In this study, Some Monoazo disperse dyes namely, 4-arylazoaminophenols (AAPs) were synthesized via diazotization and coupling reactions and later, polycondensation of these dyes with formaldehyde in the presence of aqueous oxalic acid was carried out. The resulting polymeric dyes namely, (4-arylazoaminophenol-formaldehyde)s (PAAP-F)s as well as their low-molecular weight precursors were characterized by yield, melting point, color, solubility, viscosimetry, Proton Nuclear Magnetic Resonance spectroscopy, UV-visible spectroscopy and Infra red spectroscopy. Their dyeing performance on nylon and polyester were assessed using standard methods. The products were obtained in good yield and had low melting points The dyes were found to be soluble in chloroform and acetone, some were found to dissolve in ethanol and methanol, and generally insoluble in water. The dyeing on nylon and polyester had yellow shades with moderate to good light and wash fastness. Their rubbing fastnesses on nylon and polyester were very good. Polymerizations of the monomeric dyes on dyed nylon and polyester have also been carried out. The dyeing properties of the monomeric and polymeric dyes were compared with the dyes polymerized in situ on nylon and polyester and the fastness properties were found to increase on polymerization and even better with the dyes polymerized inside the fibers
Twelve dyes were synthesized by diazotizing six primary aromatic amines, which were subsequently coupled with H-acid(1-napthol-8-amino-3,6-disulphonic acid).Each of these amines wasalso diazotized and coupled with abenzoylated H-acid.The colours obtained were mainly pink, red and orange. The various dyes synthesized were applied onto a Nylon 6.6. The molecular weights of the dyes, as well as their molar extinction coefficients were calculated and their solubility in water was determined. Their maximum absorption wavelength was measured in water. The fastness properties of the dyes were also investigated. They had good fastness properties. Benzoylated acid dyes give brighter shades and high wet fastness properties on nylon 6.6, due to their high molecular weight. They also have good exhaustion properties.
Twelve dyes were synthesized by diazotizing six primary aromatic amines, which were subsequently coupled with H-acid(1-napthol-8-amino-3,6-disulphonic acid).Each of these amines wasalso diazotized and coupled with abenzoylated H-acid.The colours obtained were mainly pink, red and orange. The various dyes synthesized were applied onto a Nylon 6.6. The molecular weights of the dyes, as well as their molar extinction coefficients were calculated and their solubility in water was determined. Their maximum absorption wavelength was measured in water. The fastness properties of the dyes were also investigated. They had good fastness properties. Benzoylated acid dyes give brighter shades and high wet fastness properties on nylon 6.6, due to their high molecular weight. They also have good exhaustion properties.
Removal of Methylene Blue from Aqueous Solution by Adsorption using Low Cost ...ijsrd.com
The present study deals with removal of methylene blue (basic dye)from aqueous solution using a low cost activated carbon prepared from Delonix regia(gulmohar seed pods).Batch adsorption studies were conducted by varying the contact time adsorbent dosage and pH
Removal of dye from polluted water using novel nano manganese oxide-based mat...Dr. Md. Aminul Islam
Dyes are priority pollutants, commonly found at significant concentrations in textile effluents. The presence of dyes stuffs in wastewater can cause severe problems to aquatic life and human beings. Therefore, the removal of dyes from wastewater is important in order to minimize their hazardous effects on the environment. One way of removing dyes is to use nanosized manganese oxides (MnOs). To date, there has been much work reported on the use of nanosized MnOs as sorbents for dyestuffs. They are promising sorbents for commercial use due to their amorphous nature, high specific surface areas (SSA), mesoporous structure, and low to the moderate point of zero charge (pHPZC). This review summarizes the toxicity and recent advances for removing dyes from wastewater using nanosized MnO sorbents. The article also describes the various experimental parameters necessary for adsorption optimization, such as adsorption time, pH, initial dye concentration, amount of sorbent and temperature. Adsorption mechanisms investigated by various modeling approaches are also discussed. In particular, it was observed that much work has been reported on the use of birnessite and its composites for dye removal. There are many papers reporting on the use of MnO in batch mode dye removal, but very few that report on the use of MnO in continuous column removal systems. Therefore, there is still a considerable need for further research to develop effective and economical large scale MnO column systems for commercial use.
Dyes are colored organic compounds that are used to impart color to various substrates, including paper, leather, fur, hair, drugs, cosmetics, waxes, greases, plastics and textile materials.
whereas pigments are organic and inorganic materials which are practically insoluble in medium in which they are incorporated.
Adsorptive Removal of Methylene Blue Using Groundnut Shell Activated Carbon C...IOSRJAC
In this work, activated carbon prepared from groundnut shells (GSAC) by sulphuric acid treatment was coated with Fe3O4(GSAC- Fe3O4) and tested for its efficiency as an adsorbentfor the removal of methylene blue (MB) dye from aqueous solution. The structural morphology and functional groups present were investigated using scanning electron microscope (SEM) and Fourier transform infrared (FTIR) spectroscopy. Various sorption parameters such as effect of pH, contact time, initial dye concentration and adsorbent dosage were studied. The percentage removal of methylene blue increased with decrease in initial methylene blue concentration and increased with increase in contact time and dose of the adsorbent. Equilibrium data were analysed using Langmuir and Freundlich isotherm models. Kinetic data were studied using pseudo-first order and pseudo-second order kinetic models.
ADSORPTION OF CONGO RED DYE AND METHYLENE BLUE DYE USING ORANGE PEEL AS AN A...Ajay Singh
To reduce the concentration of the dye activated charcoal is used as an adsorbent but due to the high cost of activated charcoal, the purpose of my project was to find an alternative low-cost adsorbent.
Ninhydrin
The synthesis of ninhydrin (originally described as 1,2,3-triketohydrindene, but also referred to as 1,2,3-indanetrione)
First reported by Professor Siegfried Ruhemann, of the University Chemical Laboratories at Cambridge University, England, in 1910.
The marks developed by ninhydrin can vary in colour from reddish purple to deep purple, being influenced by the composition of the mark and the substrate it is deposited on.
Ninhydrin Analogs
An analog is a chemical compound that has a similar structure and similar chemical properties to those of another compound, but differs from it by a single element or a group.
The dual goals of producing such an analog are to produce a compound that has intense, visible colored development (as good as or superior to ninhydrin) as well as a superior room temperature fluorescence.
Natural dyes are dyes or colorants derived from plants, invertebrates, or minerals. The majority of natural dyes are vegetable dyes from plant sources roots, berries, bark, leaves, and wood and other biological sources such as fungi and lichens.Archaeologists have found evidence of textile dyeing dating back to the Neolithic period. In China, dyeing with plants, barks and insects has been traced back more than 5,000 years. The essential process of dyeing changed little over time. Typically, the dye material is put in a pot of water and then the textiles to be dyed are added to the pot, which is heated and stirred until the color is transferred. Textile fibre may be dyed before spinning (dyed in the wool), but most textiles are yarn-dyed or piece dyed after weaving. Many natural dyes require the use of chemicals called mordants to bind the dye to the textile fibres; tannin from oak galls, salt, natural alum, vinegar, and ammonia from stale urine were used by early dyers. Many mordants, and some dyes themselves, produce strong odors, and large-scale dyeworks were often isolated in their own districts. Natural dyes are dyes or colorants derived from plants, invertebrates, or minerals.
