SHAPE MEMORY ALLOYS
1.0 INTRODUCTION
• A material that can remember its shape
• Shape Memory Alloys (SMAs) are metallic
alloys that undergo a solid-to-solid phase
transformation which can exhibit large
recoverable strains.

WACHIRA J.
NDUNG'U/MEMS/MECHATRONIC
ENGINEERING/JKUAT
Origin of
shape-memory effect
• Martensitic phase transformation that occurs
as a result of:
a) stress or
b) temperature change

WACHIRA J.
NDUNG'U/MEMS/MECHATRONIC
ENGINEERING/JKUAT
Thermally Induced Phase
Transformation in SMAs

WACHIRA J.
NDUNG'U/MEMS/MECHATRONIC
ENGINEERING/JKUAT
Martensitic transformation
temperatures
• Ms: temperature at which austenite begins to
transform to martensite upon cooling
• Mf: temperature at which transformation of
austenite to martensite is complete upon cooling
• As: temperature at which martensite begins to
transform to austenite upon heating
• Af: temperature at which transformation of
martensite to austenite is complete upon heating
WACHIRA J.
NDUNG'U/MEMS/MECHATRONIC
ENGINEERING/JKUAT
Types of shape-memory behavior
• One-way shape memory: transformation to the
desired shape occurs only upon heating, i.e.,
memory is with the austenite phase.
• Two-way shape memory: the deformed shape is
remembered during cooling, in addition to the
original shape being remembered during heating,
i.e., memory is with both austenite and
martensite phases (requires training to attain
memory during cooling; formation of favorably
oriented twins during cooling between Ms and
Mf)
WACHIRA J.
NDUNG'U/MEMS/MECHATRONIC
ENGINEERING/JKUAT
Applications of SMA
Use of memory alloys
for coupling tubing: A
memory alloy coupling
is expanded (a) so it fits
over the tubing (b).
When the coupling is
reheated, it shrinks
back to its original
diameter (c), squeezing
the tubing for a tight fit

WACHIRA J.
NDUNG'U/MEMS/MECHATRONIC
ENGINEERING/JKUAT
SMA in MEMS
•
•
•
•
•

Desirable properties for MEMS applications
high power to weight ( force to volume) ratio,
pseudoelasticity (or superelasticity),
high damping capacity,
good chemical resistance and biocompatibility

WACHIRA J.
NDUNG'U/MEMS/MECHATRONIC
ENGINEERING/JKUAT
SMA ACTUATORS
• TiNi actuators
• TiNi films in MEMS are focused on
microactuators, such as
micropumps, microvalves, microgrippers, springs, microspacers, micropositioners,
TiNi cantilever
showing the
actuation during
heating and
cooling
WACHIRA J.
NDUNG'U/MEMS/MECHATRONIC
ENGINEERING/JKUAT
SMA SENSORS
• TiNi Sensors
• TiNi thin films are sensitive to environmental changes
such as thermal, stress, magnetic or electrical fields.
• Examples: a gate of metal-on-silicon (M.O.S.) capacity
sensor, switches or microrelays include on-chip circuit
breakers against overheating caused by short circuit or
overload, probe tips for automatic test
equipment, fiber optics switching, automotive fuel
injectors, micro-lens positioner, light valve or on-off
optical switch for spatial light modulators, a far infrared
radiation (FIR) imaging sensor
WACHIRA J.
NDUNG'U/MEMS/MECHATRONIC
ENGINEERING/JKUAT
Examples of SMAs
• Cu-Zn-Al
• Cu-Al-Ni
• Ni-Ti (50 at.% Ti, nitinol, which stands for
Nickel Titanium Naval Ordinance Laboratory)

WACHIRA J.
NDUNG'U/MEMS/MECHATRONIC
ENGINEERING/JKUAT
SMA Applications

Scanning Electron Microscope picture of the TWSME micro-gripper for
sub-millimeter lens handling

WACHIRA J.
NDUNG'U/MEMS/MECHATRONIC
ENGINEERING/JKUAT
SMA- Example of a Microvalve

Micro-valve with SMA actuator (Ti-Ni ribbon) .The valve is
shown in its closed configuration. Dimensions of the assembly are 5 x
8mm for a thickness of 2mm. The film thickness is a few microns.

