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International Symposium on Global Sustainability
Institute of Sustainable Science



Advanced energy technology for
   sustainable development
         - Analysis of energy for sustainability-
                                     Satoshi Konishi
                              Institute for Sustainability Science,
                     Institute of Advanced Energy, Kyoto University


                                                                                  Aug.12-13, 2011


     Summer School AACIMP-2011
      Kyiv Polytechnic Institute, Ukraine
Fusion Electricity
  Institute of Sustainable Science
                                            International Symposium on Global Sustainability



Energy converted to heat and fuel
                     lithium                   Energy generated by fusion reaction
                                                                    deuterium
   neutron                                                                                     neutron
                 tritium             Fusion reactor
                                                                     tritium

   Fusion fuel                                                                                 Electricity
                                                             Power train

              breeding



      Fuel cycle                            Coolant
6.Fuel production
Why fuels?International Symposium on Global Sustainability
     Institute of Sustainable Science

    Market 3 times larger than electricity
・Carbon-free fuels required                                                                      Automobile
      - Exhausting fossil resources
      - Global warming and CO2 emission
・Future fuel use                                                                                  Aircraft
  - Fuel cells , automobile
                                                                        25
  - aircrafts, ships


                                                  Energy demand(GTOE)
                                                                                  Electricity
                                                                        20        Solid Fuel
・Dispersed electricity system                                                     Liquid Fuel
                                                                                  Gaseous Fuel
   - Cogeneration                                                       15
   - Fuel cell,
   - micro gas turbine                                                  10

                                                                        5
(could be other synthetic fuels)
                                                                             0
                                                                                 2000   2020 2040 2060 2080   2100
                                                                                               Year
 Substitute fewer than electricity source
                                        Example of Outlook of Global Energy Consumption by IPCC92a
Future Energy System    International Symposium on Global Sustainability
     Institute of Sustainable Science

 ・Electricity and Synthetic fuels mutually converted
    - Resources required for raw material and energy
    - Substitution and competition
                                                                                                     Renewables
Raw material           Energy             Conversion
                                                                                            grid

                                        Electrolysis                                   Utility gas
   Water                                                              H2
                       Electricity            Shift               CH 4
  Fossil
                                              Reaction                                transport
  resources                                                      MeOH
                            Heat
                                            Reforming             Syn.                Fuel cell           Indepenent
   Biomass                                                        fuels                                   power
                                                                                      Cogene-
                       Nuclear                                                        ration

                                                          CO2
                                   chemical               sequestration
Fuel Production from biomass
    Institute of Sustainable Science
                                           International Symposium on Global Sustainability


        16MJ
        External Heat,900℃ 8.2MJ
Biomass
   (1kg)                   +    H2O                   H2,CO
                                                                                          endothermic
 cellulose:(C6H10O5)n/6+ n/6H2O → nH2 + nCO – 136n [kJ]
 lignin: (CH1.4O0.3)n + 0.7nH2O → 1.4nH2 + nCO –136n[kJ]                                        24.2MJ


   Shift Reaction CO + H2O ⇔ H2 + CO2 + 32 [kJ]                                               Waste heat
Fischer-Tropsch reaction               hydrogen                              Carbon Neutral
                  2H2 + CO → -CH2- + H2O + 160 [kJ]                                   Waste /usable
                                                                                     8.1MJ
Carbon free OIL alcane                                                              Heat for
(0.5 litter)    15.6MJ                                                              generation
Biomass conversion to fuel
    Institute of Sustainable Science
                                               International Symposium on Global Sustainability



Biomass 1kg                             external heat                               Gas product
                                                                                    H2:0.138kg,69mol
                                         H2O     8.2MJ                              CO:0.38kg,14mol
 Cellulose, lignin
                                                                                    CO2:0.74kg,17mol
                                                                                    CH4:0.009kg,0.56mol
21MJ (CH1-2O0-1)n                      Chemical reactor
       1kg                                                                                1.0MJ
                              Waste 0.40kg                                                        24.2MJ
           53mol                                      loss 4MJ
          H2O:0.76kg,42mol
          CO2:0.13kg、3mol                                                         8.1MJ
                                                              FT synthesis
    0.4MJ CH4:0.009kg,0.56mol                                                    Heat loss or
                                                                                 generation
               diesel(hydrocarbon)                                         Fusion energy used for
                -CH2-:0.39kg,28mol                                         conversion
15.6MJ
                                                                           Energy comes from
   Carbon free oil 0.5 liter                                               waste biomass
Gasification of Cellulose
Institute of Sustainable Science
                                                International Symposium on Global Sustainability