MARKET OUTLOOK
The market outlook and growth prospects of the global dyes and pigments market for 2016-2020. The market is further categorized into three product segments, which include dyes, organic pigments and inorganic pigments. The report also segments the market on the basis of type, end-users and geography.
While the global dyes market will grow at a cagr of 3.9% between 2015 and 2020, the global pigments market will register a cagr of 4.05%. Dyes and pigments are used in various end-use applications like dye colorants for textiles, pigmented inks for printing inks, tinting and shading resins of plastics, and as colorants for paints and coatings, and the considerable growth potential of these industries bodes well for the global dyes and pigments market.
See more
https://goo.gl/gGrVe6
https://goo.gl/JQm2aX
Contact us:
Niir Project Consultancy Services
106-E, Kamla Nagar, Opp. Spark Mall,
New Delhi-110007, India.
Email: npcs.ei@gmail.com , info@entrepreneurindia.co
Tel: +91-11-23843955, 23845654, 23845886, 8800733955
Mobile: +91-9811043595
Fax: +91-11-23845886
Website: www.entrepreneurindia.co , www.niir.org
Aimed to investigate the potential of untreated jute stick charcoal as an alternative adsorbent for the treatment of dye containing wastewater. Removal of methylene blue dye from aqueous solution using jute stick charcoal has been investigated. Liquid phase adsorption experiments were conducted. Batch adsorption studies are carried out by observing the effect of experimental parameters, namely, pH, adsorbent dose, contact time and initial methylene blue concentration. The maximum removal of MB dye was 90.57% at pH 9, contact time 120 min, adsorbent dose 3 g/L and 20 mg/L initial dye concentration. Kinetic studies showed that the biosorption of MB followed Pseudo second-order kinetics. The adsorption isotherms are described by the Langmuir and Freundlich isotherms. It was found that the Freundlich equation fit better than the Langmuir equation. The maximum adsorption capacity obtained from Langmuir isotherm equation at was 29.33 mg/g. To conclude, jute stick charcoal holds promise for methylene blue removal from aqueous solution and can be used for other dyes removal and applicable in dyeing industries in Bangladesh where centralized effluent treatment plant is absent.
Pigment is derived from word “pigmentum” means coloring matter.
“Pigments are organic and inorganic materials which are practically insoluble in medium in which they are incorporated
Adsorption of Methylene Blue From Aqueous Solution with Vermicompost Produced...IJMERJOURNAL
ABSTRACT: The removal of Methylene blue as a synthetic dye from aquatic system was investigated by using vermicompost. The dye concentration, contact time and pH of the solution carried out in the adsorption studies. Batch adsorption experimental data were suitable for the Langmuir isotherm and a very good fit to the second order kinetic model (pH=10). The maximum adsorption capacity calculated 256.66 mg g-1 . Vermicompost and the dye loaded vermicompost were characterized by SEM and FTIR. It was found that the vermicompost is stable without losing their activity.
The effect of rotational speed variation on the velocity vectors in the singl...IOSR Journals
The current investigation is aimed to simulate the three-dimensional complex internal flow in a
centrifugal pump impeller with five twisted blades by using a specialized computational fluid dynamics (CFD)
software ANSYS /FLUENT 14code with a standard k-ε two-equation turbulence model.
A single blade passage will be modeled to give more accurate results for velocity vectors on (blade, hub, and
shroud). The potential consequences of velocity vectors associated with operating a centrifugal compressor in
variable rotation speed.
A numerical three-dimensional, through flow calculations to predict velocity vectors through a
centrifugal pump were presented to examined the effect of rotational speed variation on the velocity vectors of
the centrifugal pump . The contours of the velocity vectors of the blade, hub, and shroud indicates low velocity
vectors in the suction side at high rotational speed (over operation limits )and the velocity vectors increases
gradually until reach maximum value at the leading edge (2.63×10 m/s) of the blade
Removal of Methylene Blue from Aqueous Solution by Adsorption using Low Cost ...ijsrd.com
The present study deals with removal of methylene blue (basic dye)from aqueous solution using a low cost activated carbon prepared from Delonix regia(gulmohar seed pods).Batch adsorption studies were conducted by varying the contact time adsorbent dosage and pH
Removal of dye from polluted water using novel nano manganese oxide-based mat...Dr. Md. Aminul Islam
Dyes are priority pollutants, commonly found at significant concentrations in textile effluents. The presence of dyes stuffs in wastewater can cause severe problems to aquatic life and human beings. Therefore, the removal of dyes from wastewater is important in order to minimize their hazardous effects on the environment. One way of removing dyes is to use nanosized manganese oxides (MnOs). To date, there has been much work reported on the use of nanosized MnOs as sorbents for dyestuffs. They are promising sorbents for commercial use due to their amorphous nature, high specific surface areas (SSA), mesoporous structure, and low to the moderate point of zero charge (pHPZC). This review summarizes the toxicity and recent advances for removing dyes from wastewater using nanosized MnO sorbents. The article also describes the various experimental parameters necessary for adsorption optimization, such as adsorption time, pH, initial dye concentration, amount of sorbent and temperature. Adsorption mechanisms investigated by various modeling approaches are also discussed. In particular, it was observed that much work has been reported on the use of birnessite and its composites for dye removal. There are many papers reporting on the use of MnO in batch mode dye removal, but very few that report on the use of MnO in continuous column removal systems. Therefore, there is still a considerable need for further research to develop effective and economical large scale MnO column systems for commercial use.
Dyes are colored organic compounds that are used to impart color to various substrates, including paper, leather, fur, hair, drugs, cosmetics, waxes, greases, plastics and textile materials.
whereas pigments are organic and inorganic materials which are practically insoluble in medium in which they are incorporated.
Adsorptive Removal of Methylene Blue Using Groundnut Shell Activated Carbon C...IOSRJAC
In this work, activated carbon prepared from groundnut shells (GSAC) by sulphuric acid treatment was coated with Fe3O4(GSAC- Fe3O4) and tested for its efficiency as an adsorbentfor the removal of methylene blue (MB) dye from aqueous solution. The structural morphology and functional groups present were investigated using scanning electron microscope (SEM) and Fourier transform infrared (FTIR) spectroscopy. Various sorption parameters such as effect of pH, contact time, initial dye concentration and adsorbent dosage were studied. The percentage removal of methylene blue increased with decrease in initial methylene blue concentration and increased with increase in contact time and dose of the adsorbent. Equilibrium data were analysed using Langmuir and Freundlich isotherm models. Kinetic data were studied using pseudo-first order and pseudo-second order kinetic models.
