1) The document discusses the crystal structure and atomic arrangement of metals, including the space lattice, unit cell, and grain boundaries. 2) It describes different crystal structures like body centered cubic (BCC) and face centered cubic (FCC), providing examples for alpha, delta, and gamma iron. 3) Various microstructural defects are outlined, including point defects, surface defects like grain boundaries, and line defects like dislocations which allow deformation through motion.

1. Ilyas (15006)
Mithun (15010)

2. Grains
Crystal
Structure
Basic Metallurgy

3. X
Y
Z
Space Lattice: A collection of
points that divided space into
smaller sized segments.
Unit Cell: A subdivision of the
lattice that still retains the overall
characteristics of the entire lattice.
Crystal Structure
(Atomic Arrangement)
Basic Metallurgy
Atom

4. Formation of Polycrystalline Material
Liquid
a b
c d
Solid (Unit Cell)
a) Small crystalline nuclei b) Growth of Crystals
c) Irregular grain shapes
formed upon completion
of solidification
d) Final grain structure
Grain Boundary: The zone of
crystalline mismatch between
adjacent grains. The lattice has
different orientation on either
side of the grain boundary
Basic Metallurgy

5. Grain Boundary

6. BCC - Delta Iron (d)
FCC - Gamma Iron (g)
BCC - Alpha Iron (a)
1540 oC
1400 oC
910 oC
Atomic Packing in Iron (Allotropic)
Basic Metallurgy

7. Body Centered Cubic (BCC)
Alpha & Delta Iron (a , d)
Total 2 Atoms/Unit Cell
α Lattice Parameter (a) = 0.287 nm
δ Lattice Parameter (a) = 0.293 nm
a
Squared Packed Layer
Basic Metallurgy

8. Face Centered Cubic (FCC)
Gamma Iron (g)
Total 4 Atoms/Unit Cell
g Lattice Parameter (a) = 0.359 nm
a
Close Packed Layer
Basic Metallurgy

9. 1) Point defects: a) vacancies, b) interstitial atoms, c) small substitional
atoms, d) large substitional atoms, … etc.
2) Surface defects: Imperfections, such
as grain boundaries, that form a two-
dimensional plane within the crystal.
Microstructural Defects
Basic Metallurgy

10. 3) Line defects: dislocations (edge, screw, mixed)
Dislocation: A line imperfection in
the lattice or crystalline material
Movement of dislocations helps to
explain how materials deform.
Interface with movement of
dislocations helps explain how
materials are strengthened.
They are typically introduced into
the lattice during solidification of
the material or when the material is
deformed.
Microstructural Defects
Basic Metallurgy

11. Motion of Dislocation
When a shear stress is applied to the dislocation in (a), the atoms
displaced, causing the dislocation to move one step (Burger’s vector) in
the slip (b). Continued movement of the dislocation eventually creates a
step (deformation) direction (C)
Basic Metallurgy

12. STEEL = IRON + Alloying Elements ( C + Mn, Si, Ni, …)
IRON + < 2 % Carbon = STEEL
IRON + > 2 % Carbon = CAST IRON
What is the difference between “STEEL” and “CAST IRON” ?
Basic Metallurgy

13. Atomic Packing in Iron (Allotropic)
BCC - Delta Iron (d)
FCC - Gamma Iron (g)
BCC - Alpha Iron (a)
Basic Metallurgy

14. 14

15. 15

16. Basic Metallurgy
Weight Percentage Carbon
Temperature(oC)
( g + Fe3C )
( g + L )
Austenite (g )
Liquid (L)1540
1495
727 °C
910
Cementite (Fe3C)+ Pearlite
( a + g )
Ferrite + Pearlite
Ferrite (a )
1000 -
1200 -
1400 -
1600 -
1.0
800 -
2.0
400 -
600 -
200 -
0 -
0.8%
Eutectoid
Delta Ferrite
( d )
( d + g )
Peritectic
( d + L )
1150 °C
Ferrite
Cementite
~0% C
0.2% C
0.35% C
0. 5% C
0. 7% C
0. 8% C
1.2% C

17. 17
Martensite
Gray Cast Iron

18. 18

19. 19