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BIOGAS PRODUCTION FROM
SEWAGE
Overview
•Biogas
•Composition of biogas
•Advantages and disadvantages
•Biochemical reaction and stages of anaerobic digestion
•Modes of operation
•Types of anaerobic digesters
•Paper presentation
What is biogas?
Biogas is a methane rich flammable gas that results from the
decomposition of organic waste material
Biogas is produced by anaerobic digestion or fermentation of
biodegradable materials such as biomass, manure, sewage,
municipal waste, green waste, plant material and energy crops.
Biogas also called as ‘Marsh gas’
Biogas is a type of biofuel.
This type of biogas comprises primarily methane and carbon
dioxide
Composition of biogas
• Biogas is generated by the activity of anaerobic bacteria
• Composition depends on: the composition of raw material,
organic loading to digesters, time and temperature of
anaerobic digestion
Composition of biogas
Substances Symbol Percentage
Methane CH4 50 - 70
Carbon Dioxide CO2 30 - 40
Hydrogen H2 5 - 10
Nitrogen N2 1 - 2
Water vapour H2O 0.3
Hydrogen Sulphide H2S Traces
Advantages of biogas
• Production of large amount of methane gas (ambient
temperature storage)
• Production of free flowing thick sludge
• Odourless sludge
• Sludge can be used as fertilizer and soil conditioner
• Sanitary way for human and animal waste disposal
• Conservation of scarce resources like wood
• Explosion chances
• High capital lost
• Incorrect handling of liquid sludge causes pollution
• Requires control and maintenance
• Needs proper condition
• Use as a fuel requires removal of CO2 and H2S
Disadvantages
Factors affecting yield and production of
biogas
Many factors affecting the fermentation process of
organic substances under anaerobic condition are,
The quantity and nature of organic matter
The temperature
Acidity and alkanity (PH value) of substrate
The flow and dilution of material
GENERAL FEATURES OF BIOGAS
Biochemical reactions
Organic matter
Stages of anaerobic digestion:
1. Liquefaction by hydrolytic enzymes
2. Acid formation
3. Methane formation with methanogen production
CH4 + CO2 + H2 + NH3 + H2S
Liquefaction by hydrolytic enzymes
• Complex organic matter is degraded to basic structure
by hydraulic bacteria.
 Protein - Polypeptide and Amino Acid
 Fat -Glycerin and Fatty Acid
 Amylose - Monosacride and Polysacride
Acid Production
• Also called the acidogenesis
• Simple organic matters are converted into acetic acid, H2
and CO2
• Acting bacteria in this process are called hydrogen-
producing bacteria and acid-producing bacteria.
Methane Production
• Methanogenesis
• In this process, acetic acid, H2, CO2, are converted into CH4.
• Methane-producing bacteria have strict PH requirement and
low adaptability to temperature.
• Methanococcus jannaschii, Methanobacterium thermoautotrophicum
Flow chart of anaerobic digestion
Modes of operation
• Batch
• Semi-continuous – regular feeding of digester and
decrease of organic matter at intervals
• Continuous – for liquid waste treatment
Continuous-fed System
• Suited for large-scale manure substrate bioreactor.
• Steady biogas production can be expected.
• May require auxiliary equipments.
• Requires high liquid content.
• Temperature, loading rate, and solid content need to be
carefully monitored.
Batch-fed System
• The simplest design.
• Low cost.
• The feedstock is loaded one batch at time.
• Irregular biogas production.
• Can operate on high solid content.
• Requires manual labor.
Types of digesters
A typical biogas system consists of the following components:
• (1) Manure collection
• (2) Anaerobic digester
• (3) Effluent storage
• (4) Gas handling
• (5) Gas use.
TWO MAIN TYPES:
1. Digesters utilizing dispersed growth of bacteria
2. Digesters utilizing attached growth of bacteria
DISPERSED GROWTH DIGESTERS
1. Fixed dome digester
2. Floating gas holder digester (Indian)
3. Plug flow digester (horizontal displacement)
4. Bag digester (Taiwan and Korea)
5. Separate gas holder digester
6. Conventional digester
Fixed dome digester
 Drumless digester.
 Underground brick
masonry compartment
(fermentation chamber)
with a dome on the top
for gas storage.