                  >95% carbon was converted to fuel gases
                   (H2, CO and CH4) with Ni catalyst.
                                                                           Thermochemical equilibrium
                  100
                                                                                    CH4
                  80       Co                                                       CO2
  Conversion[%]




                          Ni                                                        CO
                  60
                        No Cat.
                                                                               experiments
                  40
                                                                                   CH4
                  20                                                               CO2
                                                                                   CO
                   0
                        600       700     800      900 1000
                                  Temperature[℃]


                   This conversion efficiency is practical level.
Gasification of Cellulose
  Institute of Sustainable Science
                                     International Symposium on Global Sustainability



Cellulose as a representative of waste biomass
(garbage, paper, wood, straw…)




          Simple experiment can prove this reaction.
Concept of the biomass reactor  International Symposium on Global Sustainability
    Institute of Sustainable Science


                                                                               cellulose             rignin
                                                        Reaction               0.29                  0.41
Assumed biamass:6Mton/year
                                                        heat(kJ)
 (cellulose 70%,lignin 30%)                                                    60                    60
                                                        Reaction
                                                        time(s)
                                       biomass
                                                          steam



Fusion                                                   10m
reactor
Liquid metal
     900℃
                                                           Liquid metal path
                                                 Diameter:~3.5m
Reactor tube:29500            Gas product
                                                                   Biomass/product path path
                    Concept of the reactor
High temperature reactor>900゜C
      Institute of Sustainable Science
                                                International Symposium on Global Sustainability

                                         Loop operated >900 ゜ C
                                         Only in the test vessel




    SiC module




                                                                                ヒーティングコイル

                                                           アルミナ管
                                              IHX heat transfer from LiPb to He


Installed in 900 ゜ C vessel
Use of Fusion Energy
Institute of Sustainable Science
                                       International Symposium on Global Sustainability


Neutron
                                           SynFUEL


                                                 HEAT
                 Fusion Plant

                                                                                     Industries
                Heat               generation

                                                               heat
   Efficient
   generation                                                                       desalination
                                                  Domestic use
Biomass and Fusion
                                             International Symposium on Global Sustainability
     Institute of Sustainable Science

      Biomass converted to fuels by endothermic reaction.
 (C6H10O5)n+ nH2O → 6nH2 + 6nCO – 816n [kJ]
                                        Biomass (waste, urban and agricultural)
                                               (18Mton/year⇔ 2120 t/h
                                                   Current Japanese burnable
                                                   Garbage 60Mton/year)
    Fusion Plant
                                                                 Hydrogen 280 t/h
1GW electricity
 equivalent                                  Reactor

            heat                                    Fuel Cell Vehicle 1.1M/day*
                                                     feeds 17M/year1700**
  Free from Carnot’s
  Efficiency limit.                           steam(640 t/h)* 6kg/day.vehicle
                                                                          ** 460g/year.vehicle

  Fusion energy can be converted to hydrogen, and fuels.
Energy Conversion efficiencyInternational Symposium on Global Sustainability
   Institute of Sustainable Science

                                                              water
                                    Electricity                                             ~30%
 Nuclear heat                       generation                                       hydrogen
                            Thermal cycle                          Electrolysis
                            Loss (40~70%~30C)                      Loss
                                                  water                                     ~50%
  Nuclear heat                            IS process                                  hydrogen


           Biomass                                            Chemical cycle
                           water                              Loss(50%~120C)
           (with enthalpy)
                                         Biomass                                            ~270%
 Nuclear heat                            gasification                                 Hydrogen+CO
     Electricity                      Chemical cycle
~20%                                  Loss(30%~300C)                                 FT oil ~200%
     generation
Biomass conversion power plant
     Institute of Sustainable Science
                                                  International Symposium on Global Sustainability


