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CHAPTER 4
CHEMICAL COMPOSITIONOF
       THE CELL
       4.4 LIPIDS
   Energy rich organic compounds made of :
    1) carbon
    2) hydrogen
    3) oxygen

   The percentage of oxygen in lipids is lower
    than in carbohydrate.

   Some lipids contain nitrogen and phosphorus.

   As lipids are non-polar molecules, they are
    insoluble in water but dissolve readily in other
    lipids and in non-polar solvents such as ether
    and ethanol.
 Fats and oils (triglycerides)
 Waxes
 Phospholipids
 Steroids
 Store large amounts of energy for long
  terms.
 Act as sources of energy.
 Form a major part of the structure of cell
  membranes.
 Act as a metabolic source of water.
 Reduce the lost of water by evaporation.
   Fats are solid at room temperature while oils are
    liquid.
   Fats and oils are triglycerides.
   Triglycerides is formed from a condensation
    reaction between one molecules of glycerol and
    three molecules of fatty acids. The bonds formed
    are called ester bonds. Three molecules of
    water are removed in this reaction.
   Fats often contain only saturated fatty acids
    while oils usually contain unsaturated fatty acids.
Glycerol                    triglycerides
       +         condensation         +
3 molecules of                  3 molecules of
Fatty acids        hydrolysis      water
GLYCEROL
Fatty acid                 fatty acid
    +      condensation

Fatty acid              GLYCEROL          fatty acid
              hydrolysis                     +

Fatty acid                   fatty acid    3H2O
COMPARING AND CONTRASTING SATURATED
    FATS WITH UNSATURATED FATS

                       SIMILARITIES

 Both  are triglycerides.
 They yield 38kJ per gram.
 Their molecules aggregate
  into globules because of
  their hydrophobic
  properties.
DIFFERENCES
SATURATED              TYPES OF FATS        UNSATURATED
   FATS                                         FATS
   absent        PRESENCE OF DOUBLE BONDS     presence
                       IN FATTY ACIDS
   unable          ABILITY TO REACT WITH         able
                   ADDITIONAL HYDROGEN
                           ATOMS
    Solid           CONDITION AT ROOM           Liquid
                      TEMPERATURE
   higher              MELTING POINT            lower
    likely         CAUSE DISEASES OF THE       unlikely
                    HEART AND ARTERIES
   unlikely        BECOME RANCID DUE TO         likely
                        OXIDATION
Butter, animal           EXAMPLES           Olive oil, corn
     fats                                         oil
CREATE BY : ASMIDAR
    MOHD JAMIL
 FARY_LURVIST 101’

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4.4 lipids

  • 1. CHAPTER 4 CHEMICAL COMPOSITIONOF THE CELL 4.4 LIPIDS
  • 2. Energy rich organic compounds made of : 1) carbon 2) hydrogen 3) oxygen  The percentage of oxygen in lipids is lower than in carbohydrate.  Some lipids contain nitrogen and phosphorus.  As lipids are non-polar molecules, they are insoluble in water but dissolve readily in other lipids and in non-polar solvents such as ether and ethanol.
  • 3.  Fats and oils (triglycerides)  Waxes  Phospholipids  Steroids
  • 4.  Store large amounts of energy for long terms.  Act as sources of energy.  Form a major part of the structure of cell membranes.  Act as a metabolic source of water.  Reduce the lost of water by evaporation.
  • 5. Fats are solid at room temperature while oils are liquid.  Fats and oils are triglycerides.  Triglycerides is formed from a condensation reaction between one molecules of glycerol and three molecules of fatty acids. The bonds formed are called ester bonds. Three molecules of water are removed in this reaction.  Fats often contain only saturated fatty acids while oils usually contain unsaturated fatty acids.
  • 6. Glycerol triglycerides + condensation + 3 molecules of 3 molecules of Fatty acids hydrolysis water
  • 7. GLYCEROL Fatty acid fatty acid + condensation Fatty acid GLYCEROL fatty acid hydrolysis + Fatty acid fatty acid 3H2O
  • 8. COMPARING AND CONTRASTING SATURATED FATS WITH UNSATURATED FATS SIMILARITIES  Both are triglycerides.  They yield 38kJ per gram.  Their molecules aggregate into globules because of their hydrophobic properties.
  • 9. DIFFERENCES SATURATED TYPES OF FATS UNSATURATED FATS FATS absent PRESENCE OF DOUBLE BONDS presence IN FATTY ACIDS unable ABILITY TO REACT WITH able ADDITIONAL HYDROGEN ATOMS Solid CONDITION AT ROOM Liquid TEMPERATURE higher MELTING POINT lower likely CAUSE DISEASES OF THE unlikely HEART AND ARTERIES unlikely BECOME RANCID DUE TO likely OXIDATION Butter, animal EXAMPLES Olive oil, corn fats oil
  • 10. CREATE BY : ASMIDAR MOHD JAMIL FARY_LURVIST 101’