This document summarizes an X-ray crystallography study of a new pyrazole compound. Key findings include:
1) X-ray diffraction revealed the compound crystallized in the primitive monoclinic system with space group P21/n. Unit cell parameters and bond lengths/angles are reported.
2) The pyrazole ring is centered in the molecule and makes angles between 35-70 degrees with the phenyl, chlorophenyl, and chlorophenoxy rings.
3) The crystal structure is stabilized by intermolecular C-H...Cl and C-H...π hydrogen bonds.
4) Geometric parameters of the molecule are as expected and consistent with standard values
International Journal of Research in Engineering and Science is an open access peer-reviewed international forum for scientists involved in research to publish quality and refereed papers. Papers reporting original research or experimentally proved review work are welcome. Papers for publication are selected through peer review to ensure originality, relevance, and readability.
The IOSR Journal of Pharmacy (IOSRPHR) is an open access online & offline peer reviewed international journal, which publishes innovative research papers, reviews, mini-reviews, short communications and notes dealing with Pharmaceutical Sciences( Pharmaceutical Technology, Pharmaceutics, Biopharmaceutics, Pharmacokinetics, Pharmaceutical/Medicinal Chemistry, Computational Chemistry and Molecular Drug Design, Pharmacognosy & Phytochemistry, Pharmacology, Pharmaceutical Analysis, Pharmacy Practice, Clinical and Hospital Pharmacy, Cell Biology, Genomics and Proteomics, Pharmacogenomics, Bioinformatics and Biotechnology of Pharmaceutical Interest........more details on Aim & Scope).
All manuscripts are subject to rapid peer review. Those of high quality (not previously published and not under consideration for publication in another journal) will be published without delay.
This Journal publishes original research work that contributes significantly to further the scientific knowledge in pharmacy.
International Journal of Research in Engineering and Science is an open access peer-reviewed international forum for scientists involved in research to publish quality and refereed papers. Papers reporting original research or experimentally proved review work are welcome. Papers for publication are selected through peer review to ensure originality, relevance, and readability.
The IOSR Journal of Pharmacy (IOSRPHR) is an open access online & offline peer reviewed international journal, which publishes innovative research papers, reviews, mini-reviews, short communications and notes dealing with Pharmaceutical Sciences( Pharmaceutical Technology, Pharmaceutics, Biopharmaceutics, Pharmacokinetics, Pharmaceutical/Medicinal Chemistry, Computational Chemistry and Molecular Drug Design, Pharmacognosy & Phytochemistry, Pharmacology, Pharmaceutical Analysis, Pharmacy Practice, Clinical and Hospital Pharmacy, Cell Biology, Genomics and Proteomics, Pharmacogenomics, Bioinformatics and Biotechnology of Pharmaceutical Interest........more details on Aim & Scope).
All manuscripts are subject to rapid peer review. Those of high quality (not previously published and not under consideration for publication in another journal) will be published without delay.
This Journal publishes original research work that contributes significantly to further the scientific knowledge in pharmacy.
Targeted Intermediates of Eudesmic Acid: Synthesis and X-ray Investigationsijtsrd
it was carried out synthesis of esters and their dinitro derivatives of 3,4,5-trimethoxybenzoic (eudesmic) acid. Esterification of eudesmic acid carried out n absolute methanol or ethanol and corresponding methyl and ethyl 3,4,5-trimethoxybenzoates (2, 3) have been synthesized in good yields. It was revealed that nitration of these esters gives only dinitro products. The structure of the synthesized compounds of the methyl and ethyl 2,6-dinitro-3,4,5-trimethoxybenzoates (4, 5) was determined by X-ray diffraction analysis (XRD). In the asymmetric part of the crystal structures of 4, 5 one and two molecules are observed, respectively. In crystalline structures a flat nitro groups and carboxylic groups do not participate in the conjugation with aromatic rings. In the crystal structure of 4, an intermolecular C8-H...O9 hydrogen bond is observed, these H bonds link the molecules along the [010] axis. In the crystal structure of 5, intermolecular C9B-H...O4A and C10B-H...O8A hydrogen bonds form chains along the [011] axis. The formed chains are cross linked by the intermolecular C9B-H...O5A hydrogen bonds. Olimova M.I. | Okmanov R. Ya. | Elmuradov B. Zh."Targeted Intermediates of Eudesmic Acid: Synthesis and X-ray Investigations" Published in International Journal of Trend in Scientific Research and Development (ijtsrd), ISSN: 2456-6470, Volume-1 | Issue-6 , October 2017, URL: http://www.ijtsrd.com/papers/ijtsrd2417.pdf http://www.ijtsrd.com/chemistry/other/2417/targeted-intermediates-of-eudesmic-acid--synthesis-and-x-ray-investigations/olimova-mi
The IOSR Journal of Pharmacy (IOSRPHR) is an open access online & offline peer reviewed international journal, which publishes innovative research papers, reviews, mini-reviews, short communications and notes dealing with Pharmaceutical Sciences( Pharmaceutical Technology, Pharmaceutics, Biopharmaceutics, Pharmacokinetics, Pharmaceutical/Medicinal Chemistry, Computational Chemistry and Molecular Drug Design, Pharmacognosy & Phytochemistry, Pharmacology, Pharmaceutical Analysis, Pharmacy Practice, Clinical and Hospital Pharmacy, Cell Biology, Genomics and Proteomics, Pharmacogenomics, Bioinformatics and Biotechnology of Pharmaceutical Interest........more details on Aim & Scope).