                                           H2                      CO + H2O ⇔ H2 + CO2
                Hydrogen                 9.0kg/s
                Liquid fuel                          Gas separator                                   CO2:90kg/s
                                                                                                     CH4:1.5kg/s
                                                       Shift reactor
                                                          300℃             water
                                                                           25kg/s
                                                                      biomass
                  Heat exchange                                        63kg/s
                  reactor                                  Preheat                     No thermal cycle
                                                                                       used.
                                                                     water             No waste heat
                                                                     28kg/s            Discarded.
                                                          gas
  Fusion reactor:500MW                                H2        5.3kg/s
                                        residue       CO        39kg/s
Carbon free heat source                 10kg/s        CO2       29kg/s
                                                      CH4       1.5kg/s
Biomass-Fusion Hybrid plant
      Institute of Sustainable Science
                                             International Symposium on Global Sustainability


 5700ton/day
 Kyoto×4
   Biomass                                                                 Electricity
    supply                                                                Thermal energy to reactor
    Landfill cost
                                                                                        300[MW/sec]
   Reactor cost                                            Fusion
  Product fuel                                                             First generation
  price                                                                    FUSION plant can
      Diesel fuel                                                          Supply fuel to the
                                                                           market with
  1620kl/day
Thermal energy flow                                                        competitive price.
                              HER: Heat exchanger reactor
Electrical energy flow
                              SEG: Steam-electric generator                Fuel is used for
     material flow            FTR: Fischer-Tropsche reactor                generators in microgrids.
      money flow              FST: Fuel Storage Tank
Why waste biomass?
                                        International Symposium on Global Sustainability
Institute of Sustainable Science



Large amount of biomass is discarded
 - burnable garbage
 - agricultural byproduct
 - woods
 - (plastics)
                                                  Combustion
                                                    Landfill
External                                                                                    CO2
Energy                     Conversion to                          use
Source                         Fuel                                                         emission

                                                                                           (regarded
                                   Reduction of
                                      fossil                                               as neutral)
                                   consumption
                             replacing fossil reduces
                                   CO2 emission
Case Study Summary  International Symposium on Global Sustainability
   Institute of Sustainable Science



                                      Garbage            Woody                 Agriculture       Forestry
                                                         Biomass
Cost(JPY/L)                           -51.6              -42.66                44.16             50.1
Biomass production(t/year)            7,746,000          267,000               1,195,000         446,000

Diesel Product(kL/year)               2,045,000          114,000               487,000           191,000S

Required energy(MW)                   941                61                    263               101
Fusion energy efficiency              2.90               2.51                  2.47              2.51
Total energy efficiency               0.70               0.64                  0.65              0.63


・fusion energy efficiency=product diesel chemical energy/fusion heat
・total energy efficiency= product diesel chemical energy/consumed energy
National Total
                                             International Symposium on Global Sustainability
  Institute of Sustainable Science

                                       garbage         agriculture           forestry           Woody
                                                                                                waste
Waste total(t/year)                    38,067,000      14,650, 000           2,068, 000         1,497, 000

Diesel production                      8,992, 000      4,819, 000            714, 000           517, 000
(kL/year)
                            Diesel total:15,000,000kL/year
                                     aircrafts        kerosene                diesel


 Oil demand                          5,324,600        (24,382,000)            36,323,000
 (kL/year)
                      Transport demand:42,000,000kL/year
                 ・36% demand can be supplied
                 Replace fossil with carbon free fuel to recuce
                 CO2 emission
Cost of running vehicles International Symposium on Global Sustainability
                       Institute of Sustainable Science
                                   Electricity price(8.2¥/kWh)                                                Based on
                       35          EV
  Running cost[¥/km]


                                                                                                              Kyoto area
                       25
                       15                                 diesel                                          Dielsel milage
                                                                                                          15km/L
                        5
                                                                     Biomass diesel
                       -5
                            0                 10           20           30           40 Electric vehicle
                                               Cost of electricity[¥/kWh] Running distance[km]     200
                                                                                  Battery capacity[kWh]                24
  Biomass diesel cost starting                                                    Battery cost[104¥/kWh]               10
  from-1.8[¥/km]                                                                  Battery livce[104km]                 10

