KEY


                         GENERAL CHEMISTRY-I (1411)
                                  S.I. # 10

1. Balance the following equations:

a. 6      Li (s) + __1__ N2 (g)  ___2__ Li3N (s)

b. __1     La2O3 (s) + __3__ H2O (l)  ___2__ La(OH)3 (aq)

c. __2     NH4NO3 (s)  __2__ N2 (g) + ___1__ O2 (g) + ___4__ H2O (g)

d. __1     Ca3P2 (s) + __6__ H2O (l)  ___3__ Ca(OH)2 (aq) + ___2__ PH3 (g)

e. __3     Ca(OH)2 (aq) + __2__ H3PO4 (aq) ___1_ Ca3(PO4)2 (s) + _6__ H2O (l)

f. __2    AgNO3 (aq) + __1_Na2SO4 (aq)  ___1__ Ag2SO4 (s) + __2_ NaNO3 (aq)
g. _4    CH3NH2 (g) + _9_O2 (g) _4__ CO2 (g) + __10__ H2O (g) + ___2__ N2 (g)


2. Determine the formula weights (FW) of each of the following:
       a. Nitrous Oxide, N2O             ____44 amu_____
       b. benzoic acid, HC7H5O2          ____122 amu _____
       c. Magnesium Hydroxide, Mg(OH)2____58.3 amu _____
       d. Urea (NH2)2CO                  ____60 amu _____
       e. isopentyl acetate CH3CO2C5H11 ____130 amu _____

3. Calculate the percent by mass of:
       a. carbon in acetylene, C2H2
               FW = 26      %C = [(2)(12.0 amu) / (26.0 amu)] x 100 = 92.3%
       b. Hydrogen in ascorbic acid HC6H7O6
               FW = 176     %H = [(8)(1.0 amu) / (176.0 amu)] x 100 = 4.5%
       c. Hydrogen in ammonium sulfate (NH4)2SO4
               FW = 132.1 %H = [(8)(1.0 amu) / (132.1 amu)] x 100 = 6.1%
       d. Platinum in PtCl2(NH3)2
               FW = 300.1 %Pt = [(1)(195.1 amu) / (300.1 amu)] x 100 = 65.01%
       e. Oxygen in C18H24O2
               FW = 272.0 %O = [(2)(16.0 amu) / (272.0 amu)] x 100 = 11.8%
       f. carbon in C18H27NO3
               FW = 305.0 %C = [(18)(12.0 amu) / (305.0 amu)] x 100 = 70.8%

4. a. What is Avogadro’s number, and how is it related to the mole? b. What is the
relationship between the formula weight of a substance and its molar mass?
       a. 6.022x1023. This is the number of objects in a mole of anything
       b. The formula weight of a substance in amu has the same numerical value as the
molar mass expressed in grams.
5. a. what is the mass, in grams, of a mole of 12C? b. How many carbon atoms are
KEY


present in a mole of 12C?
      a. exactly 12 g        b. 6.0221421x1023, Avogadro’s number

6. a. What is the mass, in grams, of 0.0714 mol of iron(III) sulfate?
       Fe2(SO4)3 FW=Molar Mass= 399.9 g / mol

       0.0714 mol Fe2(SO4)3 x (399.9 g Fe2(SO4)3) = 28.6 g Fe2(SO4)3
                                    1 mol

   b. How many moles of ammonium ions are in 8.776 g of ammonium carbonate?
      (NH4)2CO3 MM = 96.087 g / mol

       8.776 g (NH4)2CO3 x ( 1 mol (NH4)2CO3 )x( 2 mol NH4+)       = 0.1827 mol NH4+
                           (96.087g (NH4)2CO3) (1 mol (NH4)2CO3)
   c. What is the mass, in grams, of 6.52x1021 molecules of aspirin, C9H8O4?
       C9H8O4 MM=180.2 g / mol

       6.52x1021molecules x (1 mol)               x (180.2 g C9H8O4)= 1.95 g
                            (6.022x1023molecules)    (1 mol aspirin)

7. A sample of the male sex hormone testosterone, C19H28O2, contains 7.08x1020
atoms of hydrogen. a. How many atoms of carbon does it contain? b. How many
molecules of testosterone does it contain? c. How many moles of testosterone does it
contain? d. What is the mass of this sample in grams?

       a. 7.08x1020 H atoms x (19 C atoms) = 4.80x1020 C atoms
                              (28 H atoms)

       b. 7.08x1020 H atoms x (1 C19H28O2 molecule) = 2.53x1019 C19H28O2 molecules
                              (28 H atoms)

       c. 2.529x1019 C19H28O2 molecules x ( 1 mol )         = 4.199x10-5 mol C19H28O2
                                            (6.022x1023 molecules)

       d. C19H28O2 MM = 288.4 g / mol

              4.199x10-5 mol C19H28O2 x (288.4 g C19H28O2) = 0.0121 g C19H28O2
                                           (1 mol)

