This document provides an introduction to organic chemistry for A-level students. It begins with an overview of organic chemistry and the special properties of carbon that allow for the vast number of carbon compounds. It then discusses specific topics like functional groups, isomers, naming conventions (IUPAC), and more. The document is intended to help students understand key concepts in organic chemistry.
Structural diagrams,condensed structures and line structures of hydrocarbons.How to identify a substance as Organic and inorganic ?.How to classify hydrocarbons? What is the difference between alkanes,alkenes and alkynes?
Organic Chemistry
1. History
2. Properties of Organic Chemistry
3. comparison of Compounds
4. Sources of Organic Compounds
5. Types of Organic Compounds
6.Types of Organic Formula
7. Carbon
8. Structural Formulas of Carbon
9. Isomerism
10 Classification of Organic Compounds
11. HydroCarbons
Structural diagrams,condensed structures and line structures of hydrocarbons.How to identify a substance as Organic and inorganic ?.How to classify hydrocarbons? What is the difference between alkanes,alkenes and alkynes?
Organic Chemistry
1. History
2. Properties of Organic Chemistry
3. comparison of Compounds
4. Sources of Organic Compounds
5. Types of Organic Compounds
6.Types of Organic Formula
7. Carbon
8. Structural Formulas of Carbon
9. Isomerism
10 Classification of Organic Compounds
11. HydroCarbons
Organic chemistry has two main divisions. One division deals with aliphatic (fatty) compounds, the first compounds you encountered in Organic Chemistry I. The second division includes the aromatic (fragrant) compounds, of which benzene is a typical example.
Alkanes are organic compounds that consist entirely of single-bonded carbon and hydrogen atoms and lack any other functional groups. Alkanes have the general formula CnH2n+2 and can be subdivided into the following three groups: the linear straight-chain alkanes, branched alkanes, and cycloalkanes.
Organic chemistry has two main divisions. One division deals with aliphatic (fatty) compounds, the first compounds you encountered in Organic Chemistry I. The second division includes the aromatic (fragrant) compounds, of which benzene is a typical example.
Alkanes are organic compounds that consist entirely of single-bonded carbon and hydrogen atoms and lack any other functional groups. Alkanes have the general formula CnH2n+2 and can be subdivided into the following three groups: the linear straight-chain alkanes, branched alkanes, and cycloalkanes.
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Or Ganic Intro
1. AN INTRODUCTION TO ORGANIC CHEMISTRY A guide for A level students KNOCKHARDY PUBLISHING
2. INTRODUCTION This Powerpoint show is one of several produced to help students understand selected topics at AS and A2 level Chemistry. It is based on the requirements of the AQA and OCR specifications but is suitable for other examination boards. Individual students may use the material at home for revision purposes or it may be used for classroom teaching if an interactive white board is available. Accompanying notes on this, and the full range of AS and A2 topics, are available from the KNOCKHARDY SCIENCE WEBSITE at... www.knockhardy.org.uk/sci.htm Navigation is achieved by... either clicking on the grey arrows at the foot of each page or using the left and right arrow keys on the keyboard KNOCKHARDY PUBLISHING ORGANIC CHEMISTRY
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5. ORGANIC CHEMISTRY Organic chemistry is the study of carbon compounds . It is such a complex branch of chemistry because... • CARBON ATOMS FORM STRONG COVALENT BONDS TO EACH OTHER • THE CARBON-CARBON BONDS CAN BE SINGLE, DOUBLE OR TRIPLE • CARBON ATOMS CAN BE ARRANGED IN STRAIGHT CHAINS BRANCHED CHAINS and RINGS • OTHER ATOMS/GROUPS OF ATOMS CAN BE PLACED ON THE CARBON ATOMS • GROUPS CAN BE PLACED IN DIFFERENT POSITIONS ON A CARBON SKELETON
6. SPECIAL NATURE OF CARBON - CATENATION CATENATION is the ability to form bonds between atoms of the same element . Carbon forms chains and rings, with single, double and triple covalent bonds, because it is able to FORM STRONG COVALENT BONDS WITH OTHER CARBON ATOMS Carbon forms a vast number of carbon compounds because of the strength of the C-C covalent bond . Other Group IV elements can do it but their chemistry is limited due to the weaker bond strength. BOND ATOMIC RADIUS BOND ENTHALPY C-C 0.077 nm +348 kJmol -1 Si-Si 0.117 nm +176 kJmol -1 The larger the atoms , the weaker the bond . Shielding due to filled inner orbitals and greater distance from the nucleus means that the shared electron pair is held less strongly .
