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 Fibers are fine hair like structures of animal,
vegetable, mineral or synthetic origin
 They can be defined as “elongated thick
walled cells, with pointed ends.”
 The quality of surgical dressings depends
upon the type of fiber used to prepare
dressings.
 Dressings make direct contact with the
wound
 Bandages used to hold dressings in place.
 However B.P classify them as same thing.
 Commercially available fibers have
diameters ranging less than 0.004 to 0.2mm.
 The fibers used for surgical dressings have
shorter length.
 For textile use. Fibers must have length of at
least 1000 times to its diameter.
 They may be of different forms.
a) Staple or chopped: they are short fibers.
b) Monofilament: it is continuous single fiber.
c) Tow: it is untwisted bundles of continuous
filaments.
d) Yarn: it is twisted bundles of continuous
filaments.
 These are classified based upon their origin.
These include:
1. Animal fiber
2. Vegetable fiber
3. Regenerated fibers
4. Mineral fibers
5. Synthetic fibers
 They are obtained from animals.
 All animal fibers are complex proteins.
 They are resistant to most organic acids and
to certain powerful mineral acids such as
H2SO4.
 They may be damaged by mild alkalies and
may be dissolved by strong alkalies such as
sodium hydroxide.
 E.g. Silk and Wool
 They are obtained from plants and are
generally based on the arrangement of
cellulose, often with lignin.
 These fibers are mainly made up of
cellulose.
 They resist alkalies and most organic acids.
However they are dstroyed by strong mineral
acids.
 There are four major types of vegetable
fibers:
i- Seed Fibers
 These are the soft hairs that surround the
seeds of certain plants e.g. Cotton, Kapoka
(Ceiba) etc.
ii- Bast fibers
 These are the tough fibers that grow
between the bark and the stem of many
dicotyledonous plants e.g. Flax, Hemp, Jute
and Sunn etc
iii-Vascular fibers
 These are the tough fibers found in the
leaves and stem of monocotyledonous e.g.
Agave (sisal), Henequen etc.
iv-Grass stem fibers
 They are obtained from entire stem of some
grasses and straw, such as esparto.
 They are prepared from naturally occurring
polysacchrides e.g. cellulose.
 The cellulose is modified to prepare a
suitable fiber form. It is prepared by
dissolving the cellulose in chemicals and
making it into fiber again.
Examples are Viscose, cellulose acetate,
oxidized cellulose, nitrocellulose etc.
 They are obtained from minerals.
 Examples include Glass fibers, asbestos
fibers and aluminium fibers.
 These are produced by polycondensation of
organic molecules i.e. cellulose
 These are stronger than natural fibers e.g.
nylon, terylens and polyethylene etc.
 Fibers can be distinguished by chemical
tests and by studying their microscopic
structures.
 Synthetic and mineral fibers give negative
tests of vegetable and animal fibers.
 Biological source: Gossypium herbeceum
 Family: Malvaceae
 Parts used: hairs and epidermal trichomes of
seeds of small trees and shrubs
 Habitat: majorly grown in india for atleast
5000 years. From india, it spread to China,
Egypt and USA and now cultivated there as
a crop.
Half of the cotton of the world is produced in
USA and the other important sources are
Egypt, India and Pakistan.
 Preparation: plants are shrubs or small trees
producing capsules containing numerous
small seeds. Capsules open upon maturity
and seeds get exposed. Seeds are covered
with mass having long white hairs or cotton
fibers called “lint”. Cotton fibers are collected
in the absence of rain and dew drops and
dried in shade. After drying, they are
ginned to remove the hairs from the seeds.
Seeds are again subjected to another type of
gin which is used to separate smaller hairs
called “Linters” from the seeds. These short
hairs are used to make cotton wools while
seeds are used in the preparation of cotton
seed or cattle cake. The cotton obtained is
called raw cotton which have various impurities
such as broken seeds, fragment, leaves etc.
most of these impurities are removed during
manufacturing of yarn.
 Structure and characters: cotton consists of
unicellular hairs. Each of these hairs is
flattened, tabular with spiral twist. The length
of fiber is upto 5cm with a diametet of 9-24
micrometer. The number of twists in the
indian, pakistani cotton fibers is 75 per cm.