                                                                       ・battery cost 32¥/kWh


・to run vehicles, using electricity to convert biomass to
 diesel could be cheaper than Evs.
Summary of biomass fuel
      Institute of Sustainable Science
                                         International Symposium on Global Sustainability


•    Fuel production from biomass has larger market than
     electricity.
•    Substituting Oil contributes CO2 reduction
•    As renewable, fuel production is more important than
     electricity.
•    Biomass-Fusion Hybrid will give a good chance for
     Hybrid Device smaller than ITER and easier.
•    Advanced fission or renewable electricity can be
     used for biofuel production.
•    Utilizing waste biomass promote material recycle and
     improve green industry.
    Biomass can respond to global environment
    and resource problem in the near future!
Future world with fusion hydrogen


       WASTE          RECYCLE          FUEL    Independent
                                               Electricity

                                 HEAT         Grid electricity
                      HYDROGEN
  TRANSPORT
  FUEL

 VEHICLE                                Fusion Plant
                        Desalination
           AIRCRAFT     Of seawater
Future world with fusion hydrogen

                        Fusion Plant


               Heat
factory                                                   Farming


 electricity
                                             Desalination Plant
                 HYDROGEN

     houses                      Transport
Edo era.
Poor but sustainable with controlled energy supply

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Advanced energy technology for sustainable development. Part 3

