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International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 07 Issue: 02 | Feb 2020 www.irjet.net p-ISSN: 2395-0072
© 2020, IRJET | Impact Factor value: 7.34 | ISO 9001:2008 Certified Journal | Page 2022
A REVIEW ON FEASIBILITY OF GEOPOLYMER SEA SAND CONCRETE IN
INTERLOCKING CONCRETE PAVEMENT BLOCKS
Afrin fathima1, Dr.Smitha K K2
1PG student, Civil Engineering Department, Toc H Institute of Science and Technology, Kerala, India
2Associate Professor, Civil Engineering Department, Toc H Institute of Science and Technology, Kerala, India
---------------------------------------------------------------------***---------------------------------------------------------------------
Abstract - Interlocking Block Pavement (IBP) has been
extensively used in a number of countries as a problem-
solving technique for providing pavement in areas where
conventional types of construction are less durable due to
many operational and environmental constraints. Portland
cement concrete is a major material used in interlocking
pavement blocks. It is a composite material comprising
Portland cement, coarse aggregate, fine aggregate, and
water. But its increased use in construction is exhausting
natural resources used in its production and also cause
environmental effects, making it necessary to find
alternative materials. One potential method is to use sea
sand as fine aggregate to produce alkali activated fly
ash/GGBS concrete. Sea sand has various advantages, it is
more rounded or cubical similar to river sand, the grading is
generally good and consistent, contains no organic
contaminant or silt and can be mined at a low cost, also the
utilization of fly ash and GGBS as an alternative to Portland
cement in producing alkali-activated slag concrete (ASC)
contributes to environmental protection by reducing CO2
emissions. This study presents a critical review of existing
studies on the effects of using sea-sand and alkali activated
geopolymer concrete.
Key Words: Fly Ash, Ground Granulated Blast Furnace
Slag, Alkali Activated Concrete.
1. INTRODUCTION
River sand is an essential raw material in construction
industry for making concrete. Especially during monsoons
the sources of river sand are unpredictable due to the rise
in river water table. Also governments have imposed
norms on the mining and utilization of river sand for
construction purposes. The over collection of river sand
from river beds affects our ecological cycle directly or
indirectly and so instead of river sand, sea sand that is
present at high level in comparison with the river sand in
nature at sea shores. Only if the concrete has natural
aggregates, the strength and durability would be
enhanced. In the current scenario, most of the building
agencies and MNC companies adopt artificial sand in their
projects. Sea sand is less expensive and reduces the overall
construction cost, which also helps to protect river sand
from being destruction.
Construction has been most important human activity
since ancient time. Concrete is widely used and reliable
material for construction. Some of challenges in industry
are global warming and insufficiency of construction
material. One of the methods for replacing concrete
constituents is the use of geo-polymer which helps in
using very less quantity of cement in concrete.
1.1 Sea Sand in Concrete
Sea sand is a potential method is to use as fine aggregate
in concrete. It is less expensive and reduces the overall
construction cost, which also helps to protect river sand
from being destruction. The chloride ions present in sea
sand, make its application potentially threatening to the
durability of concrete structures made by using it.
Therefore, the salt content of the sea sand must be
eliminated before it is utilized to avoid the potential
hazards. Desalination can be done by the various methods
like, water immersion, natural Sunlight exposure, rinsing,
mechanical methods etc. , after preliminary treatments
chloride analysis are done for maximum chloride content
of sand deemed acceptable for concrete works.
1.2 Geopolymer Concrete
In 1978, Davidovits proposed that a binder could be
produced by a polymerisation process involving a reaction
between alkaline liquids and compounds containing
aluminium and silicon. The binders created were termed
"geopolymers". Unlike ordinary portland/pozzolanic
cements, geopolymers do not form calcium-silicate-
hydrates (CSHs) for matrix formation and strength, but
silica and alumina reacting with an alkaline solution
produce an aluminosilicate gel that binds the aggregates
and provides the strength of concrete. Source materials
and alkaline liquids are the two main constituents of
geopolymers, the strengths of which depend on the nature
of the materials and the types of liquids.
2. LITERATURE SURVEY
In recent years, many studies were conducted by various
researchers on environmental friendly concrete materials.
Geopolymer concrete is a construction materials that can
be used in the construction industry. The goal which is
expected from the paper is to study the effect of
geopolymer sea sand concrete in interlocking concrete
pavement blocks.
