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Shape Memory Alloys
By: SIDDESH KUMAR N M 180939013
Mars Rovers
Curiosity Rover
Launched Nov 2011
By NASA
Still operating
Travelled 20km
Speed .14 km/hour
Opportunity Rover
Launched July 2013
By NASA
ceased 2018
Travelled 45km
Speed 1 km/hour
LUNOKHOD 2
Moon walker
Launched in 1973 by Russia
Travelled 39 km
Wheels made up of aluminum
Speed of the rover is 1 - 2km/hour
Distance travelled by different rovers
What is the main reason
the failure of rovers
Wheels are made up of Nickel Titanium Alloy
Shape
memory alloys
 Shape Memory Alloys (SMAs) are metallic alloys that undergo a
solid-to-solid phase transformation which can exhibit large
recoverable strains.
 The two most prevalent shape-memory alloys are
 Copper-aluminium-nickel
 Nickel-titanium (Ni Ti)
 Iron and copper based shape memory alloys
 Fe-Mn-Si
 Cu-Zn-Al
 Cu-Al-Ni
Properties of Nickel & Titanium
Properties Nickel Titanium
Density 8.908 g/cm3 4.197 g/cm3
Melting point 1455 °C 1668 °C
Magnetic property Ferro magnetic Para magnetic
Young's modulus 200 GPa 116 GPa
Shear modulus 76 GPa 44 GPa
Bulk modulus 180 GPa 110GPa
At elevated temperature and
pressure
Will remain same Will change the properties
Application Can be used at high temperature
& high pressure
Cannot be used at high
temperature
Austenite
 High temperature phase
 Cubic Crystal Structure
Martensite
 Low temperature phase
 Monoclinic Crystal Structure
Twinned Martensite Detwinned Martensite
Crystal structure
Mf Ms As Af
Austenite
Martensite TEMPERATURE
Mf Ms As Af
Austenit
e
Martensite TEMPERATURE
(twinned)
(twinned)
Phase Transformation
Machining
 Nitinol is a very abrasive material to machine due
to its tough titanium oxide surface.
 Milling, turning, and grinding are possible with
excellent results, but expect a lot of tool wear.
 Carbide tooling is highly recommended.
 Nitinol can be electrical discharge machined
(EDM), water-jet cut, and laser machined with
excellent results
Cold working
Nitinol wire and tube typically will have 30-40%
cold work reduction during the last drawing
steps.
In sheet and strip products, that value is usually
closer to 20% reduction. The amount of cold
work a material has prior to its shape set anneal
decides the ultimate strength of the material.
Nitinol in the cold work condition (as drawn or
as rolled) is material that has not been subject
to a final heat treatment (shape set anneal).
Surface finish
Mechanically polished surface
Nitinol wire and strip is abrasively polished to a shiny,
bright surface prior to straightening.
This surface looks very similar to stainless steel and is
very popular for its cosmetic appeal.
A centreless grinding method is applied to Nitinol wire
and tubes to achieve a bright surface
Coatings
Nitinol can be coated with polymers such as
polyurethane and Teflon.
Polyurethane extruded over Nitinol is common for cell
phone antennas.
Teflon extrusion and spray coating of Nitinol is becoming
more common today.
Joining to
Nitinol
Soldering: Sn-Ag solder can be used
Welding: Laser, TIG, and resistance welding
A Nitinol tube connector can be expanded
either mechanically or by cooling it to
martensite and deforming it.
The Nitinol connector is then inserted over
another element and allowed to return to
austenite, causing it to clamp down on the
element.
Beneficial Properties of Ni Ti SMAs
Ductility is improved
Excellent corrosion resistance
(comparable to 300 stainless steel)
Stable transformation temperature
High biocompatibility
More recoverable motion
Adding alloying element 1% change
mechanical property and phase
transformation temperature.
Fe and Cr can added to lower the
Transformation temperature
Applications
• Aero space
• Space vehicle
• Bio medical
• Automobile
• Actuators
Nickel Titanium Alloy
Thank you …….