7. CHAINS AND RINGS CARBON ATOMS CAN BE ARRANGED IN STRAIGHT CHAINS BRANCHED CHAINS and RINGS THE SPECIAL NATURE OF CARBON You can also get a combination of rings and chains
8. MULTIPLE BONDING AND SUBSTITUENTS CARBON-CARBON COVALENT BONDS CAN BE SINGLE, DOUBLE OR TRIPLE THE SPECIAL NATURE OF CARBON
9. MULTIPLE BONDING AND SUBSTITUENTS CARBON-CARBON COVALENT BONDS CAN BE SINGLE, DOUBLE OR TRIPLE DIFFERENT ATOMS / GROUPS OF ATOMS CAN BE PLACED ON THE CARBONS The basic atom is HYDROGEN but groups containing OXYGEN , NITROGEN , HALOGENS and SULPHUR are very common. CARBON SKELETON FUNCTIONAL CARBON SKELETON FUNCTIONAL GROUP GROUP The chemistry of an organic compound is determined by its FUNCTIONAL GROUP THE SPECIAL NATURE OF CARBON
10. MULTIPLE BONDING AND SUBSTITUENTS ATOMS/GROUPS CAN BE PLACED IN DIFFERENT POSITIONS ON A CARBON SKELETON THE SPECIAL NATURE OF CARBON THE C=C DOUBLE BOND IS IN A DIFFERENT POSITION THE CHLORINE ATOM IS IN A DIFFERENT POSITION PENT-1-ENE PENT-2-ENE 1-CHLOROBUTANE 2-CHLOROBUTANE
11. TYPES OF FORMULAE - 1 MOLECULAR FORMULA C 4 H 10 The exact number of atoms of each element present in the molecule EMPIRICAL FORMULA C 2 H 5 The simplest whole number ratio of atoms in the molecule STRUCTURAL FORMULA CH 3 CH 2 CH 2 CH 3 CH 3 CH(CH 3 )CH 3 The minimal detail using conventional groups, for an unambiguous structure there are two possible structures DISPLAYED FORMULA Shows both the relative placing of atoms and the number of bonds between them THE EXAMPLE BEING USED IS... BUTANE
12. SKELETAL FORMULA A skeletal formula is used to show a simplified organic formula by removing hydrogen atoms from alkyl chains, leaving just a carbon skeleton and associated functional groups TYPES OF FORMULAE - 2 CYCLOHEXANE THALIDOMIDE for
13. SKELETAL FORMULA A skeletal formula is used to show a simplified organic formula by removing hydrogen atoms from alkyl chains, leaving just a carbon skeleton and associated functional groups GENERAL FORMULA Represents any member of for alkanes it is... C n H 2n+2 a homologous series possible formulae... CH 4 , C 2 H 6 .... C 99 H 200 The formula does not apply to cyclic compounds such as cyclohexane is C 6 H 12 - by joining the atoms in a ring you need fewer H’s TYPES OF FORMULAE - 2 CYCLOHEXANE THALIDOMIDE for
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15. FUNCTIONAL GROUPS Organic chemistry is a vast subject so it is easier to split it into small sections for study. This is done by studying compounds which behave in a similar way because they have a particular atom, or group of atoms, FUNCTIONAL GROUP , in their structure. Functional groups can consist of one atom, a group of atoms or multiple bonds between carbon atoms. Each functional group has its own distinctive properties which means that the properties of a compound are governed by the functional group(s) in it. Carbon Functional Carbon Functional skeleton Group = AMINE skeleton Group = ALCOHOL H H H H H H C C C C C OH H H H H H H H H H H H C C C C C NH 2 H H H H H
