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Magnetic Properties 
Iron single crystal photomicrographs 
magnetic domains change shape as a 
magnetic field (H) is applied. 
domains favorably oriented with the field 
grow at the expense of the unfavorably 
oriented domains.
Forces can be represented by imaginary lines grouped as fields 
c18f01 
Basic Concepts 
Magnetic forces appear when moving charges 
Magnetic field lines of force around a current loop and a bar magnet.
MAGNETIC DIPOLES 
The magnetic moment represented by a vector
c18f03 
Magnetic Field Vectors 
magnetic field strength (H) & magnetic flux density (B) 
Magnetic flux density 
H = B  
B = H 0 0  
relative permeability 
 
 
0 
r = 
 
magnetization 
= + 0 0B  H  M 
M = H m  
magnetic susceptibility 
= -1 m r   
NI 
l 
Magnetic field strengthH =
Origins of Magnetic Moments: 
Responds to quantum mechanics laws 
Two main contributions: (a) an orbiting electron and (b) electron spin. 
Bohr magneton (B) 
Most fundamental magnetic moment 
B = ±9.27x10-24 A-m2 
The spin is an 
intrinsic 
property of the 
electron and it 
is not due to its 
rotation
c18f05 
18.3 Diamagnetism and Paramagnetism 
Diamagnetic material 
in the presence of a field, dipoles 
are induced and aligned opposite 
to the field direction. 
Paramagnetic material
The flux density B versus the magnetic field 
strength H for diamagnetic and paramagnetic 
materials. 
 
B = 0H + 0M = 0H + 0mH 
 
 = 0(1 + m)
FERROMAGNETISM 
mutual alignment of atomic 
dipoles 
even in the absence of an external 
magnetic field. 
coupling forces align the magnetic 
spins 
B H M 
=  + 
 
 
 
0 0 
B M 
0 
Domains with mutual spin alignment 
B grows up to a saturation magnetization Ms with a saturation flux 
Bs = Matom × Natoms (average moment per atom times density of atoms) 
Matom = 2.22B, 1.72B, 0.60B for Fe, Co, Ni, respectively
1986: superconductivity 
discovered in layered 
compound La2-xBaxCuO4 
with a transition T much 
higher than expected. 
Little was known about 
copper oxides 
c18f08 
Antiferromagnetism & Ferrimagnetism 
ANTIFERROMAGNETISM 
Antiparallel alignment of spin 
magnetic moments for 
antiferromagnetic manganese 
oxide (MnO) 
At low T 
Above the Neel temperature they 
become paramagnetic 
Parent materials, La2CuO4, and YBa2Cu3O6, 
demonstrated that the CuO2 planes exhibit 
antiferromagnetic order. 
This work initiated a continuing exploration 
of magnetic excitations in copper-oxide 
superconductors, crucial to the mechanism 
of high-temperature superconductivity.
FERRIMAGNETISM 
spin magnetic moment 
configuration for Fe2+ and Fe3+ ions 
in Fe3O4. Above the Curie 
temperature becomes 
paramagnetic
18tf03
18.6 The Influence of Temperature on magnetic Behavior 
TC: Curie temperature (ferromagnetic, ferrimagnetic) 
TN: Neel temperature (antiferromagnetic) 
material become paramagnetic
c18f11 
18.7 Domains and Hysteresis 
Domains in a ferromagnetic or ferrimagnetic 
material; arrows represent atomic magnetic 
dipoles. 
Within each domain, all dipoles are aligned, 
whereas the direction of alignment varies from 
one domain to another. 
Gradual change in magnetic dipole 
orientation across a domain wall.
c18f13 
B versus H 
ferromagnetic or 
ferrimagnetic material 
initially unmagnetized 
Domain configurations 
during several stages of 
magnetization 
Saturation flux density, Bs 
Magnetization, Ms, 
initial permeability i
Magnetic flux density 
versus magnetic field 
strength 
ferromagnetic material 
subjected to forward and 
reverse saturations (S & S’). 
hysteresis loop (red) 
initial magnetization (blue) 
remanence, Br 
coercive force, Hc
Comparison magnetic versus nonmagnetic
Superconductivity 
Temperature 
dependence of the electrical resistivity 
for normally conducting and 
superconducting materials in the 
vicinity of 0 K.
Critical temperature, 
current density, and magnetic 
field boundary separating 
superconducting and normal 
conducting states (schematic).
Representation of 
the Meissner effect. 
While in the superconducting state, a body of 
material (circle) excludes a magnetic field 
(arrows) from its interior. 
The magnetic field penetrates the same 
body of material once it becomes 
normally conductive.
SUMMARY 
• A magnetic field can be produced by: 
--putting a current through a coil. 
• Magnetic induction: 
--occurs when a material is subjected to a magnetic field. 
--is a change in magnetic moment from electrons. 
• Types of material response to a field are: 
--ferri- or ferro-magnetic (large magnetic induction) 
--paramagnetic (poor magnetic induction) 
--diamagnetic (opposing magnetic moment) 
• Hard magnets: large coercivity. 
• Soft magnets: small coercivity. 
• Magnetic storage media: 
--particulate g-Fe2O3 in polymeric film (tape or floppy) 
--thin film CoPtCr or CoCrTa on glass disk (hard drive)

