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ELECTRICAL ENGINEERING
MATERIALS
MR. ASIF L. JAMADAR
BOHR POSTULATE
 Absorb or emit the frequencies of electromagnetic radiation by the atom
 Neils Bohr’s conclusion over discrete frequency absorbed or emitted by atom
 Bohr postulate:
 An electron did not radiate energy if it stayed in one orbit
 When the electrons moved from one orbit to another, it either radiated or absorbed
energy.
 For an electron to remain in its orbit, the electrostatic attraction between the
electron and nucleus ……..
2
WAVE / PARTICLE DUALITY
 Both wave & particles have a dual nature.
 An electron speeding down the column of an electron, in microscope as
electron produces such wave like diffraction effects upon interaction with the
materials.
 Wave/particle duality is expressed by
λ = h / p = h / mv
 Plank’s Constant (h = 6.62 X 10-34 J-s)
3
QUANTUM NUMBER
 Modern atomic theory indicates that the position and momentum of electrons
 State of an electron in an atom can be described by four quantum numbers.
 Principle quantum number, n
 Orbital quantum number, l
 Magnetic quantum number, ml
 Spin quantum number, ms
4
ELECTRON ENERGY LEVEL TRANSITIONS
 Set of electrons
 Energies of electrons depends on quantum number
 Electron transitions between two levels
 Excitation
 De-excitation
E2 - E1 = ∆E = hv12 = hc / λ
 As computational aid,
∆E (eV) = 1.24 / λ (μm)
5
THANK
YOU
6

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Electrical Engineering Material Part-II

  • 2. BOHR POSTULATE  Absorb or emit the frequencies of electromagnetic radiation by the atom  Neils Bohr’s conclusion over discrete frequency absorbed or emitted by atom  Bohr postulate:  An electron did not radiate energy if it stayed in one orbit  When the electrons moved from one orbit to another, it either radiated or absorbed energy.  For an electron to remain in its orbit, the electrostatic attraction between the electron and nucleus …….. 2
  • 3. WAVE / PARTICLE DUALITY  Both wave & particles have a dual nature.  An electron speeding down the column of an electron, in microscope as electron produces such wave like diffraction effects upon interaction with the materials.  Wave/particle duality is expressed by λ = h / p = h / mv  Plank’s Constant (h = 6.62 X 10-34 J-s) 3
  • 4. QUANTUM NUMBER  Modern atomic theory indicates that the position and momentum of electrons  State of an electron in an atom can be described by four quantum numbers.  Principle quantum number, n  Orbital quantum number, l  Magnetic quantum number, ml  Spin quantum number, ms 4
  • 5. ELECTRON ENERGY LEVEL TRANSITIONS  Set of electrons  Energies of electrons depends on quantum number  Electron transitions between two levels  Excitation  De-excitation E2 - E1 = ∆E = hv12 = hc / λ  As computational aid, ∆E (eV) = 1.24 / λ (μm) 5