2.1 Studies on Interlocking Concrete Pavement Blocks
Jamshidi, et.al (2019) conducted comprehensive
researches on the State-of-the-art of interlocking concrete
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 07 Issue: 02 | Feb 2020 www.irjet.net p-ISSN: 2395-0072
© 2020, IRJET | Impact Factor value: 7.34 | ISO 9001:2008 Certified Journal | Page 2023
block pavement technology in Japan as a post-modern
pavement (PMP). They studied the relevant literature in
English and Japanese, including journals, conference
proceedings, technical reports, books, and theses, over a
span of 47 years (1971–2018), and found the structural
and functional performances of the ICBP in different
facilities. Also examines its waste material use, less noise
emission, air purifying characteristics, and heat island
reduction, the environmental performance of ICBP was in
harmony with sustainable practices. In addition,
pavements users, both able and differently abled, rated the
ICBP as a more appropriate pavement system owing to its
physical appearance, serviceability, aesthetic features,
lower heat island effect, rapid maintenance, and positive
psychologic effects after earthquake and tsunami events.
From all the studies they concluded that, the ICBP can be
recommended as a PMP for the design and development of
resilient transportation infrastructure assets in Japan.
Sadek, et.al (2017) evaluating the physico-mechanical and
durability-related properties of concrete paving blocks
containing cement kiln dust (CKD) used as a partial
replacement or as an addition to cement. Hexagonal-
shaped metallic moulds with approximately 34,000 mm2
area and 80 mm thickness was selected here. From the
study they concluded that, It is possible to use high
volumes of CKD in the production of environmental-
friendly interlocking paving blocks. The quality of paving
blocks depends on both of method of using CKD (i.e.,
addition or replacement of cement) and its percentage in
the mix. At the same CKD percentage, using CKD as an
addition is better than being used as a partial replacement
of cement. Paving blocks containing 20% CKD as an
addition to cement have comparable properties to the
control blocks without CKD. Up to 40% CKD can be used in
the production of paving blocks for heavy traffic
applications, while 60% CKD blocks are suitable for areas
subjected to medium traffic applications such as in city
streets. Also, it is recommended to use the control blocks
and 20% CKD blocks (as addition) in heavy traffic
applications, even after 11 months of exposure to 1% HCl.
2.2 Studies on Concrete Made With Sea Sand
Cheng, et.al (2018) investigate the durability performances
of coral sand concrete (CSC) produced by using porous
coral sand aggregate and supplementary cementitious
materials compared to river sand concrete (RSC). The
durability properties of CSC were evaluated in terms of
chloride penetration, water absorption, drying shrinkage,
accelerated carbonation, and sulphate drying-wetting
cycle. The results indicated that the CSC exhibited higher
drying shrinkage, capillary water absorption, carbonation
depths, and a slightly lower later compressive strength
compared with RSC. However, porous coral aggregate
provided a more rapid early age strength, better resistance
to chloride ion penetration, and sulphate drying wetting
cycle than the RSC due to its internal curing. Additionally,
the combinations of internal curing and pozzolanic
reaction contributed to the microstructure improvement of
CSC, which conformed good durability properties of CSC
containing SCMs. Moreover, the ecological evaluation
demonstrated that the CSC incorporation of SCMs resulted
in a significant reduction of CO2 emission.
Xiao, et.al (2017) provide a critical review of existing
studies on the effects of using sea-sand and/or seawater as
raw materials of concrete on the properties of the resulting
concrete, including its workability, short and long-term
strength as well as durability. Both sea-sand and seawater
are likely to accelerate the strength development of
concrete during early stages due to the rich chloride
content in sea-sand and seawater. Concrete made with sea-
sand and/ or seawater has a significantly higher 7-day
compressive strength, a comparable 28-day compressive
strength and a similar long-term compressive strength to
ordinary concrete. Also it is shown that the use of sea-sand
and seawater may have a significant effect on chloride
induced steel corrosion but has only a negligible effect on
the carbonation process of concrete. Strong evidence exists
that a combination of mineral admixtures for the concrete
and reinforcement with fiber reinforced polymer can
effectively solve the durability problem associated with the
abundance of chloride ions in sea-sand seawater concrete.
Erdogan, et.al (2016) studied the potential beneficial use of
untreated and treated marine dredged material (DM) in
ready-mix concrete (RMC) as a fine aggregate. For this
study DMs collected from four Turkish ports/harbours.