Any queries ….????

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Shape Memory alloy Nitnol

  • 1. Shape Memory Alloys By: SIDDESH KUMAR N M 180939013
  • 2. Mars Rovers Curiosity Rover Launched Nov 2011 By NASA Still operating Travelled 20km Speed .14 km/hour Opportunity Rover Launched July 2013 By NASA ceased 2018 Travelled 45km Speed 1 km/hour
  • 3. LUNOKHOD 2 Moon walker Launched in 1973 by Russia Travelled 39 km Wheels made up of aluminum Speed of the rover is 1 - 2km/hour
  • 4. Distance travelled by different rovers
  • 5. What is the main reason the failure of rovers
  • 6. Wheels are made up of Nickel Titanium Alloy
  • 7. Shape memory alloys  Shape Memory Alloys (SMAs) are metallic alloys that undergo a solid-to-solid phase transformation which can exhibit large recoverable strains.  The two most prevalent shape-memory alloys are  Copper-aluminium-nickel  Nickel-titanium (Ni Ti)  Iron and copper based shape memory alloys  Fe-Mn-Si  Cu-Zn-Al  Cu-Al-Ni
  • 8. Properties of Nickel & Titanium Properties Nickel Titanium Density 8.908 g/cm3 4.197 g/cm3 Melting point 1455 °C 1668 °C Magnetic property Ferro magnetic Para magnetic Young's modulus 200 GPa 116 GPa Shear modulus 76 GPa 44 GPa Bulk modulus 180 GPa 110GPa At elevated temperature and pressure Will remain same Will change the properties Application Can be used at high temperature & high pressure Cannot be used at high temperature
  • 9. Austenite  High temperature phase  Cubic Crystal Structure Martensite  Low temperature phase  Monoclinic Crystal Structure Twinned Martensite Detwinned Martensite Crystal structure
  • 10. Mf Ms As Af Austenite Martensite TEMPERATURE Mf Ms As Af Austenit e Martensite TEMPERATURE (twinned) (twinned) Phase Transformation
  • 11. Machining  Nitinol is a very abrasive material to machine due to its tough titanium oxide surface.  Milling, turning, and grinding are possible with excellent results, but expect a lot of tool wear.  Carbide tooling is highly recommended.  Nitinol can be electrical discharge machined (EDM), water-jet cut, and laser machined with excellent results
  • 12. Cold working Nitinol wire and tube typically will have 30-40% cold work reduction during the last drawing steps. In sheet and strip products, that value is usually closer to 20% reduction. The amount of cold work a material has prior to its shape set anneal decides the ultimate strength of the material. Nitinol in the cold work condition (as drawn or as rolled) is material that has not been subject to a final heat treatment (shape set anneal).
  • 13. Surface finish Mechanically polished surface Nitinol wire and strip is abrasively polished to a shiny, bright surface prior to straightening. This surface looks very similar to stainless steel and is very popular for its cosmetic appeal. A centreless grinding method is applied to Nitinol wire and tubes to achieve a bright surface Coatings Nitinol can be coated with polymers such as polyurethane and Teflon. Polyurethane extruded over Nitinol is common for cell phone antennas. Teflon extrusion and spray coating of Nitinol is becoming more common today.
  • 14. Joining to Nitinol Soldering: Sn-Ag solder can be used Welding: Laser, TIG, and resistance welding A Nitinol tube connector can be expanded either mechanically or by cooling it to martensite and deforming it. The Nitinol connector is then inserted over another element and allowed to return to austenite, causing it to clamp down on the element.
  • 15. Beneficial Properties of Ni Ti SMAs Ductility is improved Excellent corrosion resistance (comparable to 300 stainless steel) Stable transformation temperature High biocompatibility More recoverable motion Adding alloying element 1% change mechanical property and phase transformation temperature. Fe and Cr can added to lower the Transformation temperature
  • 16. Applications • Aero space • Space vehicle • Bio medical • Automobile • Actuators
  • 18. Thank you ……. Any queries ….????