoneLimestone
MarbleMarble
MarlMarl
SeashellsSeashells
ShaleShale
SlagSlag
Blast-furnaceBlast-furnace
flue dustflue dust
ClayClay
Iron oreIron ore
Mill scaleMill scale
Ore washingsOre washings
Pyrite cindersPyrite cinders
ShaleShale
Calcium silicateCalcium silicate
Cement rockCement rock
ClayClay
Fly ashFly ash
Fuller’s earthFuller’s earth
LimestoneLimestone
LoessLoess
MarlMarl
Ore washingsOre washings
QuartziteQuartzite
Rice-hull ashRice-hull ash
SandSand
SandstoneSandstone
ShaleShale
SlagSlag
TraprockTraprock
Aluminum-oreAluminum-ore
refuserefuse
BauxiteBauxite
Cement rockCement rock
ClayClay
Copper slagCopper slag
FlyFly ashash
Fuller’s earthFuller’s earth
GranodioriteGranodiorite
LimestoneLimestone
LoessLoess
Ore washingsOre washings
ShaleShale
SlagSlag
StauroliteStaurolite
AnhydriteAnhydrite
CalciumCalcium
sulfatesulfate
GypsumGypsum
Source: PCA, 2003
Traditional Manufacture ofTraditional Manufacture of
Portland CementPortland Cement
1. Stone is first reduced to 125 mm (5 in.)
size, then to 20 mm (3/4 in.), and stored.Source: PCA, 2003
2. Raw materials are ground to powder and blended.
or
2. Raw materials are ground, mixed with water to form slurry,
and blended.
Source: PCA, 2003
3. Burning changes raw mix chemically into cement clinker.
Source: PCA, 2003
Pyro-Pyro-
ProcessingProcessing
Source: PCA, 2003
4. Clinker is ground with gypsum into portland cement and
shipped.
Source: PCA, 2003
ClinkerClinker Gypsum
Source: PCA, 2003
GrindingGrinding
Clinker is ground withClinker is ground with
gypsum (calcium sulfate) togypsum (calcium sulfate) to
produce portland cementproduce portland cement
Fine grinding is necessaryFine grinding is necessary
for high early strengthfor high early strength
– 85-95% -325 mesh (4585-95% -325 mesh (45
microns)microns)
– ~ 7 trillion particles per~ 7 trillion particles per
poundpound
Gypsum absorbs water andGypsum absorbs water and
prevents setting of Cprevents setting of C33AA
during shipmentduring shipment
Source: van Oss and Padovani, 2002
Process of Clinker ProductionProcess of Clinker Production
Source: PCA, 2003
Source: PCA, 2003
Source: PCA, 2003
Source: Taylor, 1997
Source: MacLaren and White, 2003
Source: MacLaren and White, 2003
Clinker PhasesClinker Phases
AliteAlite oror 3CaO•SiO3CaO•SiO22 oror CC33SS
– Hydrates & hardens quicklyHydrates & hardens quickly
– High early strengthHigh early strength
– Higher heat of hydrationHigher heat of hydration
(setting)(setting)
BeliteBelite oror 2CaO• SiO2CaO• SiO22 oror CC22SS
– Hydrates & hardens slowerHydrates & hardens slower
than alitethan alite
– Gives off less heatGives off less heat
– High late strength (> 7 days)High late strength (> 7 days)
Modern cements areModern cements are
manufactured to be higher inmanufactured to be higher in
alite for early strengthalite for early strength
Clinker PhasesClinker Phases
AluminateAluminate oror 3CaO• Al3CaO• Al22OO33 oror
CC33AA
– Very high heat of hydrationVery high heat of hydration