WACHIRA J.
NDUNG'U/MEMS/MECHATRONIC
ENGINEERING/JKUAT
The Olympus Co. micro-endoscope .
Left: The endoscope winding around a match; right: exploded view of the
inside structure.
WACHIRA J.
NDUNG'U/MEMS/MECHATRONIC
ENGINEERING/JKUAT

Shape memory alloys

  • 1.
  • 2.
    1.0 INTRODUCTION • Amaterial that can remember its shape • Shape Memory Alloys (SMAs) are metallic alloys that undergo a solid-to-solid phase transformation which can exhibit large recoverable strains. WACHIRA J. NDUNG'U/MEMS/MECHATRONIC ENGINEERING/JKUAT
  • 3.
    Origin of shape-memory effect •Martensitic phase transformation that occurs as a result of: a) stress or b) temperature change WACHIRA J. NDUNG'U/MEMS/MECHATRONIC ENGINEERING/JKUAT
  • 4.
    Thermally Induced Phase Transformationin SMAs WACHIRA J. NDUNG'U/MEMS/MECHATRONIC ENGINEERING/JKUAT
  • 5.
    Martensitic transformation temperatures • Ms:temperature at which austenite begins to transform to martensite upon cooling • Mf: temperature at which transformation of austenite to martensite is complete upon cooling • As: temperature at which martensite begins to transform to austenite upon heating • Af: temperature at which transformation of martensite to austenite is complete upon heating WACHIRA J. NDUNG'U/MEMS/MECHATRONIC ENGINEERING/JKUAT
  • 6.
    Types of shape-memorybehavior • One-way shape memory: transformation to the desired shape occurs only upon heating, i.e., memory is with the austenite phase. • Two-way shape memory: the deformed shape is remembered during cooling, in addition to the original shape being remembered during heating, i.e., memory is with both austenite and martensite phases (requires training to attain memory during cooling; formation of favorably oriented twins during cooling between Ms and Mf) WACHIRA J. NDUNG'U/MEMS/MECHATRONIC ENGINEERING/JKUAT
  • 7.
    Applications of SMA Useof memory alloys for coupling tubing: A memory alloy coupling is expanded (a) so it fits over the tubing (b). When the coupling is reheated, it shrinks back to its original diameter (c), squeezing the tubing for a tight fit WACHIRA J. NDUNG'U/MEMS/MECHATRONIC ENGINEERING/JKUAT
  • 8.
    SMA in MEMS • • • • • Desirableproperties for MEMS applications high power to weight ( force to volume) ratio, pseudoelasticity (or superelasticity), high damping capacity, good chemical resistance and biocompatibility WACHIRA J. NDUNG'U/MEMS/MECHATRONIC ENGINEERING/JKUAT
  • 9.
    SMA ACTUATORS • TiNiactuators • TiNi films in MEMS are focused on microactuators, such as micropumps, microvalves, microgrippers, springs, microspacers, micropositioners, TiNi cantilever showing the actuation during heating and cooling WACHIRA J. NDUNG'U/MEMS/MECHATRONIC ENGINEERING/JKUAT
  • 10.
    SMA SENSORS • TiNiSensors • TiNi thin films are sensitive to environmental changes such as thermal, stress, magnetic or electrical fields. • Examples: a gate of metal-on-silicon (M.O.S.) capacity sensor, switches or microrelays include on-chip circuit breakers against overheating caused by short circuit or overload, probe tips for automatic test equipment, fiber optics switching, automotive fuel injectors, micro-lens positioner, light valve or on-off optical switch for spatial light modulators, a far infrared radiation (FIR) imaging sensor WACHIRA J. NDUNG'U/MEMS/MECHATRONIC ENGINEERING/JKUAT
  • 11.
    Examples of SMAs •Cu-Zn-Al • Cu-Al-Ni • Ni-Ti (50 at.% Ti, nitinol, which stands for Nickel Titanium Naval Ordinance Laboratory) WACHIRA J. NDUNG'U/MEMS/MECHATRONIC ENGINEERING/JKUAT
  • 12.
    SMA Applications Scanning ElectronMicroscope picture of the TWSME micro-gripper for sub-millimeter lens handling WACHIRA J. NDUNG'U/MEMS/MECHATRONIC ENGINEERING/JKUAT
  • 13.
    SMA- Example ofa Microvalve Micro-valve with SMA actuator (Ti-Ni ribbon) .The valve is shown in its closed configuration. Dimensions of the assembly are 5 x 8mm for a thickness of 2mm. The film thickness is a few microns. WACHIRA J. NDUNG'U/MEMS/MECHATRONIC ENGINEERING/JKUAT
  • 14.
    The Olympus Co.micro-endoscope . Left: The endoscope winding around a match; right: exploded view of the inside structure. WACHIRA J. NDUNG'U/MEMS/MECHATRONIC ENGINEERING/JKUAT