All manuscripts are subject to rapid peer review. Those of high quality (not previously published and not under consideration for publication in another journal) will be published without delay.
Nuclear Magnetic Resonance (NMR) Analysis of D - (+) - Glucose: A Guide to Sp...IOSR Journals
NMR spectroscopy has a wide range of applications including exchange phenomena, the
identification and structural studies of complex biomolecules. 1D 1H-NMR without water suppression, 1D
Carbon, 1D 13C-DEPT135, 2D Cosy, 2D HSQC, 2D TOCSY, 2D HMQC, and 2D HMBC techniques were used
to completely elucidate the structure of glucose with spectral induced at 400MHz.. The spectral were analysed
using spinworks 3. The results obtained from the spectral data were systematically combined to elucidate the
structure of the D-glucose. Full characterisation of D-glucose was achieved by assigning 1H and 13C signals,
starting from the known to unknown signals.
Influence of the alkyl chain length of alkyltriazoles on the corrosion inhibi...Al Baha University
Abstract. Steel is an important material and has been widely used in today's industrial production. Using organic
corrosion inhibitors is an effective means to prevent steel from corrosion. Generally, the molecular structures of
inhibitors can have a major impact on their corrosion inhibition efficiency. In this work, the influence of alkyl chain
length of three alkyltriazoles on the corrosion inhibition of iron has been investigated by density functional based tight
binding (DFTB) approach. Several typical descriptors such as frontier molecular orbital, adsorption energy, density of
states have been discussed in detail. Our findings will contribute to the understanding of the inhibition mechanism and
the designing of novel corrosion inhibitors.
SIMONA CAVALU_Adsorption behavior of hyaluronidase onto silverSimona Cavalu
Surface enhanced Raman scattering (SERS) and ATR-FTIR spectroscopy was applied in this work, in order to get
information about the adsorption behavior of the title macromolecule with respect to different surfaces. In this case, the
silver substrate can be considered as artificial substrate and the investigations regarding the mechanisms of adsorption can
be useful in order to elucidate the active site properties of this enzyme. Our purpose is to study the adsorption mechanism
of hyaluronidase onto silver nanoparticles and PMMA (polymethyl methacrylate) substrates as well as qualitative and
quantitative aspects regarding perturbations of protein secondary structure (α-helix, β-sheet and unordered structures) upon
adsorption, using deconvolution techniques.
Synthesis, spectroscopic, electrochemical, magnetic properties and super oxid...IOSR Journals
Five new mixed-ligand nickel (II) complexes; viz; [Ni (BHM)(PMDT)]1; [Ni(BHM)(dien)] 2; [Ni(BHM)(L1)]3; [Ni(BHM)(L2)] 4, [Ni(BHM)(L3)] 5; where H2BHM= N’-(1E)-(5-bromo-2-hydroxyphenyl) methylidene] benzoylhydrazide, PMDT= N,N,N’,N,”N”-Pentamethyldiethylenetriamine; dien= diethylenetriamine; L1 = N,N- dimethyl-N’ (Pyrid-2-yl-methyl) ethylenediamine; L2= N-methyl-N’-(pyrid-2-ylmethyl)ethylenediamine; L3 = N,N-dimethyl-N’-(6-methyl)pyrid-2-ylmethyl) ethylenediamine, have been synthesized and characterized by using elemental analyses, FAB (fast atomic bombardment), magnetic measurements, electronic absorption , conductivity measurements, cyclic voltammetry (CV) and IR- spectroscopy . All the complexes yielded an irreversible couple that can be assigned to a NiII→ NiI redox process. Infrared spectra, ligand field spectra and magnetic susceptibility measurements agree with the observed octahedral environment. H2BHM is a diprotic tridentate Schiff base ligand (ONO donor atom) whereas L1-L3 possessing N3 coordination sites. The SOD activities have been measured using alkaline DMSO as a source of superoxide radical (O2–) and nitro blue tetrazolium (NBT) as O2– scavenger.
