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International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 06 Issue: 05 | May 2019 www.irjet.net p-ISSN: 2395-0072
© 2019, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 7132
Experimental Investigations on Combination of Castor and Neem
Biodiesel & its Blends with Diesel used in Diesel Engine
Rathnagiri Mahesh Goud1, Roshan Zameer Ahamed2, Aiman Quraishi3,
Mohammed Ashfaque Inayath4
1,2Asst.Professor, Department of Mechanical Engineering, LIET-Hyderabad,TS, 500091.
2,3Research Scholar, Department of Mechanical Engineering, LIET-Hyderabad, TS, 500091.
---------------------------------------------------------------------------***---------------------------------------------------------------------------
Abstract - In this experiment, the work is to study the performance & emission characteristics of single cylinder, 4-Stroke, and
diesel engine fueled with the biodiesel made by mixture of Castor & Neem methyl esters and its blends with diesel such as B10, B20
and B30 and compare the results with pure diesel. The experiment is carried out at endless speed of 1500 rpm, at constant IOP of
200bar for various CR as 16.5, 17.5& 18.5 at dissimilar loads of percentage 50, 75 and 100. The experimental readings are taken
by using lab view software, emission values are taken with the help of multi gas analyzer & smoke values are taken by smoke
meter. The outcomes are showing that castor & neem blend B10 has higher performance and lower emissions than other blends
and performance almost equivalent to diesel at 18.5 CR and emissions are optimum at 18.5 CR. So, without any modifications
castor & neem biodiesel combination can be used as blend B10 in the diesel engine.
Key words: Combination of Castor & Neem methyl esters, Castor & Neem blends, Diesel Engine, Performance, Emissions.
1. INTRODUCTION
In the modern years, fossil fuels are declining abruptly. Fossil fuels are non-renewable energy resources; even natural
processes are molding them because they take million years to form. We almost used up the existing coal, petroleum and the
other natural resources the earth has in it. Fossil fuels have wide range of applications these are the main sources of electric
power and used for industries and automobiles etc. because of increment in industrialization and substantial increment in the
quantity of vehicles have come about immense interest for oil based goods, with the addition request of non-renewable energy
sources everywhere throughout the world its supply in the market will keep on depleting. This increasing claim for petroleum-
based fuels has run to oil crisis in the modern times. Due to rapid depleting of oil reserves, it is time to search for an alternative
to petroleum-based fuels, which are readily available & easily producible. Biodiesel is a promising alternate fuel, which can be
used in diesel engine without any adjustment to engine. There are many sources, which can produce biodiesel like castor
seeds, sunflower seeds, jatropha etc. Using of biofuel is eco-friendly & decreases the dependence on fossil fuels. So many
researchers have done experiments on diesel engines by using different biodeisels. Liaquat et al.[1] examined the
performance& emissions of coconut bio diesel as blends B5 and B15 and compare the results with diesel at dissimilar loads
with speed variation 1500 to 2400 rpm. They concluded that torque reduction for B5 is 0.69% & 2.58% for B15. Dawody et al.
[2] have done experiments on pilot engine by using soyabean biodiesel blends [B20, B40, B100] at endless speed of 1500 rpm
for numerous loads and showed that all blends have less bsfc than diesel. The investigations of Senthil Kumar et al. [3] on
direct injection diesel motor by using Kapok methyl ester mixes and proved that the lean blends of Kapok methyl ester is a
promising alternate to diesel fuel that shows appreciate engine efficiencies and considerable decrement in CO, HC & smoke
emissions where as rich blends showed increment in BSFC and cut in BTE and NOX outflows also more compare to diesel.
Sivaramakrishan [4] has inspected the performance &emission features of variable compression, multifuel engine fueled with
karanja biofuel mingled with diesel such as B20, B25 & B30 for various CR of 15:1, 16:1, 17:1 and 18:1. He concluded that the
B25 of karjana biodiesel at 18:1 CR is optimum. Jayasri Nairt et al. [5] tested the performance of neem oil blends in 4-stroke
diesel engine & results disclosed that the B10 of neem biodiesel has higher BTE & lower emissions than diesel. Kasiraman et al.
[6] used the cashew but shell oil in diesel engine & concluded that 70% of cashew nut shell oil and 30% of camper oil blend
gives nearly same values as diesel like BTE for blend is 29.1% where as diesel efficiency 30.1%. Dinesh et al. [7] have tested
the execution and discharges of cymbopogon flexosus biofuel mixes with diesel in various extents as B10, B20, B30, B40 and
B100. As per American culture for testing measures, this trial was done in diesel motor at consistent speed of 1500 rpm. The
outcomes presented that the B20 has higher B.T.E. among the blends and lower HC, CO emissions contrast to diesel. The
research done by Panwar et al. [8] on VCR diesel engine for various loads by using castor oil blends. The outcomes are shown
that the lower proportion blends have higher BTE and lower fuel consumption.
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 06 Issue: 05 | May 2019 www.irjet.net p-ISSN: 2395-0072
© 2019, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 7133
1.1 History of oils.
Castor Oil: The regular name is castor oil, from where the plant was, gets its introduction, perhaps originates from its use as a
additional for castoreum, a perfume base done from the dried perinea glands of the beaver (castor in Latin). Castor oil is a
colorless or very pale yellow fluid with a discrete taste & odor once first swallowed. Its boiling point of oil is 313 °C (595 °F) &
its density was 961 kg/m3. Almost 90% of fatty-acid chains are ricinolates in a triglyceride. Oleate & linoleates are the other
important components. Castor oil is used in the manufacture of soaps, coatings, inks, lubricants, hydraulic & brake fluids,
paints, dyes, waxes, cold resistant plastics, & polishes, pharmaceuticals & perfumes.
