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International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395 -0056
Volume: 04 Issue: 02 | Feb -2017 www.irjet.net p-ISSN: 2395-0072
© 2017, IRJET | Impact Factor value: 5.181 | ISO 9001:2008 Certified Journal | Page 1020
REHABILITATION OF REINFORCED GEOPOLYMER CONCRETE BEAM
K.Santhosekumar1
1Student
Department of civil engineering
KLN College of information technology.
---------------------------------------------------------------------***---------------------------------------------------------------------
Abstract - The aim and scope of this project is to prepare
eco-friendly geopolymer RC beam with 100% replacement of
cement along with wrapping of oven dried fibre mat with
number of layers and achieving the required target mean
flexural strength of conventional concrete. This project
comprises material testing of ingredients for geopolymer
concrete such as Low Calcium Fly Ash, Metakaolin, Lime,
Alkaline liquids (sodium silicate+sodium hydroxide), Fine
Aggregate (natural sand) and coarse aggregates.At first, The
conventional ReinforcedConcretebeamofgradeM20iscasted
and testing of conventional RC beam for finding the load
carrying capacity and flexuralstrengthwasdoneafter28days
curing period. The report represents the comprehensive
summary of extensive studies conducted on fly ash based
geopolymer concrete. Test data are used to identify the effects
of salient factors that influence the properties of geopolymer
concrete in the fresh and hardened states. These results are
utilized to propose sample for the design of geopolymer
concrete mixtures.
Key Words: Low Calcium Fly Ash, Metakaolin, Lime,
Alkaline liquids (sodium silicate+sodium hydroxide)
1. INTRODUCTION
Concrete is the most abundant manmade material in the
world. One of the main ingredients in a normal concrete
mixture is Portland cement. However, the production of
cement is responsible for approximately 5% of the world’s
carbon dioxide emissions. Among the Green house gases
Carbon dioxide is the one which contributes about 65% for
climatic change in the environment. In order to create a
more sustainable world, engineers and scientists must
develop and put into use a greener building material. This is
unacceptable in a world where sustainable and green
building has become a major issue. This brings up a very
good question: Is there a cleaner, more efficient, more
reliable, and even stronger substitute to the concrete that is
currently used? The answer is geopolymer concrete.
1.1 GEOPOLYMER CONCRETE
Geopolymer concrete does not usePortlandcement;itusesa
highly abundant material called fly ash. Fly ash is a waste by
product of thermal power plant with high fineness (> OPC)
which produces an impermeable geopolymer concrete.
Geopolymer concrete is also much more durable that
ordinary concrete due to its resistance to corrosion.Itisalso
much stronger than ordinary concrete.There are two main
constituents of geopolymers, namely the source materials
and the alkaline liquids. The source materials for
geopolymers based on alumina-silicate should be rich in
silicon (Si) and aluminium (Al). These could be natural
minerals such as kaolinite, clays, etc. Alternatively, by-
product materials such as fly ash, silica fume, slag, rice-husk
ash, red mud, etc could be used as source materials. The
choice of the source materials for making geopolymers
depends on factors such as availability, cost, type of
application, and specific demand of the end users. The
alkaline liquids are from soluble alkali metals that are
usually sodium or potassium based. The most common
alkaline liquid used in geopolymerisationisa combination of
sodium hydroxide (NaOH) or potassium hydroxide (KOH)
and sodium silicate or potassium silicate. Low-calcium
(ASTM Class F) fly ash is preferred as a source material than
high-calcium (ASTM Class C) fly ash. Since class F fly ash is
preferred over class C due to a lower percentage of calcium.
Presence of calcium in elevated levels could hinder the
polymerization reaction and leads to flash set due to the
formation of calcium hydrate products.
1.2 COMPOSITION AND CREATION
Geopolymer concrete is made of up multiple ingredients.
Like normal concrete, about 75%-80% of the mass is made
of coarse and fine aggregates. An example of coarse
aggregate is crushed stone or gravel and an example of fine
aggregate is sand. Chemical admixtures such as air
entrainers or super plasticizers can be addedtotheconcrete
mixture so that its qualities can be adjusted to meet the
needs of the project. Air entrainers add air bubbles into the
mixture and super plasticizersreducetheamountof waterin
the mixture and allow it to be much more workable.
However, while ordinary concrete uses cement to bind the
aggregates together, geopolymer concrete mixtures use a
geopolymer paste. Geopolymer paste is created by
combining fly ash, which contains silicon and aluminum,
with a sodium hydroxide and sodiumsilicatesolution.Thisis
also known as water glass. The resulting reaction starts the
process of geopolymerization which leads to the creation of
a geopolymer.
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395 -0056
Volume: 04 Issue: 02 | Feb -2017 www.irjet.net p-ISSN: 2395-0072
© 2017, IRJET | Impact Factor value: 5.181 | ISO 9001:2008 Certified Journal | Page 1021
1.3 APPLICATION OF GEOPOLYMER CONCRETE
 Pre-cast concrete products: Structural and non-
structural members forbuildingsystemsand bridge
structures, Railway sleepers, Electric power poles,
Sewer system, and other products for
infrastructure.
 Waste containment/encapsulation.
 Road bases, marine structures.
 Geopolymer resins and binders.
 Fire-resistant materials, thermal insulation, foams.
