The document discusses the rules for naming hydrocarbons according to IUPAC nomenclature. It explains that the root or parent chain is the longest chain that can include any double or triple bonds. Side chains are called alkyl groups like methyl or ethyl. Numbers are assigned to the carbons in the parent chain with double or triple bonded carbons numbered first consecutively. The name of each side chain is determined and attached alphabetically to the parent name along with its carbon position. Identical side chains are grouped using prefixes. An example demonstrates applying the rules to name a hydrocarbon with multiple side chains.
I hope You all like it. I hope It is very beneficial for you all. I really thought that you all get enough knowledge from this presentation. This presentation is about materials and their classifications. After you read this presentation you knowledge is not as before.
Hydrocarbon nomenclature
1. Naming Hydrocarbons (nomenclature)
2. Drawing Structures: It’s All Good CH3 C H C H CH3 CH3 CH3 CH3 CH CH CH3 2-butene This is called the “condensed structure” C C C C H H H H H H H H CH3 CH CH CH3 On a test, choose a method that shows all Hs CH3CH=CHCH3 Using brackets can also shorten some formulas: CH3CH2CH2CH2CH2CH3 vs. CH3(CH2)4CH3
3. Basic Naming of Hydrocarbons Hydrocarbon names are based on: 1) type, 2) # of carbons, 3) side chain type and position 1) name will end in -ane, -ene, or -yne 2) the number of carbons is given by a “prefix” 1 meth- 2 eth- 3 prop- 4 but- 5 pent- 6 hex- 7 hept- 8 oct- 9 non- 10 dec- Actually, all end in a, but a is dropped when next to a vowel. E.g. a 6 C alkene is hexene Q - What names would be given to these: 7C, 9C alkane 2C, 4C alkyne 1C, 3C alkene heptane, nonane ethyne, butyne methene, propene
4. Mnemonic for First Four Prefixes First four prefixes • Meth- • Eth- • Prop- • But- Monkeys Eat Peeled Bananas
5. ? Decade Decimal Decathalon Other Prefixes •
I hope You all like it. I hope It is very beneficial for you all. I really thought that you all get enough knowledge from this presentation. This presentation is about materials and their classifications. After you read this presentation you knowledge is not as before.
Hydrocarbon nomenclature
1. Naming Hydrocarbons (nomenclature)
2. Drawing Structures: It’s All Good CH3 C H C H CH3 CH3 CH3 CH3 CH CH CH3 2-butene This is called the “condensed structure” C C C C H H H H H H H H CH3 CH CH CH3 On a test, choose a method that shows all Hs CH3CH=CHCH3 Using brackets can also shorten some formulas: CH3CH2CH2CH2CH2CH3 vs. CH3(CH2)4CH3
3. Basic Naming of Hydrocarbons Hydrocarbon names are based on: 1) type, 2) # of carbons, 3) side chain type and position 1) name will end in -ane, -ene, or -yne 2) the number of carbons is given by a “prefix” 1 meth- 2 eth- 3 prop- 4 but- 5 pent- 6 hex- 7 hept- 8 oct- 9 non- 10 dec- Actually, all end in a, but a is dropped when next to a vowel. E.g. a 6 C alkene is hexene Q - What names would be given to these: 7C, 9C alkane 2C, 4C alkyne 1C, 3C alkene heptane, nonane ethyne, butyne methene, propene
4. Mnemonic for First Four Prefixes First four prefixes • Meth- • Eth- • Prop- • But- Monkeys Eat Peeled Bananas
5. ? Decade Decimal Decathalon Other Prefixes •
Structural diagrams,condensed structures and line structures of hydrocarbons.How to identify a substance as Organic and inorganic ?.How to classify hydrocarbons? What is the difference between alkanes,alkenes and alkynes?
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Alkanes are organic compounds that consist entirely of single-bonded carbon and hydrogen atoms and lack any other functional groups. Alkanes have the general formula CnH2n+2 and can be subdivided into the following three groups: the linear straight-chain alkanes, branched alkanes, and cycloalkanes.
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2. Naming Side Chains CH3
• The names of molecules H C CH3
3
with branches are based
on: side chains, root
CH3
2,3-dimethylpentane
• The “root” or “parent chain” is usually the
longest possible hydrocarbon chain.
