The document discusses Carbon Recycling International's process for making renewable fuel by recycling carbon dioxide (CO2) emissions from industrial sources. It involves a patented process to convert CO2 emissions into liquid fuels like renewable methanol using hydrogen and water. Carbon Recycling International has built a pilot plant and plans to have an industrial-scale plant operational in Iceland by 2011. The plant will produce fuel for use in Iceland and for export, helping to reduce greenhouse gas emissions and make use of stranded renewable energy sources.
Presentation given by Dr EJ Anthony from Cranfield University about Direct Air Capture at the UKCCSRC Direct Air Capture/Negative Emissions Workshop held in London on 18 March 2014
Selection of amine solvents for CO2 capture from natural gas power plant - presentation by Jiafei Zhang in the Natural Gas CCS session at the UKCCSRC Cardiff Biannual Meeting, 10-11 September 2014
Episode 3 : Production of Synthesis Gas by Steam Methane ReformingSAJJAD KHUDHUR ABBAS
Episode 3 : Production of Synthesis Gas by Steam Methane Reforming
History of Synthesis Gas
In 1780, Felice Fontana discovered that combustible gas develops if water vapor is passed over carbon at temperatures over 500 °C. This CO and H2 containing gas was called water gas and mainly used for lighting purposes in the19th century.
As of the beginning of the 20th century, H2/CO-mixtures were used for syntheses of hydrocarbons and then, as a consequence, also called synthesis gas.
Haber and Bosch discovered the synthesis of ammonia from H2 and N2 in 1910 and the first industrial ammonia synthesis plant was commissioned in 1913.
The production of liquid hydrocarbons and oxygenates from syngas conversion over iron catalysts was discovered in 1923 by Fischer and Tropsch.
Much of the syngas conversion processes were being developed in Germany during the first and second world wars at a time when natural resources were becoming scare and alternative routes for hydrogen production, ammonia synthesis, and transportation fuels were a necessity.
In 1943/44, this was applied for large-scale production of artificial fuels from synthesis gas in Germany.
Presentation given by Dr EJ Anthony from Cranfield University about Direct Air Capture at the UKCCSRC Direct Air Capture/Negative Emissions Workshop held in London on 18 March 2014
Selection of amine solvents for CO2 capture from natural gas power plant - presentation by Jiafei Zhang in the Natural Gas CCS session at the UKCCSRC Cardiff Biannual Meeting, 10-11 September 2014
Episode 3 : Production of Synthesis Gas by Steam Methane ReformingSAJJAD KHUDHUR ABBAS
Episode 3 : Production of Synthesis Gas by Steam Methane Reforming
History of Synthesis Gas
In 1780, Felice Fontana discovered that combustible gas develops if water vapor is passed over carbon at temperatures over 500 °C. This CO and H2 containing gas was called water gas and mainly used for lighting purposes in the19th century.
As of the beginning of the 20th century, H2/CO-mixtures were used for syntheses of hydrocarbons and then, as a consequence, also called synthesis gas.
Haber and Bosch discovered the synthesis of ammonia from H2 and N2 in 1910 and the first industrial ammonia synthesis plant was commissioned in 1913.
The production of liquid hydrocarbons and oxygenates from syngas conversion over iron catalysts was discovered in 1923 by Fischer and Tropsch.
Much of the syngas conversion processes were being developed in Germany during the first and second world wars at a time when natural resources were becoming scare and alternative routes for hydrogen production, ammonia synthesis, and transportation fuels were a necessity.
In 1943/44, this was applied for large-scale production of artificial fuels from synthesis gas in Germany.
Barry Jones, General Manager - Asia Pacific for the Global CCS Institute, provides an overview of carbon capture and storage technology including its rationale and a summary of current projects. The presentation also examines impediments to its deployment and recommendations for how to overcome them.
Introduction and Theoretical Aspects
Catalyst Reduction and Start-up
Normal Operation and Troubleshooting
Shutdown and Catalyst Discharge
Nickel Carbonyl Hazard
The Global CCS Institute and USEA co-hosted a briefing on the importance of R&D in advancing energy technologies on June 29 2017. This is the presentation given by Ron Munson, Global Lead-Capture at the Global CCS Institute.