ER Publication,
IJETR, IJMCTR,
Journals,
International Journals,
High Impact Journals,
Monthly Journal,
Good quality Journals,
Research,
Research Papers,
Research Article,
Free Journals, Open access Journals,
erpublication.org,
Engineering Journal,
Science Journals,
ITJEMAST5(1): Latest Research from International Transaction Journal of Engin...drboon
Latest Research from International Transaction Journal of Engineering, Management, & Applied Sciences & Technologies ITJEMAST5(1):
Effects of Calcination Treatment of Diatomite on Dimethyl Ether Synthesis from Methanol
Effect of Blend Ratio on Cure Characteristics, Mechanical Properties, and Aging Resistance of Silica-filled ENR/SBR Blends
An Efficient Formulation of Off-line Model Predictive Control for Nonlinear Systems Using Polyhedral Invariant Sets
Effect of Modeling Parameters on System Hydrodynamics of Air Reactor in Chemical Looping Combustion Using CFD Simulation
Flow Behavior of Geldart A and Geldart C Particles in a Co-current Downflow Circulating Fluidized Bed Reactor
Optimization of Enzymatic Clarification from Corncob
Synthesis of Alkali Metal/CaO Sorbent for CO2 Capture at Low Temperature
Synthesis, Physicochemical Characterization and Structure Determination of So...IOSR Journals
Some novel nickel(II) complexes with the ligand (z)-4-((2-hydroxy-3-
methoxyphenyl)diazenyl)-1,5-dimethyl-2-phenyl-1H-pyrazol-3-(2H)-one,GAAP,guiacolazoantipyrine, L
having molecular formulae [Ni(L)2X2] and [Ni(L)2(NCS)Cl] where X = Cl-, Br-, NO3
- were synthesized and
characterized. The elemental analysis, Spectral (IR, UV-Visible, EPR, FAB – mass) studies and thermo
gravimetric analysis reveals that the Ni(II) is six coordinated in its complexes. A rhombic symmetry can be
tentatively proposed for the complexes. The magnetic susceptibility measurements show that the complexes are
paramagnetic in nature. The powder XRD study shows its anisotropic nature
Targeted Intermediates of Eudesmic Acid: Synthesis and X-ray Investigationsijtsrd
it was carried out synthesis of esters and their dinitro derivatives of 3,4,5-trimethoxybenzoic (eudesmic) acid. Esterification of eudesmic acid carried out n absolute methanol or ethanol and corresponding methyl and ethyl 3,4,5-trimethoxybenzoates (2, 3) have been synthesized in good yields. It was revealed that nitration of these esters gives only dinitro products. The structure of the synthesized compounds of the methyl and ethyl 2,6-dinitro-3,4,5-trimethoxybenzoates (4, 5) was determined by X-ray diffraction analysis (XRD). In the asymmetric part of the crystal structures of 4, 5 one and two molecules are observed, respectively. In crystalline structures a flat nitro groups and carboxylic groups do not participate in the conjugation with aromatic rings. In the crystal structure of 4, an intermolecular C8-H...O9 hydrogen bond is observed, these H bonds link the molecules along the [010] axis. In the crystal structure of 5, intermolecular C9B-H...O4A and C10B-H...O8A hydrogen bonds form chains along the [011] axis. The formed chains are cross linked by the intermolecular C9B-H...O5A hydrogen bonds. Olimova M.I. | Okmanov R. Ya. | Elmuradov B. Zh."Targeted Intermediates of Eudesmic Acid: Synthesis and X-ray Investigations" Published in International Journal of Trend in Scientific Research and Development (ijtsrd), ISSN: 2456-6470, Volume-1 | Issue-6 , October 2017, URL: http://www.ijtsrd.com/papers/ijtsrd2417.pdf http://www.ijtsrd.com/chemistry/other/2417/targeted-intermediates-of-eudesmic-acid--synthesis-and-x-ray-investigations/olimova-mi
The IOSR Journal of Pharmacy (IOSRPHR) is an open access online & offline peer reviewed international journal, which publishes innovative research papers, reviews, mini-reviews, short communications and notes dealing with Pharmaceutical Sciences( Pharmaceutical Technology, Pharmaceutics, Biopharmaceutics, Pharmacokinetics, Pharmaceutical/Medicinal Chemistry, Computational Chemistry and Molecular Drug Design, Pharmacognosy & Phytochemistry, Pharmacology, Pharmaceutical Analysis, Pharmacy Practice, Clinical and Hospital Pharmacy, Cell Biology, Genomics and Proteomics, Pharmacogenomics, Bioinformatics and Biotechnology of Pharmaceutical Interest........more details on Aim & Scope).
All manuscripts are subject to rapid peer review. Those of high quality (not previously published and not under consideration for publication in another journal) will be published without delay.