ADSORPTION OF CONGO RED DYE AND METHYLENE BLUE DYE USING ORANGE PEEL AS AN A...Ajay Singh
To reduce the concentration of the dye activated charcoal is used as an adsorbent but due to the high cost of activated charcoal, the purpose of my project was to find an alternative low-cost adsorbent.
Ninhydrin
The synthesis of ninhydrin (originally described as 1,2,3-triketohydrindene, but also referred to as 1,2,3-indanetrione)
First reported by Professor Siegfried Ruhemann, of the University Chemical Laboratories at Cambridge University, England, in 1910.
The marks developed by ninhydrin can vary in colour from reddish purple to deep purple, being influenced by the composition of the mark and the substrate it is deposited on.
Ninhydrin Analogs
An analog is a chemical compound that has a similar structure and similar chemical properties to those of another compound, but differs from it by a single element or a group.
The dual goals of producing such an analog are to produce a compound that has intense, visible colored development (as good as or superior to ninhydrin) as well as a superior room temperature fluorescence.
Natural dyes are dyes or colorants derived from plants, invertebrates, or minerals. The majority of natural dyes are vegetable dyes from plant sources roots, berries, bark, leaves, and wood and other biological sources such as fungi and lichens.Archaeologists have found evidence of textile dyeing dating back to the Neolithic period. In China, dyeing with plants, barks and insects has been traced back more than 5,000 years. The essential process of dyeing changed little over time. Typically, the dye material is put in a pot of water and then the textiles to be dyed are added to the pot, which is heated and stirred until the color is transferred. Textile fibre may be dyed before spinning (dyed in the wool), but most textiles are yarn-dyed or piece dyed after weaving. Many natural dyes require the use of chemicals called mordants to bind the dye to the textile fibres; tannin from oak galls, salt, natural alum, vinegar, and ammonia from stale urine were used by early dyers. Many mordants, and some dyes themselves, produce strong odors, and large-scale dyeworks were often isolated in their own districts. Natural dyes are dyes or colorants derived from plants, invertebrates, or minerals.
MARKET OUTLOOK
The market outlook and growth prospects of the global dyes and pigments market for 2016-2020. The market is further categorized into three product segments, which include dyes, organic pigments and inorganic pigments. The report also segments the market on the basis of type, end-users and geography.
While the global dyes market will grow at a cagr of 3.9% between 2015 and 2020, the global pigments market will register a cagr of 4.05%. Dyes and pigments are used in various end-use applications like dye colorants for textiles, pigmented inks for printing inks, tinting and shading resins of plastics, and as colorants for paints and coatings, and the considerable growth potential of these industries bodes well for the global dyes and pigments market.
See more
https://goo.gl/gGrVe6
https://goo.gl/JQm2aX
Contact us:
Niir Project Consultancy Services
106-E, Kamla Nagar, Opp. Spark Mall,
New Delhi-110007, India.
Email: npcs.ei@gmail.com , info@entrepreneurindia.co
Tel: +91-11-23843955, 23845654, 23845886, 8800733955
Mobile: +91-9811043595
Fax: +91-11-23845886
Website: www.entrepreneurindia.co , www.niir.org
Aimed to investigate the potential of untreated jute stick charcoal as an alternative adsorbent for the treatment of dye containing wastewater. Removal of methylene blue dye from aqueous solution using jute stick charcoal has been investigated. Liquid phase adsorption experiments were conducted. Batch adsorption studies are carried out by observing the effect of experimental parameters, namely, pH, adsorbent dose, contact time and initial methylene blue concentration. The maximum removal of MB dye was 90.57% at pH 9, contact time 120 min, adsorbent dose 3 g/L and 20 mg/L initial dye concentration. Kinetic studies showed that the biosorption of MB followed Pseudo second-order kinetics. The adsorption isotherms are described by the Langmuir and Freundlich isotherms. It was found that the Freundlich equation fit better than the Langmuir equation. The maximum adsorption capacity obtained from Langmuir isotherm equation at was 29.33 mg/g. To conclude, jute stick charcoal holds promise for methylene blue removal from aqueous solution and can be used for other dyes removal and applicable in dyeing industries in Bangladesh where centralized effluent treatment plant is absent.
Pigment is derived from word “pigmentum” means coloring matter.
“Pigments are organic and inorganic materials which are practically insoluble in medium in which they are incorporated
Adsorption of Methylene Blue From Aqueous Solution with Vermicompost Produced...IJMERJOURNAL
ABSTRACT: The removal of Methylene blue as a synthetic dye from aquatic system was investigated by using vermicompost. The dye concentration, contact time and pH of the solution carried out in the adsorption studies. Batch adsorption experimental data were suitable for the Langmuir isotherm and a very good fit to the second order kinetic model (pH=10). The maximum adsorption capacity calculated 256.66 mg g-1 . Vermicompost and the dye loaded vermicompost were characterized by SEM and FTIR. It was found that the vermicompost is stable without losing their activity.
The effect of rotational speed variation on the velocity vectors in the singl...IOSR Journals
The current investigation is aimed to simulate the three-dimensional complex internal flow in a
centrifugal pump impeller with five twisted blades by using a specialized computational fluid dynamics (CFD)
software ANSYS /FLUENT 14code with a standard k-ε two-equation turbulence model.
A single blade passage will be modeled to give more accurate results for velocity vectors on (blade, hub, and
shroud). The potential consequences of velocity vectors associated with operating a centrifugal compressor in
variable rotation speed.
A numerical three-dimensional, through flow calculations to predict velocity vectors through a
centrifugal pump were presented to examined the effect of rotational speed variation on the velocity vectors of
the centrifugal pump . The contours of the velocity vectors of the blade, hub, and shroud indicates low velocity
vectors in the suction side at high rotational speed (over operation limits )and the velocity vectors increases
gradually until reach maximum value at the leading edge (2.63×10 m/s) of the blade
The Effects of Rauwolfia Vomitoria Extract on the Liver Enzymes of Carbon Tet...IOSR Journals
Rauwolfia vomitoria is a natural medicinal plant which has been used over the years for the treatment of various ailments. The effects of extract of rauwolfia vomitoria on liver enzymes of carbon tetrachloride induced hepatotoxicity were observed in adult wistar rats weighing between 120g and 190g. They were divided into four groups A,B, C and D of six rats each. Group A served as the control and received 0.41ml of distilled water. The experimental groups B, C and D received different doses of drugs as follows : group B received 0.50ml of rauwolfia vomitoria extract, group C received 0.5ml of carbon tetrachloride and group D received 0.41ml of carbon tetrachloride + 0.4ml of rauwolfia vomitoria extract. The drugs were administered once in a day using intubation method for a period of twenty one days. Twenty four hours after the last administration, the animals were anaesthetized under chloroform vapour and dissected . liver tissues were removed and weighed. Blood samples were collected by cardiac puncture and Serum samples were separated from clot by centrifugation using bench top centrifuge. Activities of serum aspartate aminotransferase, alanine aminotransferase and alkaline phosphatase were determined using randox kit method. The relative liver weight for carbon tetrachloride treated group were significantly higher (p<0.001)><0.001) than the control. The extract exhibited a liver protective effect against carbon tetrachloride induced hepatotoxicity
Interfacing of Java 3D objects for Virtual Physics Lab (VPLab) Setup for enco...IOSR Journals
During this paper we target the combination of web accessible physics experiments (VPLabs) combined with the Sun’s toolkit for making cooperative 3D virtual worlds. Among such a cooperative setting these tools give the chance for academics and students to figure along as avatars as they control actual instrumentation, visualize natural phenomenon generated by the experiment, and discuss the results. Especially we'll define the steps of integration, future goals, yet because the price of a collaboration area in Wonderland's virtual world.