Here silica sand was replaced with untreated- and treated-
composites of marine at five ratios, 0%, 25%, 50%, 75%,
and 100%, respectively. For all the mixes Mechanical,
durability, leaching, mineralogical/micro-structural
properties are analysed. Test results shows that, concretes
having 50% untreated dredged materials and 100%
treated dredged materials met the minimum requirement
of control mix. Therefore Marine DM can be beneficially
used in RMC production after pre-treatment.
Sun, et.al (2014) analyse the micro structure of sea sand
concrete by the Accelerated Surface Area and Porosimetry
System (ASAPS) to detect the concrete micro-prorous
structure distribution, the Tabletop Scanning Electron
Micro-scope (TSEM) to analysis the sea sand concrete
internal microstructure, as well as the X-Ray
Diffractometer (XRD) and the Thermal
gravimetric/Differemtial Thermal Anylyzer (TG/DTA)to
observe the composition of concrete. The influence on
hydration processes of concrete caused by sea sand was
reseached from four aspects which are the influences of fly
ash on concrete, chlorine salts on sea sand concrete,
chlorine salt on fly ash added sea sand concrete and
desalination sea sand and not desalination sea sand
concrete micro structure eatures to evaluate the effect of
sea sand on regular sea sand concrete and fly ash added
sea sand concrete micro structure features and chemical
composition. Test results shows that, 20%fly ash added
concrete is rich in hydration products and the content of C-
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 07 Issue: 02 | Feb 2020 www.irjet.net p-ISSN: 2395-0072
© 2020, IRJET | Impact Factor value: 7.34 | ISO 9001:2008 Certified Journal | Page 2024
S-H gels coming from the secondary hydration are more
than the concrete without fly ash added. In XRD picture
both of Ca(OH)2 crystal’s diffraction peaks are not high and
the endothermic peaks of Ca crystal are similar in TG/DTA
picture.
2.3 Studies on Alkali Activated Slag Concrete
Thunuguntla, et.al, (2018) studies the mechanical and
durability performance of Alkali Activated Slag Concrete
(AASC) prepared using ground granulated blast furnace
slag as the sole binder material. The influence of sodium
hydroxide concentration (1 M and 8 M), binder content
(300 kg/m3 and 450 kg/m3) and alkaline solution/ binder
ratio (0.4 and 0.55) on the mechanical and durability
properties of alkali activated slag concrete (AASC) were
reported. From the study they concluded that, NaOH
concentration is found to be the most influential parameter
on mechanical and durability characteristics of AASC. The
capillary sorptivity of AASC is low, which indicates it offers
high resistance to water absorption, also offers high
resistance to nitrates and chlorides compared to sulfates.
The deterioration of AASC specimens immersed in sulfuric
acid started at corners and progresses inwards, few pop
outs were also observed on the surface of specimens. AASC
mixes with higher NaOH concentration exhibited better
resistance to acid attack as compared to mixes with lower
NaOH concentration, which may be attributed to high
alkalinity and strong porous structure of concrete.
Puertas, et.al, (2018) studied the behaviour of fresh and
hardened alkali-activated slag (AAS) and OPC concretes
and was compared and the effect of mixing time assessed.
Two mixing protocols was deployed to prepare both the
OPCC and AASC systems. Protocol 1 corresponds to AAS
concrete dosage previously determine in RILEM TC 247-
DTA. In protocol 2 a longer mixing time of all concrete
components was considered according to previous
rheological studies. From the study they concluded that,
the slump and rheological behaviour of OPCC and AASC
differed, particularly where AASC was activated with water
glass. It has been demonstrated that the nature of the
alkaline activator is the key determinant in AAS concrete
rheology. Longer mixing times had an adverse effect on
dynamic and static yield stress and prompted significant
and irreversible coagulation among cement particles
(decline in workability) in OPC and AAS N concretes. In
contrast, longer mixing times were favourable in AAS-WG
concrete, in which they would be required to break down
the microstructure to enhance rheological behaviour.
These results proved that for AAS-WG concrete
preparation is recommended to longer mixing time. That
would have effect on future standardization of these eco-
efficient building materials.