Nuclear Magnetic Resonance (NMR) Analysis of D - (+) - Glucose: A Guide to Sp...IOSR Journals
NMR spectroscopy has a wide range of applications including exchange phenomena, the
identification and structural studies of complex biomolecules. 1D 1H-NMR without water suppression, 1D
Carbon, 1D 13C-DEPT135, 2D Cosy, 2D HSQC, 2D TOCSY, 2D HMQC, and 2D HMBC techniques were used
to completely elucidate the structure of glucose with spectral induced at 400MHz.. The spectral were analysed
using spinworks 3. The results obtained from the spectral data were systematically combined to elucidate the
structure of the D-glucose. Full characterisation of D-glucose was achieved by assigning 1H and 13C signals,
starting from the known to unknown signals.
Influence of the alkyl chain length of alkyltriazoles on the corrosion inhibi...Al Baha University
Abstract. Steel is an important material and has been widely used in today's industrial production. Using organic
corrosion inhibitors is an effective means to prevent steel from corrosion. Generally, the molecular structures of
inhibitors can have a major impact on their corrosion inhibition efficiency. In this work, the influence of alkyl chain
length of three alkyltriazoles on the corrosion inhibition of iron has been investigated by density functional based tight
binding (DFTB) approach. Several typical descriptors such as frontier molecular orbital, adsorption energy, density of
states have been discussed in detail. Our findings will contribute to the understanding of the inhibition mechanism and
the designing of novel corrosion inhibitors.
SIMONA CAVALU_Adsorption behavior of hyaluronidase onto silverSimona Cavalu
Surface enhanced Raman scattering (SERS) and ATR-FTIR spectroscopy was applied in this work, in order to get
information about the adsorption behavior of the title macromolecule with respect to different surfaces. In this case, the
silver substrate can be considered as artificial substrate and the investigations regarding the mechanisms of adsorption can
be useful in order to elucidate the active site properties of this enzyme. Our purpose is to study the adsorption mechanism
of hyaluronidase onto silver nanoparticles and PMMA (polymethyl methacrylate) substrates as well as qualitative and
quantitative aspects regarding perturbations of protein secondary structure (α-helix, β-sheet and unordered structures) upon
adsorption, using deconvolution techniques.
Synthesis, spectroscopic, electrochemical, magnetic properties and super oxid...IOSR Journals
Five new mixed-ligand nickel (II) complexes; viz; [Ni (BHM)(PMDT)]1; [Ni(BHM)(dien)] 2; [Ni(BHM)(L1)]3; [Ni(BHM)(L2)] 4, [Ni(BHM)(L3)] 5; where H2BHM= N’-(1E)-(5-bromo-2-hydroxyphenyl) methylidene] benzoylhydrazide, PMDT= N,N,N’,N,”N”-Pentamethyldiethylenetriamine; dien= diethylenetriamine; L1 = N,N- dimethyl-N’ (Pyrid-2-yl-methyl) ethylenediamine; L2= N-methyl-N’-(pyrid-2-ylmethyl)ethylenediamine; L3 = N,N-dimethyl-N’-(6-methyl)pyrid-2-ylmethyl) ethylenediamine, have been synthesized and characterized by using elemental analyses, FAB (fast atomic bombardment), magnetic measurements, electronic absorption , conductivity measurements, cyclic voltammetry (CV) and IR- spectroscopy . All the complexes yielded an irreversible couple that can be assigned to a NiII→ NiI redox process. Infrared spectra, ligand field spectra and magnetic susceptibility measurements agree with the observed octahedral environment. H2BHM is a diprotic tridentate Schiff base ligand (ONO donor atom) whereas L1-L3 possessing N3 coordination sites. The SOD activities have been measured using alkaline DMSO as a source of superoxide radical (O2–) and nitro blue tetrazolium (NBT) as O2– scavenger.