Unification Scheme in Double Radio Sources: Bend Angle versus Arm Length Rati...IOSR Journals
From radio source unification scheme, asymmetries are more pronounced in quasars than in radio galaxies. Using a sample of 625 double radio sources (316 radio galaxies and 309 quasars), we investigated the variations between bend angle, arm-length ratio and redshift. We find no significant correlation (0.045) between bend angle and redshift for the entire sample and at low z for radio galaxies while a weak correlation (0.121) between bend angle and redshift for quasars for the entire sampleis observed. A weak correlation (radio galaxies, r = 0.173 and quasars, r = 0.102) between the bend angle and arm-length ratio for the double radio sources used in this study is observed. Kharbet al. (2008) in their study of powerful classical double radio galaxies noted that this correlation could suggest that the environmental asymmetries that give rise to the arm-length ratio could be contributory to the misalignment angles in these sources. Quasars appear much more bent and misaligned. This is consistent with quasars being radio galaxies viewed at small angles.
Documentaries use for the design of learning activitiesIOSR Journals
Abstract: Documentaries used in the training field constitute the rich sources of information. They have the
advantage to associate the elements of knowledge with events which request the episodic memory of the
learner.Thus, these documentaries increase the probability of retention of knowledge they convey. However, the
logical sequence of knowledge does not guarantee an efficient construction which can be mobilized in situations
of action. In this paper, we seek how to benefit from the potential of these documentaries to promote the
construction and mobilization of knowledge by the learner in an elearning platform. Particularly, we propose a
method allowing segmenting the contents of a documentary to design learning activities. Based on a case study
related to the field of mechatronics, we begin by segmenting the content of a documentary in terms of elements
of knowledge (facts, concepts, procedures, and rules) then we connect with each of these problems they seek to
find answers. We reorganize learning activities to promote the acquisition and mobilization of knowledge by the
learner. We conclude by proposing a pedagogical scenario to implement these activities in elearning platform.
Keywords: LMS, IMS-LD, Documentary, Design, Elearning
Stress Analysis of Automotive Chassis with Various ThicknessesIOSR Journals
Abstract : This paper presents, stress analysis of a ladder type low loader truck chassis structure consisting of
C-beams design for application of 7.5 tonne was performed by using FEM. The commercial finite element
package CATIA version 5 was used for the solution of the problem. To reduce the expenses of the chassis of the
trucks, the chassis structure design should be changed or the thickness should be decreased. Also determination
of the stresses of a truck chassis before manufacturing is important due to the design improvement. In order to
achieve a reduction in the magnitude of stress at critical point of the chassis frame, side member thickness,
cross member thickness and position of cross member from rear end were varied. Numerical results showed that
if the thickness change is not possible, changing the position of cross member may be a good alternative.
Computed results are then compared to analytical calculation, where it is found that the maximum deflection
agrees well with theoretical approximation but varies on the magnitude aspect.
Keywords - Stress analysis, fatigue life prediction and finite element method etc.
Analysis of Transport Properties and Acoustical Parameters of Sulphanilamide ...IOSR Journals
Sulphanilamide is the parent compound of all the sulpha-durgs which is important in urinary tract infections and meningococcal meningitis profilaxes. Ultrasonic velocity measurements are highly sensitive to molecular interactions and used to provide qualitative informations about the physical nature and strength of the molecular ∕inter-ionic interactions. In the present work, non-aqueous solutions of Sulphanilamide have been prepared with different concentrations and the experiments were carried out from a low temperature of 50c to a high temperature of 550c. The ultrasonic velocity data combined with density and viscosity provides the standard means for determining the internal pressure, free volume and acoustical parameters. The various interactions occurring in the solutions are interpreted interms of ion-ion and ion-solvent interactions. An attempt is made to identify the entry of solvate into the samples and the entry of drug molecules into the solvate which supports to identify the molecular structure.
Analysis of Interfacial Microsstructure of Post Weld Heat Treated Dissimilar ...IOSR Journals
In Prototype Fast Breeder Reactor (PFBR), the main vessel which contains the primary sodium and supports the
core is suspended from the roof slab. The materials for construction for main vessel and roof slab are type 316LN austenitic
stainless steel and Carbon steel of grade A48P2, respectively. As the materials of construction are different, a transition joint
between austenitic stainless steel and C-steel is necessary. In this investigation the effect of post-weld heat treatment (PWHT) on the interfacial microstructure of as-welded and PWHTed type 316LN/C-steel joint welded with Inconel 182 was investigated. These joints were PWHTed to various temperatures between 898 to 973K for 1h and results were evaluated. From the above results, different methods to temper the martensitic structure or to change to an equilibrium structure without PWHT are also presented.