2. MATERIALS USED
2.1 FLYASH
FLY ASH is consumed of the non-combustible mineral
portion of coal. When coal is consumed in a power plant, itis
first ground to the fineness of powder. Blown intothepower
plant’s boiler, the carbon is consumed leaving molten
particles rich in silica, alumina and calcium. These particles
solidify as microscopic, glassy spheres that are collected
from the power plant’s exhaust before they can “Fly” away-
hence the product’s name: FLY ASH. Geopolymer concrete
generally requires the use of Class F fly ash
Table -1: Physical / Mechanical properties of fly ash:
S.No Properties
Test Result Range Specified
Requirements
As Per Is:3821
(Part - I) -1966
1. Fineness–Specific
surface by Blainess
permeability method.
3267 – 6842 cm2 3200 cm2
minimum
2.
Reactivity
a. Lime reactivity
strength of
kg/cm2
b. Compressive
strength of
cement mortar
cubes at the age of
28 days
47.4 – 83.4 kg/cm2
80.4 – 94.5 kg/cm2
40 kg / cm2
minimum
Not less than 80
% of the
strength of
corresponding
plain cement
mortar cubes
3.
Soundness by autoclave 0.1 – 0.2 cm
0.02 – 0.07 cm
0.15 cm
maximum
0.8 cm
maximum
2.2 ALKALINE LIQUIDS
The most common alkaline liquid used in geopolymerization
is a combination of sodium hydroxide (NaOH) or potassium
hydroxide(KOH)and sodiumsilicateor potassiumsilicateto
form alkaline solution(NaOH + Na2Sio3).
2.3 NATURAL SAND
Sand (>0.07mm) is used as a fine aggregate in mortar and
concrete.
2.4 FINE AGGREGATE
Natural sand of size between 75µm - 4.75mm is used as fine
aggregate.
2.5 SUPER PLASTICIZER (CONPLAST SP-430)
Super plasticizers, also known as high rangewaterreducers,
are chemical admixtures used where well-dispersedparticle
suspension is required. The strength of concrete increases
when the water to cement ratio decreases.
2.6 LIME
In order to overcome the creep effect in geopolymer
concrete beam we introduce lime for curing in ambient
temperature with a percentage of 5% by the weight of total
fly ash.
2.7 METAKAOLIN
Metakaolin is a dehydroxylated form of the clay
mineral kaolinite. Rocks that are rich in kaolinite are known
as china clay or kaolin, traditionally used in the manufacture
of porcelain. The particle size of metakaolin is smaller
than cement particles, but not as fine as silica fume.
Table -2: Properties of Aggregates
Property Coarse Aggregate Fine Aggregate
20 mm 12.5 mm
Specific Gravity 2.60 2.60 2.58
Fineness modulus 6.55 6.55 4.165
3. MIX PROPORTION OF GEOPOLYMER CONCRETE
Density of G.P.C. = 2400 kg/m3
F.A. (30% of total aggregate) = 0.3×1848 = 555 kg/m3
C.A (70% of T.A) = 0.7× 1848 = 1293 kg/m3
Sodium silicate / sodium Hydroxide = 2.5 (assumed)
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395 -0056
Volume: 04 Issue: 02 | Feb -2017 www.irjet.net p-ISSN: 2395-0072
© 2017, IRJET | Impact Factor value: 5.181 | ISO 9001:2008 Certified Journal | Page 1022
Fine aggregate + coarse aggregate = 77% of 2400=1848 kg/
m3
2400 - Total aggregate = Fly ash + sodium Silicate +
sodium Hydroxide (alkaline solution)
Alkaline Liquid/ fly ash = 0.4 (assumed)
SIZE OF BEAM 150 mm X 230 mm X 2100 mm.
Table -3: Material required for one beam
Materials Quantity
Fly ash 25,71 Kg
metakaolin
2.86 Kg
Fine aggregate
40.20 Kg
Coarse aggregate
93.68 Kg
Sodium hydroxide
1090gm
Sodium silicate
(2.5 x 1090 gm + water)
4. MIXING PROCESS OF GEOPOLYMER CONCRETE
Chemical liquid reacts with the Si and Al atoms in the source
material (for example, low-calcium fly ash). Gel formation
(or polymerization), is assisted by applied heat, then Gel
binds the loose coarse aggregate, fine aggregate, and un-
reacted source material to give Geopolymer Concrete. Mix
Sodium Hydroxide flakesandwaterina designedproportion
and mix sodium silicate paste and water in a designed
proportion. Then, mix the above solutions and keep it for 24
hours. The above solution is mixed with fly ash, metakaolin
and aggregates to get geopolymer concrete.
Fig -1: Sand+Fly Ash+Metakaolin Fig -2: Alkaline Solution
Fig -3: Geo Polymer Concrete Beam
5. REINFORCEMENT ON RC BEAM
Mild steel rods of 2 no’s of 8mm diameter bars are provided
at the bottom and 2 no’s of 6mm diameter bars at the top
with stirrups of 6mm diameter at 150mm spacing.
Fig -4: Reinforcement Details
6. SPECIMEN DETAILS
Table -4: Specimen Details on RC Beams
Beam Dimensions (mm) Soffit Soffit + sides Total
Controlled
concrete
150 x 210 x 2100 1 1 2
Geo
polymer
concrete
150 x 210 x 2100 1 1 2
7. OVEN ROVEN GLASS FIBRE MAT
Oven roven glass fibres are used mainly in applications
where they offer a unique combinationofproperties,suchas
high specific strength combined with toughness and creep
resistance. The outstanding toughness of aramid is oftenthe
reason they are used over cheaper, stiffer or even stronger
fibre.
