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Metallic and Ionic
Nanoparticles
Extendable Structures: Solids
Extendable Structures: Solids
© McREL 2009
2
Iron nanoparticles
in
YOUR
backyard?
Nanoparticles
Extendable Structures: Solids
© McREL 2009
3
Metallic Metal Atoms Metallic bonds Extendable
Ionic Cations and
anions
Ionic bonds Extendable
Network
covalent
Atoms Covalent bonds Extendable
Molecular Molecules Covalent bonds
and
intermolecular
forces
Discrete
Types of Solids
Extendable Structures: Solids
© McREL 2009
4
ExtendableExtendable Discrete,
Molecular-type
Discrete,
Molecular-type
can be
or
metallic,
ionic, or
network
solids
molecular
solids
Solid Structures
Extendable Structures: Solids
© McREL 2009
5
Metallic Solids
Extendable Structures: Solids
© McREL 2009
6
Metallic Ionic
Nanoparticles
Extendable Structures: Solids
© McREL 2009
7
Metallic Ionic
Nanoparticles
Extendable Structures: Solids
© McREL 2009
8
Metallic Solids
Extendable Structures: Solids
© McREL 2009
9
High melting points
Ionic Solids
Extendable Structures: Solids
© McREL 2009
10
Metallic Macroparticles contain
moles of atoms
Metallic Nanoparticles contain
10-70,000 particles
Metallic Solids
Extendable Structures: Solids
© McREL 2009
11
Why is
SIZE
such a
critical factor?
Metallic Nanoparticles
Extendable Structures: Solids
© McREL 2009
12
As the size of the nanoparticle decreases,
 the ratio of surface atoms to interior atoms
increases.
 the percentage of surface atoms in the sample
increases.
 the average coordination number in the sample
decreases.
Metallic Nanoparticles
Extendable Structures: Solids
© McREL 2009
13
Did the basic shape of the
nanoparticles change?
Metallic Nanoparticles
Extendable Structures: Solids
© McREL 2009
14
Metallic Nanoparticles
Extendable Structures: Solids
© McREL 2009
15
Large number of surface atoms
compared to the
number of interior atoms
Metallic Nanoparticles
Extendable Structures: Solids
© McREL 2009
16
Professor Christopher Chidsey,
Department of Chemistry, Stanford University
Nanoparticles
Extendable Structures: Solids
© McREL 2009
17
1. What is the effect of particle size on the
surface area to volume ratio?
2. What is the effect of particle size on
coordination number?
3. How do you think surface area to volume
ratio relate to surface energy?
4. What properties could be most effected by
surface energy?
Making Connections
Extendable Structures: Solids
© McREL 2009
18
Lesson 1.2 What
Makes Nanoscience
so Different?
What makes
Nanoscience so
different?
Compare Newtonian
and Quantum
Chemistry Regimes as
they relate to
nanoscale science
Lesson 1.3 What
Makes Nanoscience so
Important?
Interdisciplinary
science
The development of
new technologies and
instrumentation
applications whose risk
and benefits have yet to
be determined
Lesson 3.1
Carbon Chemistry
Lesson 1.1 What is
Nanoscience?
What is
Nanoscience?
Examine and
Compare size:
macro, micro, sub-
micro (nano)
SI prefixes
Lesson 2.2 Extendable
Solids: Reactivity, Catalysis,
Adsorption
Lesson 2.3
Extendable Structures:
Melting Point, Color
Conductivity
Lesson 3.2
Fullerenes and Nanotubes
Lesson 2.1 Extendable
Solids
As the size of the
sample decreases the
ratio of surface
particles to interior
particles increases in
ionic and metallic
solids
Poster Assessment
Students will further
investigate the essential
question that they have
considered throughout the
module: How and why do
the chemical and physical
properties of nanosamples
differ from those of
macrosamples?
Module Flow Chart

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Metal Nanoparticles - Solids