Synthesis, Characterization and Dyeing Performance of Novel Bisazo Bisazometh...ijtsrd
Azo dyes and pigment forms the largest group of all the synthetic colorants and play a prominent role in almost every type of applications. In the last couple of decades a number of major changes have occurred primarily aimed at minimizing the major weakness of anthraquinone dyes. For this purpose attempts were made to replace anthraquinone dyes by azo dyes. For this purpose we have undertaken the work in this direction with a view to synthesize novel bisazo bisazomethine disperse dyes. Therefore, it is worthwhile to describe the chemistry and development of azo and bisazo dyes in brief for the sake of better understanding. Bisazo and bisazomethine dyes are of current important, however there are very few reports regarding bisazo bisazomethine disperse dye. In the textile industry, different fibers used for dyeing are all natural fiber like cellulose linen, cotton or animal protein fibers wool, silk, animal hair and synthetic fibers like nylon, polyester, polyacrylonitrile and blends of two or more fibers. The development of a new substrate presents new dyes and dyeing methods and it influence dyeing technology in a fundamental manner. New bisazo bisazomethine disperse dyes were prepared by the coupling of diazotized solutions of various aromatic primary amines with 2, 2’ {1,4 phenylenebis nitrilomethylylidene } diphenol Schiff base . Schiff base was prepared by the condensation of 2 hydroxybenzaldehyde with 4 aminoaniline. The resultant dyes were characterized by elemental analysis, IR and 1H NMR Spectral Studies. The UV visible absorption spectral data were investigated in dimethylformamide DMF and are discussed in terms of structure property relationship. The dyes when applied on polyester fabric, gave pale yellow to orange shades having fairly good to good light fastness, very good to excellent washing, perspiration and sublimation fastness and good to very good rubbing fastness properties. D M Patel | Rakshit G Patel "Synthesis, Characterization and Dyeing Performance of Novel Bisazo-Bisazomethine Disperse Dyes on Polyester Fabric" Published in International Journal of Trend in Scientific Research and Development (ijtsrd), ISSN: 2456-6470, Volume-6 | Issue-4 , June 2022, URL: https://www.ijtsrd.com/papers/ijtsrd50248.pdf Paper URL: https://www.ijtsrd.com/chemistry/other/50248/synthesis-characterization-and-dyeing-performance-of-novel-bisazobisazomethine-disperse-dyes-on-polyester-fabric/d-m-patel
Synthesis And Characterization of Novel Processable Poly (EtherAzomethine)S C...inventionjournals
The novel dialdehyde 1,1-bis[4-(4-benzaldehyde oxy) phenyl] cyclopentane (III) (BBPC) was synthesized starting from cyclopentanone and phenol to give 1, 1-Bis (4-hydroxy phenyl) cyclopentane (II); followed by reaction with p- fluorobenzaldehyde in N, N-dimethyl formamide (DMAc), containing anhydrous potassium carbonate. New series of poly (ether – azomethine)s were synthesized from (BBPC) with different diamines such as 4, 4’- diamino diphenyl ether (ODA),4,4’-diaminodiphenyl methane(MDA),4-aminophenyl sulfone(SDA), p-phenylene diamines, etc. in DMAc with 5 wt% LiCl by solution polycondensation technique. Inherent viscosities of these polymers were in the range 0.19 to 0.42 dL/g indicating formation of moderate molecular weights. These polymers exhibited good solubility in various polar aprotic solvents such as Nmethylpyrrolidone (NMP), N, N-dimethylacetamide (DMAc) and N,N-dimethyl formamide (DMF), etc. X-Ray diffraction pattern of polymers showed that introduction of cardo cyclopentylidene moiety containing ether linkage would disrupt the chain regularity and packing, leading to amorphous nature. Thermal analysis by TGA showed excellent thermal stability of polymers. The structure- property correlation among these polyazomethines were studied; in view of their potential applications as high performance polymers.
Synthesis and Application of Azo Disperse Reactive Dyes derived from p-Aminob...IJERA Editor
Disperse reactive dyes were synthesized by diazotizing p-aminobenzaldehyde and coupling with different substituted pyridones and 2-naphthol. The dyeing performance of the dyes was assessed on polyester, nylon, cotton and wool fabrics. The dyes obtained gave various shades of yellow with good depth, brightness and leveling properties on the fabrics. The dyed fabric showed fairly good to very good light fastness and very good to excellent fastness to washing, hot pressing and rubbing. The dyebath exhaustion on the polyester, nylon, wool and cotton fabrics was found to be very good and fixation on wool was better than on cotton fabric.
Synthesis, Structure Investigation and Dyeing Assessment of Novel Bisazo Disp...IOSR Journals
Novel bisazo-disperse dyes were prepared by the coupling of diazotized solutions of various aromatic diamines with 2,4-dihydroxybenzophenone. The resultant bisazo disperse dyes were characterized by elemental analysis, IR and 1H NMR spectral studies. The UV Visible absorption spectral data were investigated in dimethylformamide. and are discussed in terms of structural property relationship. Their dyeing assessment of bisazo disperse dyes has been made on polyester fabrics. The results show that a better hue was obtained on polyester fabrics and have mild to moderate fastness properties.
Potential of Neem Leaf Powder as Bio Adsorbents for Dye Colour Removalijtsrd
In this study, two types of eco friendly and low cost bio adsorbents, Neem leaf powder NLP and acid treated Neem leaf powder TNLP were prepared for the removal of dye color from Congo red solution. The physicochemical parameters of the prepared absorbents were measured. The structural features of these absorbents were analyzed by FTIR, XRD, and SEM. These experiments were conducted with different process parameters such as adsorbent dosage and agitating time using batch adsorption method. Firstly, the dosage amount of adsorbents was optimized for constant shaking for one hour and it was observed that the maximum percent adsorption was found at 91 of 0.4 g for NLP and 76 of 0.4 g for TNLP. The optimum dosage amount of adsorbents, 0.4 g was selected for further study. After optimizing the adsorbent dosage, the optimum agitating time was observed at 60 min with the percent removal of 91 for NLP and 76 for TNLP. From this research, it was observed that NLP and TNLP can be used as bio adsorbents to remove the color of the dye solution. Thet Thet Wai | Ei Mon Aung | Nyein Chan Kyaw "Potential of Neem Leaf Powder as Bio-Adsorbents for Dye Colour Removal" Published in International Journal of Trend in Scientific Research and Development (ijtsrd), ISSN: 2456-6470, Volume-3 | Issue-5 , August 2019, URL: https://www.ijtsrd.com/papers/ijtsrd27987.pdfPaper URL: https://www.ijtsrd.com/engineering/chemical-engineering/27987/potential-of-neem-leaf-powder-as-bio-adsorbents-for-dye-colour-removal/thet-thet-wai
Chemo bio synthesis of silver nanoparticlesJagpreet Singh
Silver nanoparticles have a lot of ways of synthesis like physical and chemical
methods; some of these methods use a lot of chemical substances and are
very hazardous for humans and environment, so a novel, great, environmental
friendly, cheap and easy to use world of green chemistry has been used. A
number of characterization techniques such as UV-visible spectroscopy, Fourier
transformation infrared spectroscopy, X-ray diffraction study and scanning
electron microscopy revealed that silver nanoparticles have been used. Thus
the different response of the functional groups and the difference in the peaks
and UV-visible data was studied and then compared to understand and know
the way these different reducing agents react to the same starting material. The
green synthesis had a UV-visible peak at 446 nm while the one with chemical
synthesis had a peak at 395 nm. FTIR results of silver nanoparticles synthesis
by trisodium citrate (TSC) showed a peak at 1505 cm-1 which shows that the
compound has a stretching of the -C=C – bond. In another case, which was done
by using Sodium borohydride (NaBH4) a peak at 1695 cm-1 showed a –C=O- bond
indicating stretching and a weak absorption intensity. Another peak was present
which indicates a –O-H bond formation and presence which is a strong bond are
found to exist. A notable peak came for synthesis by orange peel at 1517 cm-1
which represents a –C=C- bond stretching as in aromatic compounds. Another
peak at 1732 cm-1 indicates the –C=O- bond. The XRD results on one of the
silver sample prepared by green methods showed silver nanomaterials formed
which had a average particle size of around 42 nm. FE-SEM results revealed that
silver nanomaterials were formed and had a flake like appearance in one of the
results. All the overall comparison showed that different modes of synthesis
of silver nanomaterials and different reducing agents give same materials but
with different peaks and intensities. All this data provided knowledge about the
fact that an alternative method can be used to create new nanoparticles if one
of the previously considered to tried method fails thus helping in extending the
broadways for research.
