Carboxylic acids and amines are named using IUPAC or common systems. Carboxylic acids contain a -COOH functional group and are named by replacing the "-ane" ending with "-oic acid". Amines are derived from NH3 and named by adding "-amine" or treating the nitrogen as the main part. Carboxylic acids have higher boiling points than hydrocarbons and amines have higher boiling points than hydrocarbons of the same size. Amines are generally basic in nature.
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Chemistry of aromatic amines, Classification of amines, Preparation, reactions of amines, synthetic uses of aromatic amines, basicity of aromatic amines and factor affecting basicity amine.
Similar to Tang 03 carboxylic acids & amines 2013 version (20)
3. CARBOXYLIC ACIDS
IUPAC naming system
A carboxylic acid contains a –COOH
functional group (carboxyl). This
group must be included in the main C-
chain that is named as carbon #1.
4. CARBOXYLIC ACIDS
The “e” of –ane, –ene and –yne endings
is replaced with –oic acid.
HCOOH methanoic acid
CH3COOH ethanoic acid
CH3CH2COOH propanoic acid
5. CARBOXYLIC ACIDS
Common naming system
The prefix used with aldehydes may
also be used with carboxylic acids. In
this case an –ic acid is the suffix.
HCOOH formic acid
CH3COOH acetic acid
CH3CH2COOH proprionic acid
6. CARBOXYLIC ACIDS
Example #1
a) What is the structural formula for
propenoic acid? O
OH
b) What is the IUPAC name for the
following acid?
CH2-CH-COOH
CH3 CH3
2-methylbutanoic acid
7. CARBOXYLIC ACIDS
Properties of Carboxylic Acids
Carboxylic acids have higher boiling points
than their corresponding hydrocarbon.
Carboxylic acids have similar solubility
properties as their corresponding alcohol.
All carboxylic acids have acidic properties.
10. AMINES
All amines are essentially derived from NH3.
Depending on the number of carbon side-
chains off of the N, we can form different
types of amines.
primary amine secondary amine tertiary amine
12. AMINES
IUPAC naming system
When there is more than one amine group
present, keep the “e” ending of the C-chain
root.
butane-1,2-diamine
H2N
NH2
hexane-2,3,4-triamine NH2 NH2
NH2
13. AMINES
IUPAC naming system
If there are carbon side-chains off of the N-
group, it is denoted by an “N-” prefix.
N-methylbutan-1-amine H
N
N,N-dimethylmethananime
H3C N CH3
CH3
14. AMINES
IUPAC naming system
The N-group is treated as a side-chain and is
added as a prefix on the C-chain root if a
group with a higher priority is present.
O
NH2
O
OH NH2
OH
3-aminobutan-2-ol 5-amino-3-hydroxy-2-oxohexanal
15. AMINES
Common naming system
This system treats the N as the main part of
the molecule. Everything else is a side-chain
off of the N.
butylamine
H2N
isopropylamine
H2N
17. AMINES
Example #2
Write the IUPAC and the common name
for the following molecule.
CH3 – N – CH3
CH3CHCH3
IUPAC: N,N-dimethylpropan-2-amine
Common: isopropyldimethylamine
18. AMINES
Example #3
Draw a 1°, 2° and 3° amine which each contain a
total of three carbons.
CH3CH2CH2 N H CH3CH2 N H
H CH3
primary secondary
H3C N CH3
CH3
tertiary
19. AMINES
Properties of Amines
Amines have higher boiling points than their
hydrocarbon counterparts.
Smaller amines are more soluble in water than
larger amines.
For mp and bp of amines of the same size,
3° < 2° < 1°
In general, amines are basic in nature.