  • 1. International Symposium on Global Sustainability Institute of Sustainable Science Advanced energy technology for sustainable development - Analysis of energy for sustainability- Satoshi Konishi Institute for Sustainability Science, Institute of Advanced Energy, Kyoto University Aug.12-13, 2011 Summer School AACIMP-2011 Kyiv Polytechnic Institute, Ukraine
  • 2. Fusion Electricity Institute of Sustainable Science International Symposium on Global Sustainability Energy converted to heat and fuel lithium Energy generated by fusion reaction deuterium neutron neutron tritium Fusion reactor tritium Fusion fuel Electricity Power train breeding Fuel cycle Coolant
  • 4. Why fuels?International Symposium on Global Sustainability Institute of Sustainable Science Market 3 times larger than electricity ・Carbon-free fuels required Automobile - Exhausting fossil resources - Global warming and CO2 emission ・Future fuel use Aircraft - Fuel cells , automobile 25 - aircrafts, ships Energy demand(GTOE) Electricity 20 Solid Fuel ・Dispersed electricity system Liquid Fuel Gaseous Fuel - Cogeneration 15 - Fuel cell, - micro gas turbine 10 5 (could be other synthetic fuels) 0 2000 2020 2040 2060 2080 2100 Year Substitute fewer than electricity source Example of Outlook of Global Energy Consumption by IPCC92a
  • 5. Future Energy System International Symposium on Global Sustainability Institute of Sustainable Science ・Electricity and Synthetic fuels mutually converted - Resources required for raw material and energy - Substitution and competition Renewables Raw material Energy Conversion grid Electrolysis Utility gas Water H2 Electricity Shift CH 4 Fossil Reaction transport resources MeOH Heat Reforming Syn. Fuel cell Indepenent Biomass fuels power Cogene- Nuclear ration CO2 chemical sequestration
  • 6. Fuel Production from biomass Institute of Sustainable Science International Symposium on Global Sustainability 16MJ External Heat,900℃ 8.2MJ Biomass (1kg) + H2O H2,CO endothermic cellulose:(C6H10O5)n/6+ n/6H2O → nH2 + nCO – 136n [kJ] lignin: (CH1.4O0.3)n + 0.7nH2O → 1.4nH2 + nCO –136n[kJ] 24.2MJ Shift Reaction CO + H2O ⇔ H2 + CO2 + 32 [kJ] Waste heat Fischer-Tropsch reaction hydrogen Carbon Neutral 2H2 + CO → -CH2- + H2O + 160 [kJ] Waste /usable 8.1MJ Carbon free OIL alcane Heat for (0.5 litter) 15.6MJ generation
  • 7. Biomass conversion to fuel Institute of Sustainable Science International Symposium on Global Sustainability Biomass 1kg external heat Gas product H2:0.138kg,69mol H2O 8.2MJ CO:0.38kg,14mol Cellulose, lignin CO2:0.74kg,17mol CH4:0.009kg,0.56mol 21MJ (CH1-2O0-1)n Chemical reactor 1kg 1.0MJ Waste 0.40kg 24.2MJ 53mol loss 4MJ H2O:0.76kg,42mol CO2:0.13kg、3mol 8.1MJ FT synthesis 0.4MJ CH4:0.009kg,0.56mol Heat loss or generation diesel(hydrocarbon) Fusion energy used for -CH2-:0.39kg,28mol conversion 15.6MJ Energy comes from Carbon free oil 0.5 liter waste biomass
  • 8. Gasification of Cellulose Institute of Sustainable Science International Symposium on Global Sustainability >95% carbon was converted to fuel gases (H2, CO and CH4) with Ni catalyst. Thermochemical equilibrium 100 CH4 80 Co CO2 Conversion[%] Ni CO 60 No Cat. experiments 40 CH4 20 CO2 CO 0 600 700 800 900 1000 Temperature[℃] This conversion efficiency is practical level.
  • 9. Gasification of Cellulose Institute of Sustainable Science International Symposium on Global Sustainability Cellulose as a representative of waste biomass (garbage, paper, wood, straw…) Simple experiment can prove this reaction.
  • 10. Concept of the biomass reactor International Symposium on Global Sustainability Institute of Sustainable Science cellulose rignin Reaction 0.29 0.41 Assumed biamass:6Mton/year heat(kJ) (cellulose 70%,lignin 30%) 60 60 Reaction time(s) biomass steam Fusion 10m reactor Liquid metal 900℃ Liquid metal path Diameter:~3.5m Reactor tube:29500 Gas product Biomass/product path path Concept of the reactor
  • 11. High temperature reactor>900゜C Institute of Sustainable Science International Symposium on Global Sustainability Loop operated >900 ゜ C Only in the test vessel SiC module ヒーティングコイル アルミナ管 IHX heat transfer from LiPb to He Installed in 900 ゜ C vessel
  • 12. Use of Fusion Energy Institute of Sustainable Science International Symposium on Global Sustainability Neutron SynFUEL HEAT Fusion Plant Industries Heat generation heat Efficient generation desalination Domestic use
  • 13. Biomass and Fusion International Symposium on Global Sustainability Institute of Sustainable Science Biomass converted to fuels by endothermic reaction. (C6H10O5)n+ nH2O → 6nH2 + 6nCO – 816n [kJ] Biomass (waste, urban and agricultural) (18Mton/year⇔ 2120 t/h Current Japanese burnable Garbage 60Mton/year) Fusion Plant Hydrogen 280 t/h 1GW electricity equivalent Reactor heat Fuel Cell Vehicle 1.1M/day* feeds 17M/year1700** Free from Carnot’s Efficiency limit. steam(640 t/h)* 6kg/day.vehicle ** 460g/year.vehicle Fusion energy can be converted to hydrogen, and fuels.