Synthesis and Application of Direct Dyes Derived From Terephthalic and Isopht...IOSR Journals
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were used as the source of diazo components. The amide derivatives were characterized by Gas
Chromatography/Mass Spectrometry and Infra-red analysis. The spectroscopic properties of the dyes in various
solvents were also examined and most of the dyes showed bathochromic shifts when the solvent was changed to
more polar solvents. The dyes also showed positive and negative halochromism with the addition of few drops of
hydrochloric acid (HCl). The synthesized dyes were applied to cotton fabrics and their performance properties
evaluated. They have good exhaustion in the presence of electrolyte and have good wash fastness properties
upon application of after-treating agents of values of 3-4, 4 and 4-5. They also had good fastness properties to
light of values between 4-7. Their resistance to rubbing and perspiration had values between 3 and 4-5. The
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miceand they were found to be non-toxic.
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Synthesis, Characterization and Electrical Properties of Polyaniline Doped wi...IJERA Editor
The polyaniline were prepared by using different inorganic and organic acids via oxidative polymerization
method. The prepared samples were characterized by FTIR, the peaks are found to be at 507 cm˗1, 592 cm˗1, 798
cm˗1, 1138 cm˗1, 1244 cm˗1, 1302 cm˗1, 1471 cm˗1 and 1556 cm˗1. These predominant peaks may be
confirming the formation of polyaniline. The structural analysis was studied by employing XRD; found that
polyaniline is amorphous in nature. The SEM studies reveal that they are agglomerated, irregular and size of
these grain increases with increasing amount of polyaniline with different organic and inorganic acids. The dc
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1600C. At higher temperature it is found that conductivity increases because of hopping of polarons from one
localized states to another localized states. The ac conductivity of polyaniline was prepared by oxalic acid show
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formulas [M(L)(NA)2Cl] ,where M =
Fe(II),Co(II),Ni(II),Cu(II),and Zn(II) and NA=nicotinamide.
The 1H-NMR, FT-IR, UV-Vis and elemental analysis
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were structurally studied through AAS, FT-IR, UV-Vis,
chloride contents, conductance, and magnetic susceptibility
measurements. All complexes are non-electrolytes in DMSO
solution. Octahedral geometries have been suggested for each
of the complexes. The Schiff base ligands function as
tridentates and the deprotonated enolic form is preferred for
coordination. In order to evaluate the effect of the bactericidal
activity, these synthesized complexes, in comparison to the un
complexed Schiff base has been screened against bacterial
species, Staphy
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Synthesis of new chelating ion exchange resins derived from guaran and diviny...IOSR Journals
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Synthesis, Characterization and Application of Some Polymeric Dyes Derived From Monoazo Disperse Dyes
1. IOSR Journal of Applied Chemistry (IOSR-JAC)
e-ISSN: 2278-5736.Volume 5, Issue 3 (Sep. – Oct. 2013), PP 42-47
www.iosrjournals.org
www.iosrjournals.org 42 | Page
Synthesis, Characterization and Application of Some Polymeric
Dyes Derived From Monoazo Disperse Dyes
S. Habibu1
, S. M. Gumel1
, M. B. Ibrahim1
, M. Ladan1
and I. I. Fagge2
1
Department of Pure and Industrial Chemistry, Bayero University, P.M.B 3011 Kano, Nigeria
2
Department of Chemistry, Kano University of Science and Technology, Wudil P.M.B. 3244 Kano, Nigeria
Abstract: In this study, Some Monoazo disperse dyes namely, 4-arylazoaminophenols (AAPs) were synthesized
via diazotization and coupling reactions and later, polycondensation of these dyes with formaldehyde in the
presence of aqueous oxalic acid was carried out. The resulting polymeric dyes namely, (4-arylazoaminophenol-
formaldehyde)s (PAAP-F)s as well as their low-molecular weight precursors were characterized by yield,
melting point, color, solubility, viscosimetry, Proton Nuclear Magnetic Resonance spectroscopy, UV-visible
spectroscopy and Infra red spectroscopy. Their dyeing performance on nylon and polyester were assessed using
standard methods. The products were obtained in good yield and had low melting points The dyes were found to
be soluble in chloroform and acetone, some were found to dissolve in ethanol and methanol, and generally
insoluble in water. The dyeing on nylon and polyester had yellow shades with moderate to good light and wash
fastness. Their rubbing fastnesses on nylon and polyester were very good. Polymerizations of the monomeric
dyes on dyed nylon and polyester have also been carried out. The dyeing properties of the monomeric and
polymeric dyes were compared with the dyes polymerized in situ on nylon and polyester and the fastness
properties were found to increase on polymerization and even better with the dyes polymerized inside the fibers.
Key words: Color fastness, Disperse dye, Nylon, Polymeric dye, Polyester.
I. Introduction
From prehistoric times people have been fascinated by the colors of nature, and have attempted to
duplicate these in their artifacts, usually for aesthetic, religious or purely functional purposes. For thousands of
years they could achieve the desired effects only by isolating naturally occurring colorants, such as certain
minerals, or the pigments to be found in plants and animal species [1].The modern era of Color Chemistry began
in 1856 when William Henry Perkins synthesized the first “coal tar” dye which he called mauve. Since that time
many thousands of colorants have been synthesized to color everything from textiles to food. A number of
classes of dyestuffs and pigments have been synthesized over the years to address the particular needs of various
applications [2]. Today a new class of materials, polymeric colorants, has gained recognition and applicability
as an alternative to the classical methods of coloration using dyes and pigments. The marriage of polymer and
dye chemistries enables the chemist to design unique materials that exploit the best characteristics of both dyes
and pigments. The motivation for the development of this existing new class of materials is performance.
Polymeric dyes (colorants) are chromophores that have polymeric chains attached to them [3].
II. Materials and Methods
2.1 Reagents
All the reagents used in this research were of laboratory grade obtained from Sigma-Aldrich and used
as received. The formaldehyde was used as 37% aqueous solution of technical grade.
2.2 Instruments
The melting points were determined using Gallenkamp electro-thermal melting point apparatus,
intrinsic viscosities were measured in acetone using Ostwald viscometer. Absorbance was taken using Shimadzu
1601 Spectrophotometer in the region 200-800nm.1
H-NMR spectra were recorded on Jeol JNM-LA400 FT-
NMR system.
2.3 Synthesis of Diazonium Salt Solutions
The diazo components were diazotized using similar procedure adopted by [4]. Using a 400ml beaker,
0.06 mole of each diazo component was dispersed in 20ml of distilled water which stands in an ice-bath. To this
was added 10ml of concentrated HCl over a period of two minutes while the dispersion was stirred with
magnetic stirrer. The temperature of the ice-bath was maintained at between 0-50
C by addition of common salt
(NaCl). 4.3g (0.06 mol.) of sodium nitrite was dissolved in 20ml distilled water in a 50ml beaker. The resulting
solution was added drop-wise to the stirred suspension over a period of one hour to attain complete
diazotization.