16. COMMON FUNCTIONAL GROUPS GROUP ENDING GENERAL FORMULA EXAMPLE ALKANE - ane RH C 2 H 6 ethane ALKENE - ene C 2 H 4 ethene ALKYNE - yne C 2 H 2 ethyne HALOALKANE halo - RX C 2 H 5 Cl chloroethane ALCOHOL - ol ROH C 2 H 5 OH ethanol ALDEHYDE -al RCHO CH 3 CHO ethanal KETONE - one RCOR CH 3 COCH 3 propanone CARBOXYLIC ACID - oic acid RCOOH CH 3 COOH ethanoic acid ACYL CHLORIDE - oyl chloride RCOCl CH 3 COCl ethanoyl chloride AMIDE - amide RCONH 2 CH 3 CONH 2 ethanamide ESTER - yl - oate RCOOR CH 3 COOCH 3 methyl ethanoate NITRILE - nitrile RCN CH 3 CN ethanenitrile AMINE - amine RNH 2 CH 3 NH 2 methylamine NITRO nitro- RNO 2 CH 3 NO 2 nitromethane SULPHONIC ACID - sulphonic acid RSO 3 H C 6 H 5 SO 3 H benzene sulphonic acid ETHER - oxy - ane ROR C 2 H 5 OC 2 H 5 ethoxyethane
18. HOW MANY STRUCTURES? Draw legitimate structures for each molecular formula and classify each one according to the functional group present. Not all the structures represent stable compounds . carbon atoms have 4 covalent bonds surrounding them oxygen atoms 2 nitrogen atoms 3 hydrogen 1 halogen atoms 1 C 2 H 6 ONE C 3 H 7 Br TWO C 4 H 8 FIVE - 3 with C=C and 2 ring compounds with all C-C’s C 2 H 6 O TWO - 1 with C-O-C and 1 with C-O-H C 3 H 6 O SIX - 2 with C=O, 2 with C=C and 2 with rings C 2 H 7 N TWO C 2 H 4 O 2 SEVERAL - Only 2 are stable C 2 H 3 N TWO
19. HOW MANY STRUCTURES? Draw legitimate structures for each molecular formula and classify each one according to the functional group present. Not all the structures represent stable compounds . carbon atoms have 4 covalent bonds surrounding them oxygen atoms 2 nitrogen atoms 3 hydrogen 1 halogen atoms 1 C 2 H 6 ONE C 3 H 7 Br TWO C 4 H 8 FIVE - 3 with C=C and 2 ring compounds with all C-C’s C 2 H 6 O TWO - 1 with C-O-C and 1 with C-O-H C 3 H 6 O SIX - 2 with C=O, 2 with C=C and 2 with rings C 2 H 7 N TWO C 2 H 4 O 2 SEVERAL - Only 2 are stable C 2 H 3 N TWO
20. NOMENCLATURE Ideally a naming system should tell you everything about a structure without ambiguity. There are two types of naming system commonly found in organic chemistry; Trivial : based on some property or historical aspect; the name tells you little about the structure Systematic : based on an agreed set of rules (I.U.P.A.C); exact structure can be found from the name (and vice-versa). HOMOLOGOUS SERIES trivial name systematic name example(s) paraffin alkane methane, butane olefin alkene ethene, butene fatty acid alkanoic (carboxylic) acid ethanoic acid INDIVIDUAL COMPOUNDS trivial name derivation systematic name methane methu = wine (Gk.) methane (CH 4 ) butane butyrum = butter (Lat.) butane (C 4 H 10 ) acetic acid acetum = vinegar (Lat.) ethanoic acid (CH 3 COOH)
21. I.U.P.A.C. NOMENCLATURE A systematic name has two main parts. STEM number of carbon atoms in longest chain bearing the functional group + a prefix showing the position and identity of any side-chain substituents. Apart from the first four, which have trivial names , the number of carbons atoms is indicated by a prefix derived from the Greek numbering system. The list of alkanes demonstrate the use of prefixes. The ending -ane is the same as they are all alkanes. Prefix C atoms Alkane meth- 1 methane eth- 2 ethane prop- 3 propane but- 4 butane pent- 5 pentane hex- 6 hexane hept- 7 heptane oct- 8 octane non- 9 nonane dec- 10 decane Working out which is the longest chain can pose a problem with larger molecules.
