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By Marinela Buzo
The reaction rate
๏‚ž The reaction rate or speed of reaction for
a reactant or product in a
particular reaction is intuitively defined as
how fast or slow a reaction takes place.
For example, the oxidative
rusting of iron under Earth's atmosphere is
a slow reaction that can take many years,
but the combustion of cellulose in a fire is a
reaction that takes place in fractions of a
second.
The nature of the
reaction
FACTORS AFFECTING
THE REACTION RATE
๏‚ž Some reactions are naturally faster than
others. The number of reacting species,
their physical state (the particles that
form solids move much more slowly than
those of gases or those in solution), the
complexity of the reaction and other
factors can greatly influence the rate of a
reaction.
Concentration:
Reaction rate increases
with concentration, as
described by the rate
law and explained
by collision theory. As
reactant concentration
increases, the frequency
of collision increases.
Pressure:
The rate of gaseous reactions
increases with pressure, which
is, in fact, equivalent to an
increase in concentration of
the gas . The reaction rate
increases in the direction
where there are fewer moles
of gas and decreases in the
reverse direction. For
condensed-phase reactions,
the pressure dependence is
weak.
A catalyst
Factors affecting the
reaction rate
๏‚ž The presence of a catalyst increases the
reaction rate (in both the forward and
reverse reactions) by providing an
alternative pathway with a
lower activation energy.
Surface Area
Factors affecting the
reaction rate
๏‚ž In reactions on surfaces, which take
place for example during heterogeneous
catalysis, the rate of reaction increases
as the surface area does. That is
because more particles of the solid are
exposed and can be hit by reactant
molecules.
The mathematical expression for
the rate of reaction
๏‚ž For a chemical reaction
a A + b B โ†’ p P + q Q,
the rate equation or rate law is
a mathematical expression used in
chemical kinetics to link the rate of a
reaction to the concentration of each
reactant. It is of the kind:
factors affecting the reaction rate
factors affecting the reaction rate

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factors affecting the reaction rate

  • 2. The reaction rate ๏‚ž The reaction rate or speed of reaction for a reactant or product in a particular reaction is intuitively defined as how fast or slow a reaction takes place. For example, the oxidative rusting of iron under Earth's atmosphere is a slow reaction that can take many years, but the combustion of cellulose in a fire is a reaction that takes place in fractions of a second.
  • 3. The nature of the reaction FACTORS AFFECTING THE REACTION RATE ๏‚ž Some reactions are naturally faster than others. The number of reacting species, their physical state (the particles that form solids move much more slowly than those of gases or those in solution), the complexity of the reaction and other factors can greatly influence the rate of a reaction.
  • 4.
  • 5. Concentration: Reaction rate increases with concentration, as described by the rate law and explained by collision theory. As reactant concentration increases, the frequency of collision increases.
  • 6. Pressure: The rate of gaseous reactions increases with pressure, which is, in fact, equivalent to an increase in concentration of the gas . The reaction rate increases in the direction where there are fewer moles of gas and decreases in the reverse direction. For condensed-phase reactions, the pressure dependence is weak.
  • 7. A catalyst Factors affecting the reaction rate ๏‚ž The presence of a catalyst increases the reaction rate (in both the forward and reverse reactions) by providing an alternative pathway with a lower activation energy.
  • 8.
  • 9. Surface Area Factors affecting the reaction rate ๏‚ž In reactions on surfaces, which take place for example during heterogeneous catalysis, the rate of reaction increases as the surface area does. That is because more particles of the solid are exposed and can be hit by reactant molecules.
  • 10.
  • 11. The mathematical expression for the rate of reaction ๏‚ž For a chemical reaction a A + b B โ†’ p P + q Q, the rate equation or rate law is a mathematical expression used in chemical kinetics to link the rate of a reaction to the concentration of each reactant. It is of the kind: