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Design and development of an anaerobic bio-digester for
application in sewage sludge digestion for biogas and bio-
solids generation using Acti-zyme as bio-catalyst
2nd ZIMBABWE RENEWABLE ENERGY CONFERENCE & EXHIBITION
Harare, Zimbabwe, 2015
By
M. M. Manyuchi, R. Marisa, D.I.O Ikhu-Omoregbe and O. O. Oyekola
Introduction
• Sewage sludge problems
• Energy Issues
• Environmental issues with sewage
• Biogas production- green solution to sewage management
• Acti-zyme properties
• Development of digester
Acti-zyme
• A bio-catalyst that promotes digestion of
sewage to produce biogas
• Exists in pellets forms
• Has been successfully used in sewage
treatment2
• Hinders production of H2S and
ammonia gases2
• Hence improves biogas quality
• Low quantities of bio-solids produced at
the end
Sewage properties
Parameter High Medium Low
COD 1200 750 500
BOD 560 350 230
TKN 100 60 30
NH3 75 45 20
TP 25 15 6
TSS 600 400 250
pH 8.0 7.5 7.0
Alkalinity eqv/m3 7 4 1
COD/BOD 2.5–3.5 2.0–2.5 1.5–2.0
COD/TP 45–60 35–45 20–35
Typical municipal wastewater characterization adopted from (Metcalf and Eddy Inc., 2003).
Materials and methods
• Retention time varied up to 60 days
• Acti-zyme loading: 35-70 g/m3
• Temperature: 35 oC
• Conditions: Anaerobic in 190 mL
digesters
• Agitation: 60 rpm
• Lab experiments
• Fabrication of Prototype
• Biogas Generation
• Bio-solids collection
(digestate for use as bio-fertiliser)
Sampling valve
Biodigester
Bio-solids outlet
Biogas
collector
Biogas outlet
Biogas quantity measuring jar
Acti-zyme
Biogas and bio-solids composition
Gas % (Acti-zyme) % (without Acti-zyme)
CH4 72-78 53-65
CO2 16-20 22-27
Traces (H2S, N2, H2) 5-9 8-12
Biogas
Parameter % Composition
Nitrogen 8.17±0.15
Phosphorous 5.84±0.03
Potassium 1.32±0.02
Copper 0.0073±0.0002
Iron 0.0087±0.0003
Calcium 0.0079±0.002
Magnesium 0.016±0.0021
Bio-solids
Mass balance over the bio-digester
Bio-digester design considerations
Components of Bio Digester
Body Construction
Material of construction
Sealing
Safety Valve
Capacity
Bio-digester design considerations
cont.….
• Baffles
• Shape of Bio-Digester
• Batch Time
Designed bio-digester depended on the Chitungwiza plant capacity
Batch kinetics in the bio-digester
0
10
20
30
40
50
60
70
80
90
0 10 20 30 40 50 60
CH4 (A1) CH4 (Ao)
Biogascomposition(%)
Retention time (days)
Exponential phase
Stationery phase
Deceralation phase
Lag phase
Bio-digester with Acti-zyme
generated the most biogas >15%
Bio-digester geometric considerations
Bio-digester fabricated prototype
Bio-digester process control
• Control and monitoring bio-digester system
• Temperature
• Sewage sludge flow rate
• Pressure
• pH
Bio-digester design parameters
summaryParameter Value
Volume 0.39 m3 (390 L)
Height 2 m
Diameter 0.5 m
Temperature 35 oC
Working pressure 1 atmos
Retention time 40 days
Height to diameter ratio 4
Type of head Hemispherical
Bio-digester design parameters summary
cont…..