Neem Oil: Neem (Azadirachta indica) is a tree in the mahogany family Meliaceae, which is richly grownup in different places
of India. The Neem rises on almost all kinds of soils containing clayey, alkaline & saline conditions. Neem seed acquired from
its tree is collected, sun dried, depulped & crushed for oil extraction. The seeds are having 45% of oil which was high potential
for the making of biodiesel. Neem oil is usually light to dark-brown, bitter & has a slightly strong odour that is said to combine
the odours of peanut & garlic. It comprises mainly of triglycerides & large amounts of triterpenoids compounds, which are
answerable for the bitter taste.
Table - 1. Properties of biodiesels.
2. EXPERIMENTAL SETUP
A vertical, 4-stroke cycle, single cylinder, water-cooled, compression ignition engine was used for the experiment. The engine
is coupled to an Eddy Current Dynamometer. Air temperature, coolant temperature and throttle position are connected to
open ECU which control fuel injector, fuel pump and idle air. The engine was modified and provision were provided to vary the
compression ratio from 16.5:1 to 18.5:1,rated Injection opening pressure 200bar and rated crank angle. The line diagram of
the engine setup is shown in the fig.1 below and the engine specifications shown in the table.2.Initially the engine was run with
pure diesel and after blends of C&N[50:50] biodiesel as B10,B20 and B30 at various compression ratios for different loads
varying with help of loading unit. Various engine performance parameters BTE and BSFC were measured with the help of
digital lab view software and emission parameters like HC, CO and NOx were measured with Emission Gas Analyzer. Smoke
opacity is measured with the help of smoke meter and the results were plotted against brake power.
Line Diagram
Fig-1. Line diagram of Experimental setup
Properties Castor Neem Castor& Neem Diesel
Density(gm/cc) 0.956 0.919 0.885 0.830
Viscosity(cst) 52 34 8.0 5.0
Flash point(deg C) 320 300 140 57
Calorific value(kJ/kg) 36000 35200 39974 42000
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 06 Issue: 05 | May 2019 www.irjet.net p-ISSN: 2395-0072
© 2019, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 7134
Table - 2. Specifications of Test Rig.
3. RESULTS AND DISCUSSION
3.1. Brake Specific Fuel Consumption
1.4 1.6 1.8 2.0 2.2 2.4 2.6 2.8 3.0 3.2 3.4 3.6
0.34
0.36
0.38
0.40
0.42
0.44
0.46
0.48
0.50
0.52
0.54
0.56
0.58
0.60
0.62
0.64
0.66
BSFC(kg/kW-hr)
BP (kW)
16.5 CR
B0
B10
B20
B30
1.4 1.6 1.8 2.0 2.2 2.4 2.6 2.8 3.0 3.2 3.4 3.6
0.30
0.32
0.34
0.36
0.38
0.40
0.42
0.44
0.46
0.48
0.50
0.52
0.54
0.56
0.58
BSFC(kg/kW-hr)
BP (kW)
17.5 CR
B0
B10
B20
B30
1.4 1.6 1.8 2.0 2.2 2.4 2.6 2.8 3.0 3.2 3.4 3.6
0.28
0.30
0.32
0.34
0.36
0.38
0.40
0.42
0.44
0.46
0.48
0.50
0.52
0.54
BSFC(kg/kW-hr)
BP (kW)
18.5 CR
B0
B10
B20
B30
Fig-2. Variation of BSFC Vs BP for various compression ratios.
PARTICULARS SPECIFICATIONS
Type Vertical, 4-Stroke Cycle, Single Acting, Totally Enclosed, Water cooled
Type of Ignition Compression Ignition
Rated Power 3.5 kW
Injection opening pressure 200 bar
Constant Speed 1500 RPM
Variable compression ratio 16.5:1 to 18.5:1
Fuel Injection Direct Injection
Injection Timing 23° BTDC
Dynamometer Eddy Current Type
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 06 Issue: 05 | May 2019 www.irjet.net p-ISSN: 2395-0072
© 2019, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 7135
Fig. shows that the graphs presented variation of specific fuel consumption v/s break power of combination of neem & castor
methyl ester (50:50) blends B10, B20 & B30 with diesel for compression ratios 16.5, 17.5 and 18.5. From the graph it is shown
that on an average, the BSFC is reduced by 17%, when compression ratio increases from 16.5 to 18.5 for blends, which could
be due to low heat losses and better combustion at higher compression ratio. The BSFC depreciates gradually with increment
in load; at high load run, it shows optimum. The blend B10 shows less BSFC comparing to other blends B20 & B30 at all
compression ratios but it is increased compared to that of diesel by 17%, 6% and 20% at compression ratios 16.5, 17.5 and
18.5 respectively. As the concentration of blend increase for biodiesel, showing increment in BSFC for all loads which is due to
lower calorific values of B20 & B30 resulted more fuel consumption for same output energy.
3.2. Brake Thermal Efficiency
1.4 1.6 1.8 2.0 2.2 2.4 2.6 2.8 3.0 3.2 3.4 3.6
12
14
16
18
20
22
24
26
28
30
32
BTE(%)
BP (kW)
16.5 CR
B0
B10
B20
B30
1.4 1.6 1.8 2.0 2.2 2.4 2.6 2.8 3.0 3.2 3.4 3.6
14
16
18
20
22
24
26
28
30
32
BTE(%)
BP (kW)
18.5 CR
B0
B10
B20
B30
1.6 1.8 2.0 2.2 2.4 2.6 2.8 3.0 3.2 3.4 3.6
16
18
20
22
24
26
28
30
32
BTE(%)
BP (kW)
17.5 CR
B0
B10
B20
B30
Fig-3. Variation of BTE Vs BP for various compression ratios.
Fig. shows the BTE of combination of neem & castor methyl ester blends and diesel against BP (break power) at compression
ratios 16.5, 17.5 and 18.5. The graph clears that on an average, the break thermal efficiency is increased by 8%, when
compression ratio increases from 16.5 to 18.5 for all the blends. Because of increment in compression ratio cause to complete
combustion, and this may increase the efficiency. The BTE increases steadily with increment in load due to higher power
produced at high load run. The blend B10 shows more BTE compared to other blends B20 & B30 at all compression ratios but
it is still reduced by an average 17% compared to that of diesel at various compression ratios.
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 06 Issue: 05 | May 2019 www.irjet.net p-ISSN: 2395-0072
© 2019, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 7136
3.3. Carbon Monoxide
1.4 1.6 1.8 2.0 2.2 2.4 2.6 2.8 3.0 3.2 3.4 3.6
0.02
0.03
0.04
0.05
0.06
0.07
0.08
0.09
0.10
0.11
0.12
0.13
0.14
CO(%)
BP (kW)
16.5 CR
B0
B10
B20
B30
1.4 1.6 1.8 2.0 2.2 2.4 2.6 2.8 3.0 3.2 3.4 3.6
0.02
0.03
0.04
0.05
0.06
0.07
0.08
0.09
0.10
0.11
0.12
0.13
0.14
CO(%)
BP (kW)
18.5 CR
B0
B10
B20
B30
1.4 1.6 1.8 2.0 2.2 2.4 2.6 2.8 3.0 3.2 3.4 3.6
0.02
0.03
0.04
0.05
0.06
0.07
0.08
0.09
0.10
0.11
0.12
0.13
0.14
0.15
CO(%)
BP (kW)
17.5 CR
B0
B10
B20
B30
Fig-4. Variation of CO Vs BP for various compression ratios.
Fig. shows the variation in emissions of carbon monoxide v/s break power for blends B10, B20 & B30 of castor & neem
biodiesel and diesel at CR 16.5, 17.5 and 18.5. From the figure, it is clear that CO emissions are low at higher compression ratio
due to adequate heat of compression boosts ignition; therefore, on an average, the CO emissions are decreased by 14% with
increase in compression ratio from 16.5 to 18.5 for all the blends. Blends B10 & B20 have fewer emissions than B30 and diesel.
On an average, B10 & B20 CO emissions are reduced compared to that of diesel by 25% and 17% respectively for compression
ratios 16.5, 17.5 and 18.5.
3.4. Hydrocarbon
1.4 1.6 1.8 2.0 2.2 2.4 2.6 2.8 3.0 3.2 3.4 3.6
25
30
35
40
45
50
55
60
65
70
75
HC(ppm)
BP (kW)
16.5 CR
B0
B10
B20
B30
1.4 1.6 1.8 2.0 2.2 2.4 2.6 2.8 3.0 3.2 3.4 3.6
30
35
40
45
50
55
60
65
70
HC(ppm)
BP (kW)
18.5 CR
B0
B10
B20
B30
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 06 Issue: 05 | May 2019 www.irjet.net p-ISSN: 2395-0072
© 2019, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 7137
1.4 1.6 1.8 2.0 2.2 2.4 2.6 2.8 3.0 3.2 3.4 3.6
30
35
40
45
50
55
60
65
70
75
80
HC(ppm)
BP (kW)
17.5 CR
B0
B10
B20
B30
Fig-5.Variation of HC Vs BP for various compression ratios
Fig. shows the variation of unburnt hydrocarbons for different blends of neem &castor combination biodiesel and diesel at
compression ratios 16.5, 17.5 and 18.5. From the graph, it is clear that the HC emissions are increasing with load increases for
all the blends and diesel. On an average, the HC emissions were diminished by 8% for all the blends along with unadulterated
diesel as compression ratio increases from 16.5 to 18.5.this increment prompts increase in temperature and pressure, that
high temperature and high pressure ensure complete combustion, because of this complete combustion HC emissions were
low. In addition, from the graphs it is cleared that B10 and B20 have less unburnt HC emissions than B30 & diesel. On an
average, the HC emissions of B10 & B20 were reduced by 20% and 13% respectively, compared to that of diesel at
compression ratios 16.5, 17.5 and 18.5.
3.5. NOx Emissions
1.4 1.6 1.8 2.0 2.2 2.4 2.6 2.8 3.0 3.2 3.4 3.6
500
600
700
800
900
1000
1100
1200
1300
1400
NOx(ppm)
BP (kW)
16.5 CR
B0
B10
B20
B30
1.4 1.6 1.8 2.0 2.2 2.4 2.6 2.8 3.0 3.2 3.4 3.6
600
700
800
900
1000
1100
1200
1300
1400
1500
NOx(ppm)
BP (kW)
17.5 CR
B0
B10
B20
B30
1.4 1.6 1.8 2.0 2.2 2.4 2.6 2.8 3.0 3.2 3.4 3.6
500
600
700
800
900
1000
1100
1200
1300
1400
1500
NOx(ppm)
BP (kW)
18.5 CR
B0
B10
B20
B30
Fig-6. Variation of NOx Vs BP for various compression ratios
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 06 Issue: 05 | May 2019 www.irjet.net p-ISSN: 2395-0072
© 2019, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 7138
Fig. shows the variation of NOx emissions as a function of break power of diesel and C&N (50:50) blends as B10, B20 and B30
for various compression ratios 16.5, 17.5 and 18.5. From the figure, it is noticed that NOx outflows are increased on an
average by 10% for all the blends and diesel, when compression ratio was increased from 16.5 to 18.5. This is due to higher
combustion temperature makes nitrogen to react with oxygen in high proportion. In addition, B10 and diesel are having fewer
NOx emissions as compared to that of B20 & B30. On an average, NOx discharges of B10, B20 and B30 were enhanced by 9%,
23% and 32% respectively, for various compression ratios 16.5, 17.5 and 18.5.