Mohebi, et.al (2015) studied the abrasion resistance of
Alkali-Activated Slag (AAS) concrete. Four affecting factors
including curing temperature, alkaline solution to slag
weight ratio, concentration of sodium hydroxide solution
and sodium hydroxide to sodium silicate weight ratio was
considered to achieve the maximum compressive strength
and abrasion resistance of AAS concrete using the Taguchi
design of experiment method. From all the results and
discussions they concluded that, the mixture with alkaline
solution to slag weight ratio of 0.45, curing temperature of
95oC, sodium hydroxide concentration of 6 M and sodium
hydroxide to sodium silicate weight ratio of 3 resulted in
the maximum compressive strength and also, the mixture
with alkaline solution to slag weight ratio of 0.4, sodium
hydroxide concentration of 6M, sodium hydroxide to
sodium silicate weight ratio of 3, which had been cured at
25oC, was found as optimal mixture for the maximum
abrasion resistance. Water curing regime improved the
surface condition and considerably increased the abrasion
resistance of AAS concrete. Comparison between alkali-
activated slag concrete and ordinary Portland concrete
efficiency showed that the CO2 footprint of alkali-activated
slag concrete was approximately 51% less than that of
comparable concrete containing 100% ordinary Portland
concrete binder and the eco-mechanical performance of
alkali-activated slag concrete was superior than that of
ordinary concrete.
2.4 Studies on Alkali Activated Slag Sea Sand Concrete
Yang, et.al (2019) studied the mechanical properties of
alkali-activated slag concrete (ASC) mixed by seawater and
sea sand. Four types of ASC are prepared by considering
the effects of seawater, sea sand and combination of the
two constituents, respectively. Based on the SEM (scanning
electron microscope) and XRD (X-ray diffraction) analysis,
the seawater and sea sand are found to have some effect on
the morphology and hydration products of the ASC. The
strengths of the four ASC are close to each other. The ASC
with seawater or sea sand has slightly higher drying
shrinkage but better resistance to chloride ion
permeability. Bond performance of FRP (fiber-reinforced
polymer) and steel bars to ASC is studied using pull-out
tests. The short-term bond strength, interfacial shear
rigidity and shear fracture energy of steel bars with ASC
are apparently higher than those of FRP bars with ASC. But
the ratios of the residual frictional stress to the bond
strength are larger for the FRP bars. The bond strength and
residual frictional stress in the ASC with sea water or sea
sand are slightly higher and the largest shear fracture
energy is observed in the ASC with the combination of sea
water and sea sand.
Nguyen, et.al (2018) studies the mechanical properties of
geopolymer concrete prepared with sea sand as the fine
aggregate, and the corrosion of steel bar embedded in the
concrete subjected to accelerated corrosion tests. From all
the results and discussions they concluded that, the
compressive strength of geopolymer concrete using sea
sand as fine aggregate reached its highest value at an
alkaline to fly ash ratio of 0.35–0.45. This range is similar to
that of normal geopolymer concrete. For sea sand
geopolymer concrete, the effect of aggregate to fly ash ratio
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 07 Issue: 02 | Feb 2020 www.irjet.net p-ISSN: 2395-0072
© 2020, IRJET | Impact Factor value: 7.34 | ISO 9001:2008 Certified Journal | Page 2025
is the same as aggregate to cement (A/C) in conventional
concrete. When this ratio is low, the geopolymer paste
tends to cover the aggregate, and fill the voids inside the
concrete specimens. As a result, the geopolymer concrete
has enhanced high compressive strength. There was a
regular increase in compressive strength, when the Si/Al
ratio changed from 1.16 to 1.52. And then, the compressive
strength slightly went up as the Si/Al increased from 1.52
to 1.67. Under accelerated corrosion conditions, the
potential of steel bar in the geopolymer concrete using sea
sand as fine aggregate was higher than in Portland cement
concrete, result shows that it takes more time for steel bar
in geopolymer concrete using sea sand to be attacked and
corroded, compared to the steel bar in normal concrete. In
conclusion, geopolymer concrete using sea sand as fine
aggregate shows good potential as an alternative material
to traditional Portland cement concrete.
3. CONCLUSIONS
To avoid scarcity of river sand, sea sand is used as a fine
aggregate in concrete batching. Researchers say that using
sea sand as a replacement for river sand would increase
the bonding between cement and sand because of lesser
amount of silt content present in the sea sand .Sea sand
and seawater develops its early strength faster than that of
ordinary concrete, but the former achieves a similar long-
term strength to the latter. Many researches shows that
use of mineral admixtures can improve the properties.
In the context of reducing CO2 emissions, the one prospect
currently practiced is replacing Portland cement with high
volumes of supplementary cementitious materials (SCMs).