 The fermentation chamber and gas holder are combined as one unit.
 Eliminates the use of costlier mild steel gas holder which is
susceptible to corrosion.
 20 to 50 years.
Floating gas holder digester
 In this design, the digester chamber is made of brick masonry in cement
mortar.
 A mild steel drum is placed on top of the digester to collect the biogas
produced from the digester. Thus, there are two separate structures for
gas production and collection.
 Jashu Bhai J Patel developed a
design of floating drum biogas
plant
 Popularly known as Gobar Gas
plant.
Bag Biodigester
• It consists of a long cylinder made of PVC or red mud plastic.
• The bag digester was developed to solve the problems experienced
with brick and metal digesters.
Attached growth digesters
1. Anaerobic filter
2. Up-flow anaerobic sludge
blanket (UABSR)
Anaerobic filter
 The methane forming bacteria form a film on the large surface of the packing
medium and are not carried out of the digester with the effluent.
 For this reason, these reactors are also known as "fixed film" or "retained film"
digesters.
 It consists of a column
filled with a packing
medium.
 A great variety of non-
biodegradable materials
have been used as
packing media for
anaerobic filter reactors
such as stones, plastic,
coral, mussel shells,
reeds, and bamboo rings.
UASBR
 The UASB reactors contain no packing medium, instead, the
methane forming bacteria are concentrated in the dense granules of
sludge blanket which covers the lower part of the reactor.
 The feed liquid enters from the bottom of the reactor and biogas is
produced while liquid flows up through the sludge blanket.
Gas Production potential of various types of dung
Types of Dung
Gas Production Per Kg Dung
(m3)
Cattle (cows and buffaloes) 0.023 - 0.040
Pig 0.040 - 0.059
Poultry (Chickens) 0.065 - 0.116
Human 0.020 - 0.028
Source: www.fao.org.in
Material and methods
• The Sewage Treatment Plant has capacity to treat 18 mld sewage
from main pumping station.
• After primary and secondary treatment, sludge is remain left that is
being collected in thickener.
• Around 96X105 liters sludge is being drained from thickener to
digester tank at each 12 hrs.
•
• The sludge was taken from thickener and digester tank and
Temperature, pH, Total solids %, Volatile solids %, and Alkalinity
parameters were analyzed
 The present study was done in the months of winter and
summer and the sampling were done seasonally from the
sewage treatment plant.
 Raw sewage consists of organic and inorganic solids in
dissolved and suspended form with 90-99.9% of water
Results
Materials and methods
• In this study, experiments were conducted to investigate the production of
biogas from municipal solid waste (MSW) and domestic sewage by using
anaerobic digestion process.
• The MSW is collected from the Perungudi yard at the Chennai metropolitan
city. The yard has an area of approximately 10 km2.
• Domestic sewage is collected from a college campus before disposal to the
treatment plant. It is used in all digestion experiments for diluting the feedstock
to achieve the required total concentration of TS.
• The domestic sewage is added to MSW, which is in the form of dry and
shredded waste. Here both the wastes are mixed so that it forms slurry.
Experimental set up
Results
• The digester was operated at different organic feeding rates of 0.5, 1.0,
2.3, 2.9, 3.5 and 4.3 kg of volatile solids (VS)/m3 of digester slurry per
day.
• Biogas generation was enhanced by the addition of domestic sewage to
MSW.
• The maximum biogas production of 0.36m3/kg of VS added per day
occurred at the optimum organic feeding rate of 2.9 kg of VS/m3/day.
References
Henry, C., 2006." What is an Anaerobic biodigester?”