USA cotton fibers have 150 twists per cm.
hair has cellulose wall which is covered with
waxy cuticle layer. Due to the presence of
cuticle it is non-absorbent.
 Identification test:
1. On ignitin, cotton burns with a flame, giving
little odour of burning leaves and fumes. The
ash leftovers easily crumbles. Small samples
of burning cotton can be blown out as in
candle.
2. Raw cotton dissolves in copper oxide
ammonia solution (cuoxam) forming a blue
color.
3. Raw cotton is soluble in cold sulphuric acid
80% w/w.
4. Raw cotton is insoluble in warm HCL, in
5%potassium hydroxide solution and in
acetone.
5. It is insoluble in 90% formic acid or 90%
phenol.
6. When raw cotton is treated with cold
shirlastain-A for one minute, it gives blue or
purple color after washing.
7. When raw cotton is treated with cold
shirlastain-C for minutes, it gives mauve to
reddish-brown color after wahing.
 Chemical constituents:
Cellulose 91%
Wax and fat 0.4%
Protoplasm and other cell contents 0.6%
Ash 2%
Moisture 7.8%
 Uses:
1. raw cotton is used as filtering medium
2. It is a chief constituents of many surgical
dessings and insulating materials.
3. Used in textile industry
4. Used to manufacture explosives, cellulose
acetate and other cellulose derivatives.
 Synonyms: absorbent wool, purified cotton.
 Botanical source: Gossypium herbceum and
other species of Malvaceae family.
 Family: Malvaceae
 Parts used: epidermal hairs of seeds of
plants of Malvaceae family
 It is made from cotton waste i.e. fibers or
hairs (comber waste, linters, sardstrip or
cardfly) which are rejected or seperated
By cotton combing machine during the
preparation of cotton for spinning (to draw out
and twist into threads)
 Preparation: following steps are involved;
S1: remove impurities from comber waste
firstly.
S2: comber waste is heated with dilute sodium
hydroxide solution and soda ash (Na2CO3)
solution at 1-3 atmospheric pressure for 10-15
hours. Most of the fatty cuticle is removed and
the trichome wall becomes absorbent in this
process.
S3: in this step, the cotton is washed with water,
decolorizd with sodium hypochlorite solution and
treated with dilute HCl and than dried.
S4: the dried fibers are in matted condition i.e.
twisted together into a thick mass, so they are
opened up by machines.
S5: in this step the absorbent cotton is converted
into thin continuous sheets with the help of a
carding machine. Several sheets are placed upon
one another and paper is kept between the two
sheets. Finally they are packed into rolls and
sterilization.
 Chemical tests: same as that of raw cotton.
 Characters: absorbent cotton occurs as
white, soft, fine hairy filaments. The filaments
consists of unicellular hair of 2.5-5cm in
length. The diameter is 9-24 µm. Hairs are
cylindrical when young and becomes
flattened and twisted at maturity. The
number of twists varies from 75 per cm to
150 per cm for different species. Absorbent
cotton is odorless and tasteless.
 Chemical nature:
Absorbent cotton consists of cellulose.
Cellulose is compose of a number of glucose
units linked together by beta 1, 4 glucosidic
bonds.
 Uses:
a) Absorbent cottons is used for surgical
dresssings e.g, it is used to absorb blood,
mucus, pus, and for mechanism support.
b) As it is sterlized and purified, therefore used
to protect wound from bacteria.
 Synonyms: animal wool or sheep’s wool.
 Biological Source: Zoological name is Ovis
arries
 Family is Bovidae.
 Parts used: Wool obtained from the fleece of
domestic sheep
 Geographical Source: Wool producing
countries include; Australia, Russia,
Argentina, India and America.
 Preparation: The fleece of sheep is generally
cut once in a year, usually in the spring or early
summer. Wool from the different parts of the
same fleece varies greatly in length of fibers,
fitness and structure. Wool from shoulders and
sides of the sheep is usually superior to that
from other parts of the body.
The following steps are involved in the preparation
of wool.
S1: the hairs are removed from the fleece of the
sheep. As the length and quality of the hairs
varies, so they are spread on a frame, covered
with wire netting to separate it into wool of
different sizes and qualities.
S2: the fibers are beaten over the netting to
remove dust and dirt. The other foreign
substances are also removed.