7.1 CHARACTERISTICS
 Good resistance to abrasion.
 Good resistance to organic solvents.
 High strength in axial tension.
 No melting point, degradation starts from 500°C.
 Low flammability.
 Good fabric integrity at elevated.
 Sensitive to acids and salts.
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395 -0056
Volume: 04 Issue: 02 | Feb -2017 www.irjet.net p-ISSN: 2395-0072
© 2017, IRJET | Impact Factor value: 5.181 | ISO 9001:2008 Certified Journal | Page 1023
8. EPOXY RESIN
Epoxy resins, also known as polyepoxides are a class of
reactive prepolymers and polymers which contain epoxide
groups. Epoxy resins may be reacted (cross-linked) either
with themselves through catalytic homopolymerisation, or
with a wide range of co-reactants including polyfunctional
amines, acids (and acid anhydrides), phenols, alcohols, and
thiols. These co-reactants are often referred to as hardeners
or curatives, and the cross-linking reaction is commonly
referred to as curing. Epoxy has a wide rangeofapplications,
including metal coatings, use in electronic and electrical
components, high tension electrical insulators, fibre-
reinforced plastic materials, and structural adhesives.
8.1 CURING ON EPOXY RESIN
Curing may be achieved by reacting an epoxy with itself
(homopolymerisation) or by forming a copolymer with
polyfunctional curatives or hardeners.In principle, any
molecule containing reactive hydrogen may react with the
epoxide groups of the epoxy resin. Common classes of
hardeners for epoxy resins include amines, acids, acid
anhydrides, phenols, alcohols and thiols. Relative reactivity
(lowest first) is approximately in the order:
Phenol < Anhydride < Aromatic amine < Cycloaliphatic
Amine < Aliphatic Amine < Thiol.
9. RESULT AND DISCUSSIONS
9.1 ULTIMATE LOAD AND ULTIMATE MOMENT
Ultimate load and Ultimate moment of Geopolymer and
Conventional RC beam is determined for M20 grade. The
beam mould of size 1500mm X 230mm X 2100mm is used.
After curing of 28 days, all the RC beams are tested using
universal testing machine of capacity 40 tones. The ultimate
load taken by each beam (both conventional and
Geopolymer concrete)
Table -5: Ultimate Load and Ultimate Moment
Beam Beam ID Ultimate load
(KN)
Ultimate moment
(KNm)
Conventional
beam without
fibre
CRCB -0 62.7 18.81
Conventional
beam with
fibre (soffit)
CRCB –S 65.3 19.59
Conventional
beam with
fibre (soffit +
U)
CRCB –S+U 75.4 22.62
Geo polymer
beam without
GPRC -0 63.64 19.09
fibre
Geo polymer
beam with
fibre (soffit)
GPRC –S 67.17 20.151
Geo polymer
beam with
fibre (soffit +
U)
GPRC–S+U 79.92 23.98
Chart -1: ultimate load and ultimate moment
This is evident that the yield load and yield moment of
Conventional and Geopolymer RC beams with wrapping
(soffit or U) improves the behavior of beam compared with
conventional and Geopolymer RC beams without wrapping.
9.2 YIELD LOAD AND YIELD MOMENT
Yield load and Yield moment of Geopolymer and
Conventional RC beam is determined for M20 grade. The
Yield load taken by each beam (both conventional and
Geopolymer concrete).
Table -6: Yield Load and Yield Moment
Beam Beam ID Yield load (KN) Yield moment (KNm)
Conventional
beam without
fibre
CRCB -0 40 12
Conventional
beam with fibre
(soffit)
CRCB –S 42 12.6
Conventional
beam with fibre
(soffit + U)
CRCB –S+U 48 14.4
Geo polymer
beam without
fibre
GPRC -0 41 12.3
Geo polymer
beam with fibre
(soffit)
GPRC –S 43 12.9
Geo polymer
beam with fibre
(soffit + U)
GPRC–S+U 51.15 15.345
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395 -0056
Volume: 04 Issue: 02 | Feb -2017 www.irjet.net p-ISSN: 2395-0072
© 2017, IRJET | Impact Factor value: 5.181 | ISO 9001:2008 Certified Journal | Page 1024
Chart -2: Yield Load and Yield Moment
This is evident that the yield load and yield moment of
Conventional and Geopolymer RC beams with wrapping
(soffit or U) improves the behavior of beam compared with
conventional and Geopolymer RC beams without wrapping.
9.3 WORKING LOAD
Working load and Working moment of Geopolymer and
Conventional RC beam is determined for M20 grade. The
Working load taken by each beam (both conventional and
Geopolymer concrete).
Table -6: Working Load
Beam Beam ID Working load (KN)
Conventional beam
without fibre
CRCB -0 32.5
Conventional beam with
fibre (soffit)
CRCB –S 35.75
Conventional beam with
fibre (soffit + U)
CRCB –S+U 36.95
Geo polymer beam
without fibre
GPRC -0 34
Geo polymer beam with
fibre (soffit)
GPRC –S 36.27
Geo polymer beam with
fibre (soffit + U)
GPRC–S+U 39.17
Chart -3: Working Load
This is evident that the Working load or Initial crack load of
Conventional and Geopolymer RC beams with wrapping
(soffit or U) improves the behavior of beam compared with
conventional and Geopolymer RC beams without wrapping.
