Resonance structures represent different arrangements of electrons in a molecule that have the same positions of nuclei but different bonding patterns. Resonance contributes to the stability of molecules like benzene by delocalizing electrons across multiple equivalent structures. The actual structure of a molecule represented by resonance is a hybrid of the contributing structures, with bond lengths intermediate between single and double bonds. Delocalization of electrons is depicted using curved arrows between resonance structures.
This presentation describes the concept of Hyperconjugation in simple words, gives definition of hyperconjugation, explains why it is called as 'No bond Resonance' and gives the effects of hyperconjugation on the chemical properties of compounds: alkyl cations and their relative stability, alkyl radicals and their relative stability, alkenes and their relative stability, bond length, anomeric effect and Baker - Nathan effect.
Cyclohexane exists in different conformations viz chair, boat, twist boat and half chair. These conformations possess different energies. Therefore they differ in energy.
An organic species which has a carbon atom bearing only six electrons in its outermost shell and has a positive charge is called carbocation.
The positively charged carbon of carbocation is sp2 hybridized.
The unhybridized p-orbital remains vacant.
They are highly reactive and act as reaction intermediate.
They are also called carbonium ion.
This presentation describes the concept of Hyperconjugation in simple words, gives definition of hyperconjugation, explains why it is called as 'No bond Resonance' and gives the effects of hyperconjugation on the chemical properties of compounds: alkyl cations and their relative stability, alkyl radicals and their relative stability, alkenes and their relative stability, bond length, anomeric effect and Baker - Nathan effect.
Cyclohexane exists in different conformations viz chair, boat, twist boat and half chair. These conformations possess different energies. Therefore they differ in energy.
An organic species which has a carbon atom bearing only six electrons in its outermost shell and has a positive charge is called carbocation.
The positively charged carbon of carbocation is sp2 hybridized.
The unhybridized p-orbital remains vacant.
They are highly reactive and act as reaction intermediate.
They are also called carbonium ion.
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1. Resonance
• Resonance structures are a way of understanding
the positioning of electrons. This is a vital topic
for chemists, as understanding where electrons are
located within the molecule is the key to
understanding the molecules chemical behavior.
You can't really say anything about chemical
reactivity or chemical properties without knowing
what parts of the molecule are electron-rich
(containing a large density of electrons) and
which are electron-poor
2. RESONANCE
• Defination.
• When a compound can be represented by more
than one Lewis structure and actual structure is
hybrid of all structures, the compound is said to
possess Resonance
• OR
• The representation of structure of a molecule as a
weighted average of two or more hypothetical
structures, which only differ by the arrangement
of electrons but with same positions for atoms is
referred to as resonance.
3. EXAMPLES OF RESONANCE
STRUCTURES
• The following resonance structures can be
written for benzene which are hypothetically
possible due to delocalization of π electrons.
The Kekule structures have more weightage
than Dewar structures.
4. The actual structure of benzene is thus shown to be
the hybrid of these contributing structures. The
bond order of every C-C bond is 1.5 and hence the
every C-C bond length is reported to be same and
equals to 1.39 Ao, which is in between the bond
length values of C-C single bond (1.54 Ao) and
C=C double bond (1.20 Ao).
Due to resonance, benzene gets extra stability and
does not undergo electrophilic addition reactions.
However it shows electrophilic substitution
reactions. This phenomenon is known as
aromaticity.
5. Features of resonance:
• * The hypothetical structures with different
arrangement of electrons but with identical
positions for atoms are called resonance
structures or canonical forms or contributing
structures.
• * The resonance structures are only imaginary
and the actual structure of the molecule is
considered as the hybrid of all the valid
resonance structures.
6. Features of resonance
• * The resonance structures are formed (only on
paper) due to delocalization of electrons and
not by changing the positions of atoms.
• * The delocalization of electrons is shown
using curved arrows.
• * The energy of resonance hybrid is always
less than the energy of any of the contributing
resonance structure.
7. RULES OF RESONANCE
• The valid resonance structures must satisfy the
following rules:
• * They must be valid Lewis structures obeying
octet rule.
• E.g. Carbon or Nitrogen with five bonds is not
allowed.
• In the structure (II), the nitrogen atom violated
the octet. It has 10 electrons around it.
8.
9. * They should possess same number of electrons
and equal net charge.
* The number of unpaired electrons in them must
be same.
E.g. Following structure for butadiene is not valid.
10. STABILITY OF RESONANCE
STRUCTURE
• * The actual structure i.e., resonance hybrid of a
molecule has lower energy than any of the
contributing form and hence the resonance is a
stabilizing phenomenon.
• * Greater the number of contributing structures,
greater is the stability of the resonance hybrid.
• * All the structures do not contribute equally to
the hybrid.
• * Greater the stability of a resonance structure,
larger is its contribution to the resonance hybrid.
11. * The contributing structures that have atoms with
full octets are more stable than the ones with open
octets.
* The contributing structure with more covalent
bonds is more stable.
E.g. Among the following, the structure II is more
stable since all the atoms have octet configuration
and there are more covalent bonds.
12.
13. STABILITY
• * Resonance structures with fewer charges are
more stable than those with more charges.
• E.g. The second structure with two negative
charges is not only less stable.
14. RESONANCE EFFECT
• The increase in electron densinty at one
position with a coresponding decrease at
another position is called resonance effect
• It is symbolized by M or R.
• Negative resonance or mesomeric effect (-M
or -R)
• E.g. -NO2, Carbony group (C=O), -C≡N, -
COOH, -SO3H etc.
15. Positive resonance or mesomeric effect (+M or
+R): The groups show positive mesomeric
effect when they release electrons to the rest of
the molecule by delocalization. These groups
are denoted by +M or +R. Due to this effect, the
electron density on rest of the molecular entity
is increased.
E.g. -OH, -OR, -SH, -SR, -NH2, -NR2 etc.
16. +M or +R EXAMPLES
• 1-In phenol, the -OH group shows +M effect
due to delocalization of ione pair on oxygen
atom towards the ring. Thus the electron
density on benzene ring is increased
particularly on ortho and para positions.
17. 2-The -NH2 group in aniline also exhibits +R
effect. It releases electrons towards benzene ring
through delocalization. As a result, the electron
density on benzene ring increases particularly at
ortho and para positions. Thus aniline activates
the ring towards electrophilic substitution.
18. -M or –R EXAMPLES
• 1) The negative resonance effect (-R or -M) of
carbonyl group is shown below. It withdraws
electrons by delocalization of π electrons and
reduces the electron density particularly on 3rd
carbon.
19. 2) The negative mesomeric effect (-R or -M)
shown by cyanide group in acrylonitrile is
illustrated below. The electron density on third
carbon decreases due to delocalization of π
electrons towards cyanide group.
21. Benzyl bromide undergoes C-Br bond cleavage to generate the
benzyl cation A. Through resonance the positive charge can be
delocalised through the ring. Identify resonance structures C
and D and draw in the curly-arrows
Br
Br
A B C D
22. The 4-methoxybenzylic bromide A undergoes C-Br bond cleavage
much more easily to generate the benzyl cation B, than does the C-Br
bond in benzyl bromide in question 3. Indentify B and then draw in
the curly arrows that lead to the resonance structure C.
Br
OMe
Br
OMe
A B C