ER Publication,
IJETR, IJMCTR,
Journals,
International Journals,
High Impact Journals,
Monthly Journal,
Good quality Journals,
Research,
Research Papers,
Research Article,
Free Journals, Open access Journals,
erpublication.org,
Engineering Journal,
Science Journals,
ITJEMAST5(1): Latest Research from International Transaction Journal of Engin...drboon
Latest Research from International Transaction Journal of Engineering, Management, & Applied Sciences & Technologies ITJEMAST5(1):
Effects of Calcination Treatment of Diatomite on Dimethyl Ether Synthesis from Methanol
Effect of Blend Ratio on Cure Characteristics, Mechanical Properties, and Aging Resistance of Silica-filled ENR/SBR Blends
An Efficient Formulation of Off-line Model Predictive Control for Nonlinear Systems Using Polyhedral Invariant Sets
Effect of Modeling Parameters on System Hydrodynamics of Air Reactor in Chemical Looping Combustion Using CFD Simulation
Flow Behavior of Geldart A and Geldart C Particles in a Co-current Downflow Circulating Fluidized Bed Reactor
Optimization of Enzymatic Clarification from Corncob
Synthesis of Alkali Metal/CaO Sorbent for CO2 Capture at Low Temperature
Synthesis, Physicochemical Characterization and Structure Determination of So...IOSR Journals
Some novel nickel(II) complexes with the ligand (z)-4-((2-hydroxy-3-
methoxyphenyl)diazenyl)-1,5-dimethyl-2-phenyl-1H-pyrazol-3-(2H)-one,GAAP,guiacolazoantipyrine, L
having molecular formulae [Ni(L)2X2] and [Ni(L)2(NCS)Cl] where X = Cl-, Br-, NO3
- were synthesized and
characterized. The elemental analysis, Spectral (IR, UV-Visible, EPR, FAB – mass) studies and thermo
gravimetric analysis reveals that the Ni(II) is six coordinated in its complexes. A rhombic symmetry can be
tentatively proposed for the complexes. The magnetic susceptibility measurements show that the complexes are
paramagnetic in nature. The powder XRD study shows its anisotropic nature
Synthesis, Physicochemical Characterization and Structure Determination of So...
Similar to Crystal and Molecular Structure Studies of 1-(5-(4-chlorophenoxy)-3-methyl-1-phenyl-4,5-dihydro-1H-pyrazol-4-yl)-N-(4-chlorophenyl)methanimine
A Semi-empirical based QSAR study of indole휷- Diketo acid, Diketo acid and Ca...iosrjce
In this study, a set of novel synthesized indole훽- diketo acid, diketo acid and carboxamide
derivativeswas investigated by quantitative structure–activity relationship (QSAR) analysis using semiempirical
(PM3) based descriptors. The best molecular descriptors identified were LogP, polar area
corresponding to absolute values of electrostatic potential greater than 75 (P-area(75)), Energy (E), Minimum
values of electrostatic potential (as mapped onto an electron density surface) (MinEIPot), Polar surface area
and Maximum values of electrostatic potential (as mapped onto an electron density surface) (MaxEIPot) that
contributed to the anti-HIV activity of the indole훽- diketo acid, diketo acid and carboxamide derivatives as
independent factors. The correlation of these descriptors with their anti-HIV activity increases indicating their
importance in studying biological activity. Quantitative structure activity relationship (QSAR) analysis was
applied to 37 of the above mentioned derivatives using physicochemical and structural molecular descriptors
obtained by the semi-empirical method by employing PM3 basis set. By using the multiple linear regression
(MLR) technique several QSAR models have been drown up with the help these calculated descriptors and the
anti-HIV activity of indole훽- diketo acid, diketo acid and carboxamide derivatives. The regression method was
used to derive the most significant models as a calibration model for predicting the LogIC50 of this class of
compounds. Among the obtained QSAR models presented in the study from the MLR method, statistically the
most significant one is the last model with the squared correlation coefficient 0.8932, Q = 3.1854 and F=
27.8644 that could be useful to predict the biological activity of indole훽- diketo acid, diketo acid and carboxamide derivatives as Potent HIV-1 Drugs.
Morphology and characterization of srxcu1 xo [x=0.1]eSAT Journals
Abstract The application of Nanostructured materials is enormous as their physical and chemical properties depend upon size. Here an attempt is made first time to synthesis (Srx Cu1-xO) nanoparticles by sol–gel method. Sr(No3)2and Cu(No3)2.3H2O were taken as starting material. Ethanol, distilled water and PVA are mixed with these powders of nitrates and solution was stirred by magnetic stirrer at a temperature of 80 0C till a gel was formed. It was then dried at low temperature and finally calcinated at 400 0C for four hours. XRD of the sample shows its crystalline nature and particle size was determined to be 34nm by Debye Schherrer formula. The FTIR study shows two broad peak at 1455 cm-1and 532 cm-1. The UV-VIS analysis shows a absorption peak at 202nm .The TEM images clearly shows the individual nanoparticles having diameter less than 20 nm. In one image a nano rod is also visible whose further study is also required. Keywords:-nano materials, XRD, FTIR, TEM, UV-VIS, band gap, strontium