9.4 FLEXURAL STRENGTH
Flexural strength of Geopolymer and Conventional RC beam
is determined for M20 grade. After 28 days curing, all theRC
beams are tested for flexural strengthusinguniversal testing
machine of capacity 40 tones. The maximum flexural
strength taken by each beam (both conventional and
geopolymer).
Table -7: Flexural Strength
Beam Beam ID Ultimate load
(KN)
Flexural strength
(N/mm2)
Conventional
beam without
fibre
CRCB -0 62.7 14.2
Conventional
beam with fibre
(soffit)
CRCB –S 65.3 14.81
Conventional
beam with fibre
(soffit + U)
CRCB –S+U 75.4 17.10
Geo polymer
beam without
fibre
GPRC -0 63.64 14.43
Geo polymer
beam with fibre
(soffit)
GPRC –S 67.17 15.24
Geo polymer
beam with fibre
(soffit + U)
GPRC–S+U 79.92 18.13
Chart -4: Flexural Strength
This it is evident that the flexural strength of Conventional
and Geopolymer RC beams with wrapping (soffit and U)
improves the behavior of beam comparedwithconventional
and Geopolymer RC beams without wrapping.
9.5 DISPLACEMENT
Displacement of both conventional and Geopolymer RC
beam with fiber (soffit and U) and without fiber are noted
down. Displacement of all RC Beams are shown below,
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395 -0056
Volume: 04 Issue: 02 | Feb -2017 www.irjet.net p-ISSN: 2395-0072
© 2017, IRJET | Impact Factor value: 5.181 | ISO 9001:2008 Certified Journal | Page 1025
Chart -5: Displacement of RC Beams
9.6 MODE OF FAILURE
Table -8: Mode of Failure
Beam Mode of failure
Conventional beam without fibre Crushing of concrete
Conventional beam with fibre (soffit)
Delamination of fiber
Conventional beam with fibre (soffit +
U)
Tearing of fiber
Geo polymer beam without fibre
Crushing of concrete
Geo polymer beam with fibre (soffit)
Delamination of fiber
Geo polymer beam with fibre (soffit +
U)
Tearing of fiber
9.7 TESTING ON RC BEAMS
Fig -4: Testing Of Beam With Fibre (Soffit), (Soffit+ U)
Wrapping
Fig -5: Crack Patterns Observed At Ultimate Load in
Conventional Beam with Fiber at Soffit
9.8 ECONOMIC BENEFITS OF GEOPOLYMER
CONCRETE
Heat cured low calcium fly ash based geo polymer concrete
offers several economic benefits over Portland cement
concrete. The price of one ton of fly ash is only a small
fraction of the price of one ton of Portland cement.
Therefore, after allowing the price of alkalineliquidsneeded
to make the geo polymer concrete, the price of fly ash based
geo polymer concrete is estimated to be about 10 to 30%
cheaper than that of Portland cement concrete. In addition
the appropriate usage of one ton of fly ash earns
approximately one carbon-credit that has a redemption
value of about 10 to 20 euros. Based on the information
given in this report, one ton of low calcium fly ash can be
utilized to manufacture approximately 2.5 cubic meters of
high quality fly ash based geo polymer concrete, and hence
earn monetary benefits through carbon trade. Furthermore,
the very little drying shrinkage, the low creep, the excellent
resistance to sulfate attack, and good acid resistance offered
by the heat cured low calcium fly ash based geo polymer
concrete may yield additional economic benefits when it is
utilized in infrastructure applications.
10 CONCLUDING REMARKS
10.1 CONCLUSION
By introducing reinforcementandpastingtheglassfibre mat
we can achieve improved flexural strength.
 The load deflection characteristics of Conventional
RC and Geopolymer RC beams are observedsimilar.
 Deflection of GPRC beam under ultimate load isless
when compared to CRC beam while it is
rehabilitated with glass fibre mat.
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395 -0056
Volume: 04 Issue: 02 | Feb -2017 www.irjet.net p-ISSN: 2395-0072
© 2017, IRJET | Impact Factor value: 5.181 | ISO 9001:2008 Certified Journal | Page 1026
 Bonding strength between steel and geopolymer
concrete shows very good performance.
 The load carrying capacity and flexural strength of
GPRC beam is 1 - 2% more when compared to
CRC beam.
 The load carrying capacity and flexural strength of
GPRC beam with glass fiber at soffit gives 2 - 6%
more when compared with CRC beam with glass
fiber at soffit.
 The load carrying capacity and flexural strength of
GPRC beam with glass fiber at soffit and sides gives
3 - 8% more when compared with CRC beam with
glass fiber at soffit and sides.
REFERENCES
[1] ACI Committee 232 (2004). Use of Fly Ash in Concrete.
Farmington Hills, Michigan, USA, American Concrete
Institute: 41.
[2] Davidovits, J. (1988b). Geopolymer Chemistry and
Properties. Paper presented attheGeopolymer’88,First
European Conference on Soft Mineralurgy, Compiegne,
France.
[3] Gourley, J. T. (2003). Geopolymers; Opportunities for
Environmentally Friendly Construction Materials.
Materials 2003 Conference: Adaptive Materials for a
Modern Society, Sydney, Institute of Materials
Engineering Australia.
[4] Hardjito, D. and Rangan, B. V. (2005) Development and
Properties of Low-Calcium Fly Ash-based Geopolymer
Concrete, Research Report GC1, Faculty of Engineering,
Curtin University of Technology, Perth.
[5] Hardjito, D., Wallah, S. E., & Rangan, B. V. (2002a).