Steam Reforming - The Basics of reforming, shapes and carbon:
Steam Reforming Catalysis :
Chemical reactions
Catalyst shape design
Catalyst chemistry
Carbon formation and removal
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2. Hydrogenation
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Hydrogen Plant Flowsheet - Effects of Low Steam RatioGerard B. Hawkins
Effect of Low Steam Ratio on the Steam Reformer
Effect of Low Steam Ratio on H T Shift & PSA
Effect of Low Steam Ratio on Gross Efficiency
Effect of Low Steam Ratio on Net Efficiency
Alternative schemes for improving heat recovery
Barry Jones – Global CCS Institute – Global development and prospect of CCS p...Global CCS Institute
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Barry Jones, General Manager - Asia Pacific for the Global CCS Institute, provides an overview of carbon capture and storage technology including its rationale and a summary of current projects. The presentation also examines impediments to its deployment and recommendations for how to overcome them.
Introduction and Theoretical Aspects
Catalyst Reduction and Start-up
Normal Operation and Troubleshooting
Shutdown and Catalyst Discharge
Nickel Carbonyl Hazard
The Global CCS Institute and USEA co-hosted a briefing on the importance of R&D in advancing energy technologies on June 29 2017. This is the presentation given by Ron Munson, Global Lead-Capture at the Global CCS Institute.
Steam Reforming - The Basics of reforming, shapes and carbon:
Steam Reforming Catalysis :
Chemical reactions
Catalyst shape design
Catalyst chemistry
Carbon formation and removal
1. Introduction reasons for purification, types of poisons, and typical systems
2. Hydrogenation
3. Dechlorination
4. Sulfur Removal
5. Purification system start-up and shut-down
Hydrogen Plant Flowsheet - Effects of Low Steam RatioGerard B. Hawkins
Effect of Low Steam Ratio on the Steam Reformer
Effect of Low Steam Ratio on H T Shift & PSA
Effect of Low Steam Ratio on Gross Efficiency
Effect of Low Steam Ratio on Net Efficiency
Alternative schemes for improving heat recovery
Barry Jones – Global CCS Institute – Global development and prospect of CCS p...Global CCS Institute
Barry Jones, General Manager, Policy and Membership, Global CCS Institute, presented on the global CCS project developments and prospects at the Global CCS Institute's Japanese Members' Meeting held in Tokyo on 8 June 2012.
The NCS delivers carbon accounting and carbon management courses both online and through face to face workshops. The NCS developed Australia's first accredited short course in carbon accounting, and Australia's first Diploma of Carbon Management
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Making Renewable Fuel by Carbon Recycling - KC Tran - Carbon Recycling International - April 2010
1. Making Renewable Fuel by Carbon
Recycling
By: K-C Tran
CEO and Co-founder, Carbon Recycling International
Fulbright US Iceland Partnership Award Recipient
“Emission Reduction, Energy Storage and Sustainability”
2. CO2 as Feedstock
• Greenhouse Gas Emissions
– World temperature rise – ~ 0.6 oC
– CO2 concentration rise – ~180 ppm
– Source of CO2 – primarily from energy production
• Energy Resources
– Fossil Fuel Limits
o Forms 86% of world’s primary energy sources
o R/P ratios in years: Oil (40), Natural Gas (55), Coal (137)
– Infrastructure and Technology Limits
o Off peak and off grid energy capture
o Stranded renewable energy sources: wind, geothermal,
tidal, and biomass
2
3. Sources of Energy
• Response
– Renewable Energy Directives
– Biofuel and green energy targets
– Off peak pricing strategies
• Implementation
– Renewable energy (geothermal, wind, solar etc.)