#10 Key

  • 1.
    KEY GENERAL CHEMISTRY-I (1411) S.I. # 10 1. Balance the following equations: a. 6 Li (s) + __1__ N2 (g)  ___2__ Li3N (s) b. __1 La2O3 (s) + __3__ H2O (l)  ___2__ La(OH)3 (aq) c. __2 NH4NO3 (s)  __2__ N2 (g) + ___1__ O2 (g) + ___4__ H2O (g) d. __1 Ca3P2 (s) + __6__ H2O (l)  ___3__ Ca(OH)2 (aq) + ___2__ PH3 (g) e. __3 Ca(OH)2 (aq) + __2__ H3PO4 (aq) ___1_ Ca3(PO4)2 (s) + _6__ H2O (l) f. __2 AgNO3 (aq) + __1_Na2SO4 (aq)  ___1__ Ag2SO4 (s) + __2_ NaNO3 (aq) g. _4 CH3NH2 (g) + _9_O2 (g) _4__ CO2 (g) + __10__ H2O (g) + ___2__ N2 (g) 2. Determine the formula weights (FW) of each of the following: a. Nitrous Oxide, N2O ____44 amu_____ b. benzoic acid, HC7H5O2 ____122 amu _____ c. Magnesium Hydroxide, Mg(OH)2____58.3 amu _____ d. Urea (NH2)2CO ____60 amu _____ e. isopentyl acetate CH3CO2C5H11 ____130 amu _____ 3. Calculate the percent by mass of: a. carbon in acetylene, C2H2 FW = 26 %C = [(2)(12.0 amu) / (26.0 amu)] x 100 = 92.3% b. Hydrogen in ascorbic acid HC6H7O6 FW = 176 %H = [(8)(1.0 amu) / (176.0 amu)] x 100 = 4.5% c. Hydrogen in ammonium sulfate (NH4)2SO4 FW = 132.1 %H = [(8)(1.0 amu) / (132.1 amu)] x 100 = 6.1% d. Platinum in PtCl2(NH3)2 FW = 300.1 %Pt = [(1)(195.1 amu) / (300.1 amu)] x 100 = 65.01% e. Oxygen in C18H24O2 FW = 272.0 %O = [(2)(16.0 amu) / (272.0 amu)] x 100 = 11.8% f. carbon in C18H27NO3 FW = 305.0 %C = [(18)(12.0 amu) / (305.0 amu)] x 100 = 70.8% 4. a. What is Avogadro’s number, and how is it related to the mole? b. What is the relationship between the formula weight of a substance and its molar mass? a. 6.022x1023. This is the number of objects in a mole of anything b. The formula weight of a substance in amu has the same numerical value as the molar mass expressed in grams. 5. a. what is the mass, in grams, of a mole of 12C? b. How many carbon atoms are
  • 2.
    KEY present in amole of 12C? a. exactly 12 g b. 6.0221421x1023, Avogadro’s number 6. a. What is the mass, in grams, of 0.0714 mol of iron(III) sulfate? Fe2(SO4)3 FW=Molar Mass= 399.9 g / mol 0.0714 mol Fe2(SO4)3 x (399.9 g Fe2(SO4)3) = 28.6 g Fe2(SO4)3 1 mol b. How many moles of ammonium ions are in 8.776 g of ammonium carbonate? (NH4)2CO3 MM = 96.087 g / mol 8.776 g (NH4)2CO3 x ( 1 mol (NH4)2CO3 )x( 2 mol NH4+) = 0.1827 mol NH4+ (96.087g (NH4)2CO3) (1 mol (NH4)2CO3) c. What is the mass, in grams, of 6.52x1021 molecules of aspirin, C9H8O4? C9H8O4 MM=180.2 g / mol 6.52x1021molecules x (1 mol) x (180.2 g C9H8O4)= 1.95 g (6.022x1023molecules) (1 mol aspirin) 7. A sample of the male sex hormone testosterone, C19H28O2, contains 7.08x1020 atoms of hydrogen. a. How many atoms of carbon does it contain? b. How many molecules of testosterone does it contain? c. How many moles of testosterone does it contain? d. What is the mass of this sample in grams? a. 7.08x1020 H atoms x (19 C atoms) = 4.80x1020 C atoms (28 H atoms) b. 7.08x1020 H atoms x (1 C19H28O2 molecule) = 2.53x1019 C19H28O2 molecules (28 H atoms) c. 2.529x1019 C19H28O2 molecules x ( 1 mol ) = 4.199x10-5 mol C19H28O2 (6.022x1023 molecules) d. C19H28O2 MM = 288.4 g / mol 4.199x10-5 mol C19H28O2 x (288.4 g C19H28O2) = 0.0121 g C19H28O2 (1 mol)