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Chapter 8 Solutions 
8.2 
Electrolytes and Nonelectrolytes 
General, Organic, and Biological Chemistry Copyright © 2010 Pearson Education, Inc. 1
Solutes and Ionic Charge 
In water, 
 strong electrolytes produce ions and conduct an 
electric current 
 weak electrolytes produce a few ions 
 nonelectrolytes do not produce ions 
General, Organic, and Biological Chemistry Copyright © 2010 Pearson Education, Inc. 2
Strong Electrolytes 
Strong electrolytes 
 dissociate in water, producing positive and negative 
ions 
 dissolved in water will conduct an electric current 
 in equations show the formation of ions in aqueous 
(aq) solutions 
H2O 100% ions 
NaCl(s) Na+(aq) + Cl-(aq) 
H2O 
CaBr2(s) Ca2+(aq) + 2Br-(aq) 
General, Organic, and Biological Chemistry Copyright © 2010 Pearson Education, Inc. 3
Learning Check 
Complete each of the following equations for strong 
electrolytes dissolving in water. 
H2O 
A. CaCl2 (s) ? 
1) CaCl2(s) 2) Ca2+(aq) + Cl2 
−(aq) 
3) Ca2+(aq) + 2Cl−(aq) 
H2O 
B. K3PO4 (s) ? 
1) 3K+(aq) + PO4 
3−(aq) 2) K3PO4(s) 
3) K3 
+(aq) + P3−(aq) + O4 
−(aq) 
General, Organic, and Biological Chemistry Copyright © 2010 Pearson Education, Inc. 4
Solution 
Complete each of the following equations for strong 
electrolytes dissolving in water. 
H2O 
A. CaCl2 (s) ? 
3) Ca2+(aq) + 2Cl−(aq) 
H2O 
B. KPO(s) 34 ? 
1) 3K+(aq) + PO3−(aq) 
4 
General, Organic, and Biological Chemistry Copyright © 2010 Pearson Education, Inc. 5
Weak Electrolytes 
A weak electrolyte 
 dissociates only slightly in water 
 in water forms a solution of a few ions and mostly 
undissociated molecules 
HF(g) + H2O(l) H3O+(aq) + F-(aq) 
NH3(g) + H2O(l) NH4 
+(aq) + OH-(aq) 
General, Organic, and Biological Chemistry Copyright © 2010 Pearson Education, Inc. 6
Nonelectrolytes 
Nonelectrolytes 
 dissolve as 
molecules in water 
 do not produce ions 
in water 
 do not conduct an 
electric current 
General, Organic, and Biological Chemistry Copyright © 2010 Pearson Education, Inc. 7
Classification of Solutes in 
Aqueous Solutions 
General, Organic, and Biological Chemistry Copyright © 2010 Pearson Education, Inc. 
8
Equivalents 
An equivalent (Eq) is the amount of an electrolyte or an 
ion that provides 1 mole of electrical charge (+ or –). 
1 mole Na+ = 1 Eq 
1 mole Cl− = 1 Eq 
1 mole Ca2+ = 2 Eq 
1 mole Fe3+ = 3 Eq 
General, Organic, and Biological Chemistry Copyright © 2010 Pearson Education, Inc. 9
Electrolytes in IV Solutions 
General, Organic, and Biological Chemistry Copyright © 2010 Pearson Education, Inc. 10
Electrolytes in Body Fluids 
In replacement solutions for body 
fluids, the electrolytes are given in 
milliequivalents/L (mEq/L). 
Ringer’s Solution 
Cations Anion_____ 
Na+ 147 mEq/L Cl− 155 mEq/L 
K+ 4 mEq/L 
Ca2+ 4 mEq/L 
155 mEq/L = 155 mEq/L 
General, Organic, and Biological Chemistry Copyright © 2010 Pearson Education, Inc. 11
Learning Check 
A. In 1 mole of Fe3+, there are 
1) 1 Eq 2) 2 Eq 3) 3 Eq 
B. In 2.5 mole of SO4 
2−, there are 
1) 2.5 Eq 2) 5.0 Eq 3) 1.0 Eq 
C. An IV bottle contains only NaCl. If the Na+ is 
34 mEq/L, the Cl− is 
1) 34 mEq/L 2) 0 mEq/L 3) 68 mEq/L 
General, Organic, and Biological Chemistry Copyright © 2010 Pearson Education, Inc. 12
Solution 
A. In 1 mole of Fe3+, there are 
3) 3 Eq 
B. In 2.5 mole of SO4 
2−, there are 
2) 5.0 Eq 
2.5 moles SO4 
2− x 2 Eq = 5.0 Eq of SO4 
2− 
1 mole SO4 
2− 
C. An IV bottle contains only NaCl. If the Na+ is 
34 mEq/L, the Cl− is 
1) 34 mEq/L 
General, Organic, and Biological Chemistry Copyright © 2010 Pearson Education, Inc. 13

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Elektrolit dan Nonelektrolit

  • 1. Chapter 8 Solutions 8.2 Electrolytes and Nonelectrolytes General, Organic, and Biological Chemistry Copyright © 2010 Pearson Education, Inc. 1
  • 2. Solutes and Ionic Charge In water,  strong electrolytes produce ions and conduct an electric current  weak electrolytes produce a few ions  nonelectrolytes do not produce ions General, Organic, and Biological Chemistry Copyright © 2010 Pearson Education, Inc. 2
  • 3. Strong Electrolytes Strong electrolytes  dissociate in water, producing positive and negative ions  dissolved in water will conduct an electric current  in equations show the formation of ions in aqueous (aq) solutions H2O 100% ions NaCl(s) Na+(aq) + Cl-(aq) H2O CaBr2(s) Ca2+(aq) + 2Br-(aq) General, Organic, and Biological Chemistry Copyright © 2010 Pearson Education, Inc. 3
  • 4. Learning Check Complete each of the following equations for strong electrolytes dissolving in water. H2O A. CaCl2 (s) ? 1) CaCl2(s) 2) Ca2+(aq) + Cl2 −(aq) 3) Ca2+(aq) + 2Cl−(aq) H2O B. K3PO4 (s) ? 1) 3K+(aq) + PO4 3−(aq) 2) K3PO4(s) 3) K3 +(aq) + P3−(aq) + O4 −(aq) General, Organic, and Biological Chemistry Copyright © 2010 Pearson Education, Inc. 4
  • 5. Solution Complete each of the following equations for strong electrolytes dissolving in water. H2O A. CaCl2 (s) ? 3) Ca2+(aq) + 2Cl−(aq) H2O B. KPO(s) 34 ? 1) 3K+(aq) + PO3−(aq) 4 General, Organic, and Biological Chemistry Copyright © 2010 Pearson Education, Inc. 5
  • 6. Weak Electrolytes A weak electrolyte  dissociates only slightly in water  in water forms a solution of a few ions and mostly undissociated molecules HF(g) + H2O(l) H3O+(aq) + F-(aq) NH3(g) + H2O(l) NH4 +(aq) + OH-(aq) General, Organic, and Biological Chemistry Copyright © 2010 Pearson Education, Inc. 6
  • 7. Nonelectrolytes Nonelectrolytes  dissolve as molecules in water  do not produce ions in water  do not conduct an electric current General, Organic, and Biological Chemistry Copyright © 2010 Pearson Education, Inc. 7
  • 8. Classification of Solutes in Aqueous Solutions General, Organic, and Biological Chemistry Copyright © 2010 Pearson Education, Inc. 8
  • 9. Equivalents An equivalent (Eq) is the amount of an electrolyte or an ion that provides 1 mole of electrical charge (+ or –). 1 mole Na+ = 1 Eq 1 mole Cl− = 1 Eq 1 mole Ca2+ = 2 Eq 1 mole Fe3+ = 3 Eq General, Organic, and Biological Chemistry Copyright © 2010 Pearson Education, Inc. 9
  • 10. Electrolytes in IV Solutions General, Organic, and Biological Chemistry Copyright © 2010 Pearson Education, Inc. 10
  • 11. Electrolytes in Body Fluids In replacement solutions for body fluids, the electrolytes are given in milliequivalents/L (mEq/L). Ringer’s Solution Cations Anion_____ Na+ 147 mEq/L Cl− 155 mEq/L K+ 4 mEq/L Ca2+ 4 mEq/L 155 mEq/L = 155 mEq/L General, Organic, and Biological Chemistry Copyright © 2010 Pearson Education, Inc. 11
  • 12. Learning Check A. In 1 mole of Fe3+, there are 1) 1 Eq 2) 2 Eq 3) 3 Eq B. In 2.5 mole of SO4 2−, there are 1) 2.5 Eq 2) 5.0 Eq 3) 1.0 Eq C. An IV bottle contains only NaCl. If the Na+ is 34 mEq/L, the Cl− is 1) 34 mEq/L 2) 0 mEq/L 3) 68 mEq/L General, Organic, and Biological Chemistry Copyright © 2010 Pearson Education, Inc. 12
  • 13. Solution A. In 1 mole of Fe3+, there are 3) 3 Eq B. In 2.5 mole of SO4 2−, there are 2) 5.0 Eq 2.5 moles SO4 2− x 2 Eq = 5.0 Eq of SO4 2− 1 mole SO4 2− C. An IV bottle contains only NaCl. If the Na+ is 34 mEq/L, the Cl− is 1) 34 mEq/L General, Organic, and Biological Chemistry Copyright © 2010 Pearson Education, Inc. 13