FT IR and FT RAMAN SPECTRA of 4 Chloro 2 Methyl Benzonitrileijtsrd
FT IR spectrum of 4 chloro 2 methyl benzonitrile in the region 400 4000 cm 1 has been recorded in KBr pellet technique with a Bruker IFS 66 Fourier transform spectrometer. FT Raman spectrum in powder form has been recorded in the region 50 4000 cm on a Bruker IFS 66 optical bench with an FRA 106 Raman module attachment interfaced to a microcomputer. Geometry and vibrational wavenumbers were calculated using ab initio calculations with HF method. The results were compared with experimental values. The observed FT IR and FT Raman vibrational frequencies were analyzed and assigned to different normal modes of the molecule. Most of the modes have wavenumbers in the expected range and the error obtained was, in general, very low. Using PEDs, the contributions were determined for different modes to each wave number. From the PED, it is apparent that the frequency corresponding to C=N stretching contains 88 contribution from the C=N stretching force constant and it mixes with C CN stretching mode to the extent of 12 . Virendra Kumar Sharma "FT-IR and FT RAMAN SPECTRA of 4-Chloro 2 Methyl Benzonitrile" Published in International Journal of Trend in Scientific Research and Development (ijtsrd), ISSN: 2456-6470, Volume-6 | Issue-3 , April 2022, URL: https://www.ijtsrd.com/papers/ijtsrd49470.pdf Paper URL: https://www.ijtsrd.com/physics/other/49470/ftir-and-ft-raman-spectra-of-4chloro-2-methyl-benzonitrile/virendra-kumar-sharma
Preparation and Antimicrobial Studies of Oxadiazine Containing Heterocyclic C...ijtsrd
The triazole derivative say 2 3 methylthio 5 phenyl 4H 1,2,4 triazol 4 yl acetohydrazide 1 was prepared. Various Schiff bases 3a e of 1 were prepared by reacting with various benzaldehyde derivatives 2a e . All the 3a e compounds condensed with benzoyl isothiocyanate 4 to afford N 2 aryl 6 phenyl 4 thioxo 2H 1,3,5 oxadiazin 3 4H yl 2 3 methylthio 5 phenyl 4H 1,2,4 triazol 4 yl acetamide derivatives 5a e . All the synthesized compounds characterized spectroscopically and tested for antimicrobial activity. Reeta Tripathi | Diwa Mishra | Arun Singh "Preparation and Antimicrobial Studies of Oxadiazine Containing Heterocyclic Compounds" Published in International Journal of Trend in Scientific Research and Development (ijtsrd), ISSN: 2456-6470, Volume-3 | Issue-5 , August 2019, URL: https://www.ijtsrd.com/papers/ijtsrd25349.pdfPaper URL: https://www.ijtsrd.com/chemistry/other/25349/preparation-and-antimicrobial-studies-of-oxadiazine-containing-heterocyclic-compounds/reeta-tripathi
The cholesteric liquid-crystal poly[oxycarbonyl-1,4-phenylene-oxy-1,4 terephthaloyl-oxy-1,4-phenylenecarbonyloxy(
1,2-dodecane)] [C34H36O8]n, named PTOBDME, synthesized by polycondensation reaction from
equimolar quantities of TOBC and the racemic mixture of glycol (R-S-1,2 dodecanediol), exhibits unexpected
optical activity and chiral morphology. The structure of racemic-PTOBDME, under different polymerization
kinetics conditions, is analyzed by conventional NMR techniques and compared with those of polymer
enantiomers R-PTOBDME and S-PTOBDME obtained starting R(+)1,2 and S(-)1,2-dodecanediol respectively.
Molecular models based on the NMR signals intensities are proposed. The optical activity of racemic-
PTOBDME is evaluated by measuring the ORD values during kinetics study, and compared to the chiral
polymers. Each enantiomeric polymer seems to present the same stereoregular head-tail, isotactic structure than
the racemic, which we explain by the higher reactivity of the primary hydroxyl than the secondary one in the
glycol through polycondensation. For each enantiomer, two independent sets of signals were observed by NMR,
explained as two diastereomeric helical conformers: gg and gt, related with two possible staggered
conformations, along the copolymer backbone. Chirality in racemic-PTOBDME is proposed to be due to the
kinetic resolution of a preferable helical diastereomer, such as Sgt, with respect to the possible four forms, while
the R/S ratio of asymmetric carbon atoms remained 50:50. Chiral amplification is observed in R-PTOBDME and
S-PTOBDME due to a helical screw sense excess. Optimum yield was obtained for racemic PTOBDME, after
120 minutes polycondensated and decanted in toluene for 24 hours. Two weeks later a second fraction
precipitated from the toluene mother liquor with 67.6% chiral excess. After eight months and two weeks a third
fraction precipitated with 85.2% chiral excess.