2. Synthesis, Characterization And Application Of Some Polymeric Dyes Derived From Monoaz
www.iosrjournals.org 43 | Page
2.4 Azo Coupling of Diazonium salts
0.06 moles of each coupling component was suspended in 20ml distilled water contained in a 250ml
beaker at 0-50
C in an ice-bath. Solution of the diazonium salt was added drop-wise to the coupling component
over a period of 10 minutes with gentle but continuous stirring. The stirring was continued for further 45
minutes as the dye crystals precipitated. The precipitated dyes were filtered and washed with water and then
recrystallized.
2.5 Polycondensation of Monomeric Dyes with Formaldehyde
0.05 moles of each monomeric dye was suspended in 50ml distilled water and then 0.5ml of 37% w/v
formaldehyde solution and 0.5g oxalic acid were added. The reaction mixture was gradually heated to 90-950
C
and maintained at that temperature for 1hour. The reaction mixture was cooled, filtered and washed with water
till the filtrate was neutral. Finally, it was washed with 20ml methanol and air-dried [5].
2.6 Dyeing of Nylon and Polyester
High temperature dyeing was carried out using a similar method reported by [5].
2.7Polycondensation of Monomeric Dyes on Dyed Nylon and Polyester
After dyeing, the dyed fabrics were rinsed with water, squeezed and introduced into 100ml of water
containing 0.5ml of 37% w/v formaldehyde and 0.5g oxalic acid. The temperature was allowed to rise gradually
to 90-95 and maintained for 1hr. After cooling, the fabrics were washed with water and treated with 0.2% w/v
detergent solution in water at 800
C for 30 minutes. After washing with water, the fabrics were dried at room
temperature [5].
2.8 Characterization
The following characterization techniques were employed:
2.8.1 UV-Visible Spectroscopy
The electronic spectra were measured by means of a Shimadzu 1601 Spectrophotometer in the region
200–800nm. [6].
2.8.2 Fourier Transformed Infra-red (FT-IR) Spectroscopy
The sample prepared were characterized using KBr disc sampling method. The discs were prepared by
grinding the samples (2% by weight) with KBr which was then compressed in to a disc and were analyzed FTIR
Spectrometer (Perkin Elmer model) [7].
2.8.3 Proton Nuclear Magnetic Resonance (1
H-NMR) Spectroscopy
1
H-NMR spectra were recorded on a Joel Lambda 400 MHz Nuclear Magnetic Resonance
spectrometer. An appropriate quantity of the sample was weighted and dissolved in a vial in deuterated DMSO
containing tetramethyl silane (TMS) as internal standard. Using a pipette; the liquid was transferred through the
pipette filler into the NMR tube and the spectra were recorded. FT-IR yields information about the arrangement
of pendants groups such as alkyl, phenyl, etc.
2.8.4 Determination of Melting Point and Solubility
The melting points were determined with Gallenkamp melting point apparatus.
The solubility of each sample was tested in a variety of solvents which include: water, ethanol, methanol,
chloroform, carbon tetrachloride, n-hexane, ethyl acetate, petroleum ether, acetone and N,N-dimethyl
formamide (DMF). 5cm3
of each solvent was added to about 0.1g of the sample in a test tube and shaken
vigorously. The solubility was carefully observed and recorded.
2.8.5 Dilute Solution Viscometry (DSV)
Viscosity measurements were conducted at 300
C using Ostwald Viscometer as described by [8].
2.9 Color Fastness Properties
2.9.1 Fastness to Light
The light fastness properties of the dyed samples were assessed using the standard methods (B.S 1006).
It was carried out on an artificial light fastness tester MK1 fitted with mercury-tungsten (MBTF) 500 watt lamp.
The samples were exposed together with blue wool standards for about 96hrs and assessed.
3. Synthesis, Characterization And Application Of Some Polymeric Dyes Derived From Monoaz
www.iosrjournals.org 44 | Page
2.9.2 Fastness to washing
The fastness to washing of the dyed samples was assessed using a similar method adopted by [9].
2.9.3 Fastness to Rubbing
A piece of the dyed fabric was rubbed on a plane dry white cloth and then a wet white cloth. The
staining of the white cloth was observed and assessed [9].
III. Results and Discussions
The proposed synthetic scheme for the polymeric dyes and their low-molecular weight precursors is
outlined below:
Ar NH2
diazotization
aromatic amine
Ar N NCl
diazonium salt
OH
N
N
N
CH3
CH3
X
coupling
formaldehyde
aq. oxalic acid
OH
N
N
N
CH3
CH3
X
CH2
monoazo dye
polymeric dye
When, X = H: Dye A1 [poly (4-hydroxy-2-N,N-dimethylphenylazo-3’-nitrobenzene)] When, X
= NO2: Dye D1 [ poly (4-hydroxy-2-N,N-dimethylphenylazobenzene)]
Figure 1: Synthesis of Simple and Polymeric Dyes
Table 1: Yield, Color and Melting Point of the Dye Samples
Dye Yield (%) Color M/Pt. (0
C)
B 83.0 Orange 110-112
C 67.2 Orange 76-80
E 77.4 Yellow 85-90
B1 70.5 Orange 138-143
C1 52.0 Orange 130-132
E1 38.9 Yellow 138-142
The percentage yields for the synthesized dyes are good 89.5% and 48% for the monomeric dyes A and D
respectively and 53% for the corresponding polymeric dyes (A1 and D1). All the dyes were yellow in color,
with the polymeric dyes having deeper shades. The dyes were of low melting points, 78-800
C, 80-840
C for the
monomeric dyes A and D respectively and 128-1300
C and 96-1010
C for the corresponding polymeric dyes A1
and D1 respectively.
3.1 UV-Visible Spectroscopy
This technique was employed in order to determine the wavelength of maximum absorption (λ max) for
the synthesized dyes. Results obtained are presented in the TABLE below.
Table 2: λ max Values for the dye samples
Sample λmax (nm) Absorbance
P 402 2.834
Q 457 3.436
R 416 2.916
P1 462 3.436
Q1 493 3.524
R1 438 3.010
The λ max values of the monomeric and polymeric dyes fall between 456-488nm depending upon the nature and
position of the substituents. The synthesized dyes all have the same chromophore ( i.e –N=N-), so they all have
approximately the same λ max. However, the polymeric dyes synthesized, absorbed at slight longer wavelength
than the monomeric dyes. Hence there is a bathochromic shift.
4. Synthesis, Characterization And Application Of Some Polymeric Dyes Derived From Monoaz
www.iosrjournals.org 45 | Page
The polymeric dyes except A1 and D1 were found to have absorption higher than the corresponding monomeric
dyes indicating that, little quantity of the polymeric dye can provide sufficient colour that can only be obtained
when relatively larger quantity of the monomeric dye is used [10].