S3: in this step, fibers are cleaned because it
contains an oily substances i.e. wool grease.
So the wool is washed in tanks containing
warm, soapy water to remove the wool grease.
S4: the wool is dried by hot air. The fibers are
loosened and drawn straight into a
continuous from with the help of carding
machine. This process is known as carding.
Finally these fibers are spun into yarn.
S5: The wool grease from washing process is
collected by mechanical means or by or
organic solvents. Purified wool grease is
known as “wool fat” or anhydrous lanolin. It is
used in cosmetics and ointments.
 Structure: wool consists of elastic, shiny and
smooth hairs or fibers. The length of hair is from
2-50cm.
Under microscope, the hair can be distinguished
into three regions;
a. Cuticle; consists of epithelial scales which are
lying over each other like “tiles”. Strong
solution of ammonia can separate the epithelial
scales in a few minutes.
b. Cortex; consists of elongated cells.
c. Medulla; consists of rounded cells containing
fatty matter or pigments.
 Characters:
 A single wool fiber can resist breakage when
subjected to weight of 15-30g and when
stretched as much as 25-30% its length.
 Wool is insoluble in warm HCl and in cold
concentrated H2SO4.
 Wool fiber has great affinity for dyestuffs. It
can absorb 17 times of moisture of its
weight.
It has good resistance to dry-cleaning solvents,
strong alkalies and high temperatures.
Wool fiber may be damaged by ageing, larval
attack such as cloth moths, carpet beetles and
exposure to sunlight.
It does not continue to burn when removed
from a flame
 Identification tests:
Wool is insoluble in warm HCl and in cold
concentrated H2SO4.
they respond positively with Millon’s test i.e.
wool gives thick red color with Millon’s reagent
on gentle heating.
They are stained permanently with picric acid.
With picric acid it gives deep yellow color.
They are dissolved in 5% aquous potassium
hydroxide solution.
Wool gives blue color when treated with
ammonia copper oxide solution.
When lead acetate is added to a solution of
wool in caustic soda, black precipitates are
formed.
 Chemical constituents:
Raw wool consists of;
 Woo fibers….. 31% (wool fibers are composed
of protein called keratin which is rich in maino
acid cystine. Keratin consists of C,H,O and N
elements. It gives strength and elasticity to the
wool fiber and thus the fiber can be stretched to
an extent).
 Wool sweat or suint….. 32% (suint is an oily
substancecomposed of potassium salts of fatty
acids.
 Dirt and dust….. 25%
 Wool grease or lanolin.
 Uses:
 wool is used in pharmaceuticals as filtering
and staining medium.
 Used to prepare crepe bandages.
 An artificial textile material composed of
cellulose obtained from cotton linters or from
the pulp (soft and fleshy part) of the trees such
as Spruce (an evergreen tree of the pine
family).
 In other words, rayon is regenerated cellulose
or fibers.
 Regenerated fibers are prepared from naturally
occuring polysacchrides.
 These compounds are modified to yield a
suitable fiber form.
 Preparation:
Can be prepared by two processes.
1. Viscose process
2. Cuprammonium process.
1. Viscose process
The process was introduced by three British
chemists Baedle, Bevan, Cross in 1892.
In this process the starting material is cellulose
obtained from the crushed wood of Spruce or
from Cotton linters.
The following steps are involved in this
process.
S1: the wood of Spruce is delignified to
produce white pulp. The pulp contains 80-90%
of cellulose and some hemicellulose.
S2: as hemicellulose are alkali soluble
therefore it is removed by treating product with
NaOH. The remaining alkali cellulose is
dissolved in a mixture of carbon disulphide
and sodium hydroxide solution to form a
viscous yellow liquid Viscose. The liquid is
allowed to ripen and filtered.
S3: in this step the filterate is forced through
small holes in a nozzle into liquid bath.
The bath contains dilute sulphuric acid and
sodium sulphate. The cellulose is regenerated
in the form of continuous filaments in the bath.
This process is called Extrusion.
S4: the filaments are spun into yarns. The
yarns are combined, twisted and treated with
sodium sulphide to remove free sulphur. After
desulphurization, the yarns are bleached
washed, dried and a 10% moisture content is
adjusted. Surgical dressings are prepared from
the viscose yarns.
2. Cupramonium Process
In this process purified cellulose is treated with
cupramonium liquor then with sodium
hydroxide to form viscose. The remaining
steps are the same as that for viscose process.
Delustring and Dying
Delustring is done, when the fibers are used for
surgical dressings. The fibers can be
delustered by the addition of white pigment i.e.
titanium oxide to the solution before
preparation of yarns. The
delustered viscose also called mall viscose is
used to prepare surgical dressings. Similarly
the fibers may be dyed by the addition of
suitable dye instead of titanium oxide.
Preparation of Cellophane
when viscose soultion (formed in step 2) is
passed through a nozzle into a regenerating
bath, sheets of viscose are formed. These
sheets are washed bleached, treated with
glycerin solution and dried to produce
cellophane.
Cellophane is a valuable packing material and
is also used as dialyzing membrane. It is also
used as protective dressing.
 Characters
 Viscose is pure form of cellulose.
 It is white lustrous in color.
 Its molecule contains 450 residue units
whereas the molecules of wood cellulose
contains 9000 glucose units.
 Viscose fibers are solid, transparent, 15-
20µm in diameter and slightly twisted.
 Identification tests
On ignition, rayon burns with a flame, giving
little odor and fumes, it does not produce bead
and leaves a small white ash.
A blue color is produced, when rayon is
moistened with a mixture of iodine and
sulphuric acid.
Rayon dissolves in copper oxide ammonia
solution (cuoxam) forming a blue color.
Rayon is soluble in cold sulphuric acid 80%
w/w.
Rayon is insoluble in warm HCl, in 5%KOH
solution and in acetone.
It is insoluble in 90% formic acid or 90%
phenol.
When rayon is treated with cold shirlastain-A
for one minute, it gives blue or purple color
after washing.
When rayon is treated with cold shirlastain-C
for 5 min, it gives violet to reddish-brown color
after washing.
It does not produce red color, when treated
with phloroglucinol and HCl.
 Uses
Viscose rayon is used to prepare fabrics,
surgical dressings, absorbent wool, enzyme
and cellophane.
It has advantage over cotton dressings in that
they show no less of absorbance on storage.

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Fibers and surgical dressings

  • 1.
  • 2.  Fibers are fine hair like structures of animal, vegetable, mineral or synthetic origin  They can be defined as “elongated thick walled cells, with pointed ends.”  The quality of surgical dressings depends upon the type of fiber used to prepare dressings.
  • 3.  Dressings make direct contact with the wound  Bandages used to hold dressings in place.  However B.P classify them as same thing.
  • 4.  Commercially available fibers have diameters ranging less than 0.004 to 0.2mm.  The fibers used for surgical dressings have shorter length.  For textile use. Fibers must have length of at least 1000 times to its diameter.
  • 5.  They may be of different forms. a) Staple or chopped: they are short fibers. b) Monofilament: it is continuous single fiber. c) Tow: it is untwisted bundles of continuous filaments. d) Yarn: it is twisted bundles of continuous filaments.
  • 6.  These are classified based upon their origin. These include: 1. Animal fiber 2. Vegetable fiber 3. Regenerated fibers 4. Mineral fibers 5. Synthetic fibers
  • 7.  They are obtained from animals.  All animal fibers are complex proteins.  They are resistant to most organic acids and to certain powerful mineral acids such as H2SO4.  They may be damaged by mild alkalies and may be dissolved by strong alkalies such as sodium hydroxide.  E.g. Silk and Wool
  • 8.
  • 9.  They are obtained from plants and are generally based on the arrangement of cellulose, often with lignin.  These fibers are mainly made up of cellulose.  They resist alkalies and most organic acids. However they are dstroyed by strong mineral acids.  There are four major types of vegetable fibers:
  • 10. i- Seed Fibers  These are the soft hairs that surround the seeds of certain plants e.g. Cotton, Kapoka (Ceiba) etc. ii- Bast fibers  These are the tough fibers that grow between the bark and the stem of many dicotyledonous plants e.g. Flax, Hemp, Jute and Sunn etc
  • 11.
  • 12. iii-Vascular fibers  These are the tough fibers found in the leaves and stem of monocotyledonous e.g. Agave (sisal), Henequen etc. iv-Grass stem fibers  They are obtained from entire stem of some grasses and straw, such as esparto.