Depth of dished bottom 0.125 m
Wall thickness 0.019 m
Head thickness 0.021 m
No. of baffles 4
Width of Baffle 0.042 m
Height of Baffle 1.5 m
Power per unit volume 1.3
Sewage sludge loading 290 L/day
Acti-zyme loading 0.0195 L/day
Bio-digester HAZOP Analysis
Guide word Parameter Deviation Possible cause Consequences Corrective measures
Less Temperature Temperature < 35°C Heating steam inlet valve
fails it is closed
Low digestion rate hence low biogas yield
Inefficient reaction of Acti-zyme
Production of high quantities of bio-solids
Install temperature sensors (thermocouples, thermometers) to
detect changes in temperatures
Repair of the valve
Valves should be checked regularly
More Temperature Temperature > 35°C Heating steam inlet valve
fails, it is fails to close
Excess of temperature have an effect on product quality
Acti-zyme activity are deactivated
Mesophillic conditions deactivated, lower biogas yield
Install temperature sensors such as thermocouple, thermometer
NO Flow No flow of sewage
sludge and Acti-zyme
into the bio-digester
Pipe blockage
Valve fails to open
(control valve failure)
Pump failure
Pipe leakages
Less biogas production
No sewage sludge and Acti-zyme in the bio-digester
Low biogas yield
Install flow alarms
Maintenance (repairing the control valve and pipes)
Check valves regularly
Install sensors that detect detects any changes and gives feedback
Bio-digester HAZOP Analysis cont……
Less Flow Low flow of
sewage sludge and
Acti-zyme
Clogging of the
sewage sludge and
Acti-zyme inside the
pipes
Leakage
Low yield of biogas
Acti-zyme does not have substrate to act on
Install flow meters
Alarms
Constant repairs of valves and pipes
More Pressure Pressure > 1 atmos Build-up of gases
during the digestion
process
Bursting of the bio-digester Install pressure relief valve to purge the excess gases
inside the bio-digester
Less Pressure Pressure < 1 atmos Causes mechanical stress on the bio-digester Install pressure sensors to detect changes in the pressure
Bio-digester HAZOP Analysis cont.…
NO Agitation No agitation
inside the bio-
digester
Stirrer motor not
functioning
No mixing
Possible accumulation of sewage
sludge at bottom of bio-digester
Acti-zyme cells tend to clump
together
Rate of digestion is slower
Low retention time
Maintenance of the stirrer motor
More Agitation More agitation
inside the bio-
digester
Stirrer motor
control fails (high
motor speed)
More collision of Acti-zyme and may
result in breakage of the cells
Repair of the stirrer motor
Conclusion
• The designed bio-digester can be applied in sewage sludge management
• The bio-digester can be used for biogas generation from any organic waste
Acknowledgements
• Harare Institute of Technology
• Cape Peninsula University of Technology
• HIT Chemical Engineering Department
Thank You!!!!!!!

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Design and development of an anaerobic bio-digester for application in sewage sludge digestion for biogas and bio-solids generation using Acti-zyme as bio-catalyst

  • 1. Design and development of an anaerobic bio-digester for application in sewage sludge digestion for biogas and bio- solids generation using Acti-zyme as bio-catalyst 2nd ZIMBABWE RENEWABLE ENERGY CONFERENCE & EXHIBITION Harare, Zimbabwe, 2015 By M. M. Manyuchi, R. Marisa, D.I.O Ikhu-Omoregbe and O. O. Oyekola
  • 2. Introduction • Sewage sludge problems • Energy Issues • Environmental issues with sewage • Biogas production- green solution to sewage management • Acti-zyme properties • Development of digester
  • 3. Acti-zyme • A bio-catalyst that promotes digestion of sewage to produce biogas • Exists in pellets forms • Has been successfully used in sewage treatment2 • Hinders production of H2S and ammonia gases2 • Hence improves biogas quality • Low quantities of bio-solids produced at the end
  • 4. Sewage properties Parameter High Medium Low COD 1200 750 500 BOD 560 350 230 TKN 100 60 30 NH3 75 45 20 TP 25 15 6 TSS 600 400 250 pH 8.0 7.5 7.0 Alkalinity eqv/m3 7 4 1 COD/BOD 2.5–3.5 2.0–2.5 1.5–2.0 COD/TP 45–60 35–45 20–35 Typical municipal wastewater characterization adopted from (Metcalf and Eddy Inc., 2003).