3.6. Smoke Opacity
1.4 1.6 1.8 2.0 2.2 2.4 2.6 2.8 3.0 3.2 3.4 3.6
5
10
15
20
25
30
35
40
HSU
BP (kW)
16.5 CR
B0
B10
B20
B30
1.4 1.6 1.8 2.0 2.2 2.4 2.6 2.8 3.0 3.2 3.4 3.6
10
15
20
25
30
35
40
45
HSU BP (kW)
17.5 CR
B0
B10
B20
B30
1.4 1.6 1.8 2.0 2.2 2.4 2.6 2.8 3.0 3.2 3.4 3.6
10
15
20
25
30
35
40
HSU
BP (kW)
18.5 CR
B0
B10
B20
B30
Fig-7. Variation of HSU Vs BP for various compression ratios
Fig. shows the smoke opacity graphs of castor & neem combination(50:50) biodiesel blends along with diesel were plotted
against break power for various compression ratios 16.5,17 .5 and 18.5. From the graph it is cleared that smoke emissions of
different blends of C&N[50:50] in form of B10,B20 & B30 were reduced on an average by 14%, when compression ratio was
increased from 16.5 to 18.5. On an average, the smoke emissions were increased compared to that of diesel by 7%, 19% and
19% for B10, B20 and B30 respectively. This is due to higher viscosity results in slow combustion increasing smoke emissions.
Conclusions
From the exploratory examination on performance and emission test on diesel engine with blends of castor & neem biodiesel,
we can infer that:
 Castor & neem biodiesel combination blend B10 is showing more brake thermal efficiency and less BSFC than
remaining blends B20 and B30 at all compression ratios. However, it shows less brake thermal efficiency and more
BSFC than pure diesel by an average 17% and 15% respectively.
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 06 Issue: 05 | May 2019 www.irjet.net p-ISSN: 2395-0072
© 2019, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 7139
 CO & HC outflows of B10 were less compared to other blends and those were reduced compared to diesel by an
average 25% and 20% respectively, but NOX discharges and smoke discharges were enhanced compared to diesel by
an average 9% and 7% respectively.
 For all the blends, BSFC is lowered and BTE is enhanced by an average 17% and 8% respectively, when compression
ratio was increased from 16.5 to 18.5. In addition, CO, HC and smoke emissions were reduced by an average 14%, 8%
and 14% respectively, where as NOx emissions were increased by an average 10%.
 Finally, the blend B10 is showing good performance and optimum emissions at compression ratio 18.5:1. Therefore,
we can replace diesel with B10 in diesel engine without any modification.
Table-3. Nomenclature
B10 10% Caser & neem +90% Diesel
B20 20% Caser & neem +80% Diesel
B30 30% Caser & neem +70% Diesel
BSFC Brake Specific Fuel Consumption
BTE Brake Thermal Efficiency
C &N Caster & Neem
CO Carbon monoxide
CR Compression Ratio
HC Hydrocarbons
HSU Hat ridge Smoke Unit
IOP Injection opening pressure
References
[1] A.M. Liaquat, H.H. Masjuki, M.A. Kalam, I.M. Rizwanul Fattah, M.A. Hazrat, M. Varman, M. Mofijur, M. Shahabuddin,
Performance and emission analysis of coconut biodiesel in diesel engine, Procedia Eng. 56 (2013) 583–590.
[2] Mohamed F. Al Dawody, S.K. Bhatti, Experimental investigation on pilot engine by using soya bean biodiesel blends, Energy
Procedia 52(2014) 421–430.
[3]T.Senthil Kumar, P.Senthil Kumar, and K.Annamalai. Experimental study on the performance and emission measures of
direct injection diesel engine with Kapok methyl ester and itsblends,DOI:10.1016/j.renene.2014.09.022.
[4] K. Sivaramakrishnan, Investigation on performance and emission characteristics of a variable compression multi fuel
engine fuelled with Karanja biodiesel–diesel blend, Egypt. J. Petrol. (2017), http://dx.doi.org/10.1016/j.ejpe.2017.03.001.
[5] J.N.Nair, Arun Kumar Daram: Analysis of performance and emission on compression ignition engine fuelled with blends of
neem biodiesel, Egypt.J. Petrol. (2016), http://dx.doi.org/10.1016/j.ejpe.2016.09.005.
[6] G.Kasiraman, B.Nagalingam, M.Bala Krishnan: Performance, emission and combustion improvements in a direct injection
diesel engine using cashew nut shell oil as fuel with camphor oil blending, https://doi.org/10.1016/j.energy.2012.09.022.
[7] Dhinesh Balasubramanian, Isaac Joshua Ramesh Lalvani, Parthasarathy Murugesan, K. Annamalai: An assessment on
performance, emission and combustion characteristics of single cylinder diesel engine powered by Cymbopogon flexuous
biofuel, DOI: 10.1016/j.enconman.2016.03.049.
[8] Panwar, NL, Hemant, Y, ShrirameRathore, NS, Sudhakar, J: Performance evaluation of a diesel engine fueled with methyl
ester of castor seed oil. Appl. Therm. Eng. 30, 245-249 (2010).