http://manure.unl.edu/adobe/v7n10_01.pdf
http://www.fao.org.in (Biogas technology: a training manual
for extension" (FAO/CMS, 1996)
http://www.habmigern2003.info/biogas/Baron-
digester/Baron-digester-Dateien/image006.jpg
http://www. en.wikipedia.org/wiki/Biogas
http://www.renewableoil.com/pages/applications.html
http://www.omafra.gov.on.ca/english/engineer/facts/04-
097.html
Polprasert, C., 1989. Biogas production. In: Organic waste
recycling. John Wiley Sons. Ltd., Great Britain. 105-144
fdocuments.in_biogas-production-from-waste.ppt

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fdocuments.in_biogas-production-from-waste.ppt

  • 2. Overview •Biogas •Composition of biogas •Advantages and disadvantages •Biochemical reaction and stages of anaerobic digestion •Modes of operation •Types of anaerobic digesters •Paper presentation
  • 3. What is biogas? Biogas is a methane rich flammable gas that results from the decomposition of organic waste material Biogas is produced by anaerobic digestion or fermentation of biodegradable materials such as biomass, manure, sewage, municipal waste, green waste, plant material and energy crops. Biogas also called as ‘Marsh gas’ Biogas is a type of biofuel. This type of biogas comprises primarily methane and carbon dioxide
  • 4. Composition of biogas • Biogas is generated by the activity of anaerobic bacteria • Composition depends on: the composition of raw material, organic loading to digesters, time and temperature of anaerobic digestion Composition of biogas Substances Symbol Percentage Methane CH4 50 - 70 Carbon Dioxide CO2 30 - 40 Hydrogen H2 5 - 10 Nitrogen N2 1 - 2 Water vapour H2O 0.3 Hydrogen Sulphide H2S Traces
  • 5. Advantages of biogas • Production of large amount of methane gas (ambient temperature storage) • Production of free flowing thick sludge • Odourless sludge • Sludge can be used as fertilizer and soil conditioner • Sanitary way for human and animal waste disposal • Conservation of scarce resources like wood
  • 6. • Explosion chances • High capital lost • Incorrect handling of liquid sludge causes pollution • Requires control and maintenance • Needs proper condition • Use as a fuel requires removal of CO2 and H2S Disadvantages
  • 7. Factors affecting yield and production of biogas Many factors affecting the fermentation process of organic substances under anaerobic condition are, The quantity and nature of organic matter The temperature Acidity and alkanity (PH value) of substrate The flow and dilution of material
  • 9. Biochemical reactions Organic matter Stages of anaerobic digestion: 1. Liquefaction by hydrolytic enzymes 2. Acid formation 3. Methane formation with methanogen production CH4 + CO2 + H2 + NH3 + H2S
  • 10. Liquefaction by hydrolytic enzymes • Complex organic matter is degraded to basic structure by hydraulic bacteria.  Protein - Polypeptide and Amino Acid  Fat -Glycerin and Fatty Acid  Amylose - Monosacride and Polysacride
  • 11. Acid Production • Also called the acidogenesis • Simple organic matters are converted into acetic acid, H2 and CO2 • Acting bacteria in this process are called hydrogen- producing bacteria and acid-producing bacteria.
  • 12. Methane Production • Methanogenesis • In this process, acetic acid, H2, CO2, are converted into CH4. • Methane-producing bacteria have strict PH requirement and low adaptability to temperature. • Methanococcus jannaschii, Methanobacterium thermoautotrophicum
  • 13. Flow chart of anaerobic digestion
  • 14. Modes of operation • Batch • Semi-continuous – regular feeding of digester and decrease of organic matter at intervals • Continuous – for liquid waste treatment
  • 15. Continuous-fed System • Suited for large-scale manure substrate bioreactor. • Steady biogas production can be expected. • May require auxiliary equipments. • Requires high liquid content. • Temperature, loading rate, and solid content need to be carefully monitored.
  • 16. Batch-fed System • The simplest design. • Low cost. • The feedstock is loaded one batch at time. • Irregular biogas production. • Can operate on high solid content. • Requires manual labor.
  • 17. Types of digesters A typical biogas system consists of the following components: • (1) Manure collection • (2) Anaerobic digester • (3) Effluent storage • (4) Gas handling • (5) Gas use. TWO MAIN TYPES: 1. Digesters utilizing dispersed growth of bacteria 2. Digesters utilizing attached growth of bacteria
  • 18. DISPERSED GROWTH DIGESTERS 1. Fixed dome digester 2. Floating gas holder digester (Indian) 3. Plug flow digester (horizontal displacement) 4. Bag digester (Taiwan and Korea) 5. Separate gas holder digester 6. Conventional digester
  • 19. Fixed dome digester  Drumless digester.  Underground brick masonry compartment (fermentation chamber) with a dome on the top for gas storage.  The fermentation chamber and gas holder are combined as one unit.  Eliminates the use of costlier mild steel gas holder which is susceptible to corrosion.  20 to 50 years.