3.2 FT-IR Spectroscopy
Identification of the type of functional groups present in a polymer is effectively achieved by IR
analysis. From the result obtained, the hydroxyl stretching vibration bands for the dye samples were observed in
the region 3436.21cm-1
, 3398.55 cm-1
for A and D respectively and 3422.01 cm-1
and 3398.55 cm-1
respectively
for A1 and D1. Bands in the region1528.82 cm-1
- 1617.67 cm-1
were assigned to the –N=N- group. The IR
spectra of the monomeric and polymeric dyes are almost identical in their important characteristics. However,
the main difference between the IR spectra of the polymeric dyes and those of their low molecular weight
precursors is the presence of medium bands at 2901.92 cm-1
and 2930.07 cm-1
due to asymmetric (CH2)
methylene bridges in the spectra of polymeric dyes A1 and D1 and respectively.
Table 3: Infra-red absorption bands
Sample Group
-OH -N=N- C-N N-H CH2
B 3426.55 cm-1
1590.08 cm-1
C 3400.40 cm-1
1542.03 cm-1
E 1522.82 cm-1
1333.98 cm-1
3433.33 cm-1
B1 3413.97 cm-1
1589.84 cm-1
2972.57 cm-1
C1 3394.50 cm-1
1624.17 cm-1
2901.78 cm-1
E1 1529.45 cm-1
1259.57 cm-1
3370.16 cm-1
2927.53 cm-1
From the result in TABLE 3, the hydroxyl stretching vibration bands for the dye samples except for sample E
and E1, were observed in the region 3394.50 cm-1
– 3436.21cm-1
. Bands in the region1522.82 cm-1
- 1624.17 cm-1
were assigned to the –N=N- group. Bands at 1259 cm-1
and 1333.98 cm-1
were due to C-N stretching of aromatic
amine for E1 and E respectively. Bands at 3433.33 cm-1
and 3370.16 cm-1
of the spectrum of sample E and E1
respectively, are assignable to the aromatic N-H group. The IR spectra of all monomeric and polymeric dyes are
almost identical in their important characteristics. However, the main difference between the IR spectra of the
polymeric dyes and those of their low molecular weight precursors is the presence of medium bands at 2901.92
cm-1
, 2972.57 cm-1
, 2901.78 cm-1
, 2930.07 cm-1
, and 2927.53 cm-1
due to asymmetric (CH2) methylene bridges in
the spectra of polymeric dyes A1, B1, C1, D1 and E1 respectively.
3.31
H-NMR Spectroscopy
In the 1
H-NMR Spectral data of the synthesized dyes were observed Ar-H at 7.16 – 7.44ppm as
multiples, the OH peaks appeared at 2.0 – 3.05ppm and the aromatic NH peaks appeared at 3.90 – 4.77ppm. The
1
H-NMR spectra of the monomeric and polymeric dyes are almost similar in their important characteristics.
However, there is appearance of peak at around 2.88ppm assignable to some traces of -CH2- in the spectra of the
polymeric dyes.
3.4 Solubility
The dyes were found to be soluble in chloroform and acetone, some were found to dissolve in ethanol
and methanol, and generally insoluble in water. Their insolubility in water may be attributed to their disperse
nature.
3.5 Dilute Solution Viscometry (DSV)
The viscosities of the polymer samples are presented in the figures below:
5. Synthesis, Characterization And Application Of Some Polymeric Dyes Derived From Monoaz
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Figure 2: Plots of Inherent Viscosity against Concentration of the Polymeric Dyes
Figure 3: Plots of Reduced Viscosity against Concentration of the Polymeric Dyes
The plots of inherent viscosities of the polymeric dyes obtained are shown in figure 1. The relative positions of
these plots give an idea of the viscosity of the samples. The variation in the viscosities of the samples is a direct
relation with molecular mass. The plots of reduced viscosity against concentration are shown in figure 2. The
intercepts of the plots with the vertical axis correspond to the limiting or intrinsic viscosities of the samples at
infinite dilution. These intercepts can be used in combination with appropriate constants in the Mark-Houwink-
Sakurada equation to evaluate the viscosity average molar mass Ḿv. However, the constants k and α, are
specific for a polymer/solvent at a given temperature. The samples were of low viscosity and this implies low
molecular weight and hence, better ability to penetrate the fibers [11]
3.6 Color Fastness Properties
Fastness properties of dyed fabrics show resistance of the color to external agencies. Wash fastness
measures the resistance to laundry treatments while light fastness measures resistance to sunlight [12]. The color
fastness properties of polymeric dyes and their low-molecular weight precursors are summarized in table 4.
As indicated in tables 4, the light fastness of the monomeric dyes on both Nylon and Polyester varied
from moderate to good. The washing fastness varied from moderate to very good. The wash fastness of the
polymeric dyes on both nylon and polyester is not better than those of the corresponding monomeric dyes.
However, the light and wash fastness increases after polymerization of the simple dye on nylon and polyester.
6. Synthesis, Characterization And Application Of Some Polymeric Dyes Derived From Monoaz
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Table 4: Color Fastness Properties of the Monomeric, Polymeric and Dyes Polymerized on Nylon and
Polyester
Monomeric Dyes
Nylon Polyester
Dye Light Washing Rubbing Light Washing Rubbing
P 2-3 3-4 4-5 3-4 4-5 4-5
Q 2-3 3 3-4 2-3 4 3-4
R 2-3 4-5 4-5 2-3 4-5 4-5
Polymeric Dyes
P1 3-4 4-5 4-5 5 4-5 4-5
Q1 4-5 4-5 4-5 5 4-5 4-5
R1 4-5 4-5 4-5 5 4-5 4-5
Polymerized Dyes
P2 4-5 4-5 4-5 5 4-5 4-5
Q2 3-4 3-4 4 4-5 4-5 4
R2 4-5 4-5 4-5 5-6 5 4-5
The rubbing fastness for the dyes is excellent on both fibers. Generally, those dyes polymerized on the fabrics
showed better fastness and more attractive hues. The fastness properties of the synthesized dyes are comparable
to those reported by [12] and [13].
IV. Conclusion
In this study, two polymeric dyes were synthesized via diazotization and coupling reactions followed
by condensation with formaldehyde in the presence of aqueous oxalic acid. The synthesized dyes have been
characterized using color, melting point, yield, dilute solution viscometry, UV-visible, proton-nuclear magnetic
resonance, and IR spectroscopy. The melting points of the dyes were generally low. The absorbances of the
polymeric dyes were found to be higher than those of their low molecular weight precursors. Generally, the dyes
have good exhaustion in both the fibers though they exhaust better in nylon than polyester. Their fastness
properties on nylon and polyester were good with the polymeric dyes having more brilliant colours generally,
the polymerization of potential monomeric dyes on nylon and polyester leads to brilliancy of shade and increase
in fastness properties.
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