Synthesis and characterization of some Chromium(III) complexes of dibasic tri...IJERA Editor
Coordination complexes of Cr(III)with four tridentate Schiff base ligands viz. N-(2-hydroxy-1-naphthaldehyde)- -(4-nitrobenzoyl)hydrazone(HNNH = H2L 1 ), N-(2-hydroxy-4-methoxybenzaldehyde)- -(2-furoyl) hydrazone (HMFH = H2L 2 ), N-(2-hydroxyacetophenone)- -(2-theonyl) hydrazone (HATH = H2L 3 ) and N-(2- hydroxy-5-methylacetophenone)- -(3-toloyl) hydrazone (HMAT = H2L 4 ) have been synthesized and characterized by elemental analysis, magnetic susceptibility, molar conductance, thermogravimetric analysis and spectral (IR, electronic, NMR) measurements. IR spectra indicates that the ligand behave as dibasic tridentate ligand in a chelate coordinating to Cr(III) ion through ketonic oxygen, azomethine nitrogen and by both enolic and phenolic protons (except in H2L 1 by naphtholic oxygen atom) via double deprotonation of ligands. The magnetic and spectral data indicate chelate in octahedral environment and analytical data suggest 1:1 stoichiometries for the complexes
Synthesis of 1,2,3-Triazole 5-Chloroisatin Derivatives via Copper-Catalyzed 1...IJAEMSJORNAL
A facile and simple protocol for the ‘Click’ cycloaddition of organic azides with N-propargylchloroisatine catalyzed by CuI, produces in good yields novel of 1,4-disubstituted 1,2,3-triazoles were obtained. Compared to the uncatalyzed cycloaddition, the yields are significantly improved in the presence of CuI as catalyst, without alteration of the selectivity. The regio- and stereochemistry of the cycloadducts has been corroborated by 1H, 13C NMR spectroscopy.
Study of characterization of (peo+kclo4) polymer electrolyte systemeSAT Journals
Abstract Solid state polymer electrolytes have been prepared by using poly (ethylene oxide) (PEO) and KClO4 salt in the Wt% ratios of (90:10), (80:20) and (70:30) by solution – casting technique by using methanol (water-free) as solvent. The complexation of pure PEO with KClO4 salts has been extensively studied using IR studies. In the Differential Scanning Calorimetry (DSC) curves it observed that, pure PEO melting temperature (Tm) slight shift towards lower temperature is due to the addition of KClO4 salt to the polymer. XRD data for these films clearly confirm the complexation between the KClO4 salt and the polymer PEO. The d-values calculated from the X-ray diffraction of pure PEO and various compositions of KClO4 complexed films are clearly indicate the complexation of PEO and KClO4. Keywords: Polymer electrolytes, IR studies, differential scanning calorimetry, X-ray diffraction.
Study of characterization of (peo+kclo4) polymer electrolyte systemeSAT Publishing House
IJRET : International Journal of Research in Engineering and Technology is an international peer reviewed, online journal published by eSAT Publishing House for the enhancement of research in various disciplines of Engineering and Technology. The aim and scope of the journal is to provide an academic medium and an important reference for the advancement and dissemination of research results that support high-level learning, teaching and research in the fields of Engineering and Technology. We bring together Scientists, Academician, Field Engineers, Scholars and Students of related fields of Engineering and Technology
Similar to Crystal and Molecular Structure Studies of 1-(5-(4-chlorophenoxy)-3-methyl-1-phenyl-4,5-dihydro-1H-pyrazol-4-yl)-N-(4-chlorophenyl)methanimine (20)
About
Indigenized remote control interface card suitable for MAFI system CCR equipment. Compatible for IDM8000 CCR. Backplane mounted serial and TCP/Ethernet communication module for CCR remote access. IDM 8000 CCR remote control on serial and TCP protocol.
• Remote control: Parallel or serial interface.
• Compatible with MAFI CCR system.
• Compatible with IDM8000 CCR.
• Compatible with Backplane mount serial communication.
• Compatible with commercial and Defence aviation CCR system.
• Remote control system for accessing CCR and allied system over serial or TCP.
• Indigenized local Support/presence in India.
• Easy in configuration using DIP switches.
Technical Specifications
Indigenized remote control interface card suitable for MAFI system CCR equipment. Compatible for IDM8000 CCR. Backplane mounted serial and TCP/Ethernet communication module for CCR remote access. IDM 8000 CCR remote control on serial and TCP protocol.
Key Features
Indigenized remote control interface card suitable for MAFI system CCR equipment. Compatible for IDM8000 CCR. Backplane mounted serial and TCP/Ethernet communication module for CCR remote access. IDM 8000 CCR remote control on serial and TCP protocol.
• Remote control: Parallel or serial interface
• Compatible with MAFI CCR system
• Copatiable with IDM8000 CCR
• Compatible with Backplane mount serial communication.
• Compatible with commercial and Defence aviation CCR system.
• Remote control system for accessing CCR and allied system over serial or TCP.
• Indigenized local Support/presence in India.