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IRJET- Experimental Investigations on Combination of Castor and Neem Biodiesel & its Blends with Diesel Used in Diesel Engine

  • 1. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 06 Issue: 05 | May 2019 www.irjet.net p-ISSN: 2395-0072 © 2019, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 7132 Experimental Investigations on Combination of Castor and Neem Biodiesel & its Blends with Diesel used in Diesel Engine Rathnagiri Mahesh Goud1, Roshan Zameer Ahamed2, Aiman Quraishi3, Mohammed Ashfaque Inayath4 1,2Asst.Professor, Department of Mechanical Engineering, LIET-Hyderabad,TS, 500091. 2,3Research Scholar, Department of Mechanical Engineering, LIET-Hyderabad, TS, 500091. ---------------------------------------------------------------------------***--------------------------------------------------------------------------- Abstract - In this experiment, the work is to study the performance & emission characteristics of single cylinder, 4-Stroke, and diesel engine fueled with the biodiesel made by mixture of Castor & Neem methyl esters and its blends with diesel such as B10, B20 and B30 and compare the results with pure diesel. The experiment is carried out at endless speed of 1500 rpm, at constant IOP of 200bar for various CR as 16.5, 17.5& 18.5 at dissimilar loads of percentage 50, 75 and 100. The experimental readings are taken by using lab view software, emission values are taken with the help of multi gas analyzer & smoke values are taken by smoke meter. The outcomes are showing that castor & neem blend B10 has higher performance and lower emissions than other blends and performance almost equivalent to diesel at 18.5 CR and emissions are optimum at 18.5 CR. So, without any modifications castor & neem biodiesel combination can be used as blend B10 in the diesel engine. Key words: Combination of Castor & Neem methyl esters, Castor & Neem blends, Diesel Engine, Performance, Emissions. 1. INTRODUCTION In the modern years, fossil fuels are declining abruptly. Fossil fuels are non-renewable energy resources; even natural processes are molding them because they take million years to form. We almost used up the existing coal, petroleum and the other natural resources the earth has in it. Fossil fuels have wide range of applications these are the main sources of electric power and used for industries and automobiles etc. because of increment in industrialization and substantial increment in the quantity of vehicles have come about immense interest for oil based goods, with the addition request of non-renewable energy sources everywhere throughout the world its supply in the market will keep on depleting. This increasing claim for petroleum- based fuels has run to oil crisis in the modern times. Due to rapid depleting of oil reserves, it is time to search for an alternative to petroleum-based fuels, which are readily available & easily producible. Biodiesel is a promising alternate fuel, which can be used in diesel engine without any adjustment to engine. There are many sources, which can produce biodiesel like castor seeds, sunflower seeds, jatropha etc. Using of biofuel is eco-friendly & decreases the dependence on fossil fuels. So many researchers have done experiments on diesel engines by using different biodeisels. Liaquat et al.[1] examined the performance& emissions of coconut bio diesel as blends B5 and B15 and compare the results with diesel at dissimilar loads with speed variation 1500 to 2400 rpm. They concluded that torque reduction for B5 is 0.69% & 2.58% for B15. Dawody et al. [2] have done experiments on pilot engine by using soyabean biodiesel blends [B20, B40, B100] at endless speed of 1500 rpm for numerous loads and showed that all blends have less bsfc than diesel. The investigations of Senthil Kumar et al. [3] on direct injection diesel motor by using Kapok methyl ester mixes and proved that the lean blends of Kapok methyl ester is a promising alternate to diesel fuel that shows appreciate engine efficiencies and considerable decrement in CO, HC & smoke emissions where as rich blends showed increment in BSFC and cut in BTE and NOX outflows also more compare to diesel. Sivaramakrishan [4] has inspected the performance &emission features of variable compression, multifuel engine fueled with karanja biofuel mingled with diesel such as B20, B25 & B30 for various CR of 15:1, 16:1, 17:1 and 18:1. He concluded that the B25 of karjana biodiesel at 18:1 CR is optimum. Jayasri Nairt et al. [5] tested the performance of neem oil blends in 4-stroke diesel engine & results disclosed that the B10 of neem biodiesel has higher BTE & lower emissions than diesel. Kasiraman et al. [6] used the cashew but shell oil in diesel engine & concluded that 70% of cashew nut shell oil and 30% of camper oil blend gives nearly same values as diesel like BTE for blend is 29.1% where as diesel efficiency 30.1%. Dinesh et al. [7] have tested the execution and discharges of cymbopogon flexosus biofuel mixes with diesel in various extents as B10, B20, B30, B40 and B100. As per American culture for testing measures, this trial was done in diesel motor at consistent speed of 1500 rpm. The outcomes presented that the B20 has higher B.T.E. among the blends and lower HC, CO emissions contrast to diesel. The research done by Panwar et al. [8] on VCR diesel engine for various loads by using castor oil blends. The outcomes are shown that the lower proportion blends have higher BTE and lower fuel consumption.
