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Chapter-3
Aliphatic Hydrocarbons
Mr. Amol R. Pagare
Department of Chemistry
Contents
• Introduction
• Alkanes
• Higher Alkanes
• Isomerism
• Nomenclature
• Preparation of Alkanes
• Reactions of Alkanes
Introduction
Organic compounds which consists of only Carbon
and Hydrogen atoms are know as hydrocarbons.
Hydrocarbons are of different types.
They are classified as follows :
Classification Of Hydrocarbon
Hydrocarbons
Aliphatic Hydrocarbon Aromatic Hydrocarbon
Benzene C6H6
Naphthalene C10H8
Alkanes C C
CnH2n+2
Methane
Ethane
Propane
Alkenes C C
CnH2n
Ethene
Propene
Alkenes C C
CnH2n-2
Acetylene
Propyne
Cyclic Aliphatic
CnH2n
Cyclo propane
Cyclo Butane
Classification by structure
 On the basis of structure, we separate all organic compounds into a
number of families (e.g. alcohol, amine, acid, alkane family). While
doing this we observe that, we have classified the compounds on the
basis of their physical and chemical properties. A Particular set of
properties is a characteristic of a particular kind of structure. The
variations in properties are also observed within a family, e.g.
Methane. b.p. is - I62"C while ethane b.p.is 88.5°C Not only this but
within a single compound there may be variations in properties, e.g.
lactic acid shows dextro and leavo rotation. These variations in
properties corresponds to variations in structure.
Alkane family
 Alkanes are saturated aliphatic hydrocarbons , containing C C .
General formula- CnH2n+2
Alkanes are also referred to as paraffin's.
The simplest alkane is the methane (CH4) which occurs in
nature. The next members-of the alkane family are ethane, propane,
butane, hexane etc. Many of them occur naturally and the chief
source of alkanes is mineral oil or petroleum. Therefore, these
hydrocarbons have been assigned to the same family as methane on
the basis of their structure.
Higher Alkanes: The Homologous Series
 When the alkanes are arranged in the increasing order of their
molecular formula we find that, the formula of each individual differ
from that of its 'neighbour by- CH2- group.
 A set of compounds, in which the members differ in composition
from one another by –CH2- is known as a homologous Series and tne
members of the series are called homologues. Homologous series is
observed in all types of organic compounds containing different
functional groups.
Different Homologous series
Alkanes Alcohols Alkyl halides
CH4 CH3 OH CH3 X
C2H6 C2H5 OH C2H5 X
C3H8 C3H7 OH C3H7 X
C4H10 C4H9 OH C4H9 X
C5H12 C5H11 OH C5H11 X
C6H14 C6H13 OH C6H13 X
C7H16 C7H15 OH C7H15 X
C8H18 C8H17 OH C8H17 X
C9H20 C9H19 OH C9H19 X
C10H22 C10H21 OH C10H21 X
Isomerism
 Compounds having same molecular formula but different structural
arrangements represent different compounds. Such compounds are
called isomers or isomerides, and the phenomenon is known as
isomerism.
 Isomer differ in their physical and chemical properties.
 As we go up the series of alkanes , we find that, as the number of
atoms increases the number of possible arrangements of these atoms
also increases. Thus, there are two different ways (I and II) of
arranging the four carbon atoms having molecular formula C4H10
Actually there exists two such compounds having different physical
properties n-butane and iso-butane.
To be Conti….
 CH3 CH2 CH2 CH3 CH3 CH CH3
 (I)- n-butane C4H10 (II)- Iso-butane C4H10
(b.p. O0c) (b.p. -120c)
CH3

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H ydrocarbon I

  • 1. Chapter-3 Aliphatic Hydrocarbons Mr. Amol R. Pagare Department of Chemistry
  • 2. Contents • Introduction • Alkanes • Higher Alkanes • Isomerism • Nomenclature • Preparation of Alkanes • Reactions of Alkanes
  • 3. Introduction Organic compounds which consists of only Carbon and Hydrogen atoms are know as hydrocarbons. Hydrocarbons are of different types. They are classified as follows :
  • 4. Classification Of Hydrocarbon Hydrocarbons Aliphatic Hydrocarbon Aromatic Hydrocarbon Benzene C6H6 Naphthalene C10H8 Alkanes C C CnH2n+2 Methane Ethane Propane Alkenes C C CnH2n Ethene Propene Alkenes C C CnH2n-2 Acetylene Propyne Cyclic Aliphatic CnH2n Cyclo propane Cyclo Butane
  • 5. Classification by structure  On the basis of structure, we separate all organic compounds into a number of families (e.g. alcohol, amine, acid, alkane family). While doing this we observe that, we have classified the compounds on the basis of their physical and chemical properties. A Particular set of properties is a characteristic of a particular kind of structure. The variations in properties are also observed within a family, e.g. Methane. b.p. is - I62"C while ethane b.p.is 88.5°C Not only this but within a single compound there may be variations in properties, e.g. lactic acid shows dextro and leavo rotation. These variations in properties corresponds to variations in structure.
  • 6. Alkane family  Alkanes are saturated aliphatic hydrocarbons , containing C C . General formula- CnH2n+2 Alkanes are also referred to as paraffin's. The simplest alkane is the methane (CH4) which occurs in nature. The next members-of the alkane family are ethane, propane, butane, hexane etc. Many of them occur naturally and the chief source of alkanes is mineral oil or petroleum. Therefore, these hydrocarbons have been assigned to the same family as methane on the basis of their structure.
  • 7. Higher Alkanes: The Homologous Series  When the alkanes are arranged in the increasing order of their molecular formula we find that, the formula of each individual differ from that of its 'neighbour by- CH2- group.  A set of compounds, in which the members differ in composition from one another by –CH2- is known as a homologous Series and tne members of the series are called homologues. Homologous series is observed in all types of organic compounds containing different functional groups.
  • 8. Different Homologous series Alkanes Alcohols Alkyl halides CH4 CH3 OH CH3 X C2H6 C2H5 OH C2H5 X C3H8 C3H7 OH C3H7 X C4H10 C4H9 OH C4H9 X C5H12 C5H11 OH C5H11 X C6H14 C6H13 OH C6H13 X C7H16 C7H15 OH C7H15 X C8H18 C8H17 OH C8H17 X C9H20 C9H19 OH C9H19 X C10H22 C10H21 OH C10H21 X
  • 9. Isomerism  Compounds having same molecular formula but different structural arrangements represent different compounds. Such compounds are called isomers or isomerides, and the phenomenon is known as isomerism.  Isomer differ in their physical and chemical properties.  As we go up the series of alkanes , we find that, as the number of atoms increases the number of possible arrangements of these atoms also increases. Thus, there are two different ways (I and II) of arranging the four carbon atoms having molecular formula C4H10 Actually there exists two such compounds having different physical properties n-butane and iso-butane.
  • 10. To be Conti….  CH3 CH2 CH2 CH3 CH3 CH CH3  (I)- n-butane C4H10 (II)- Iso-butane C4H10 (b.p. O0c) (b.p. -120c) CH3