Research into Engineering Properties of Geopolymer
Concrete. Paper presented at the Geopolymer 2002
International Conference, Melbourne.
[6] H. H. Yang: ‘Aramid fibre’, 2005, New York, John Wiley&
Sons.
[7] DuPont, 2008, Properties and Processing of DuPont
Aramid Yarn for Mechanical Rubber Goods.
[8] Blascu V., 2009 Aramid Fibers for Technical Textile I.
Between Structure and Properties.

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Rehabilitation Of Reinforced Geopolymer Concrete Beam

  • 1. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395 -0056 Volume: 04 Issue: 02 | Feb -2017 www.irjet.net p-ISSN: 2395-0072 © 2017, IRJET | Impact Factor value: 5.181 | ISO 9001:2008 Certified Journal | Page 1020 REHABILITATION OF REINFORCED GEOPOLYMER CONCRETE BEAM K.Santhosekumar1 1Student Department of civil engineering KLN College of information technology. ---------------------------------------------------------------------***--------------------------------------------------------------------- Abstract - The aim and scope of this project is to prepare eco-friendly geopolymer RC beam with 100% replacement of cement along with wrapping of oven dried fibre mat with number of layers and achieving the required target mean flexural strength of conventional concrete. This project comprises material testing of ingredients for geopolymer concrete such as Low Calcium Fly Ash, Metakaolin, Lime, Alkaline liquids (sodium silicate+sodium hydroxide), Fine Aggregate (natural sand) and coarse aggregates.At first, The conventional ReinforcedConcretebeamofgradeM20iscasted and testing of conventional RC beam for finding the load carrying capacity and flexuralstrengthwasdoneafter28days curing period. The report represents the comprehensive summary of extensive studies conducted on fly ash based geopolymer concrete. Test data are used to identify the effects of salient factors that influence the properties of geopolymer concrete in the fresh and hardened states. These results are utilized to propose sample for the design of geopolymer concrete mixtures. Key Words: Low Calcium Fly Ash, Metakaolin, Lime, Alkaline liquids (sodium silicate+sodium hydroxide) 1. INTRODUCTION Concrete is the most abundant manmade material in the world. One of the main ingredients in a normal concrete mixture is Portland cement. However, the production of cement is responsible for approximately 5% of the world’s carbon dioxide emissions. Among the Green house gases Carbon dioxide is the one which contributes about 65% for climatic change in the environment. In order to create a more sustainable world, engineers and scientists must develop and put into use a greener building material. This is unacceptable in a world where sustainable and green building has become a major issue. This brings up a very good question: Is there a cleaner, more efficient, more reliable, and even stronger substitute to the concrete that is currently used? The answer is geopolymer concrete. 1.1 GEOPOLYMER CONCRETE Geopolymer concrete does not usePortlandcement;itusesa highly abundant material called fly ash. Fly ash is a waste by product of thermal power plant with high fineness (> OPC) which produces an impermeable geopolymer concrete. Geopolymer concrete is also much more durable that ordinary concrete due to its resistance to corrosion.Itisalso much stronger than ordinary concrete.There are two main constituents of geopolymers, namely the source materials and the alkaline liquids. The source materials for geopolymers based on alumina-silicate should be rich in silicon (Si) and aluminium (Al). These could be natural minerals such as kaolinite, clays, etc. Alternatively, by- product materials such as fly ash, silica fume, slag, rice-husk ash, red mud, etc could be used as source materials. The choice of the source materials for making geopolymers depends on factors such as availability, cost, type of application, and specific demand of the end users. The alkaline liquids are from soluble alkali metals that are usually sodium or potassium based. The most common alkaline liquid used in geopolymerisationisa combination of sodium hydroxide (NaOH) or potassium hydroxide (KOH) and sodium silicate or potassium silicate. Low-calcium (ASTM Class F) fly ash is preferred as a source material than high-calcium (ASTM Class C) fly ash. Since class F fly ash is preferred over class C due to a lower percentage of calcium. Presence of calcium in elevated levels could hinder the polymerization reaction and leads to flash set due to the formation of calcium hydrate products. 1.2 COMPOSITION AND CREATION Geopolymer concrete is made of up multiple ingredients. Like normal concrete, about 75%-80% of the mass is made of coarse and fine aggregates. An example of coarse aggregate is crushed stone or gravel and an example of fine aggregate is sand. Chemical admixtures such as air entrainers or super plasticizers can be addedtotheconcrete mixture so that its qualities can be adjusted to meet the needs of the project. Air entrainers add air bubbles into the mixture and super plasticizersreducetheamountof waterin the mixture and allow it to be much more workable. However, while ordinary concrete uses cement to bind the aggregates together, geopolymer concrete mixtures use a geopolymer paste. Geopolymer paste is created by combining fly ash, which contains silicon and aluminum, with a sodium hydroxide and sodiumsilicatesolution.Thisis also known as water glass. The resulting reaction starts the process of geopolymerization which leads to the creation of a geopolymer.