• The root must include multiple bonds if they are
present. If a cyclic structure is present it will be
the root even if it is not the longest chain.
• Side chains are also called “side branches” or
“alkyl groups”. Their names end in -yl.
Common side chains :
-CH3 methyl, -CH2CH3 ethyl, -CH2CH2CH3 propyl
3. IUPAC Rules for Naming Hydrocarbons
• Choose the correct ending: -ane, -ene, or -yne
• Determine the longest carbon chain. Where a
double or triple bond is present, choose the
longest chain that includes this bond. If there is a
cyclic structure present, the longest chain starts
and stops within the cyclic structure.
• Assign numbers to each C of the parent chain.
For alkenes and alkynes the first carbon of the
multiple bond should have the smallest number.
For alkanes the first branch (or first point of
difference) should have the lowest #. Carbons in
a multiple bond must be numbered consecutively.
• Attach a prefix that corresponds to the number of
carbons in the parent chain. Add cyclo- to the
prefix if it is a cyclic structure.
4. IUPAC Rules for Naming Hydrocarbons
• Determine the correct name for each branch
(“alkyl” groups include methyl, ethyl, propyl, etc.)
• Attach the name of the branches alphabetically,
along with their carbon position, to the front of the
parent chain name. Separate numbers from
letters with hyphens (e.g. 4-ethyl-2-methyldecane)
• When two or more branches are identical, use
prefixes (di-, tri-, etc.) (e.g. 2,4-dimethylhexane).
Numbers are separated with commas. Prefixes
are ignored when determining alphabetical order.
(e.g. 2,3,5-trimethyl-4-propylheptane)
• When identical groups are on the same carbon,
repeat the number of this carbon in the name.
(e.g. 2,2-dimethylhexane)
5. Naming Side Chains
Example: use the rules on this handout
to name the following structure
CH2 CH2 CH3
CH3 CH2 C CH2 C CH3
CH3
Rule 1: choose the correct ending
ene
6. Naming Side Chains
CH2 CH2 CH3
CH3 CH2 C CH2 C CH3
CH3
Rule 2: determine the longest carbon chain
ene
7. Naming Side Chains
CH2 CH2 CH3
CH3 CH2 C CH2 C CH3
CH3
Rule 3: Assign numbers to each carbon
ene
8. Naming Side Chains
CH2 CH2 CH3
1 5 6
CH3 CH2 C CH2 C CH3
2 3 4
CH3
Rule 3: Assign numbers to each carbon
ene
9. Naming Side Chains
CH2 CH2 CH3
1 5 6
CH3 CH2 C CH2 C CH3
2 3 4
CH3
Rule 4: attach prefix (according to # of Cs)
1-hexene
ene
10. Naming Side Chains
CH2 CH2 CH3
ethyl 1 5 6
CH3 CH2 C CH2 C CH3
2 3 4 methyl
CH3
methyl
Rule 5: Determine name for side chains
1-hexene
11. Naming Side Chains
CH2 CH2 CH3
ethyl 1 5 6
CH3 CH2 C CH2 C CH3
2 3 4 methyl
CH3
methyl
Rule 6: attach name of branches alphabetically
2-ethyl-4-methyl-4-methyl-1-hexene
1-hexene
12. Naming Side Chains
CH2 CH2 CH3
ethyl 1 5 6
CH3 CH2 C CH2 C CH3
2 3 4 methyl
CH3
methyl
Rule 7,8: group similar branches
2-ethyl-4-methyl-4-methyl-1-hexene
1-hexene
13. Naming Side Chains
CH2 CH2 CH3
ethyl 1 5 6
CH3 CH2 C CH2 C CH3
2 3 4 methyl
CH3
methyl
Rule 7,8: group similar branches
2-ethyl-4,4-dimethyl-1-hexene
14. CH3 CH CH2 CH3 CH3
CH3 CH CH C CH3
CH3 CH CH CH3
2,4-dimethyl-2-pentene
CH C CH2 CH3
15. CH3 CH3
CH2 CH C CH2 CH3 CH3 C CH CH2
CH3 CH2 CH3
CH3 CH3
CH3 C C CH CH CH2
CH2 CH3
For more lessons, visit
www.chalkbored.com