22. I.U.P.A.C. NOMENCLATURE How long is a chain? Because organic molecules are three dimensional and paper is two dimensional it can confusing when comparing molecules. This is because... 1. It is too complicated to draw molecules with the correct bond angles 2. Single covalent bonds are free to rotate All the following written structures are of the same molecule - PENTANE C 5 H 12 A simple way to check is to run a finger along the chain and see how many carbon atoms can be covered without reversing direction or taking the finger off the page. In all the above there are... FIVE CARBON ATOMS IN A LINE . CH 2 CH 3 CH 2 CH 2 CH 3 CH 2 CH 2 CH 2 CH 3 CH 3 CH 3 CH 2 CH 2 CH 2 CH 3 CH 2 CH 2 CH 2 CH 3 CH 3
23. I.U.P.A.C. NOMENCLATURE How long is the longest chain? Look at the structures and work out how many carbon atoms are in the longest chain. THE ANSWERS ARE ON THE NEXT SLIDE CH 2 CH 3 CH 2 CH 2 CH CH 3 CH 3 CH 2 CH 3 CH 3 CH CH 2 CH 3 CH 3 CH 3 CH CH 2 CH 2 CH 3 CH CH 3
24. I.U.P.A.C. NOMENCLATURE How long is the longest chain? Look at the structures and work out how many carbon atoms are in the longest chain. LONGEST CHAIN = 5 LONGEST CHAIN = 6 LONGEST CHAIN = 6 C H 2 C H 3 C H 2 C H 2 C H C H 3 CH 3 C H 2 CH 3 C H 3 C H C H 2 C H 3 C H 3 CH 3 C H C H 2 C H 2 C H 3 C H CH 3
25. I.U.P.A.C. NOMENCLATURE SUBSTITUENTS Many compounds have substituents (additional atoms, or groups) attached to the chain. Their position is numbered. A systematic name has two main parts . SUFFIX An ending that tells you which functional group is present See if any functional groups are present. Add relevant ending to the basic stem. In many cases the position of the functional group must be given to avoid any ambiguity Functional group Suffix ALKANE - ANE ALKENE - ENE ALKYNE - YNE ALCOHOL - OL ALDEHYDE - AL KETONE - ONE ACID - OIC ACID 1-CHLOROBUTANE 2-CHLOROBUTANE
26. SIDE-CHAIN carbon based substituents are named before the chain name. they have the prefix -yl added to the basic stem (e.g. CH 3 is methyl). Number the principal chain from one end to give the lowest numbers . Side-chain names appear in alphabetical order butyl, ethyl, methyl, propyl Each side-chain is given its own number . If identical side-chains appear more than once, prefix with di, tri, tetra, penta, hexa Numbers are separated from names by a HYPHEN e.g. 2-methylheptane Numbers are separated from numbers by a COMMA e.g. 2,3-dimethylbutane Alkyl radicals methyl CH 3 - CH 3 ethyl CH 3 - CH 2 - C 2 H 5 propyl CH 3 - CH 2 - CH 2 - C 3 H 7 I.U.P.A.C. NOMENCLATURE
27. SIDE-CHAIN carbon based substituents are named before the chain name. they have the prefix -yl added to the basic stem (e.g. CH 3 is methyl). Number the principal chain from one end to give the lowest numbers . Side-chain names appear in alphabetical order butyl, ethyl, methyl, propyl Each side-chain is given its own number . If identical side-chains appear more than once, prefix with di, tri, tetra, penta, hexa Numbers are separated from names by a HYPHEN e.g. 2-methylheptane Numbers are separated from numbers by a COMMA e.g. 2,3-dimethylbutane Example longest chain 8 (it is an octane) 3,4,6 are the numbers NOT 3,5,6 order is ethyl, methyl, propyl 3-ethyl-5-methyl-4-propyloctane Alkyl radicals methyl CH 3 - CH 3 ethyl CH 3 - CH 2 - C 2 H 5 propyl CH 3 - CH 2 - CH 2 - C 3 H 7 I.U.P.A.C. NOMENCLATURE CH 3 CH 2 CH 3 CH CH 2 CH 2 CH 3 CH CH CH 2 CH 2 CH 3 CH 2 CH 3
28. I.U.P.A.C. NOMENCLATURE Apply the rules and name these alkanes THE ANSWERS ARE ON THE NEXT SLIDE CH 2 CH 3 CH 2 CH 2 CH CH 3 CH 3 CH 2 CH 3 CH 3 CH CH 2 CH 3 CH 3 CH 3 CH CH 2 CH 2 CH 3 CH CH 3
30. I.U.P.A.C. NOMENCLATURE Longest chain = 5 so it is a pentane A CH 3 , methyl, group is attached to the third carbon from one end... 3-methylpentane I.U.P.A.C. NOMENCLATURE Apply the rules and name these alkanes CH 2 CH 3 CH 2 CH 2 CH CH 3 CH 3 C H 2 CH 3 C H 3 C H C H 2 C H 3 CH 3 CH 3 CH CH 2 CH 2 CH 3 CH CH 3
31. I.U.P.A.C. NOMENCLATURE Longest chain = 5 so it is a pentane A CH 3 , methyl, group is attached to the third carbon from one end... 3-methylpentane I.U.P.A.C. NOMENCLATURE Apply the rules and name these alkanes Longest chain = 6 so it is a hexane A CH 3 , methyl, group is attached to the second carbon from one end... 2-methylhexane C H 2 C H 3 C H 2 C H 2 C H C H 3 CH 3 CH 2 CH 3 CH 3 CH CH 2 CH 3 CH 3 CH 3 CH CH 2 CH 2 CH 3 CH CH 3
32. I.U.P.A.C. NOMENCLATURE Longest chain = 5 so it is a pentane A CH 3 , methyl, group is attached to the third carbon from one end... 3-methylpentane I.U.P.A.C. NOMENCLATURE Apply the rules and name these alkanes Longest chain = 6 so it is a hexane A CH 3 , methyl, group is attached to the second carbon from one end... 2-methylhexane Longest chain = 6 so it is a hexane CH 3 , methyl, groups are attached to the third and fourth carbon atoms (whichever end you count from). 3,4-dimethylhexane CH 2 CH 3 CH 2 CH 2 CH CH 3 CH 3 CH 2 CH 3 CH 3 CH CH 2 CH 3 C H 3 CH 3 C H C H 2 C H 2 C H 3 C H CH 3
33. NAMING ALKENES Length In alkenes the principal chain is not always the longest chain It must contain the double bond the name ends in -ENE Position Count from one end as with alkanes. Indicated by the lower numbered carbon atom on one end of the C=C bond 5 4 3 2 1 CH 3 CH 2 CH=CH CH 3 is pent-2-ene (NOT pent-3-ene) Side-chain Similar to alkanes position is based on the number allocated to the double bond 1 2 3 4 1 2 3 4 CH 2 = CH (CH 3 ) CH 2 CH 3 CH 2 = CHCH (CH 3 ) CH 3 2-methylbut-1-ene 3-methylbut-1-ene
34. WHICH COMPOUND IS IT? Elucidation of the structures of organic compounds - a brief summary Organic chemistry is so vast that the identification of a compound can be involved. The characterisation takes place in a series of stages (see below). Relatively large amounts of substance were required to elucidate the structure but, with modern technology and the use of electronic instrumentation, very small amounts are now required. Elemental composition One assumes that organic compounds contain carbon and hydrogen but it can be proved by letting the compound undergo combustion. Carbon is converted to carbon dioxide and hydrogen is converted to water. Percentage composition by mass Found by dividing the mass of an element present by the mass of the compound present, then multiplying by 100 . Elemental mass of C and H can be found by allowing the substance to undergo complete combustion. From this one can find... mass of carbon = 12/44 of the mass of CO 2 produced mass of hydrogen = 2/18 of the mass of H 2 O produced
35. INVESTIGATING MOLECULES Empirical formula The simplest ratio of elements present in the substance . It is calculated by dividing the mass or percentage mass of each element by its molar mass and finding the simplest ratio between the answers. Empirical formula is converted to the molecular formula using molecular mass.