  • 14. Energy Conversion efficiencyInternational Symposium on Global Sustainability Institute of Sustainable Science water Electricity ~30% Nuclear heat generation hydrogen Thermal cycle Electrolysis Loss (40~70%~30C) Loss water ~50% Nuclear heat IS process hydrogen Biomass Chemical cycle water Loss(50%~120C) (with enthalpy) Biomass ~270% Nuclear heat gasification Hydrogen+CO Electricity Chemical cycle ~20% Loss(30%~300C) FT oil ~200% generation
  • 15. Biomass conversion power plant Institute of Sustainable Science International Symposium on Global Sustainability H2 CO + H2O ⇔ H2 + CO2 Hydrogen 9.0kg/s Liquid fuel Gas separator CO2:90kg/s CH4:1.5kg/s Shift reactor 300℃ water 25kg/s biomass Heat exchange 63kg/s reactor Preheat No thermal cycle used. water No waste heat 28kg/s Discarded. gas Fusion reactor:500MW H2 5.3kg/s residue CO 39kg/s Carbon free heat source 10kg/s CO2 29kg/s CH4 1.5kg/s
  • 16. Biomass-Fusion Hybrid plant Institute of Sustainable Science International Symposium on Global Sustainability 5700ton/day Kyoto×4 Biomass Electricity supply Thermal energy to reactor Landfill cost 300[MW/sec] Reactor cost Fusion Product fuel First generation price FUSION plant can Diesel fuel Supply fuel to the market with 1620kl/day Thermal energy flow competitive price. HER: Heat exchanger reactor Electrical energy flow SEG: Steam-electric generator Fuel is used for material flow FTR: Fischer-Tropsche reactor generators in microgrids. money flow FST: Fuel Storage Tank
  • 17. Why waste biomass? International Symposium on Global Sustainability Institute of Sustainable Science Large amount of biomass is discarded - burnable garbage - agricultural byproduct - woods - (plastics) Combustion Landfill External CO2 Energy Conversion to use Source Fuel emission (regarded Reduction of fossil as neutral) consumption replacing fossil reduces CO2 emission
  • 18. Case Study Summary International Symposium on Global Sustainability Institute of Sustainable Science Garbage Woody Agriculture Forestry Biomass Cost(JPY/L) -51.6 -42.66 44.16 50.1 Biomass production(t/year) 7,746,000 267,000 1,195,000 446,000 Diesel Product(kL/year) 2,045,000 114,000 487,000 191,000S Required energy(MW) 941 61 263 101 Fusion energy efficiency 2.90 2.51 2.47 2.51 Total energy efficiency 0.70 0.64 0.65 0.63 ・fusion energy efficiency=product diesel chemical energy/fusion heat ・total energy efficiency= product diesel chemical energy/consumed energy
  • 19. National Total International Symposium on Global Sustainability Institute of Sustainable Science garbage agriculture forestry Woody waste Waste total(t/year) 38,067,000 14,650, 000 2,068, 000 1,497, 000 Diesel production 8,992, 000 4,819, 000 714, 000 517, 000 (kL/year) Diesel total:15,000,000kL/year aircrafts kerosene diesel Oil demand 5,324,600 (24,382,000) 36,323,000 (kL/year) Transport demand:42,000,000kL/year ・36% demand can be supplied Replace fossil with carbon free fuel to recuce CO2 emission
  • 20. Cost of running vehicles International Symposium on Global Sustainability Institute of Sustainable Science Electricity price(8.2¥/kWh) Based on 35 EV Running cost[¥/km] Kyoto area 25 15 diesel Dielsel milage 15km/L 5 Biomass diesel -5 0 10 20 30 40 Electric vehicle Cost of electricity[¥/kWh] Running distance[km] 200 Battery capacity[kWh] 24 Biomass diesel cost starting Battery cost[104¥/kWh] 10 from-1.8[¥/km] Battery livce[104km] 10 ・battery cost 32¥/kWh ・to run vehicles, using electricity to convert biomass to diesel could be cheaper than Evs.
  • 21. Summary of biomass fuel Institute of Sustainable Science International Symposium on Global Sustainability • Fuel production from biomass has larger market than electricity. • Substituting Oil contributes CO2 reduction • As renewable, fuel production is more important than electricity. • Biomass-Fusion Hybrid will give a good chance for Hybrid Device smaller than ITER and easier. • Advanced fission or renewable electricity can be used for biofuel production. • Utilizing waste biomass promote material recycle and improve green industry. Biomass can respond to global environment and resource problem in the near future!
  • 22. Future world with fusion hydrogen WASTE RECYCLE FUEL Independent Electricity HEAT Grid electricity HYDROGEN TRANSPORT FUEL VEHICLE Fusion Plant Desalination AIRCRAFT Of seawater
  • 23. Future world with fusion hydrogen Fusion Plant Heat factory Farming electricity Desalination Plant HYDROGEN houses Transport
  • 24. Edo era. Poor but sustainable with controlled energy supply