This document provides an overview of organic chemistry concepts including hydrocarbons, functional groups, and several families of organic compounds. It discusses the four families of hydrocarbons - alkanes, alkenes, alkynes, and aromatics. It also examines some functional groups including alcohols, carboxylic acids, and esters. Finally, it analyzes the intermolecular forces between different organic molecule families and how these forces affect physical properties such as boiling points.
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Unit-2-Hydrocarbons.ppt
1. Chem 150
Unit 2 - Hydrocarbons &
Functional Groups
Organic chemistry is the chemistry of carbon. The name
“organic” reflect the fact that organic molecules are
derived from living organisms. In this unit will start by
looking at four families of organic molecules that are
grouped together as the hydrocarbons. We will also look
at some functional groups that define some of the other
families of organic molecules.
4. 4
Hydrocarbons
• Organic molecules contain carbon combined with other
elements.
• Organic molecules are grouped into families
• Members of a family share common structural, physical, and chemical
characteristics.
• There are four families that contain molecules made of only
carbon and hydrogen.
• Hydrocarbons
• Alkanes
• Alkenes
• Alkynes
• Aromatics
6. 6
Alkanes
Alkanes are hydrocarbons that contain only carbon-carbon
single bonds.
• Every carbon atom participates in 4 single bonds, either to
another carbon or to a hydrogen.
• Every hydrogen atom is bonded to a carbon by a single
bond.
8. 8
Alkanes
• Alkanes in which the carbons are connected in a straight
chain are called normal alkanes.
• Alkanes that are branched are called branched chain
alkanes.
n-hexane
2-methyl-pentane
9. Alkanes
For a discusion on the structure of alkanes,
see the Unit 2
Elaboration - Alkane Structure
10. 10
Alkanes
• Alkanes, along with the other hydrocarbons, are non-polar.
• They interact with each other only through London
dispersion forces.
• This is why they have relatively low boiling and melting
points.
11. 11
They interact with each other only through London dispersion
forces.
• Note how the boiling points increase with molecular weight.
Alkanes
15. 15
Alkanes, cannot be named based on their molecular formulas
• For example, all of the molecules shown below share the
same molecular formula, C6H14
(hexacarbon tetradecahydride?)
Alkanes
n-hexane
2-methyl-pentane 3-methyl-pentane 2,2-dimethylbutane 2,3-dimethylbutane
16. 16
Organic chemists use a systematic set of rules, called the
IUPAC rules, to name organic molecules based on their
structural formulas instead of their chemical formulas.
Alkanes
n-hexane
2-methyl-pentane 3-methyl-pentane 2,2-dimethylbutane 2,3-dimethylbutane
18. 18
When two or more molecules share the same molecular
formula, but have different atomic connections, they are
called constitutional isomers.
Constitutional Isomers
n-hexane
2-methyl-pentane 3-methyl-pentane 2,2-dimethylbutane 2,3-dimethylbutane
20. 20
Conformations
All of the 3-dimensional models shown below are for the n-
butane.
• They were generated by rotating the central carbon-carbon
bond.
• They all share the same structural formula.
21. 21
Conformations
All of the 3-dimensional models shown below are for the n-
butane.
• They were generated by rotating the central carbon-carbon
bond.
22. 22
Conformations
Switching from one conformation to another does not require
the breaking and making of covalent bonds.
• Switching from one isomer to another does require the
breaking and making of covalent bonds.
n-butane 2-methylpropane
24. 24
Cycloalkanes
When there are three or more carbons in a straight chain, the
ends can be joined to make rings.
• In naming these molecules, the prefix cyclo- is used to
indicate the ring:
• Skeletal structural formulas are used to represent the rings
in structural formulas:
25. 25
In naming these molecules, the prefix cyclo- is used to
indicate the ring:
Cycloalkanes
As Parent Chain As Substituent Group
26. 26
The carbon-carbon single bonds for the carbons in a ring are
no longer free to rotate.
• This leads to a new type of isomer
• Since the two structures share the same name, they are
not constitutional isomers.
Cycloalkanes
27. 27
Isomers which share the same atomic connections, and
therefore, the same IUPAC name are called stereoisomers.
• When this occurs due to restricted rotation about a
covalent bond, they are called geometric isomers
• The prefix cis- and trans- are used to distinguish geometric
isomers.
Cycloalkanes
28. 28
Questions
Draw the condensed structural formulas for the following
molecules:
A) 1-ethyl-2-methylcyclopentane
B) 1,1-dimethylcyclobutane
C) 1,1-dimethyl-2-propylcyclopropane
Do any of these molecules have cis- and trans- geometric
isomers?
29. 29
Alkenes, Alkynes & Aromatic Compounds
The remaining three families of hydrocarbons are
unsaturated.
• Alkanes are saturated, which means they contain the
maximum number of hydrogens per carbon.