36. INVESTIGATING MOLECULES Empirical formula The simplest ratio of elements present in the substance. It is calculated by dividing the mass or percentage mass of each element by its molar mass and finding the simplest ratio between the answers. Empirical formula is converted to the molecular formula using molecular mass. Molecular mass Traditionally found out using a variety of techniques such as ... volumetric analysis or molar volume methods (Dumas, Victor-Meyer or gas syringe experiments) . Mass spectrometry is now used. The m/z value of the molecular ion and gives the molecular mass. The fragmentation pattern gives information about the compound.
37. INVESTIGATING MOLECULES Empirical formula The simplest ratio of elements present in the substance. It is calculated by dividing the mass or percentage mass of each element by its molar mass and finding the simplest ratio between the answers. Empirical formula is converted to the molecular formula using molecular mass. Molecular mass Traditionally found out using a variety of techniques such as ... volumetric analysis or molar volume methods (Dumas, Victor-Meyer or gas syringe experiments). Mass spectrometry is now used. The m/z value of the molecular ion and gives the molecular mass. The fragmentation pattern gives information about the compound. Molecular formula The molecular formula is an exact multiple of the empirical formula . Comparing the molecular mass with the empirical mass allows one to find the true formula. e.g. if the empirical formula is CH (relative mass = 13) and the molecular mass is 78 the molecular formula will be 78/13 or 6 times the empirical formula i.e. C 6 H 6 .
38. INVESTIGATING MOLECULES Empirical formula The simplest ratio of elements present in the substance. It is calculated by dividing the mass or percentage mass of each element by its molar mass and finding the simplest ratio between the answers. Empirical formula is converted to the molecular formula using molecular mass. Molecular mass Traditionally found out using a variety of techniques such as ... volumetric analysis or molar volume methods (Dumas, Victor-Meyer or gas syringe experiments). Mass spectrometry is now used. The m/z value of the molecular ion and gives the molecular mass. The fragmentation pattern gives information about the compound. Molecular formula The molecular formula is an exact multiple of the empirical formula. Comparing the molecular mass with the empirical mass allows one to find the true formula. e.g. if the empirical formula is CH (relative mass = 13) and the molecular mass is 78 the molecular formula will be 78/13 or 6 times the empirical formula i.e. C 6 H 6 . Structural formula Because of the complexity of organic molecules, there can be more than one structure for a given molecular formula. To work out the structure, different tests are carried out.
39. INVESTIGATING MOLECULES Empirical formula The simplest ratio of elements present in the substance . It is calculated by dividing the mass or percentage mass of each element by its molar mass and finding the simplest ratio between the answers. Empirical formula is converted to the molecular formula using molecular mass. Molecular mass Traditionally found out using a variety of techniques such as ... volumetric analysis or molar volume methods (Dumas, Victor-Meyer or gas syringe experiments) . Mass spectrometry is now used. The m/z value of the molecular ion and gives the molecular mass. The fragmentation pattern gives information about the compound. Molecular formula The molecular formula is an exact multiple of the empirical formula . Comparing the molecular mass with the empirical mass allows one to find the true formula. e.g. if the empirical formula is CH (relative mass = 13) and the molecular mass is 78 the molecular formula will be 78/13 or 6 times the empirical formula i.e. C 6 H 6 . Structural formula Because of the complexity of organic molecules, there can be more than one structure for a given molecular formula. To work out the structure, different tests are carried out.
40. INVESTIGATING MOLECULES Chemical Chemical reactions can identify the functional group(s) present . Spectroscopy IR detects bond types due to absorbance of i.r. radiation NMR gives information about the position and relative numbers of hydrogen atoms present in a molecule Confirmation By comparison of IR or NMR spectra and mass spectrometry
41. REVISION CHECK What should you be able to do? Recall and explain the reasons for the large number of carbon based compounds Be able to write out possible structures for a given molecular formula Recognize the presence of a particular functional group in a structure Know the IUPAC rules for naming alkanes and alkenes Be able to name given alkanes and alkenes when given the structure Be able to write out the structure of an alkane or alkene when given its name Recall the methods used to characterise organic molecules CAN YOU DO ALL OF THESE? YES NO
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