Application
• Remote control: Parallel or serial interface.
• Compatible with MAFI CCR system.
• Compatible with IDM8000 CCR.
• Compatible with Backplane mount serial communication.
• Compatible with commercial and Defence aviation CCR system.
• Remote control system for accessing CCR and allied system over serial or TCP.
• Indigenized local Support/presence in India.
• Easy in configuration using DIP switches.
Courier management system project report.pdfKamal Acharya
It is now-a-days very important for the people to send or receive articles like imported furniture, electronic items, gifts, business goods and the like. People depend vastly on different transport systems which mostly use the manual way of receiving and delivering the articles. There is no way to track the articles till they are received and there is no way to let the customer know what happened in transit, once he booked some articles. In such a situation, we need a system which completely computerizes the cargo activities including time to time tracking of the articles sent. This need is fulfilled by Courier Management System software which is online software for the cargo management people that enables them to receive the goods from a source and send them to a required destination and track their status from time to time.
COLLEGE BUS MANAGEMENT SYSTEM PROJECT REPORT.pdfKamal Acharya
The College Bus Management system is completely developed by Visual Basic .NET Version. The application is connect with most secured database language MS SQL Server. The application is develop by using best combination of front-end and back-end languages. The application is totally design like flat user interface. This flat user interface is more attractive user interface in 2017. The application is gives more important to the system functionality. The application is to manage the student’s details, driver’s details, bus details, bus route details, bus fees details and more. The application has only one unit for admin. The admin can manage the entire application. The admin can login into the application by using username and password of the admin. The application is develop for big and small colleges. It is more user friendly for non-computer person. Even they can easily learn how to manage the application within hours. The application is more secure by the admin. The system will give an effective output for the VB.Net and SQL Server given as input to the system. The compiled java program given as input to the system, after scanning the program will generate different reports. The application generates the report for users. The admin can view and download the report of the data. The application deliver the excel format reports. Because, excel formatted reports is very easy to understand the income and expense of the college bus. This application is mainly develop for windows operating system users. In 2017, 73% of people enterprises are using windows operating system. So the application will easily install for all the windows operating system users. The application-developed size is very low. The application consumes very low space in disk. Therefore, the user can allocate very minimum local disk space for this application.
Cosmetic shop management system project report.pdfKamal Acharya
Buying new cosmetic products is difficult. It can even be scary for those who have sensitive skin and are prone to skin trouble. The information needed to alleviate this problem is on the back of each product, but it's thought to interpret those ingredient lists unless you have a background in chemistry.
Instead of buying and hoping for the best, we can use data science to help us predict which products may be good fits for us. It includes various function programs to do the above mentioned tasks.
Data file handling has been effectively used in the program.
The automated cosmetic shop management system should deal with the automation of general workflow and administration process of the shop. The main processes of the system focus on customer's request where the system is able to search the most appropriate products and deliver it to the customers. It should help the employees to quickly identify the list of cosmetic product that have reached the minimum quantity and also keep a track of expired date for each cosmetic product. It should help the employees to find the rack number in which the product is placed.It is also Faster and more efficient way.
Democratizing Fuzzing at Scale by Abhishek Aryaabh.arya
Presented at NUS: Fuzzing and Software Security Summer School 2024
This keynote talks about the democratization of fuzzing at scale, highlighting the collaboration between open source communities, academia, and industry to advance the field of fuzzing. It delves into the history of fuzzing, the development of scalable fuzzing platforms, and the empowerment of community-driven research. The talk will further discuss recent advancements leveraging AI/ML and offer insights into the future evolution of the fuzzing landscape.
Water scarcity is the lack of fresh water resources to meet the standard water demand. There are two type of water scarcity. One is physical. The other is economic water scarcity.
Welcome to WIPAC Monthly the magazine brought to you by the LinkedIn Group Water Industry Process Automation & Control.
In this month's edition, along with this month's industry news to celebrate the 13 years since the group was created we have articles including
A case study of the used of Advanced Process Control at the Wastewater Treatment works at Lleida in Spain
A look back on an article on smart wastewater networks in order to see how the industry has measured up in the interim around the adoption of Digital Transformation in the Water Industry.
Explore the innovative world of trenchless pipe repair with our comprehensive guide, "The Benefits and Techniques of Trenchless Pipe Repair." This document delves into the modern methods of repairing underground pipes without the need for extensive excavation, highlighting the numerous advantages and the latest techniques used in the industry.
Learn about the cost savings, reduced environmental impact, and minimal disruption associated with trenchless technology. Discover detailed explanations of popular techniques such as pipe bursting, cured-in-place pipe (CIPP) lining, and directional drilling. Understand how these methods can be applied to various types of infrastructure, from residential plumbing to large-scale municipal systems.
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