– Some contribution to earlySome contribution to early
strengthstrength
– Low CLow C33A for sulfateA for sulfate
resistanceresistance
FerriteFerrite oror 4CaO4CaO•• AlAl22OO33 •• FeFe22OO33
oror CC44AFAF
– Little contribution to strengthLittle contribution to strength
– Lowers clinkeringLowers clinkering
temperaturetemperature
– Controls the color of cementControls the color of cement
Microscopic Images of ClinkerMicroscopic Images of Clinker
Microscopic Images of ClinkerMicroscopic Images of Clinker
Alite
Microscopic Images of ClinkerMicroscopic Images of Clinker
Belite
Microscopic Images of ClinkerMicroscopic Images of Clinker
Aluminate
Microscopic Images of ClinkerMicroscopic Images of Clinker
Ferrite
Types of Portland CementTypes of Portland Cement
II NormalNormal
IIII Moderate sulfate resistanceModerate sulfate resistance
IIIIII High early strengthHigh early strength
IVIV Low heat of hydrationLow heat of hydration
VV High sulfate resistanceHigh sulfate resistance
ASTM C 150 (AASHTO M 85)
Source: Mindess, Young, and Darwin, 2004
Source: Mindess, Young, and Darwin, 2004
Source: Mindess, Young, and Darwin, 2004
Source: Mindess, Young, and Darwin, 2004

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Cement

  • 3. Raw Materials Necessary forRaw Materials Necessary for Portland Cement ManufacturePortland Cement Manufacture Must Provide the FollowingMust Provide the Following CalciumCalcium SilicaSilica AluminaAlumina IronIron
  • 4. CalciumCalcium IronIron SilicaSilica AluminaAlumina SulfateSulfate Alkali wasteAlkali waste AragoniteAragonite CalciteCalcite Cement-kilnCement-kiln dustdust Cement rockCement rock ChalkChalk ClayClay Fuller’s earthFuller’s earth LimestoneLimestone MarbleMarble MarlMarl SeashellsSeashells ShaleShale SlagSlag Blast-furnaceBlast-furnace flue dustflue dust ClayClay Iron oreIron ore Mill scaleMill scale Ore washingsOre washings Pyrite cindersPyrite cinders ShaleShale Calcium silicateCalcium silicate Cement rockCement rock ClayClay Fly ashFly ash Fuller’s earthFuller’s earth LimestoneLimestone LoessLoess MarlMarl Ore washingsOre washings QuartziteQuartzite Rice-hull ashRice-hull ash SandSand SandstoneSandstone ShaleShale SlagSlag TraprockTraprock Aluminum-oreAluminum-ore refuserefuse BauxiteBauxite Cement rockCement rock ClayClay Copper slagCopper slag FlyFly ashash Fuller’s earthFuller’s earth GranodioriteGranodiorite LimestoneLimestone LoessLoess Ore washingsOre washings ShaleShale SlagSlag StauroliteStaurolite AnhydriteAnhydrite CalciumCalcium sulfatesulfate GypsumGypsum Source: PCA, 2003
  • 5. Traditional Manufacture ofTraditional Manufacture of Portland CementPortland Cement 1. Stone is first reduced to 125 mm (5 in.) size, then to 20 mm (3/4 in.), and stored.Source: PCA, 2003
  • 6.
  • 7. 2. Raw materials are ground to powder and blended. or 2. Raw materials are ground, mixed with water to form slurry, and blended. Source: PCA, 2003
  • 8. 3. Burning changes raw mix chemically into cement clinker. Source: PCA, 2003
  • 10.