  • 2. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395 -0056 Volume: 04 Issue: 02 | Feb -2017 www.irjet.net p-ISSN: 2395-0072 © 2017, IRJET | Impact Factor value: 5.181 | ISO 9001:2008 Certified Journal | Page 1021 1.3 APPLICATION OF GEOPOLYMER CONCRETE  Pre-cast concrete products: Structural and non- structural members forbuildingsystemsand bridge structures, Railway sleepers, Electric power poles, Sewer system, and other products for infrastructure.  Waste containment/encapsulation.  Road bases, marine structures.  Geopolymer resins and binders.  Fire-resistant materials, thermal insulation, foams. 2. MATERIALS USED 2.1 FLYASH FLY ASH is consumed of the non-combustible mineral portion of coal. When coal is consumed in a power plant, itis first ground to the fineness of powder. Blown intothepower plant’s boiler, the carbon is consumed leaving molten particles rich in silica, alumina and calcium. These particles solidify as microscopic, glassy spheres that are collected from the power plant’s exhaust before they can “Fly” away- hence the product’s name: FLY ASH. Geopolymer concrete generally requires the use of Class F fly ash Table -1: Physical / Mechanical properties of fly ash: S.No Properties Test Result Range Specified Requirements As Per Is:3821 (Part - I) -1966 1. Fineness–Specific surface by Blainess permeability method. 3267 – 6842 cm2 3200 cm2 minimum 2. Reactivity a. Lime reactivity strength of kg/cm2 b. Compressive strength of cement mortar cubes at the age of 28 days 47.4 – 83.4 kg/cm2 80.4 – 94.5 kg/cm2 40 kg / cm2 minimum Not less than 80 % of the strength of corresponding plain cement mortar cubes 3. Soundness by autoclave 0.1 – 0.2 cm 0.02 – 0.07 cm 0.15 cm maximum 0.8 cm maximum 2.2 ALKALINE LIQUIDS The most common alkaline liquid used in geopolymerization is a combination of sodium hydroxide (NaOH) or potassium hydroxide(KOH)and sodiumsilicateor potassiumsilicateto form alkaline solution(NaOH + Na2Sio3). 2.3 NATURAL SAND Sand (>0.07mm) is used as a fine aggregate in mortar and concrete. 2.4 FINE AGGREGATE Natural sand of size between 75µm - 4.75mm is used as fine aggregate. 2.5 SUPER PLASTICIZER (CONPLAST SP-430) Super plasticizers, also known as high rangewaterreducers, are chemical admixtures used where well-dispersedparticle suspension is required. The strength of concrete increases when the water to cement ratio decreases. 2.6 LIME In order to overcome the creep effect in geopolymer concrete beam we introduce lime for curing in ambient temperature with a percentage of 5% by the weight of total fly ash. 2.7 METAKAOLIN Metakaolin is a dehydroxylated form of the clay mineral kaolinite. Rocks that are rich in kaolinite are known as china clay or kaolin, traditionally used in the manufacture of porcelain. The particle size of metakaolin is smaller than cement particles, but not as fine as silica fume. Table -2: Properties of Aggregates Property Coarse Aggregate Fine Aggregate 20 mm 12.5 mm Specific Gravity 2.60 2.60 2.58 Fineness modulus 6.55 6.55 4.165 3. MIX PROPORTION OF GEOPOLYMER CONCRETE Density of G.P.C. = 2400 kg/m3 F.A. (30% of total aggregate) = 0.3×1848 = 555 kg/m3 C.A (70% of T.A) = 0.7× 1848 = 1293 kg/m3 Sodium silicate / sodium Hydroxide = 2.5 (assumed)
  • 3. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395 -0056 Volume: 04 Issue: 02 | Feb -2017 www.irjet.net p-ISSN: 2395-0072 © 2017, IRJET | Impact Factor value: 5.181 | ISO 9001:2008 Certified Journal | Page 1022 Fine aggregate + coarse aggregate = 77% of 2400=1848 kg/ m3 2400 - Total aggregate = Fly ash + sodium Silicate + sodium Hydroxide (alkaline solution) Alkaline Liquid/ fly ash = 0.4 (assumed) SIZE OF BEAM 150 mm X 230 mm X 2100 mm. Table -3: Material required for one beam Materials Quantity Fly ash 25,71 Kg metakaolin 2.86 Kg Fine aggregate 40.20 Kg Coarse aggregate 93.68 Kg Sodium hydroxide 1090gm Sodium silicate (2.5 x 1090 gm + water) 4. MIXING PROCESS OF GEOPOLYMER CONCRETE Chemical liquid reacts with the Si and Al atoms in the source material (for example, low-calcium fly ash). Gel formation (or polymerization), is assisted by applied heat, then Gel binds the loose coarse aggregate, fine aggregate, and un- reacted source material to give Geopolymer Concrete. Mix Sodium Hydroxide flakesandwaterina designedproportion and mix sodium silicate paste and water in a designed proportion. Then, mix the above solutions and keep it for 24 hours. The above solution is mixed with fly ash, metakaolin and aggregates to get geopolymer concrete. Fig -1: Sand+Fly Ash+Metakaolin Fig -2: Alkaline Solution Fig -3: Geo Polymer Concrete Beam 5. REINFORCEMENT ON RC BEAM Mild steel rods of 2 no’s of 8mm diameter bars are provided at the bottom and 2 no’s of 6mm diameter bars at the top with stirrups of 6mm diameter at 150mm spacing. Fig -4: Reinforcement Details 6. SPECIMEN DETAILS Table -4: Specimen Details on RC Beams Beam Dimensions (mm) Soffit Soffit + sides Total Controlled concrete 150 x 210 x 2100 1 1 2 Geo polymer concrete 150 x 210 x 2100 1 1 2 7. OVEN ROVEN GLASS FIBRE MAT Oven roven glass fibres are used mainly in applications where they offer a unique combinationofproperties,suchas high specific strength combined with toughness and creep resistance. The outstanding toughness of aramid is oftenthe reason they are used over cheaper, stiffer or even stronger fibre. 7.1 CHARACTERISTICS  Good resistance to abrasion.  Good resistance to organic solvents.  High strength in axial tension.  No melting point, degradation starts from 500°C.  Low flammability.  Good fabric integrity at elevated.  Sensitive to acids and salts.
