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THE KINETIC MOLECULAR
THEORY OF SOLIDS AND
LIQUIDS
• THE ARRANGEMENT OF PARTICLES IN SOLID, LIQUIDS,
AND GASES EXPLAINING THE DIFFERENT PROPERTIES.
• THE PARTICLE IN SOLIDS ARE CLOSELY PACKED AND ARE
FREE TO MOVE, AND THEY CAN ONLY VIBRATE.
• SOLID HAS FIXED VOLUME AND SHAPE AND HAVE HIGH
DENSITY
• LIQUID PARTICLES HAVE SUFFICIENT ENERGY TO
OVERCOME THEIR ATTRACTIVE FORCES AND THE
PARTICLES SLIDE AND ROLL ON TOP OF EACH OTHER.
• LIQUIDS FLOW AND HAVE FIXED VOLUME BUT NO FIXED
SHAPE
INTERMOLECUL
AR FORCES
• IS THE FORCE OF ATTRACTION
BETWEEN NEIGHBORING
MOLECULES.
• FORCES OF ATTRACTION-ARE
CAUSED BY THE FORMATION OF
BOND BETWEEN ATOM.
• IONIC BOND- IS FORMED WHEN
THERE IS A TRANSFER OF
ELECTRONS FROM METAL TO A
NON METAL, FORMING OPPOSITE
CHARGE PARTICLES.
• IONIC COMPOUND- EXIST AS
SOLIDS AT ROOMS TEMPERATURE,
AND SO DO METALLIC ATOMS.
• COVALENT BOND- IS FORMED
WHEN THERE IS A SHARING OF
ELECTRONS BETWEEN TWO OR
MORE NON METALS.
DISPERSION FORCES
Are a type of intermolecular force of attraction.
Dispersion forces are present in all molecular substances
These are forces between induced dipoles.
Induced dipole-is created when there is temporary shift of electrons in
an atom or molecule, causing the separation of charges where the end
becomes more positive than the other hand.
DIPOLE-DIPOLE FORCES
• THE DISPERSION OF FORCES FORMED BETWEEN
NEIGHBORING MOLECULES OF PERMANENT
DIPOLES.
• POLAR MOLECULES-MOLECULES WITH
PERMANENT DIPOLES AND HAVE AN UNEVEN
SHARING OF ELECTRONS AND THE
ELECTRONEGATIVITY DIFFERENCE BETWEEN THE
ATOMS IS GREATER THAN 0.4.
• BOILING POINTS OF THE POLAR MOLECULES ARE
HIGHER THAN THOSE OF NONPOLAR BECAUSE
THERE IS ONLY INDUCED DIPOLE OR TEMPORARY
DIPOLES IN NONPOLAR MOLECULES.
ION-DIPOLE
FORCES
• AN ION-DIPOLE
INTERMOLECULAR FORCE
OF ATTRACTION REFERS TO
THE INTERACTION BETWEEN
AN ION AND A POLAR
MOLECULE.
• EX. IONIC COMPOUNDS
DISSOLVED IN POLAR
COMPOUNDS. THE ION-
DIPOLE FORCE INCREASE IN
STRENGTH WHEN THE
CHARGE OF THE ION AND
THE MAGNITUDE OF THE
DIPOLE BECOME GREATER.
HYDROGEN BOND
Is a term used for polar molecules with a
large dipole because OF VERY HIGH
ELECTRONEGATIVITY DIFFERENCE.
THIS IS TRUE FOR MOLECULES CONTAINING
O-H, N-H, AND H-F BONDS.
COMPOUNDS CONTAINING THIS BONDS
HAVE HIGHER BOILING POINTS THAN
MOLECULES WITH DIPOLE-DIPOLE FORCES.
PROPERTIES OF
LIQUIDS AND
INTERMOLECUL
AR FORCES
BASSED ON THE KINETIC MOLECULAR THEORY,
LIQUIDS HAVE THE FOLLOWING GENERAL PHYSICAL
PROPERTIES:
A. PARTICLES SLIDE AND ROLL ON TOP OF ONE
ANOTHER.
B. PARTICLE HAVE LIMITED MOVEMENT AND, HENCE,
THEY FLOW
C. MODERATELY HIGH DENSITY AND DIFFUSABILITY
D. HAVE FIXED VOLUME BUT NO FIXED SHAPE.
SURFACE TENSION
• REFERS TO THE FORCE THAT CAUSES THE MOLECULES ON THE SURFACE
OF A LIQUID TO BE PUSHED TOGETHER AND FORM A LAYER.
