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Types of crystalline solids
 Ionic solids
 Covalent solids
 Molecular solids
 Metallic solids
Ionic solids
 Lattice points are occupied by positive and negative ions.
 Hard and brittle solids.
 High m.p due to very strong electrostatic forces of attraction.
 Poor conductors of electricity in solid state but good in
molten state.
 Packing of spheres depends upon:
a) presence of charged species present.
b) difference in the size of anions and cations.
 Two types:
 AB types.
 AB2 types.
Covalent solids
 Lattice points are occupied by neutral atoms.
 Atoms are held together by covalent bonds
 Hard solids.
 High m.p.
 Poor conductors of electricity.
 Two common examples: diamond & graphite.
Molecular solids
 Lattice points are occupied by neutral molecules.
 The molecules are held together by Vander Waal’s forces.
 Very soft solids.
 Low m.p.
 Poor conductors of electricity.
Metallic solids
 Lattice points are occupied by positive metal ions
surrounded by a sea of mobile e-.
 Soft to very hard.
 Metals have high tensile strength.
 Good conductors of electricity.
 Malleable and ductile.
 Bonding electrons in metals remain delocalized over
the entire crystal.
 High density.

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Classification of crystalline solids

  • 1. Types of crystalline solids  Ionic solids  Covalent solids  Molecular solids  Metallic solids
  • 2. Ionic solids  Lattice points are occupied by positive and negative ions.  Hard and brittle solids.  High m.p due to very strong electrostatic forces of attraction.  Poor conductors of electricity in solid state but good in molten state.  Packing of spheres depends upon: a) presence of charged species present. b) difference in the size of anions and cations.  Two types:  AB types.  AB2 types.
  • 3. Covalent solids  Lattice points are occupied by neutral atoms.  Atoms are held together by covalent bonds  Hard solids.  High m.p.  Poor conductors of electricity.  Two common examples: diamond & graphite.
  • 4. Molecular solids  Lattice points are occupied by neutral molecules.  The molecules are held together by Vander Waal’s forces.  Very soft solids.  Low m.p.  Poor conductors of electricity.
  • 5. Metallic solids  Lattice points are occupied by positive metal ions surrounded by a sea of mobile e-.  Soft to very hard.  Metals have high tensile strength.  Good conductors of electricity.  Malleable and ductile.  Bonding electrons in metals remain delocalized over the entire crystal.  High density.