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Experiment No. 4
Factors Affecting Rate of
Chemical Reactions
Objectives:
 To show the effects of the different
factors in the rate of a given chemical
reaction
Procedure:
 Nature of Reactants
Compare the speeds of the following sets of
reaction and write the corresponding equations:
Experiment
No. 1
1mLof
dilute
H2SO4
adropof
BaCl2
solution
test tube
1
1mLof
dilute
magnesia
mixture
fewdropsof
disodium
phosphate
solution
test tube
2
Experiment
No. 2
dilute
KmnO4
dilute
H2SO4
test tube
1
test tube
2
acidified with
dilute
KmnO4
acidified with
dilute
H2SO4
1mLof
hydrogen
peroxide
Experiment
No. 3
3mL0f
6NHCl
test tube
1
test tube
3
test tube
2
3mL0f
6NHCl
3mL0f
6NHCl
Experim
ent No. 3
test tube
1
3mL0f
6NHCl
3mL0f
6NHCl
3mL0f
6NHCl
test tube
2
test tube
3
Experim
ent No. 3
test tube
1
3mL0f
6NHCl
3mL0f
6NHCl
3mL0f
6NHCl
test tube
2
test tube
3½gramof Zn
granules
½gramofAl
1pieceofmagnesiumriboon
Record the time for Al
and Magnesium to be
consumed.
Procedure:
 Catalyst
Experiment
No. 1
2mL
hydrogen
peroxide
apinchof
manganese
dioxide
test tube
1
test tube
2
2mL
hydrogen
peroxide
Compare the rate at which
decomposition of hydrogen
peroxide takes place in the
two test tubes.
Experiment
No. 2
5mLof
6NHCl
3mLof
1%MnSO4
test tube
1
3mLH2O
test tube
2
5mLof
6NHCl
Experiment
No. 2
5mLof
6NHCl
3mLof
1%MnSO4
test tube
1
3mLH2O
test tube
2
5mLof
6NHCl
Experiment
No. 2
5mLof
6NHCl
3mLof
1%MnSO4
test tube
1
3mLH2O
test tube
2
5mLof
6NHCl
stripof
magnesium
ribbon
stripof
magnesium
ribbon
Procedure:
 Concentration of Reactants
Experiment
No. 1
3mL0f
3NHCl
test tube
1
test tube
3
test tube
2
3mL0f
6NHCl
3mL0f
12NHCl
Experiment
No. 1
3mL0f
3NHCl
test tube
1
test tube
3
test tube
2
3mL0f
6NHCl
3mL0f
12NHCl
apieceof
magnesium
ribbon
apieceof
magnesiumribbon
apieceof
magnesium
ribbon
Procedure:
 Temperature
3mLof0.1N
sodium
oxalate
3mLof
KmnO4
test tube
1
test tube
2
3mLof0.1N
sodium
oxalate
acidified with
fewdropsof
diluteH2SO4
3mLof0.1N
sodium
oxalate
test tube
175 C
Procedure:
 Surface area of Reactants
3mLof
6NHCl
test tube
1
test tube
2
3mLof
6NHCl
folded
magnesium
ribbon
flatstrip
magnesium
ribbon
3mLof
6NHCl
test tube
1
test tube
2
3mLof
6NHCl
folded
magnesium
ribbon
flatstrip
magnesium
ribbon
Observation and Results:
 Nature of Reactants
Compare the speeds of the following sets of
reaction:
Experim
ent
No. 1
The solution
in the
second test
tube has no
reaction
after adding
a few drops
of disodium
phosphate
The solution
in the first
test tube
has the
faster
reaction
after adding
a drop of
BaCl2
Observation and Results:
 Nature of Reactants
Compare the speeds of the following sets of
reaction:
Experim
ent
No. 2
The reaction in the
first test tube
occur faster upon
adding hydrogen
peroxide.
The reaction in
the second test
tube occur fast.
Observation and Results:
 Nature of Reactants
Compare the speeds of the following sets of
reaction:
Experim
ent
No. 3
The
fastest
reaction
is in the
2nd test
tube with
a piece of
magnesiu
m ribbon
The
reaction in
the 3rd test
tube is
slow upon
adding ½
gm of Al.
In the third
test tube
with Zn,
the
reaction is
faster
than in the
3rd test
tube.
Observation and Results:
 Catalyst
Determine the rate of decomposition of H2O2 that takes place
into the two test tubes. This maybe determined from the rate
of evolution of oxygen gas.
Experim
ent
No. 1 The
decompositi
on in the 2nd
test tube is
faster upon
adding
manganese
dioxide.
Observation and Results:
 Catalyst
Time the reaction.Experim
ent
No. 2 in the 1st test
tube, the
magnesium
ribbon was
consumed
more rapidly
which occured
in only 1min.
in the 2nd test
tube, the
magnesium
ribbon was
consumed
after 3mins.
Observation and Results:
 Concentration of Reactants
Compare the reaction rates by noting the rate of
evolution of hydrogen gasExperim
ent
No. 1
The fastest
reaction is in
the 2nd test
tube with a
piece of
magnesium
ribbon which
reacted in less
than 1min.
The reaction
in the third
test tube is
slow and it
begun after
5mins.
The
magnesium
in the 1st test
tube reacted
after 3mins.
The reaction
is moderate
Observation and Results:
 Temperature
Observe the change in color and
record the time of the reaction.Experim
ent
No. 1
In 2nd test
tube, the
color also
changed from
violet to
colorless for
only 3mins.
upon heating
at 75C.
In the 1st test
tube, the
color
suddenly
change into
violet upon
adding the
potasium
permanganat
e solution.
Observation and Results:
 Surface Area of the Reactants
Record the time of the
reaction.
Experim
ent
No. 1
The flat
strip of
magnesium
ribbon
reacted in
less than
1min
the coiled
strip
reacted
after
1min.
Generalization:
There are five factors that effects the rate
of chemical reaction:
1. Nature of Reactants.
There are chemicals that are more active
than others. These can change the speed of
the reaction.
2. Presence of Catalyst.
Adding catalyst in the solution
increases the rate of reaction but the speed
depends on the solution where the catalyst is
added.
Generalization:
There are five factors that effects the rate
of chemical reaction:
3. Concentration of Reactants.
Increasing the concentration of reactants
also increases the rate of reaction because
the no. of possible collisions also increases.
4. Temperature
As the temperature rises, the collision
frequency and the collision efficiency
increases.
Generalization:
There are five factors that effects the rate
of chemical reaction:
5. Surface Area of Reactants
Increase in surface will increase reaction
rate because greater no. of reactant will come
in contact with each other.
Prepared and
presented by:
Abigail M. Sapico

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