  • 2. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 06 Issue: 05 | May 2019 www.irjet.net p-ISSN: 2395-0072 © 2019, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 7133 1.1 History of oils. Castor Oil: The regular name is castor oil, from where the plant was, gets its introduction, perhaps originates from its use as a additional for castoreum, a perfume base done from the dried perinea glands of the beaver (castor in Latin). Castor oil is a colorless or very pale yellow fluid with a discrete taste & odor once first swallowed. Its boiling point of oil is 313 °C (595 °F) & its density was 961 kg/m3. Almost 90% of fatty-acid chains are ricinolates in a triglyceride. Oleate & linoleates are the other important components. Castor oil is used in the manufacture of soaps, coatings, inks, lubricants, hydraulic & brake fluids, paints, dyes, waxes, cold resistant plastics, & polishes, pharmaceuticals & perfumes. Neem Oil: Neem (Azadirachta indica) is a tree in the mahogany family Meliaceae, which is richly grownup in different places of India. The Neem rises on almost all kinds of soils containing clayey, alkaline & saline conditions. Neem seed acquired from its tree is collected, sun dried, depulped & crushed for oil extraction. The seeds are having 45% of oil which was high potential for the making of biodiesel. Neem oil is usually light to dark-brown, bitter & has a slightly strong odour that is said to combine the odours of peanut & garlic. It comprises mainly of triglycerides & large amounts of triterpenoids compounds, which are answerable for the bitter taste. Table - 1. Properties of biodiesels. 2. EXPERIMENTAL SETUP A vertical, 4-stroke cycle, single cylinder, water-cooled, compression ignition engine was used for the experiment. The engine is coupled to an Eddy Current Dynamometer. Air temperature, coolant temperature and throttle position are connected to open ECU which control fuel injector, fuel pump and idle air. The engine was modified and provision were provided to vary the compression ratio from 16.5:1 to 18.5:1,rated Injection opening pressure 200bar and rated crank angle. The line diagram of the engine setup is shown in the fig.1 below and the engine specifications shown in the table.2.Initially the engine was run with pure diesel and after blends of C&N[50:50] biodiesel as B10,B20 and B30 at various compression ratios for different loads varying with help of loading unit. Various engine performance parameters BTE and BSFC were measured with the help of digital lab view software and emission parameters like HC, CO and NOx were measured with Emission Gas Analyzer. Smoke opacity is measured with the help of smoke meter and the results were plotted against brake power. Line Diagram Fig-1. Line diagram of Experimental setup Properties Castor Neem Castor& Neem Diesel Density(gm/cc) 0.956 0.919 0.885 0.830 Viscosity(cst) 52 34 8.0 5.0 Flash point(deg C) 320 300 140 57 Calorific value(kJ/kg) 36000 35200 39974 42000
  • 3. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 06 Issue: 05 | May 2019 www.irjet.net p-ISSN: 2395-0072 © 2019, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 7134 Table - 2. Specifications of Test Rig. 3. RESULTS AND DISCUSSION 3.1. Brake Specific Fuel Consumption 1.4 1.6 1.8 2.0 2.2 2.4 2.6 2.8 3.0 3.2 3.4 3.6 0.34 0.36 0.38 0.40 0.42 0.44 0.46 0.48 0.50 0.52 0.54 0.56 0.58 0.60 0.62 0.64 0.66 BSFC(kg/kW-hr) BP (kW) 16.5 CR B0 B10 B20 B30 1.4 1.6 1.8 2.0 2.2 2.4 2.6 2.8 3.0 3.2 3.4 3.6 0.30 0.32 0.34 0.36 0.38 0.40 0.42 0.44 0.46 0.48 0.50 0.52 0.54 0.56 0.58 BSFC(kg/kW-hr) BP (kW) 17.5 CR B0 B10 B20 B30 1.4 1.6 1.8 2.0 2.2 2.4 2.6 2.8 3.0 3.2 3.4 3.6 0.28 0.30 0.32 0.34 0.36 0.38 0.40 0.42 0.44 0.46 0.48 0.50 0.52 0.54 BSFC(kg/kW-hr) BP (kW) 18.5 CR B0 B10 B20 B30 Fig-2. Variation of BSFC Vs BP for various compression ratios. PARTICULARS SPECIFICATIONS Type Vertical, 4-Stroke Cycle, Single Acting, Totally Enclosed, Water cooled Type of Ignition Compression Ignition Rated Power 3.5 kW Injection opening pressure 200 bar Constant Speed 1500 RPM Variable compression ratio 16.5:1 to 18.5:1 Fuel Injection Direct Injection Injection Timing 23° BTDC Dynamometer Eddy Current Type
  • 4. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 06 Issue: 05 | May 2019 www.irjet.net p-ISSN: 2395-0072 © 2019, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 7135 Fig. shows that the graphs presented variation of specific fuel consumption v/s break power of combination of neem & castor methyl ester (50:50) blends B10, B20 & B30 with diesel for compression ratios 16.5, 17.5 and 18.5. From the graph it is shown that on an average, the BSFC is reduced by 17%, when compression ratio increases from 16.5 to 18.5 for blends, which could be due to low heat losses and better combustion at higher compression ratio. The BSFC depreciates gradually with increment in load; at high load run, it shows optimum. The blend B10 shows less BSFC comparing to other blends B20 & B30 at all compression ratios but it is increased compared to that of diesel by 17%, 6% and 20% at compression ratios 16.5, 17.5 and 18.5 respectively. As the concentration of blend increase for biodiesel, showing increment in BSFC for all loads which is due to lower calorific values of B20 & B30 resulted more fuel consumption for same output energy. 3.2. Brake Thermal Efficiency 1.4 1.6 1.8 2.0 2.2 2.4 2.6 2.8 3.0 3.2 3.4 3.6 12 14 16 18 20 22 24 26 28 30 32 BTE(%) BP (kW) 16.5 CR B0 B10 B20 B30 1.4 1.6 1.8 2.0 2.2 2.4 2.6 2.8 3.0 3.2 3.4 3.6 14 16 18 20 22 24 26 28 30 32 BTE(%) BP (kW) 18.5 CR B0 B10 B20 B30 1.6 1.8 2.0 2.2 2.4 2.6 2.8 3.0 3.2 3.4 3.6 16 18 20 22 24 26 28 30 32 BTE(%) BP (kW) 17.5 CR B0 B10 B20 B30 Fig-3. Variation of BTE Vs BP for various compression ratios. Fig. shows the BTE of combination of neem & castor methyl ester blends and diesel against BP (break power) at compression ratios 16.5, 17.5 and 18.5. The graph clears that on an average, the break thermal efficiency is increased by 8%, when compression ratio increases from 16.5 to 18.5 for all the blends. Because of increment in compression ratio cause to complete combustion, and this may increase the efficiency. The BTE increases steadily with increment in load due to higher power produced at high load run. The blend B10 shows more BTE compared to other blends B20 & B30 at all compression ratios but it is still reduced by an average 17% compared to that of diesel at various compression ratios.
  • 5. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 06 Issue: 05 | May 2019 www.irjet.net p-ISSN: 2395-0072 © 2019, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 7136 3.3. Carbon Monoxide 1.4 1.6 1.8 2.0 2.2 2.4 2.6 2.8 3.0 3.2 3.4 3.6 0.02 0.03 0.04 0.05 0.06 0.07 0.08 0.09 0.10 0.11 0.12 0.13 0.14 CO(%) BP (kW) 16.5 CR B0 B10 B20 B30 1.4 1.6 1.8 2.0 2.2 2.4 2.6 2.8 3.0 3.2 3.4 3.6 0.02 0.03 0.04 0.05 0.06 0.07 0.08 0.09 0.10 0.11 0.12 0.13 0.14 CO(%) BP (kW) 18.5 CR B0 B10 B20 B30 1.4 1.6 1.8 2.0 2.2 2.4 2.6 2.8 3.0 3.2 3.4 3.6 0.02 0.03 0.04 0.05 0.06 0.07 0.08 0.09 0.10 0.11 0.12 0.13 0.14 0.15 CO(%) BP (kW) 17.5 CR B0 B10 B20 B30 Fig-4. Variation of CO Vs BP for various compression ratios. Fig. shows the variation in emissions of carbon monoxide v/s break power for blends B10, B20 & B30 of castor & neem biodiesel and diesel at CR 16.5, 17.5 and 18.5. From the figure, it is clear that CO emissions are low at higher compression ratio due to adequate heat of compression boosts ignition; therefore, on an average, the CO emissions are decreased by 14% with increase in compression ratio from 16.5 to 18.5 for all the blends. Blends B10 & B20 have fewer emissions than B30 and diesel. On an average, B10 & B20 CO emissions are reduced compared to that of diesel by 25% and 17% respectively for compression ratios 16.5, 17.5 and 18.5. 3.4. Hydrocarbon 1.4 1.6 1.8 2.0 2.2 2.4 2.6 2.8 3.0 3.2 3.4 3.6 25 30 35 40 45 50 55 60 65 70 75 HC(ppm) BP (kW) 16.5 CR B0 B10 B20 B30 1.4 1.6 1.8 2.0 2.2 2.4 2.6 2.8 3.0 3.2 3.4 3.6 30 35 40 45 50 55 60 65 70 HC(ppm) BP (kW) 18.5 CR B0 B10 B20 B30
  • 6. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 06 Issue: 05 | May 2019 www.irjet.net p-ISSN: 2395-0072 © 2019, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 7137 1.4 1.6 1.8 2.0 2.2 2.4 2.6 2.8 3.0 3.2 3.4 3.6 30 35 40 45 50 55 60 65 70 75 80 HC(ppm) BP (kW) 17.5 CR B0 B10 B20 B30 Fig-5.Variation of HC Vs BP for various compression ratios Fig. shows the variation of unburnt hydrocarbons for different blends of neem &castor combination biodiesel and diesel at compression ratios 16.5, 17.5 and 18.5. From the graph, it is clear that the HC emissions are increasing with load increases for all the blends and diesel. On an average, the HC emissions were diminished by 8% for all the blends along with unadulterated diesel as compression ratio increases from 16.5 to 18.5.this increment prompts increase in temperature and pressure, that high temperature and high pressure ensure complete combustion, because of this complete combustion HC emissions were low. In addition, from the graphs it is cleared that B10 and B20 have less unburnt HC emissions than B30 & diesel. On an average, the HC emissions of B10 & B20 were reduced by 20% and 13% respectively, compared to that of diesel at compression ratios 16.5, 17.5 and 18.5. 3.5. NOx Emissions 1.4 1.6 1.8 2.0 2.2 2.4 2.6 2.8 3.0 3.2 3.4 3.6 500 600 700 800 900 1000 1100 1200 1300 1400 NOx(ppm) BP (kW) 16.5 CR B0 B10 B20 B30 1.4 1.6 1.8 2.0 2.2 2.4 2.6 2.8 3.0 3.2 3.4 3.6 600 700 800 900 1000 1100 1200 1300 1400 1500 NOx(ppm) BP (kW) 17.5 CR B0 B10 B20 B30 1.4 1.6 1.8 2.0 2.2 2.4 2.6 2.8 3.0 3.2 3.4 3.6 500 600 700 800 900 1000 1100 1200 1300 1400 1500 NOx(ppm) BP (kW) 18.5 CR B0 B10 B20 B30 Fig-6. Variation of NOx Vs BP for various compression ratios
  • 7. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 06 Issue: 05 | May 2019 www.irjet.net p-ISSN: 2395-0072 © 2019, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 7138 Fig. shows the variation of NOx emissions as a function of break power of diesel and C&N (50:50) blends as B10, B20 and B30 for various compression ratios 16.5, 17.5 and 18.5. From the figure, it is noticed that NOx outflows are increased on an average by 10% for all the blends and diesel, when compression ratio was increased from 16.5 to 18.5. This is due to higher combustion temperature makes nitrogen to react with oxygen in high proportion. In addition, B10 and diesel are having fewer NOx emissions as compared to that of B20 & B30. On an average, NOx discharges of B10, B20 and B30 were enhanced by 9%, 23% and 32% respectively, for various compression ratios 16.5, 17.5 and 18.5. 