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Diphenyl methane
Friedel craft condensation of benzyl
chloride with benzene
Properties of diphenyl methane
• Crystalline solid
• Melting point 26 C
• Reactions similar to diphenyl
• Benzyl group is ortho para orientation
Hydrogen of the methylene group is
very active. Bromination gives rise to
substitution in methylene group not in
the phenyl ring
On nitration the nitro group enters
mainly 4th position and another nitro
group enters 4’ position.
When oxidised with chromic acid it
forms benzophenone
Triphenyl methane
Triphenyl methane Structure
Triphenyl methane properties
• Colourless crystalline solid.
• Melting point 93C
• It is parent substance for triphenyl methane
dyes.
Preparation of triphenyl
methane
Friedel craft condensation between
chloroform and three molecules of
benzene
Friedel craft condensation between
benzylidine chloride and two
molecules of benzene
It is prepared by condensing the
benzaldehyde with two molecule of
benzene in the presence of zinc
chloride
Phenyl magnesium bromide react with
benzophenone gives triphenyl
methanol
When ethyl benzoate react with
phenyl magnesium bromide
Triphenyl methane react with bromine
form triphenyl methyl bromide
Triphenyl methane on oxidation gives
triphenyl carbinol
Diphenyl  and tri phenylmethane

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Diphenyl and tri phenylmethane