  • 13.
  • 14.  They are prepared from naturally occurring polysacchrides e.g. cellulose.  The cellulose is modified to prepare a suitable fiber form. It is prepared by dissolving the cellulose in chemicals and making it into fiber again. Examples are Viscose, cellulose acetate, oxidized cellulose, nitrocellulose etc.
  • 15.
  • 16.  They are obtained from minerals.  Examples include Glass fibers, asbestos fibers and aluminium fibers.
  • 17.
  • 18.  These are produced by polycondensation of organic molecules i.e. cellulose  These are stronger than natural fibers e.g. nylon, terylens and polyethylene etc.
  • 19.  Fibers can be distinguished by chemical tests and by studying their microscopic structures.  Synthetic and mineral fibers give negative tests of vegetable and animal fibers.
  • 20.  Biological source: Gossypium herbeceum  Family: Malvaceae  Parts used: hairs and epidermal trichomes of seeds of small trees and shrubs  Habitat: majorly grown in india for atleast 5000 years. From india, it spread to China, Egypt and USA and now cultivated there as a crop.
  • 21. Half of the cotton of the world is produced in USA and the other important sources are Egypt, India and Pakistan.  Preparation: plants are shrubs or small trees producing capsules containing numerous small seeds. Capsules open upon maturity and seeds get exposed. Seeds are covered with mass having long white hairs or cotton fibers called “lint”. Cotton fibers are collected in the absence of rain and dew drops and dried in shade. After drying, they are
  • 22. ginned to remove the hairs from the seeds. Seeds are again subjected to another type of gin which is used to separate smaller hairs called “Linters” from the seeds. These short hairs are used to make cotton wools while seeds are used in the preparation of cotton seed or cattle cake. The cotton obtained is called raw cotton which have various impurities such as broken seeds, fragment, leaves etc. most of these impurities are removed during manufacturing of yarn.
  • 23.  Structure and characters: cotton consists of unicellular hairs. Each of these hairs is flattened, tabular with spiral twist. The length of fiber is upto 5cm with a diametet of 9-24 micrometer. The number of twists in the indian, pakistani cotton fibers is 75 per cm. USA cotton fibers have 150 twists per cm. hair has cellulose wall which is covered with waxy cuticle layer. Due to the presence of cuticle it is non-absorbent.
  • 24.  Identification test: 1. On ignitin, cotton burns with a flame, giving little odour of burning leaves and fumes. The ash leftovers easily crumbles. Small samples of burning cotton can be blown out as in candle. 2. Raw cotton dissolves in copper oxide ammonia solution (cuoxam) forming a blue color. 3. Raw cotton is soluble in cold sulphuric acid 80% w/w.
  • 25. 4. Raw cotton is insoluble in warm HCL, in 5%potassium hydroxide solution and in acetone. 5. It is insoluble in 90% formic acid or 90% phenol. 6. When raw cotton is treated with cold shirlastain-A for one minute, it gives blue or purple color after washing. 7. When raw cotton is treated with cold shirlastain-C for minutes, it gives mauve to reddish-brown color after wahing.
  • 26.  Chemical constituents: Cellulose 91% Wax and fat 0.4% Protoplasm and other cell contents 0.6% Ash 2% Moisture 7.8%
  • 27.  Uses: 1. raw cotton is used as filtering medium 2. It is a chief constituents of many surgical dessings and insulating materials. 3. Used in textile industry 4. Used to manufacture explosives, cellulose acetate and other cellulose derivatives.
  • 28.
  • 29.  Synonyms: absorbent wool, purified cotton.  Botanical source: Gossypium herbceum and other species of Malvaceae family.  Family: Malvaceae  Parts used: epidermal hairs of seeds of plants of Malvaceae family  It is made from cotton waste i.e. fibers or hairs (comber waste, linters, sardstrip or cardfly) which are rejected or seperated
  • 30. By cotton combing machine during the preparation of cotton for spinning (to draw out and twist into threads)  Preparation: following steps are involved; S1: remove impurities from comber waste firstly. S2: comber waste is heated with dilute sodium hydroxide solution and soda ash (Na2CO3) solution at 1-3 atmospheric pressure for 10-15 hours. Most of the fatty cuticle is removed and the trichome wall becomes absorbent in this process.