3.6. Smoke Opacity 1.4 1.6 1.8 2.0 2.2 2.4 2.6 2.8 3.0 3.2 3.4 3.6 5 10 15 20 25 30 35 40 HSU BP (kW) 16.5 CR B0 B10 B20 B30 1.4 1.6 1.8 2.0 2.2 2.4 2.6 2.8 3.0 3.2 3.4 3.6 10 15 20 25 30 35 40 45 HSU BP (kW) 17.5 CR B0 B10 B20 B30 1.4 1.6 1.8 2.0 2.2 2.4 2.6 2.8 3.0 3.2 3.4 3.6 10 15 20 25 30 35 40 HSU BP (kW) 18.5 CR B0 B10 B20 B30 Fig-7. Variation of HSU Vs BP for various compression ratios Fig. shows the smoke opacity graphs of castor & neem combination(50:50) biodiesel blends along with diesel were plotted against break power for various compression ratios 16.5,17 .5 and 18.5. From the graph it is cleared that smoke emissions of different blends of C&N[50:50] in form of B10,B20 & B30 were reduced on an average by 14%, when compression ratio was increased from 16.5 to 18.5. On an average, the smoke emissions were increased compared to that of diesel by 7%, 19% and 19% for B10, B20 and B30 respectively. This is due to higher viscosity results in slow combustion increasing smoke emissions. Conclusions From the exploratory examination on performance and emission test on diesel engine with blends of castor & neem biodiesel, we can infer that:  Castor & neem biodiesel combination blend B10 is showing more brake thermal efficiency and less BSFC than remaining blends B20 and B30 at all compression ratios. However, it shows less brake thermal efficiency and more BSFC than pure diesel by an average 17% and 15% respectively.
  • 8. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 06 Issue: 05 | May 2019 www.irjet.net p-ISSN: 2395-0072 © 2019, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 7139  CO & HC outflows of B10 were less compared to other blends and those were reduced compared to diesel by an average 25% and 20% respectively, but NOX discharges and smoke discharges were enhanced compared to diesel by an average 9% and 7% respectively.  For all the blends, BSFC is lowered and BTE is enhanced by an average 17% and 8% respectively, when compression ratio was increased from 16.5 to 18.5. In addition, CO, HC and smoke emissions were reduced by an average 14%, 8% and 14% respectively, where as NOx emissions were increased by an average 10%.  Finally, the blend B10 is showing good performance and optimum emissions at compression ratio 18.5:1. Therefore, we can replace diesel with B10 in diesel engine without any modification. Table-3. Nomenclature B10 10% Caser & neem +90% Diesel B20 20% Caser & neem +80% Diesel B30 30% Caser & neem +70% Diesel BSFC Brake Specific Fuel Consumption BTE Brake Thermal Efficiency C &N Caster & Neem CO Carbon monoxide CR Compression Ratio HC Hydrocarbons HSU Hat ridge Smoke Unit IOP Injection opening pressure References [1] A.M. Liaquat, H.H. Masjuki, M.A. Kalam, I.M. Rizwanul Fattah, M.A. Hazrat, M. Varman, M. Mofijur, M. Shahabuddin, Performance and emission analysis of coconut biodiesel in diesel engine, Procedia Eng. 56 (2013) 583–590. [2] Mohamed F. Al Dawody, S.K. Bhatti, Experimental investigation on pilot engine by using soya bean biodiesel blends, Energy Procedia 52(2014) 421–430. [3]T.Senthil Kumar, P.Senthil Kumar, and K.Annamalai. Experimental study on the performance and emission measures of direct injection diesel engine with Kapok methyl ester and itsblends,DOI:10.1016/j.renene.2014.09.022. [4] K. Sivaramakrishnan, Investigation on performance and emission characteristics of a variable compression multi fuel engine fuelled with Karanja biodiesel–diesel blend, Egypt. J. Petrol. (2017), http://dx.doi.org/10.1016/j.ejpe.2017.03.001. [5] J.N.Nair, Arun Kumar Daram: Analysis of performance and emission on compression ignition engine fuelled with blends of neem biodiesel, Egypt.J. Petrol. (2016), http://dx.doi.org/10.1016/j.ejpe.2016.09.005. [6] G.Kasiraman, B.Nagalingam, M.Bala Krishnan: Performance, emission and combustion improvements in a direct injection diesel engine using cashew nut shell oil as fuel with camphor oil blending, https://doi.org/10.1016/j.energy.2012.09.022. [7] Dhinesh Balasubramanian, Isaac Joshua Ramesh Lalvani, Parthasarathy Murugesan, K. Annamalai: An assessment on performance, emission and combustion characteristics of single cylinder diesel engine powered by Cymbopogon flexuous biofuel, DOI: 10.1016/j.enconman.2016.03.049. [8] Panwar, NL, Hemant, Y, ShrirameRathore, NS, Sudhakar, J: Performance evaluation of a diesel engine fueled with methyl ester of castor seed oil. Appl. Therm. Eng. 30, 245-249 (2010).