• THE SURFACE MOLECULES LOCK INTO A THIN LAYER OF ELASTIC
MEMBRANE BECAUSE THEY ARE ALL ATTRACTED WITH EACH OTHER
AND ARE BEING PULLED BY THE MOLECULES AT THE CENTER.
• SURFACE TENSION EXPLAIN WHY DROP OF LIQUID IS SPHERICAL IN
SHAPE.
• IT ALSO EXPLAINS WHY WATER STRIDER CAN WALK ON THE SURFACE OF
THE WATER
• THE STRONGER THE INTERMOLECULAR FORCE ATTRACTION, THE
GREATER THE SURFACE TENSION, HOWEVER, AN INCREASE IN
TEMPERATURE DECREASE SURFACE TENSION.
VISCOSITY
• IS THE RESISTANCE OF FLUID TO
FLOW.
• A SUBSTANCE THAT FLOWS READILY
HAS LOW VISCOSITY.
• VISCOSITY- IS A MEASURE OF THE
SUBSTANCE’S INTERMOLECULAR
FORCE OF ATTRACTION(IMFA). IF
THE IMFA IS STRONG, THE LIQUID
WILL HAVE HIGH VISCOSITY
BECAUSE IT WILL HAVE A HIGH
RESISTANCE AGAINST FLOWING. THE
GREATER THE IMFA, THE HIGHER
THE VISCOSITY, AND THE LESS
READILY THE LIQUID FLOWS.
• TEMPERATURE ALSO AFFECT
VISCOSITY, THE HIGHER THE
TEMPERATURE, THE LOWER THE
LQUID VISCOSITY.
VAPOR PRESSURE AND BOILING POINT
• THE VAPOR PRESSURE OF A LIQUID
IS THE PRESSURE OF THE VAPOR
RESULTING FROM EVAPORATION
OF ALIQUID ABOVE A SAMPLE OF
THE LIQUID IN A CLOSED
CONTAINER.
• IF A LIQUID HAS WEAK
INTERMOLECULAR FORCES OF
ATTRACTION, THE ESCAPING
TENDENCY OF THE MOLECULES IS
HIGH.

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The kinetic molecular theory of solids and liquids

  • 1. THE KINETIC MOLECULAR THEORY OF SOLIDS AND LIQUIDS
  • 2. • THE ARRANGEMENT OF PARTICLES IN SOLID, LIQUIDS, AND GASES EXPLAINING THE DIFFERENT PROPERTIES. • THE PARTICLE IN SOLIDS ARE CLOSELY PACKED AND ARE FREE TO MOVE, AND THEY CAN ONLY VIBRATE. • SOLID HAS FIXED VOLUME AND SHAPE AND HAVE HIGH DENSITY • LIQUID PARTICLES HAVE SUFFICIENT ENERGY TO OVERCOME THEIR ATTRACTIVE FORCES AND THE PARTICLES SLIDE AND ROLL ON TOP OF EACH OTHER. • LIQUIDS FLOW AND HAVE FIXED VOLUME BUT NO FIXED SHAPE
  • 3. INTERMOLECUL AR FORCES • IS THE FORCE OF ATTRACTION BETWEEN NEIGHBORING MOLECULES. • FORCES OF ATTRACTION-ARE CAUSED BY THE FORMATION OF BOND BETWEEN ATOM. • IONIC BOND- IS FORMED WHEN THERE IS A TRANSFER OF ELECTRONS FROM METAL TO A NON METAL, FORMING OPPOSITE CHARGE PARTICLES. • IONIC COMPOUND- EXIST AS SOLIDS AT ROOMS TEMPERATURE, AND SO DO METALLIC ATOMS. • COVALENT BOND- IS FORMED WHEN THERE IS A SHARING OF ELECTRONS BETWEEN TWO OR MORE NON METALS.
  • 4. DISPERSION FORCES Are a type of intermolecular force of attraction. Dispersion forces are present in all molecular substances These are forces between induced dipoles. Induced dipole-is created when there is temporary shift of electrons in an atom or molecule, causing the separation of charges where the end becomes more positive than the other hand.