• For alkanes CnH(2n+2)
• Alkenes, Alkynes and Aromatics are unsaturated, which
means they contain less than the maximum number of
hydrogens per carbon.
• Structurally, this means that they have carbon-carbon double or triple bonds
30. 30
Alkenes, Alkynes & Aromatic Compounds
Alkenes are hydrocarbons that contain at least 1 carbon-
carbon double bond.
• Examples:
31. 31
Alkenes, Alkynes & Aromatic Compounds
Alkynes are hydrocarbons that contain at least 1 carbon-
carbon triple bond.
• Examples:
32. 32
Alkenes, Alkynes & Aromatic Compounds
Aromatics are unsaturated ring molecules
• They are often drawn to look like alkenes, but they behave
much differently than alkenes.
• They have an alternating pattern of double and single
bonds within a ring.
• Benzene is an example
33. 33
Alkenes, Alkynes & Aromatic Compounds
The physical properties of all hydrocarbons are the same
• The have essentially one noncovalent interaction, which
isthe London dispersion force.
• They have no electronegative atoms and therefore have
• No ion/ion interactions
• No dipole/dipole interactions
• No hydrogenbonding interactions
34. 34
Alkenes, Alkynes & Aromatic Compounds
Naming of Alkenes and Alkynes work the same as for
alkanes, with these added rules:
• The parent chain must include both carbons in all double
and triple bonds.
• Pick the longest chain that also contains all double and triple bonds
• The -ene ending is used of alkenes
• The -yne ending is used for alkynes.
• The number of the first carbon in the double or triple bond is
included in the name to locate the double or triple bond.
• Number the parent chain from the end that is closes to the first double or triple
bond.
35. 35
Alkenes, Alkynes & Aromatic Compounds
Naming of Aromatics is based on benzene:
• When the molecule is build on benzene, the parent name
is “benzene”.
• There are also many common names used to describe
aromatic compounds.
36. 36
Alkenes, Alkynes & Aromatic Compounds
Naming of Aromatics is based on benzene:
• Aromatic compounds can contain multiple aromatic rings
37. 37
Alkenes, Alkynes & Aromatic Compounds
Benzo(a)pyrene found in tobacco smoke is converted to
carcinogenic products in the liver (see below) which link to
DNA and cause mutations.
38. 38
Practice Quiz 1 KEY
http://www.chem.uwec.edu/Chem150_S07/course/answers/C
150-Quiz-1-key.swf
39. 39
Alkenes, Alkynes & Aromatic Compounds
There are many aromatic molecules found in biology
• Some aromatic compounds contain nitrogen and oxygen
atoms
• For example, the nucleotide base Adenine, which is used
to make DNA and RNA
40. 40
Alkenes, Alkynes & Aromatic Compounds
Like cycloalkanes, some alkenes can have cis and trans
isomers
• This is due to restricted rotation about the double-bond.
• Not all double bonds produce cis and trans isomers
• Each carbon participating in the double bond must have two different
substituents attached to them
A ≠ B AND X ≠ Y
41. 41
Alkenes, Alkynes & Aromatic Compounds
Like cycloalkanes, some alkenes can have cis and trans
isomers
42. 42
Alcohols, Carboxylic Acids & Esters
In addition to the four families of hydrocarbons, there are also
many other families of organic molecules.
These other families include elements other than carbon and
hydrogen.
• They exhibit a wide range of chemical and physical
properties.
• The families are distinguished by a group of atoms called a
functional group
43. 43
Alcohols, Carboxylic Acids & Esters
Functional Group
“A functional group is an atom, group of atoms or bond that
gives a molecule a particular set of chemical and physical
properties”
44. 44
Alcohols, Carboxylic Acids & Esters
The carbon-carbon double bonds found in alkenes is an
example of a functional group.
• A chemical property of a double is that it will absorb
hydrogen in the hydrogenation reaction.
45. 45
We look now at three families that are distinguished by a
functional group that contains the element oxygen.
Alcohols
• Members of the alcohol family contain a hydroxyl group.
• The hydroxyl group comprises an oxygen with one single
bond to a hydrogen and another single bond to an alkane-
type carbon
Alcohols, Carboxylic Acids & Esters
hydroxyl group
An alkane-type carbon atom
ethanol
46. 46
We look now at three families that are distinguished by a
functional group that contains the element oxygen.
Carboxylic acids
• Members of the carboxylic acid family contain a carboxylic
acid group
• The carboxylic acid group comprises a hydroxyl group
connected to a carbonyl group:
Alcohols, Carboxylic Acids & Esters
+
carbonyl group hydroxyl group carboxylic acid group
47. 47
Alcohols, Carboxylic Acids & Esters
Carboxylic acids
• The present of the hydroxyl group next to the cabonyl
group completely changes it properties.