  • 4. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395 -0056 Volume: 04 Issue: 02 | Feb -2017 www.irjet.net p-ISSN: 2395-0072 © 2017, IRJET | Impact Factor value: 5.181 | ISO 9001:2008 Certified Journal | Page 1023 8. EPOXY RESIN Epoxy resins, also known as polyepoxides are a class of reactive prepolymers and polymers which contain epoxide groups. Epoxy resins may be reacted (cross-linked) either with themselves through catalytic homopolymerisation, or with a wide range of co-reactants including polyfunctional amines, acids (and acid anhydrides), phenols, alcohols, and thiols. These co-reactants are often referred to as hardeners or curatives, and the cross-linking reaction is commonly referred to as curing. Epoxy has a wide rangeofapplications, including metal coatings, use in electronic and electrical components, high tension electrical insulators, fibre- reinforced plastic materials, and structural adhesives. 8.1 CURING ON EPOXY RESIN Curing may be achieved by reacting an epoxy with itself (homopolymerisation) or by forming a copolymer with polyfunctional curatives or hardeners.In principle, any molecule containing reactive hydrogen may react with the epoxide groups of the epoxy resin. Common classes of hardeners for epoxy resins include amines, acids, acid anhydrides, phenols, alcohols and thiols. Relative reactivity (lowest first) is approximately in the order: Phenol < Anhydride < Aromatic amine < Cycloaliphatic Amine < Aliphatic Amine < Thiol. 9. RESULT AND DISCUSSIONS 9.1 ULTIMATE LOAD AND ULTIMATE MOMENT Ultimate load and Ultimate moment of Geopolymer and Conventional RC beam is determined for M20 grade. The beam mould of size 1500mm X 230mm X 2100mm is used. After curing of 28 days, all the RC beams are tested using universal testing machine of capacity 40 tones. The ultimate load taken by each beam (both conventional and Geopolymer concrete) Table -5: Ultimate Load and Ultimate Moment Beam Beam ID Ultimate load (KN) Ultimate moment (KNm) Conventional beam without fibre CRCB -0 62.7 18.81 Conventional beam with fibre (soffit) CRCB –S 65.3 19.59 Conventional beam with fibre (soffit + U) CRCB –S+U 75.4 22.62 Geo polymer beam without GPRC -0 63.64 19.09 fibre Geo polymer beam with fibre (soffit) GPRC –S 67.17 20.151 Geo polymer beam with fibre (soffit + U) GPRC–S+U 79.92 23.98 Chart -1: ultimate load and ultimate moment This is evident that the yield load and yield moment of Conventional and Geopolymer RC beams with wrapping (soffit or U) improves the behavior of beam compared with conventional and Geopolymer RC beams without wrapping. 9.2 YIELD LOAD AND YIELD MOMENT Yield load and Yield moment of Geopolymer and Conventional RC beam is determined for M20 grade. The Yield load taken by each beam (both conventional and Geopolymer concrete). Table -6: Yield Load and Yield Moment Beam Beam ID Yield load (KN) Yield moment (KNm) Conventional beam without fibre CRCB -0 40 12 Conventional beam with fibre (soffit) CRCB –S 42 12.6 Conventional beam with fibre (soffit + U) CRCB –S+U 48 14.4 Geo polymer beam without fibre GPRC -0 41 12.3 Geo polymer beam with fibre (soffit) GPRC –S 43 12.9 Geo polymer beam with fibre (soffit + U) GPRC–S+U 51.15 15.345
  • 5. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395 -0056 Volume: 04 Issue: 02 | Feb -2017 www.irjet.net p-ISSN: 2395-0072 © 2017, IRJET | Impact Factor value: 5.181 | ISO 9001:2008 Certified Journal | Page 1024 Chart -2: Yield Load and Yield Moment This is evident that the yield load and yield moment of Conventional and Geopolymer RC beams with wrapping (soffit or U) improves the behavior of beam compared with conventional and Geopolymer RC beams without wrapping. 9.3 WORKING LOAD Working load and Working moment of Geopolymer and Conventional RC beam is determined for M20 grade. The Working load taken by each beam (both conventional and Geopolymer concrete). Table -6: Working Load Beam Beam ID Working load (KN) Conventional beam without fibre CRCB -0 32.5 Conventional beam with fibre (soffit) CRCB –S 35.75 Conventional beam with fibre (soffit + U) CRCB –S+U 36.95 Geo polymer beam without fibre GPRC -0 34 Geo polymer beam with fibre (soffit) GPRC –S 36.27 Geo polymer beam with fibre (soffit + U) GPRC–S+U 39.17 Chart -3: Working Load This is evident that the Working load or Initial crack load of Conventional and Geopolymer RC beams with wrapping (soffit or U) improves the behavior of beam compared with conventional and Geopolymer RC beams without wrapping. 9.4 FLEXURAL STRENGTH Flexural strength of Geopolymer and Conventional RC beam is determined for M20 grade. After 28 days curing, all theRC beams are tested for flexural strengthusinguniversal testing machine of capacity 40 tones. The maximum flexural strength taken by each beam (both conventional and geopolymer). Table -7: Flexural Strength Beam Beam ID Ultimate load (KN) Flexural strength (N/mm2) Conventional beam without fibre CRCB -0 62.7 14.2 Conventional beam with fibre (soffit) CRCB –S 65.3 14.81 Conventional beam with fibre (soffit + U) CRCB –S+U 75.4 17.10 Geo polymer beam without fibre GPRC -0 63.64 14.43 Geo polymer beam with fibre (soffit) GPRC –S 67.17 15.24 Geo polymer beam with fibre (soffit + U) GPRC–S+U 79.92 18.13 Chart -4: Flexural Strength This it is evident that the flexural strength of Conventional and Geopolymer RC beams with wrapping (soffit and U) improves the behavior of beam comparedwithconventional and Geopolymer RC beams without wrapping. 9.5 DISPLACEMENT Displacement of both conventional and Geopolymer RC beam with fiber (soffit and U) and without fiber are noted down. Displacement of all RC Beams are shown below,