  • 12. 4. Clinker is ground with gypsum into portland cement and shipped. Source: PCA, 2003
  • 14. GrindingGrinding Clinker is ground withClinker is ground with gypsum (calcium sulfate) togypsum (calcium sulfate) to produce portland cementproduce portland cement Fine grinding is necessaryFine grinding is necessary for high early strengthfor high early strength – 85-95% -325 mesh (4585-95% -325 mesh (45 microns)microns) – ~ 7 trillion particles per~ 7 trillion particles per poundpound Gypsum absorbs water andGypsum absorbs water and prevents setting of Cprevents setting of C33AA during shipmentduring shipment
  • 15. Source: van Oss and Padovani, 2002
  • 16. Process of Clinker ProductionProcess of Clinker Production Source: PCA, 2003
  • 20. Source: MacLaren and White, 2003
  • 21. Source: MacLaren and White, 2003
  • 22. Clinker PhasesClinker Phases AliteAlite oror 3CaO•SiO3CaO•SiO22 oror CC33SS – Hydrates & hardens quicklyHydrates & hardens quickly – High early strengthHigh early strength – Higher heat of hydrationHigher heat of hydration (setting)(setting) BeliteBelite oror 2CaO• SiO2CaO• SiO22 oror CC22SS – Hydrates & hardens slowerHydrates & hardens slower than alitethan alite – Gives off less heatGives off less heat – High late strength (> 7 days)High late strength (> 7 days) Modern cements areModern cements are manufactured to be higher inmanufactured to be higher in alite for early strengthalite for early strength
  • 23. Clinker PhasesClinker Phases AluminateAluminate oror 3CaO• Al3CaO• Al22OO33 oror CC33AA – Very high heat of hydrationVery high heat of hydration – Some contribution to earlySome contribution to early strengthstrength – Low CLow C33A for sulfateA for sulfate resistanceresistance FerriteFerrite oror 4CaO4CaO•• AlAl22OO33 •• FeFe22OO33 oror CC44AFAF – Little contribution to strengthLittle contribution to strength – Lowers clinkeringLowers clinkering temperaturetemperature – Controls the color of cementControls the color of cement
  • 24. Microscopic Images of ClinkerMicroscopic Images of Clinker
  • 25. Microscopic Images of ClinkerMicroscopic Images of Clinker Alite
  • 26. Microscopic Images of ClinkerMicroscopic Images of Clinker Belite
  • 27. Microscopic Images of ClinkerMicroscopic Images of Clinker Aluminate
  • 28. Microscopic Images of ClinkerMicroscopic Images of Clinker Ferrite
  • 29. Types of Portland CementTypes of Portland Cement II NormalNormal IIII Moderate sulfate resistanceModerate sulfate resistance IIIIII High early strengthHigh early strength IVIV Low heat of hydrationLow heat of hydration VV High sulfate resistanceHigh sulfate resistance ASTM C 150 (AASHTO M 85)
  • 30. Source: Mindess, Young, and Darwin, 2004
  • 31. Source: Mindess, Young, and Darwin, 2004
  • 32. Source: Mindess, Young, and Darwin, 2004
  • 33. Source: Mindess, Young, and Darwin, 2004

Editor's Notes

  1. Fig. 2-5. Aerial view of a cement plant. (70000)
  2. Table 2-1. Sources of Raw Materials Used in Manufacture of Portland Cement Sulfate, often in the form of gypsum, is added during the grinding of the clinker to regulate the setting time of the cement and to improve shrinkage and strength development properties.
  3. Fig. 2-3. Steps in the traditional manufacture of portland cement
  4. Natural Cement Rock Two Benches No Blasting only Ripping 5- 10 hour shifts Haul trucks 2 – 796C cat 1 – 35R Euclid 988 Cat Loaders
  5. Fig. 2-3. Steps in the traditional manufacture of portland cement
  6. Fig. 2-3. Steps in the traditional manufacture of portland cement
  7. Modernized in 1999 by HBZ and Fuller 1500 tpd to 2000 tpd Fuel Consumption decreased by 15% Modern – State of the Art Preheater / Precalciner System with down draft calciner/ & DeSox
  8. Kiln –2,000 stpd 12’ x 165’ 3.1 RPM
  9. Fig. 2-8. Rotary kiln (furnace) for manufacturing portland cement clinker. Inset view inside the kiln. (58927, 25139)
  10. Fig. 2-3. Steps in the traditional manufacture of portland cement
  11. Fig. 2-9. Portland cement clinker is formed by burning calcium and siliceous raw materials in a kiln. This particular clinker is about 20 mm (3¼4 in.) in diameter. (60504) Fig. 2-11. Gypsum, a source of sulfate, is interground with portland clinker to form portland cement. It helps control setting, drying shrinkage properties, and strength development. (60505)
  12. Fig. 2-10. Process of clinker production from raw feed to the final product (Hills 2000).
  13. Fig. 2-10. Process of clinker production from raw feed to the final product (Hills 2000).
  14. Fig. 2-10. Process of clinker production from raw feed to the final product (Hills 2000).