  • 31. S3: in this step, the cotton is washed with water, decolorizd with sodium hypochlorite solution and treated with dilute HCl and than dried. S4: the dried fibers are in matted condition i.e. twisted together into a thick mass, so they are opened up by machines. S5: in this step the absorbent cotton is converted into thin continuous sheets with the help of a carding machine. Several sheets are placed upon one another and paper is kept between the two sheets. Finally they are packed into rolls and sterilization.
  • 32.  Chemical tests: same as that of raw cotton.  Characters: absorbent cotton occurs as white, soft, fine hairy filaments. The filaments consists of unicellular hair of 2.5-5cm in length. The diameter is 9-24 µm. Hairs are cylindrical when young and becomes flattened and twisted at maturity. The number of twists varies from 75 per cm to 150 per cm for different species. Absorbent cotton is odorless and tasteless.
  • 33.  Chemical nature: Absorbent cotton consists of cellulose. Cellulose is compose of a number of glucose units linked together by beta 1, 4 glucosidic bonds.  Uses: a) Absorbent cottons is used for surgical dresssings e.g, it is used to absorb blood, mucus, pus, and for mechanism support. b) As it is sterlized and purified, therefore used to protect wound from bacteria.
  • 34.  Synonyms: animal wool or sheep’s wool.  Biological Source: Zoological name is Ovis arries  Family is Bovidae.  Parts used: Wool obtained from the fleece of domestic sheep  Geographical Source: Wool producing countries include; Australia, Russia, Argentina, India and America.
  • 35.
  • 36.  Preparation: The fleece of sheep is generally cut once in a year, usually in the spring or early summer. Wool from the different parts of the same fleece varies greatly in length of fibers, fitness and structure. Wool from shoulders and sides of the sheep is usually superior to that from other parts of the body. The following steps are involved in the preparation of wool. S1: the hairs are removed from the fleece of the sheep. As the length and quality of the hairs varies, so they are spread on a frame, covered with wire netting to separate it into wool of different sizes and qualities.
  • 37. S2: the fibers are beaten over the netting to remove dust and dirt. The other foreign substances are also removed. S3: in this step, fibers are cleaned because it contains an oily substances i.e. wool grease. So the wool is washed in tanks containing warm, soapy water to remove the wool grease. S4: the wool is dried by hot air. The fibers are loosened and drawn straight into a
  • 38. continuous from with the help of carding machine. This process is known as carding. Finally these fibers are spun into yarn. S5: The wool grease from washing process is collected by mechanical means or by or organic solvents. Purified wool grease is known as “wool fat” or anhydrous lanolin. It is used in cosmetics and ointments.
  • 39.  Structure: wool consists of elastic, shiny and smooth hairs or fibers. The length of hair is from 2-50cm. Under microscope, the hair can be distinguished into three regions; a. Cuticle; consists of epithelial scales which are lying over each other like “tiles”. Strong solution of ammonia can separate the epithelial scales in a few minutes. b. Cortex; consists of elongated cells. c. Medulla; consists of rounded cells containing fatty matter or pigments.
  • 40.  Characters:  A single wool fiber can resist breakage when subjected to weight of 15-30g and when stretched as much as 25-30% its length.  Wool is insoluble in warm HCl and in cold concentrated H2SO4.  Wool fiber has great affinity for dyestuffs. It can absorb 17 times of moisture of its weight.
  • 41. It has good resistance to dry-cleaning solvents, strong alkalies and high temperatures. Wool fiber may be damaged by ageing, larval attack such as cloth moths, carpet beetles and exposure to sunlight. It does not continue to burn when removed from a flame
  • 42.  Identification tests: Wool is insoluble in warm HCl and in cold concentrated H2SO4. they respond positively with Millon’s test i.e. wool gives thick red color with Millon’s reagent on gentle heating. They are stained permanently with picric acid. With picric acid it gives deep yellow color.
  • 43. They are dissolved in 5% aquous potassium hydroxide solution. Wool gives blue color when treated with ammonia copper oxide solution. When lead acetate is added to a solution of wool in caustic soda, black precipitates are formed.