  • 5. Materials and methods • Retention time varied up to 60 days • Acti-zyme loading: 35-70 g/m3 • Temperature: 35 oC • Conditions: Anaerobic in 190 mL digesters • Agitation: 60 rpm • Lab experiments • Fabrication of Prototype • Biogas Generation • Bio-solids collection (digestate for use as bio-fertiliser) Sampling valve Biodigester Bio-solids outlet Biogas collector Biogas outlet Biogas quantity measuring jar Acti-zyme
  • 6. Biogas and bio-solids composition Gas % (Acti-zyme) % (without Acti-zyme) CH4 72-78 53-65 CO2 16-20 22-27 Traces (H2S, N2, H2) 5-9 8-12 Biogas Parameter % Composition Nitrogen 8.17±0.15 Phosphorous 5.84±0.03 Potassium 1.32±0.02 Copper 0.0073±0.0002 Iron 0.0087±0.0003 Calcium 0.0079±0.002 Magnesium 0.016±0.0021 Bio-solids
  • 7. Mass balance over the bio-digester
  • 8. Bio-digester design considerations Components of Bio Digester Body Construction Material of construction Sealing Safety Valve Capacity
  • 9. Bio-digester design considerations cont.…. • Baffles • Shape of Bio-Digester • Batch Time Designed bio-digester depended on the Chitungwiza plant capacity
  • 10. Batch kinetics in the bio-digester 0 10 20 30 40 50 60 70 80 90 0 10 20 30 40 50 60 CH4 (A1) CH4 (Ao) Biogascomposition(%) Retention time (days) Exponential phase Stationery phase Deceralation phase Lag phase Bio-digester with Acti-zyme generated the most biogas >15%
  • 13. Bio-digester process control • Control and monitoring bio-digester system • Temperature • Sewage sludge flow rate • Pressure • pH
  • 14. Bio-digester design parameters summaryParameter Value Volume 0.39 m3 (390 L) Height 2 m Diameter 0.5 m Temperature 35 oC Working pressure 1 atmos Retention time 40 days Height to diameter ratio 4 Type of head Hemispherical
  • 15. Bio-digester design parameters summary cont….. Depth of dished bottom 0.125 m Wall thickness 0.019 m Head thickness 0.021 m No. of baffles 4 Width of Baffle 0.042 m Height of Baffle 1.5 m Power per unit volume 1.3 Sewage sludge loading 290 L/day Acti-zyme loading 0.0195 L/day
  • 16. Bio-digester HAZOP Analysis Guide word Parameter Deviation Possible cause Consequences Corrective measures Less Temperature Temperature < 35°C Heating steam inlet valve fails it is closed Low digestion rate hence low biogas yield Inefficient reaction of Acti-zyme Production of high quantities of bio-solids Install temperature sensors (thermocouples, thermometers) to detect changes in temperatures Repair of the valve Valves should be checked regularly More Temperature Temperature > 35°C Heating steam inlet valve fails, it is fails to close Excess of temperature have an effect on product quality Acti-zyme activity are deactivated Mesophillic conditions deactivated, lower biogas yield Install temperature sensors such as thermocouple, thermometer NO Flow No flow of sewage sludge and Acti-zyme into the bio-digester Pipe blockage Valve fails to open (control valve failure) Pump failure Pipe leakages Less biogas production No sewage sludge and Acti-zyme in the bio-digester Low biogas yield Install flow alarms Maintenance (repairing the control valve and pipes) Check valves regularly Install sensors that detect detects any changes and gives feedback
  • 17. Bio-digester HAZOP Analysis cont…… Less Flow Low flow of sewage sludge and Acti-zyme Clogging of the sewage sludge and Acti-zyme inside the pipes Leakage Low yield of biogas Acti-zyme does not have substrate to act on Install flow meters Alarms Constant repairs of valves and pipes More Pressure Pressure > 1 atmos Build-up of gases during the digestion process Bursting of the bio-digester Install pressure relief valve to purge the excess gases inside the bio-digester Less Pressure Pressure < 1 atmos Causes mechanical stress on the bio-digester Install pressure sensors to detect changes in the pressure
  • 18. Bio-digester HAZOP Analysis cont.… NO Agitation No agitation inside the bio- digester Stirrer motor not functioning No mixing Possible accumulation of sewage sludge at bottom of bio-digester Acti-zyme cells tend to clump together Rate of digestion is slower Low retention time Maintenance of the stirrer motor More Agitation More agitation inside the bio- digester Stirrer motor control fails (high motor speed) More collision of Acti-zyme and may result in breakage of the cells Repair of the stirrer motor
  • 19. Conclusion • The designed bio-digester can be applied in sewage sludge management • The bio-digester can be used for biogas generation from any organic waste
  • 20. Acknowledgements • Harare Institute of Technology • Cape Peninsula University of Technology • HIT Chemical Engineering Department