– Alternative fuels and flexible Fuel vehicles
– Off peak house hold use of energy
• Challenges
– Wind energy penetration in to grid
– Biomass and food production competition
3
4. Innovation Incentives
• Response
– Kyoto Protocol
– EU ETS and UN FCCC – JI and CDM
– UK and California Regulations on Carbon Dioxide
• Implementation
– Flexible fuel, hybrid and electric cars
– Efficiency projects
– CO2 sequestration and Reuse
• Challenges
– Policy disagreements - US, China and India
– Technology uncertainty
Carbon RecyclingInternational 4
5. Making Fuel by Recycling Carbon
Stranded
Energy
CO2
Patented
Liquid Fuels
• Renewable Methanol
Water
Reuse of Carbon Dioxide from Industrial Emissions
as Feedstock for Renewable Fuels
Carbon RecyclingInternational 5
6. Energy in Iceland
Energy Consumption in Iceland by source – in GWe (2006)
Source: statice.is, Ministry of energy
4/14/2010 Carbon RecyclingInternational
Carbon Recycling International 6
7. CO2 in Iceland
Industrial Processes consists of:
• Aluminum (3)
• Ferrosilicon (1)
• Cement (1)
Iceland CO2 emissions by sector, 2007
Carbon Recycling International Carbon RecyclingInternational 7
8. CO2 to Fuel Process
Five building blocks :
1. H2 production
2. CO2 capture and purification
3. Syngas compression
4. Methanol synthesis
5. Methanol distillation
Carbon RecyclingInternational 8
9. A Clean Fuel
Less Fossil Energy In, Less CO2 Out, Same Distance Out
164 g
95 octane gasoline CO2
2.14
1 km
MJ
Vehicles
148 g
CO2
95 octane RM10
1.9 MJ 1 km
Vehicles
Sources:
• Well to Wheel Analysis of future automotive fuels and power trains in the European Context, EC JRC, EUCAR,
CONCAWE (2007)
• CRI – Well to Wheels report (2009)
Carbon RecyclingInternational
10. Corporate History
Proof of Process
Incorporation 2006 Pilot Scale Plant
2007 Emissions To Liquids 1st Generation Patent
Pre-Feasibility studies for large scale plants
Seed financing
Environmental permits
Power Purchase Contract
Enginering Company Partnership
Basic Design 2008
Business model validation
2009
Site permits
Oil of Iceland Fuel Off-take Contract
2010 Grant - Iceland Research Council
Emissions to Liquids 2nd Generation Patent
Private Placement for Industrial Scale Plant
Construction of Industrial Ground Break for Industrial Scale Plant
Scale Plant
Carbon RecyclingInternational 10
11. Scaling Up Milestones
50 M liters
5 M liters
.05 M liters
2010 2013
2007
PSP ISP CSP 1-3
PSP: Pilot Scale Plant ISP: Industrial Scale Plant CSP: Commercial Scale Plant
Carbon RecyclingInternational 11
12. Construction Readiness of ISP Plant
Technical and Economic Feasibility studies
Patents and Applications
Construction Agreement
Feedstock Agreements
Fuel Off Take Agreement
Basic Design
Permits and Licenses
Carbon RecyclingInternational 12
13. Plant On Line – 01/01/2011
CSP-1
ISP
Carbon RecyclingInternational 13
14. Fuel for Iceland
Ex-Works CRI
Carbon RecyclingInternational 14
TD
15. Next Steps
1. Sales
• Operation of Industrial Plant 1/ 2011
• Export to UK and US
2. Opportunities
• Wind energy: US and Canada
• Geothermal: Hawaii, New Zealand,
and the Philippines
2. Growth Strategy
• Feedstock and Fuel Off-take
• Site Permits and Finance
Carbon RecyclingInternational 15
16. At Carbon Recycling International
• Be a Leader in Making Profitable
Renewable Methanol by Recycling
Carbon from Industrial Emissions
• Advance Technology for Cleaning
Carbon Dioxide and Storing Intermittent
Energy
• Employ Highly Skilled Green Work Force
• Work with Long Term Partners for
Technology, Sales and Distribution
Carbon RecyclingInternational 16