The document contains a chemistry practice problem set with 10 multiple choice questions about reaction rates and rate laws. The questions cover topics such as how the rates of reactants and products are related in a chemical reaction, how to write rate laws from reaction equations, determining reaction orders from rate equations, and calculating rate constants. It also includes a nomenclature list of 38 chemical species.

1. GENERAL CHEMISTRY-II (1412)
S.I. # 16
1. For the gas-phase reaction H2 (g) + F2 (g)  2HF (g), how is the rate of
disappearance of H2 related to the rate of appearance of HF? ___________
a. ∆[H2] / ∆t = 2 ∆[HF] / ∆t
b. ∆[H2] / ∆t = - 2 ∆[HF] / ∆t
c. ∆[H2] / ∆t = - ∆[HF] / 2∆t
d. ∆[H2] / ∆t = ∆[HF] / ∆t
e. ∆[H2] / ∆t = ∆[HF] / 2∆t
2. Consider the reaction 3A  2B.
The average rate of appearance of B is given by [B] /t. How is the average rate of
appearance of B related to the rate of disappearance of A?
3. The hydrolysis of t-butyliodide is (CH3)3Cl + H2O  (CH3)3COH + HI
and the equation governing the rate of this reaction is rate = k[(CH3)3Cl]1. What is
the order of each reactant and the over all order of the reaction?
4. If 2N2O5  4 NO2 + O2 and the rate law is 1st order in N2O5, writ the rate law for
the reaction.
5. The reaction 2 NO + 2H2  N2 + 2H2O is 1st order in H2 and 2nd order in NO.
Write the rate law for the reaction.
6. If the reaction 2 A + 3 D  products is 1st order in A and 2nd order in D, the rate
law will have the form rate equal to:
7. For 1st order reactions, the rate constant, k, has the unit(s): ________________
a. time b. time mol L-1 c. L mol-1 d. (mol/L)-1 time-1 e. time-1
8. The rate equation for the decomposition of H2O2 in the presence of I- is the rate =

2. k [H2O2][I-]. What are the unit(s) of k?
9. In the reaction A  products, the initial concentration of A is 1.56 M and the
initial rate is 0.0190 M/sec. What is the value of the rate constant k in sec-1?
10. Write the equilibrium constant fo the heterogeneous reaction
2NaHCO3 (s)  Na2CO3(s) + CO2(g) + H2O (g)
NOMENCLATURE!!!
1. Butyl Chloride 23. HgCl2
2. Butyl Alcohol 24. C2O42-
3. O3 25. Urea
4. NH4 26. Cyclopentadiene
5. Nitrite 27. Dicyclopentadiene
6. NO 28. C2H5OH
7. (CH3)2O
8. Methyl isonitrile 29. CoCl2
9. Acetonitrile 30. CCl4
10. CH3Br 31. NaOCl
11. H2O2 32. AgCl
12. Ethylene 33. FeCl3 6H2O
13. Ethane 34. Sodium Sulfate
14. Al2O3 35. Sodium Acetate
15. HCOOH 36. Ammonia
16. C2H5Br 37. Hydrogen sulfide
17. Peroxydisulfate 38. Ammonium Nitrate
18. Sucrose
19. Silica
20. H2S
21. CHCl3
22. OCl-