• The alcohol hydroxyl group and the carboxylic acid hydroxyl group are
chemically quite different, which is why molecules that have the carboxylic acid
group are placed in a separate family from the alcohols.
• Later in the semester we will learn about some of these chemical differences.
+
carbonyl group hydroxyl group carboxylic acid group
48. 48
Carboxylic acids
• The carboxylic acid group can be attached to a hydrogen,
an alkane-type carbon, or an aromatic-type carbon:
Alcohols, Carboxylic Acids & Esters
methanoic acid
(formic acid)
propanoic acid benzoic acid
49. 49
We look now at three families that are distinguished by a
functional group that contains the element oxygen.
Esters
• Chemically, esters can be synthesized by reacting a
carboxylic acid with and alcohol:
Alcohols, Carboxylic Acids & Esters
carboxylic
acid
alcohol ester water
50. 50
We look now at three families that are distinguished by a
functional group that contains the element oxygen.
Esters
• Chemically, esters can be synthesize by reacting a
carboxylic acid with and alcohol:
Alcohols, Carboxylic Acids & Esters
Ethyl propanoate
51. 51
Carboxylic acids
• The carboxylic acid group can be attached to a hydrogen,
an alkane-type carbon, or an aromatic-type carbon:
Alcohols, Carboxylic Acids & Esters
methanoic acid
(formic acid)
propanoic acid benzoic acid
52. 52
As we saw with the hydrocarbons, the physical properties of
organic molecules depend on the noncovalent intermolecular
interactions which attract one one molecule to another.
• With hydrocarbons, there is only one type of noncovalent
interaction:
• Induced dipole/Induced dipole (London dispersion force)
• The presence of the electronegative oxygen makes
alcohols, carboxylic acids and esters polar molecules,
these families, therefore, have at least two types of
noncovalent interactions:
• Induced dipole/Induced dipole (London dispersion force)
• Dipole/Dipole
Alcohols, Carboxylic Acids & Esters
53. 53
As we saw with the hydrocarbons, the physical properties of
organic molecules depend on the noncovalent intermolecular
interactions which attract one one molecule to another.
• Alcohols and Carboxylic acids also have a hydroxyl group
with a hydrogen bonded to an oxygen. This allows them to
form hydrogen bonds with each other. Therefore,
carboxylic acids have at least three different noncovalent
interactions:
• Induced dipole/Induced dipole (London dispersion force)
• Dipole/Dipole
• Hydrogen bond
Alcohols, Carboxylic Acids & Esters
54. 54
To summarize, the types of noncovalent interact ions that
each family can participate in include:
• Hydrocarbons (Alkanes, Alkenes, Alkynes &
Aromatics)
• Induced dipole/Induced dipole (London dispersion force)
• Esters
• Induced dipole/Induced dipole (London dispersion force)
• Dipole/Dipole
• Alcohols & Carboxylic acids
• Induced dipole/Induced dipole (London dispersion force)
• Dipole/Dipole
• Hydrogen bond
Alcohols, Carboxylic Acids & Esters
55. 55
These interactions are illustrated in Figure 4.23 of your
textbook.
Alcohols, Carboxylic Acids & Esters
alcohols
carboxylic acids
esters
56. 56
Boiling points are a good measure of the strength of the
noncovalent interactions between molecules.
• The stronger the interactions, the higher the boiling point
will be.
• Since all molecules have the London dispersion
interaction, the boiling points of molecules is expected to
increase with temperature.
• The next slide shows a chart using the data found in Table
4.7 of Raymond, in which the boiling points for alcohols,
carboxylic acids and esters are plotted against molecular
weight.
Alcohols, Carboxylic Acids & Esters
57. 57
Alcohols, Carboxylic Acids & Esters
• As expected, the boiling points
for members of all three
families increases with
molecular weight due to the
London dispersion interactions.
• For a given molecular weight,
the alcohols and carboxylic
acids have a higher boiling
point than esters, this is
because they can form
hydrogen bonds and esters
cannot.
• The carboxylic acids have a
slightly higher boiling point
than alcohols, because they
can form two hydrogen bonds
with a neighboring molecule
(See Figure 4.23 in Raymond)
Molecular Weight {g/mol}
Boiling
Point
{°C}
58. 58
Alcohols, Carboxylic Acids & Esters
Another distinguishing characteristic of many of the families is
odor.
• You nose is actually a highly sensitive chemical detector.
• The members of different families can interact differently
with the receptors in your nose to produce smells that are
characteristic of the families they belong to.
• For example:
• Carboxylic acids produce the pungent, sometime unpleasant odors associated
with ripe cheeses, rancid butter and vomit.
• Esters, on the other hand, produce the sweet, often pleasant order associated
with flowers, perfumes and various natural and artificial flavorings. The next
slide shows Figure 4.24 from Raymond, which gives some specific examples.