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Planetary Model of the Atom:
             Central Nucleus
     with protons & neutrons
           Electrons in orbits
Mathematical Solution to Electron Probability

                           Spherical orbitals
One Electron but
             Multiple electron shells
Ground State: level closest to nucleus
Helium with 2 electrons?

     Both are placed in Shell #1

Maximum # electrons/shell: 2n2
Lithium with 3 electrons
Extra electron goes into next shell
n=1   2e



n=2   8e
Johann Dobereiner 1817

              TRIADS:
              Li, Na, K
1868/9
Both published versions of a periodic table
                           of the elements
Left BLANK SPACES
For undiscovered elements:
           e.g. Germanium
                      1886
Coinage Metals
Chemically inert
            All gases
Progressively heavier
Li   3 electrons    2   + 1 Valence
Be   4 electrons    2 + 2 Valence
B    5 electrons    2 + 3 Valence
C    6 electrons    2 + 4 Valence
N    7 electrons    2 + 5 Valence
O    8 electrons    2 + 6 Valence
F    9 electrons    2 + 7 Valence
Ne   10 electrons   2 + 8 (filled shell)


Na   11 electrons   2 + 8 + 1 Valence
Ionization Energy
Some atoms lose electrons more easily than others

                                   L i Li+ + e-

                                 Cs  Cs+ + e-
Electron Affinity
Some atoms attract electrons more avidly
                            Cl + e-Cl-

                             F + e - F -
Ions = Electrically Charged Atoms

                Na+ + Cl-NaCl
•Always contain balanced +/- charges
                •Lots of possibilities:

                                 Li+Br-
                                  Rb+I-
                                   K+F-
Alkaline Earth atoms &Chalcogens:

                             Be  Be2+ + 2e-

                              •O + 2e-  O2-

                            •Be2+ + O2-BeO




Bromellite
Combinations:

Opposite charges must be balanced:

                Ba2+ + 2 I- BaI2

           2 Rb+ + Se2- --> Rb2Se
Carbon has 4 valence electrons
   It needs to lose or gain 4 electrons
to achieve Ne electron configuration
Electron “sharing”
     Electrons are always paired
Atoms seek to achieve an OCTET
H2O = 2 hydrogen and one Oxygen atom
Carbon = 4 valence electrons
Hydrogen = 1 valence electron
Nitrogen = 5 valence electrons
Hydrogen = 1 valence electron
Shorter and Stronger than single bonds
H2O = 2 hydrogen and one Oxygen atom
Weak bonds
Easily broken but easily reformed
Synthetic compounds
 Good heat transfer agents
Refrigerants; aerosol sprays
Ozone = O3
Absorbs ultraviolet rays
Increase in skin cancer,
             & cataracts
•Coldest place on earth

•Polar vortex traps gases

•Ice crystals enhance

    reaction
Ionic Bonding                  Covalent Bonding
Salts; electrons lost from one Electrons are shared in single
Atom and gained by another (one pair), double (two
atom                           pairs) or triple (three pairs)
                               bonds.
Loosely held electrons
    Good conductors
     Tough materials
Gases              Liquids            Solids

Atoms far apart    Atoms closer       Atoms in set
Non-interactive    Some interaction   arrangement
Fast moving        Occupies a         Atoms vibrate but
No shape           defined volume     do not translate
Formed by liquid   Solids melt        Rigid Shape
evaporation        Gases condense     Strong interaction
                                      Liquid freezes
Diamond                Graphite

High melting point     Lubricating (slippery)
Exceptional hardness
Crystalline            Amorphous
Regular repeating      Lacks a regular 3-D pattern
arrangement of atoms
Silicates (SiO4)   Non-silicates
                                      Naturally occurring
Quartz             pyrite
                                               crystalline
                                               compound
                                           with a known
                                   elemental composition
Inner Core: solid nickel/iron
         Outer Core: liquid
            Mantle: Silicates
            Crust: thin, rigid
Alfred Wegener
                               1880 - 1930

                            Meteorologist

1915 “The Origin of Continents and Oceans”
Evidence:
Mesosaurus fossils
Glossopteris ferns
   “puzzle pieces”
    Glacial debris
Divergent            Convergent                 Lateral Transform
North American and   Nazca and South American   San Andreas fault
Eurasian plates      plates
Logarithmic
              scale

      7.2 quake has
          amplitude
    10x greater than
                  6.2
30x energy released
Krakatoa 1883
Kilauea
Before and after the May 1980 eruption
Alaska 2009
The Year without a Summer
                                   (Lord Byron)
                 ““Darkness”

          “I had a dream, which was not all a dream.
       The bright sun was extinguish'd, and the stars
           Did wander darkling in the eternal space,
              Rayless, and pathless, and the icy earth
    Swung blind and blackening in the moonless air;
Morn came and went--and came, and brought no day”
1783/1784:
Laki, Iceland

Asama, Japan
Shell of gases
circling the Earth
Where all weather
            systems operate
Densest layer, due to gravity
Ozone Layer
  Jet stream
Propagates AM radio signals
           (Longer wavelengths)
Aurora Borealis (Northern Lights)
3 Billion years ago
     initially H2& He

    Nitrogen (N2),
Carbon dioxide(CO2)
     from volcanoes
CO2 + H2O -----> O2 + Glucose
N2 78%


 O2 20.9%


Ar 0.93 %


CO2 0.038%
Volume increases with higher temperature
                  Density decreases with temperature
             HOT AIR RISES and HOLDS MORE H2O
9 g @ 10°C           17 g @ 20°C          30 g @ 30°C
Amount of water vapor increases
            EXPONENTIALLY
             With temperature
Reached by
   1. Excessive evaporation
2. Rapid Temperature drop
Water condenses as Temperature drops

           Night temperatures cooler
Is formed if temperature
            approach the
   freezing point of H2O
            (32°F or 0°C)
Cooler ocean air + warm land

      Usually late afternoon
Warm front
Means rain on the way
Cold front
Tornadoes and Waterspouts
 Wind speeds 60 – 120 mph
Hurricanes & Typhoons
Warm ocean waters
temperatures > 76°F
          > 24.4°C
26 storms
June -> December
1997 – 1998 winter
 Flooding in N. & S. America
Recent drought & fires in Asia
Climate cycles:
Hot House vs. Ice Age

       Average: 15° C
Orbital variation


     Tilt change


       Solar flux
100,000 year cycles
41,000 year cycle


Greater tilt: Interglacial


    Less tilt: Glaciation
26,000 year cycle
25 April 2009
Population Boom

    Viking Travel

England exported
           wine

 Steppe Drought
Grain production

    Ergot Blight

         Plague

     Patagonian
        icefields
Role
 Of
CO2
Svante Arrhenius

                                 Fuel Burning <-> Global Warming

cutting the amount of CO2 in the atmosphere by half could lower the
                             temperature in Europe by some 4-5 oC.
CxHyOz + O2 -> CO2 + H2O
800 K temp

90x atmosphere

      96% CO2
Glacial Melting

     Permafrost thaw

Increased evaporation

     Seasonal change

 Coral reef bleaching
Severe Storms


Coastal Erosion


          Fires
Katrina
   Rita
Wilma
The Universe Around Us

     How does it Work?

    What is it made of?

  How does it affect us?
The Universe Around Us

            How does it Work?

            What is it made of?

          How does it affect us?

How have we affected the world?

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