  • 20. Floating gas holder digester  In this design, the digester chamber is made of brick masonry in cement mortar.  A mild steel drum is placed on top of the digester to collect the biogas produced from the digester. Thus, there are two separate structures for gas production and collection.  Jashu Bhai J Patel developed a design of floating drum biogas plant  Popularly known as Gobar Gas plant.
  • 21. Bag Biodigester • It consists of a long cylinder made of PVC or red mud plastic. • The bag digester was developed to solve the problems experienced with brick and metal digesters.
  • 22. Attached growth digesters 1. Anaerobic filter 2. Up-flow anaerobic sludge blanket (UABSR)
  • 23. Anaerobic filter  The methane forming bacteria form a film on the large surface of the packing medium and are not carried out of the digester with the effluent.  For this reason, these reactors are also known as "fixed film" or "retained film" digesters.  It consists of a column filled with a packing medium.  A great variety of non- biodegradable materials have been used as packing media for anaerobic filter reactors such as stones, plastic, coral, mussel shells, reeds, and bamboo rings.
  • 24. UASBR  The UASB reactors contain no packing medium, instead, the methane forming bacteria are concentrated in the dense granules of sludge blanket which covers the lower part of the reactor.  The feed liquid enters from the bottom of the reactor and biogas is produced while liquid flows up through the sludge blanket.
  • 25.
  • 26. Gas Production potential of various types of dung Types of Dung Gas Production Per Kg Dung (m3) Cattle (cows and buffaloes) 0.023 - 0.040 Pig 0.040 - 0.059 Poultry (Chickens) 0.065 - 0.116 Human 0.020 - 0.028 Source: www.fao.org.in
  • 27.
  • 28. Material and methods • The Sewage Treatment Plant has capacity to treat 18 mld sewage from main pumping station. • After primary and secondary treatment, sludge is remain left that is being collected in thickener. • Around 96X105 liters sludge is being drained from thickener to digester tank at each 12 hrs. • • The sludge was taken from thickener and digester tank and Temperature, pH, Total solids %, Volatile solids %, and Alkalinity parameters were analyzed
  • 29.  The present study was done in the months of winter and summer and the sampling were done seasonally from the sewage treatment plant.  Raw sewage consists of organic and inorganic solids in dissolved and suspended form with 90-99.9% of water Results
  • 30.
  • 31. Materials and methods • In this study, experiments were conducted to investigate the production of biogas from municipal solid waste (MSW) and domestic sewage by using anaerobic digestion process. • The MSW is collected from the Perungudi yard at the Chennai metropolitan city. The yard has an area of approximately 10 km2. • Domestic sewage is collected from a college campus before disposal to the treatment plant. It is used in all digestion experiments for diluting the feedstock to achieve the required total concentration of TS. • The domestic sewage is added to MSW, which is in the form of dry and shredded waste. Here both the wastes are mixed so that it forms slurry.
  • 34. • The digester was operated at different organic feeding rates of 0.5, 1.0, 2.3, 2.9, 3.5 and 4.3 kg of volatile solids (VS)/m3 of digester slurry per day. • Biogas generation was enhanced by the addition of domestic sewage to MSW. • The maximum biogas production of 0.36m3/kg of VS added per day occurred at the optimum organic feeding rate of 2.9 kg of VS/m3/day.
  • 35. References Henry, C., 2006." What is an Anaerobic biodigester?” http://manure.unl.edu/adobe/v7n10_01.pdf http://www.fao.org.in (Biogas technology: a training manual for extension" (FAO/CMS, 1996) http://www.habmigern2003.info/biogas/Baron- digester/Baron-digester-Dateien/image006.jpg http://www. en.wikipedia.org/wiki/Biogas http://www.renewableoil.com/pages/applications.html http://www.omafra.gov.on.ca/english/engineer/facts/04- 097.html Polprasert, C., 1989. Biogas production. In: Organic waste recycling. John Wiley Sons. Ltd., Great Britain. 105-144