  • 6. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395 -0056 Volume: 04 Issue: 02 | Feb -2017 www.irjet.net p-ISSN: 2395-0072 © 2017, IRJET | Impact Factor value: 5.181 | ISO 9001:2008 Certified Journal | Page 1025 Chart -5: Displacement of RC Beams 9.6 MODE OF FAILURE Table -8: Mode of Failure Beam Mode of failure Conventional beam without fibre Crushing of concrete Conventional beam with fibre (soffit) Delamination of fiber Conventional beam with fibre (soffit + U) Tearing of fiber Geo polymer beam without fibre Crushing of concrete Geo polymer beam with fibre (soffit) Delamination of fiber Geo polymer beam with fibre (soffit + U) Tearing of fiber 9.7 TESTING ON RC BEAMS Fig -4: Testing Of Beam With Fibre (Soffit), (Soffit+ U) Wrapping Fig -5: Crack Patterns Observed At Ultimate Load in Conventional Beam with Fiber at Soffit 9.8 ECONOMIC BENEFITS OF GEOPOLYMER CONCRETE Heat cured low calcium fly ash based geo polymer concrete offers several economic benefits over Portland cement concrete. The price of one ton of fly ash is only a small fraction of the price of one ton of Portland cement. Therefore, after allowing the price of alkalineliquidsneeded to make the geo polymer concrete, the price of fly ash based geo polymer concrete is estimated to be about 10 to 30% cheaper than that of Portland cement concrete. In addition the appropriate usage of one ton of fly ash earns approximately one carbon-credit that has a redemption value of about 10 to 20 euros. Based on the information given in this report, one ton of low calcium fly ash can be utilized to manufacture approximately 2.5 cubic meters of high quality fly ash based geo polymer concrete, and hence earn monetary benefits through carbon trade. Furthermore, the very little drying shrinkage, the low creep, the excellent resistance to sulfate attack, and good acid resistance offered by the heat cured low calcium fly ash based geo polymer concrete may yield additional economic benefits when it is utilized in infrastructure applications. 10 CONCLUDING REMARKS 10.1 CONCLUSION By introducing reinforcementandpastingtheglassfibre mat we can achieve improved flexural strength.  The load deflection characteristics of Conventional RC and Geopolymer RC beams are observedsimilar.  Deflection of GPRC beam under ultimate load isless when compared to CRC beam while it is rehabilitated with glass fibre mat.
  • 7. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395 -0056 Volume: 04 Issue: 02 | Feb -2017 www.irjet.net p-ISSN: 2395-0072 © 2017, IRJET | Impact Factor value: 5.181 | ISO 9001:2008 Certified Journal | Page 1026  Bonding strength between steel and geopolymer concrete shows very good performance.  The load carrying capacity and flexural strength of GPRC beam is 1 - 2% more when compared to CRC beam.  The load carrying capacity and flexural strength of GPRC beam with glass fiber at soffit gives 2 - 6% more when compared with CRC beam with glass fiber at soffit.  The load carrying capacity and flexural strength of GPRC beam with glass fiber at soffit and sides gives 3 - 8% more when compared with CRC beam with glass fiber at soffit and sides. REFERENCES [1] ACI Committee 232 (2004). Use of Fly Ash in Concrete. Farmington Hills, Michigan, USA, American Concrete Institute: 41. [2] Davidovits, J. (1988b). Geopolymer Chemistry and Properties. Paper presented attheGeopolymer’88,First European Conference on Soft Mineralurgy, Compiegne, France. [3] Gourley, J. T. (2003). Geopolymers; Opportunities for Environmentally Friendly Construction Materials. Materials 2003 Conference: Adaptive Materials for a Modern Society, Sydney, Institute of Materials Engineering Australia. [4] Hardjito, D. and Rangan, B. V. (2005) Development and Properties of Low-Calcium Fly Ash-based Geopolymer Concrete, Research Report GC1, Faculty of Engineering, Curtin University of Technology, Perth. [5] Hardjito, D., Wallah, S. E., & Rangan, B. V. (2002a). Research into Engineering Properties of Geopolymer Concrete. Paper presented at the Geopolymer 2002 International Conference, Melbourne. [6] H. H. Yang: ‘Aramid fibre’, 2005, New York, John Wiley& Sons. [7] DuPont, 2008, Properties and Processing of DuPont Aramid Yarn for Mechanical Rubber Goods. [8] Blascu V., 2009 Aramid Fibers for Technical Textile I. Between Structure and Properties.