  • 44.  Chemical constituents: Raw wool consists of;  Woo fibers….. 31% (wool fibers are composed of protein called keratin which is rich in maino acid cystine. Keratin consists of C,H,O and N elements. It gives strength and elasticity to the wool fiber and thus the fiber can be stretched to an extent).  Wool sweat or suint….. 32% (suint is an oily substancecomposed of potassium salts of fatty acids.  Dirt and dust….. 25%  Wool grease or lanolin.
  • 45.  Uses:  wool is used in pharmaceuticals as filtering and staining medium.  Used to prepare crepe bandages.
  • 46.  An artificial textile material composed of cellulose obtained from cotton linters or from the pulp (soft and fleshy part) of the trees such as Spruce (an evergreen tree of the pine family).  In other words, rayon is regenerated cellulose or fibers.  Regenerated fibers are prepared from naturally occuring polysacchrides.  These compounds are modified to yield a suitable fiber form.
  • 47.  Preparation: Can be prepared by two processes. 1. Viscose process 2. Cuprammonium process. 1. Viscose process The process was introduced by three British chemists Baedle, Bevan, Cross in 1892. In this process the starting material is cellulose obtained from the crushed wood of Spruce or from Cotton linters. The following steps are involved in this process.
  • 48. S1: the wood of Spruce is delignified to produce white pulp. The pulp contains 80-90% of cellulose and some hemicellulose. S2: as hemicellulose are alkali soluble therefore it is removed by treating product with NaOH. The remaining alkali cellulose is dissolved in a mixture of carbon disulphide and sodium hydroxide solution to form a viscous yellow liquid Viscose. The liquid is allowed to ripen and filtered. S3: in this step the filterate is forced through small holes in a nozzle into liquid bath.
  • 49. The bath contains dilute sulphuric acid and sodium sulphate. The cellulose is regenerated in the form of continuous filaments in the bath. This process is called Extrusion. S4: the filaments are spun into yarns. The yarns are combined, twisted and treated with sodium sulphide to remove free sulphur. After desulphurization, the yarns are bleached washed, dried and a 10% moisture content is adjusted. Surgical dressings are prepared from the viscose yarns.
  • 50. 2. Cupramonium Process In this process purified cellulose is treated with cupramonium liquor then with sodium hydroxide to form viscose. The remaining steps are the same as that for viscose process. Delustring and Dying Delustring is done, when the fibers are used for surgical dressings. The fibers can be delustered by the addition of white pigment i.e. titanium oxide to the solution before preparation of yarns. The
  • 51. delustered viscose also called mall viscose is used to prepare surgical dressings. Similarly the fibers may be dyed by the addition of suitable dye instead of titanium oxide. Preparation of Cellophane when viscose soultion (formed in step 2) is passed through a nozzle into a regenerating bath, sheets of viscose are formed. These sheets are washed bleached, treated with glycerin solution and dried to produce cellophane.
  • 52. Cellophane is a valuable packing material and is also used as dialyzing membrane. It is also used as protective dressing.  Characters  Viscose is pure form of cellulose.  It is white lustrous in color.  Its molecule contains 450 residue units whereas the molecules of wood cellulose contains 9000 glucose units.  Viscose fibers are solid, transparent, 15- 20µm in diameter and slightly twisted.
  • 53.  Identification tests On ignition, rayon burns with a flame, giving little odor and fumes, it does not produce bead and leaves a small white ash. A blue color is produced, when rayon is moistened with a mixture of iodine and sulphuric acid. Rayon dissolves in copper oxide ammonia solution (cuoxam) forming a blue color. Rayon is soluble in cold sulphuric acid 80% w/w.
  • 54. Rayon is insoluble in warm HCl, in 5%KOH solution and in acetone. It is insoluble in 90% formic acid or 90% phenol. When rayon is treated with cold shirlastain-A for one minute, it gives blue or purple color after washing. When rayon is treated with cold shirlastain-C for 5 min, it gives violet to reddish-brown color after washing. It does not produce red color, when treated with phloroglucinol and HCl.
  • 55.  Uses Viscose rayon is used to prepare fabrics, surgical dressings, absorbent wool, enzyme and cellophane. It has advantage over cotton dressings in that they show no less of absorbance on storage.