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Nano materials

  • 1. Magnetic Properties Iron single crystal photomicrographs magnetic domains change shape as a magnetic field (H) is applied. domains favorably oriented with the field grow at the expense of the unfavorably oriented domains.
  • 2. Forces can be represented by imaginary lines grouped as fields c18f01 Basic Concepts Magnetic forces appear when moving charges Magnetic field lines of force around a current loop and a bar magnet.
  • 3. MAGNETIC DIPOLES The magnetic moment represented by a vector
  • 4. c18f03 Magnetic Field Vectors magnetic field strength (H) & magnetic flux density (B) Magnetic flux density H = B  B = H 0 0  relative permeability   0 r =  magnetization = + 0 0B  H  M M = H m  magnetic susceptibility = -1 m r   NI l Magnetic field strengthH =
  • 5. Origins of Magnetic Moments: Responds to quantum mechanics laws Two main contributions: (a) an orbiting electron and (b) electron spin. Bohr magneton (B) Most fundamental magnetic moment B = ±9.27x10-24 A-m2 The spin is an intrinsic property of the electron and it is not due to its rotation
  • 6. c18f05 18.3 Diamagnetism and Paramagnetism Diamagnetic material in the presence of a field, dipoles are induced and aligned opposite to the field direction. Paramagnetic material
  • 7. The flux density B versus the magnetic field strength H for diamagnetic and paramagnetic materials.  B = 0H + 0M = 0H + 0mH   = 0(1 + m)
  • 8.
  • 9. FERROMAGNETISM mutual alignment of atomic dipoles even in the absence of an external magnetic field. coupling forces align the magnetic spins B H M =  +    0 0 B M 0 Domains with mutual spin alignment B grows up to a saturation magnetization Ms with a saturation flux Bs = Matom × Natoms (average moment per atom times density of atoms) Matom = 2.22B, 1.72B, 0.60B for Fe, Co, Ni, respectively
  • 10. 1986: superconductivity discovered in layered compound La2-xBaxCuO4 with a transition T much higher than expected. Little was known about copper oxides c18f08 Antiferromagnetism & Ferrimagnetism ANTIFERROMAGNETISM Antiparallel alignment of spin magnetic moments for antiferromagnetic manganese oxide (MnO) At low T Above the Neel temperature they become paramagnetic Parent materials, La2CuO4, and YBa2Cu3O6, demonstrated that the CuO2 planes exhibit antiferromagnetic order. This work initiated a continuing exploration of magnetic excitations in copper-oxide superconductors, crucial to the mechanism of high-temperature superconductivity.
  • 11. FERRIMAGNETISM spin magnetic moment configuration for Fe2+ and Fe3+ ions in Fe3O4. Above the Curie temperature becomes paramagnetic
  • 13.
  • 14. 18.6 The Influence of Temperature on magnetic Behavior TC: Curie temperature (ferromagnetic, ferrimagnetic) TN: Neel temperature (antiferromagnetic) material become paramagnetic
  • 15. c18f11 18.7 Domains and Hysteresis Domains in a ferromagnetic or ferrimagnetic material; arrows represent atomic magnetic dipoles. Within each domain, all dipoles are aligned, whereas the direction of alignment varies from one domain to another. Gradual change in magnetic dipole orientation across a domain wall.
  • 16. c18f13 B versus H ferromagnetic or ferrimagnetic material initially unmagnetized Domain configurations during several stages of magnetization Saturation flux density, Bs Magnetization, Ms, initial permeability i
  • 17. Magnetic flux density versus magnetic field strength ferromagnetic material subjected to forward and reverse saturations (S & S’). hysteresis loop (red) initial magnetization (blue) remanence, Br coercive force, Hc
  • 19. Superconductivity Temperature dependence of the electrical resistivity for normally conducting and superconducting materials in the vicinity of 0 K.
  • 20. Critical temperature, current density, and magnetic field boundary separating superconducting and normal conducting states (schematic).
  • 21. Representation of the Meissner effect. While in the superconducting state, a body of material (circle) excludes a magnetic field (arrows) from its interior. The magnetic field penetrates the same body of material once it becomes normally conductive.
  • 22.
  • 23. SUMMARY • A magnetic field can be produced by: --putting a current through a coil. • Magnetic induction: --occurs when a material is subjected to a magnetic field. --is a change in magnetic moment from electrons. • Types of material response to a field are: --ferri- or ferro-magnetic (large magnetic induction) --paramagnetic (poor magnetic induction) --diamagnetic (opposing magnetic moment) • Hard magnets: large coercivity. • Soft magnets: small coercivity. • Magnetic storage media: --particulate g-Fe2O3 in polymeric film (tape or floppy) --thin film CoPtCr or CoCrTa on glass disk (hard drive)