The document discusses thin film measurement solutions for anodized aluminum layers, highlighting the anodizing process and its various types including chromic, sulfuric, and hard anodizing. It emphasizes the significance of process parameters in controlling layer thickness, which can be accurately measured using the mprobe 20 spectroscopic reflectometer. Measurement results showed varying thickness at different points on the aluminum surface, indicating the method's effectiveness in evaluating anodized coatings.

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THICKNESS MEASUREMENT OF ANODIZED ALUMINUM LAYER
Anodizing is an electrochemical conversion process that is widely used for many
applications. Unlike most protective coatings, anodizing permanently changes the outer
structure of the metal. The alumina layer formed during anodizing has hardness similar to
a diamond and high abrasive resistance.
Anodizing is, typically, ranges from 0.5 μm to 100 μm thickness. Three most
common aluminum anodizing include chromic (type I),sulfuric (type 2) and hard (type 3).
Type 1 (chromic acid electrolyte) yield the thinnest coating (0.5 – 3 μm) and has
least effect on the fatigue strength. It is most frequently used in military and aerospace
application
Type 2 (sulfuric anodizing) yields thickness up to 25 μm . This anodizing most
frequently used for decorative purposes.
Type 3 (hardcoating anodizing) uses higher concentration of sulfuric acid at lower
temperature resulting in the thick (~ 100 μm) coating with the tough outer skin. This type
of anodizing is frequently used for building materials, photocopiers paper rolls, etc.
Anodizing process parameters have a significant influence of the thickness the
formed layer. Through various process controls and thickness measurement Anodizers
are able to control and correct the anodized coating applications. This is especially
important for the thin (Type 1) anodizing.
Clear anodized layer thickness can be easily measured with MProbe 20
spectroscopic reflectometer. The non-destructive optical method allows quick (< 1s)
measurement on different surfaces.
Fig. 1 Anodized Aluminum part (Type 1 anodizing)

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Fig. 2. Reflectance spectra measured at 4 different points, wavelength range:
450-1000nm. The oscillations (interference) in the spectra indicates the
presence of the layer
Fig. 3. The part of the spectrum (510-800nm) that contains most useful
information and was used for the measurement.

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Fig. 4 Results of the measurement. Peak position indicates the thickness of the
Anodized layer. The value of the thickness is displayed in the table
Point Thickness, µm
1 (center) 5.314
2 5.093
3 5.093
4 5.093
Table 1. Results of the measurement in 4 points across the surface