  • 5. DIPOLE-DIPOLE FORCES • THE DISPERSION OF FORCES FORMED BETWEEN NEIGHBORING MOLECULES OF PERMANENT DIPOLES. • POLAR MOLECULES-MOLECULES WITH PERMANENT DIPOLES AND HAVE AN UNEVEN SHARING OF ELECTRONS AND THE ELECTRONEGATIVITY DIFFERENCE BETWEEN THE ATOMS IS GREATER THAN 0.4. • BOILING POINTS OF THE POLAR MOLECULES ARE HIGHER THAN THOSE OF NONPOLAR BECAUSE THERE IS ONLY INDUCED DIPOLE OR TEMPORARY DIPOLES IN NONPOLAR MOLECULES.
  • 6. ION-DIPOLE FORCES • AN ION-DIPOLE INTERMOLECULAR FORCE OF ATTRACTION REFERS TO THE INTERACTION BETWEEN AN ION AND A POLAR MOLECULE. • EX. IONIC COMPOUNDS DISSOLVED IN POLAR COMPOUNDS. THE ION- DIPOLE FORCE INCREASE IN STRENGTH WHEN THE CHARGE OF THE ION AND THE MAGNITUDE OF THE DIPOLE BECOME GREATER.
  • 7. HYDROGEN BOND Is a term used for polar molecules with a large dipole because OF VERY HIGH ELECTRONEGATIVITY DIFFERENCE. THIS IS TRUE FOR MOLECULES CONTAINING O-H, N-H, AND H-F BONDS. COMPOUNDS CONTAINING THIS BONDS HAVE HIGHER BOILING POINTS THAN MOLECULES WITH DIPOLE-DIPOLE FORCES.
  • 8. PROPERTIES OF LIQUIDS AND INTERMOLECUL AR FORCES BASSED ON THE KINETIC MOLECULAR THEORY, LIQUIDS HAVE THE FOLLOWING GENERAL PHYSICAL PROPERTIES: A. PARTICLES SLIDE AND ROLL ON TOP OF ONE ANOTHER. B. PARTICLE HAVE LIMITED MOVEMENT AND, HENCE, THEY FLOW C. MODERATELY HIGH DENSITY AND DIFFUSABILITY D. HAVE FIXED VOLUME BUT NO FIXED SHAPE.
  • 9. SURFACE TENSION • REFERS TO THE FORCE THAT CAUSES THE MOLECULES ON THE SURFACE OF A LIQUID TO BE PUSHED TOGETHER AND FORM A LAYER. • THE SURFACE MOLECULES LOCK INTO A THIN LAYER OF ELASTIC MEMBRANE BECAUSE THEY ARE ALL ATTRACTED WITH EACH OTHER AND ARE BEING PULLED BY THE MOLECULES AT THE CENTER. • SURFACE TENSION EXPLAIN WHY DROP OF LIQUID IS SPHERICAL IN SHAPE. • IT ALSO EXPLAINS WHY WATER STRIDER CAN WALK ON THE SURFACE OF THE WATER • THE STRONGER THE INTERMOLECULAR FORCE ATTRACTION, THE GREATER THE SURFACE TENSION, HOWEVER, AN INCREASE IN TEMPERATURE DECREASE SURFACE TENSION.
  • 10. VISCOSITY • IS THE RESISTANCE OF FLUID TO FLOW. • A SUBSTANCE THAT FLOWS READILY HAS LOW VISCOSITY. • VISCOSITY- IS A MEASURE OF THE SUBSTANCE’S INTERMOLECULAR FORCE OF ATTRACTION(IMFA). IF THE IMFA IS STRONG, THE LIQUID WILL HAVE HIGH VISCOSITY BECAUSE IT WILL HAVE A HIGH RESISTANCE AGAINST FLOWING. THE GREATER THE IMFA, THE HIGHER THE VISCOSITY, AND THE LESS READILY THE LIQUID FLOWS. • TEMPERATURE ALSO AFFECT VISCOSITY, THE HIGHER THE TEMPERATURE, THE LOWER THE LQUID VISCOSITY.
  • 11. VAPOR PRESSURE AND BOILING POINT • THE VAPOR PRESSURE OF A LIQUID IS THE PRESSURE OF THE VAPOR RESULTING FROM EVAPORATION OF ALIQUID ABOVE A SAMPLE OF THE LIQUID IN A CLOSED CONTAINER. • IF A LIQUID HAS WEAK INTERMOLECULAR FORCES OF ATTRACTION, THE ESCAPING TENDENCY OF THE MOLECULES IS HIGH.