  • 2. Extendable Structures: Solids © McREL 2009 2 Iron nanoparticles in YOUR backyard? Nanoparticles
  • 3. Extendable Structures: Solids © McREL 2009 3 Metallic Metal Atoms Metallic bonds Extendable Ionic Cations and anions Ionic bonds Extendable Network covalent Atoms Covalent bonds Extendable Molecular Molecules Covalent bonds and intermolecular forces Discrete Types of Solids
  • 4. Extendable Structures: Solids © McREL 2009 4 ExtendableExtendable Discrete, Molecular-type Discrete, Molecular-type can be or metallic, ionic, or network solids molecular solids Solid Structures
  • 5. Extendable Structures: Solids © McREL 2009 5 Metallic Solids
  • 6. Extendable Structures: Solids © McREL 2009 6 Metallic Ionic Nanoparticles
  • 7. Extendable Structures: Solids © McREL 2009 7 Metallic Ionic Nanoparticles
  • 8. Extendable Structures: Solids © McREL 2009 8 Metallic Solids
  • 9. Extendable Structures: Solids © McREL 2009 9 High melting points Ionic Solids
  • 10. Extendable Structures: Solids © McREL 2009 10 Metallic Macroparticles contain moles of atoms Metallic Nanoparticles contain 10-70,000 particles Metallic Solids
  • 11. Extendable Structures: Solids © McREL 2009 11 Why is SIZE such a critical factor? Metallic Nanoparticles
  • 12. Extendable Structures: Solids © McREL 2009 12 As the size of the nanoparticle decreases,  the ratio of surface atoms to interior atoms increases.  the percentage of surface atoms in the sample increases.  the average coordination number in the sample decreases. Metallic Nanoparticles
  • 13. Extendable Structures: Solids © McREL 2009 13 Did the basic shape of the nanoparticles change? Metallic Nanoparticles
  • 14. Extendable Structures: Solids © McREL 2009 14 Metallic Nanoparticles
  • 15. Extendable Structures: Solids © McREL 2009 15 Large number of surface atoms compared to the number of interior atoms Metallic Nanoparticles
  • 16. Extendable Structures: Solids © McREL 2009 16 Professor Christopher Chidsey, Department of Chemistry, Stanford University Nanoparticles
  • 17. Extendable Structures: Solids © McREL 2009 17 1. What is the effect of particle size on the surface area to volume ratio? 2. What is the effect of particle size on coordination number? 3. How do you think surface area to volume ratio relate to surface energy? 4. What properties could be most effected by surface energy? Making Connections
  • 18. Extendable Structures: Solids © McREL 2009 18 Lesson 1.2 What Makes Nanoscience so Different? What makes Nanoscience so different? Compare Newtonian and Quantum Chemistry Regimes as they relate to nanoscale science Lesson 1.3 What Makes Nanoscience so Important? Interdisciplinary science The development of new technologies and instrumentation applications whose risk and benefits have yet to be determined Lesson 3.1 Carbon Chemistry Lesson 1.1 What is Nanoscience? What is Nanoscience? Examine and Compare size: macro, micro, sub- micro (nano) SI prefixes Lesson 2.2 Extendable Solids: Reactivity, Catalysis, Adsorption Lesson 2.3 Extendable Structures: Melting Point, Color Conductivity Lesson 3.2 Fullerenes and Nanotubes Lesson 2.1 Extendable Solids As the size of the sample decreases the ratio of surface particles to interior particles increases in ionic and metallic solids Poster Assessment Students will further investigate the essential question that they have considered throughout the module: How and why do the chemical and physical properties of nanosamples differ from those of macrosamples? Module Flow Chart

Editor's Notes

  1. New graphic Metals on one side and non-metals are on other side. Use stair step as guideline. (see book)
  2. Use three images from nanoparticle builder when all built—three-, five-, seven- layer. See Particle builder
  3. Add seven layer particle from slide 13.
  4. Judy add new screenshot