Effective use of locally available SCMs like fly ash and
ground granulated blast furnace slag (GGBFS) in
producing concrete reduces the burden on the landfills
and environmental pollution. AASC has numerous
advantages over OPCC like low environmental impact,
high strength, and rapid gain in strength and better
durability characteristics. The type and nature of binding
material, quantity and nature of alkaline activator solution
and curing conditions strongly influence the mechanical
and durability properties of AASC. Sodium silicate and
sodium hydroxide based activators are suitable
considering the mechanical properties of GBFS and FA
geopolymer. GBFS is a glassy phase material, it is,
therefore, easier to activate than fly ash. Fly ash contains a
larger portion of crystalline phase and usually requires
temperature between 40 and 85 oC to accelerate the
reaction. The mixtures with alkaline solution to slag
weight ratio of 0.45, sodium hydroxide concentration of
6M and sodium hydroxide to sodium silicate weight ratio
of 3, which had been cured at 95 oC , was chosen as the
optimal mixture given the maximum compressive
strength.
AASC using sea sand as fine aggregate shows good
potential as an alternative material to traditional Portland
cement concrete. The compressive strength of geopolymer
concrete using sea sand as fine aggregate reached its
highest value at an alkaline to fly ash ratio of 0.35–0.45.
This range is similar to that of normal geopolymer
concrete. The ASC with seawater or sea sand has slightly
higher drying shrinkage but better resistance to chloride
ion permeability.
REFERENCES
[1] Cheng S, Shui Z, Sun T, Rui Y, Zhang G, “Durability and
microstructure of coral sand concrete incorporating
supplementary cementitious materials”, Construction
and Building Materials, vol.171, 2018, pp.44 – 53.
[2] Erdogan P.O, Basar H.M, Erden I, Tolun L, “Beneficial
use of marine dredged materials as a fine aggregate in
ready-mixed concrete: Turkey example”, Construction
and Building Materials, vol.124, 2016, pp.690 – 704.
[3] Jamshidi A, Kurumisawa K, White G, Nishizawa T,
Igarashi T, Nawa T, Mao J,”State-of-the-art of
interlocking concrete block pavement technology in
Japan as a post-modern pavement”, Construction and
Building Materials, vol.200, 2019, pp.713 – 755.
[4] Mohebi R, Behfarnia K, Shojaei M, “Abrasion
resistance of alkali-activated slag concrete designed
by Taguchi method”, Construction and Building
Materials, vol.98, 2015, pp.792 – 798.
[5] Nguyen K.T, Tuan A.L, Lee K,”Evaluation of the
mechanical properties of sea sand-based geopolymer
concrete and the corrosion of embedded steel bar”,
Construction and Building Materials, vol.169, 2018,
pp. 462 – 472.
[6] Puertas F, Fonteboa B.G, Taboada I.G, Alonso M.M,
“Alkali-activated slag concrete: Fresh and hardened
behavior”, Cement and Concrete Composites, vol.85,
2018, pp.22 – 31.
[7] Sadek D.M, Attar M, Ali A.M, “Physico-mechanical and
durability characteristics of concrete paving blocks
incorporating cement kiln dust”, Construction and
Building Materials, vol.157, 2017, pp.300 – 312.
[8] Sun W, Jiang Y, Liu J, “Analysing the micro structure of
sea sand concrete”, Applied Mechanics and Materials,
vol.586, 2014, pp.1076 - 1080.
[9] Thunuguntla C.S, Gunneswara Rao T.D, “Effect of mix
design parameters on mechanical and durability
properties of alkali activated slag concrete”,
Construction and Building Materials, vol.193, 2018,
pp.173 – 188.
[10] Xiao J, Qiang C, Nanni A, Zhang K, “Use of sea sand and
seawater in concrete construction: Current status and
future opportunities”, Construction and Building
Materials, vol.155, 2017, pp.1101 - 1111.
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 07 Issue: 02 | Feb 2020 www.irjet.net p-ISSN: 2395-0072
© 2020, IRJET | Impact Factor value: 7.34 | ISO 9001:2008 Certified Journal | Page 2026
[11] Yang S, Xu J, Zang C, Rui L, Yang Q, Sun S, “Mechanical
properties of alkali-activated slag concrete mixed by
seawater and sea sand”, Construction and Building
Materials, vol.196, 2019, pp.395 - 410.

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IRJET - A Review on Feasibility of Geopolymer Sea Sand Concrete in Interlocking Concrete Pavement Blocks

  • 1. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 07 Issue: 02 | Feb 2020 www.irjet.net p-ISSN: 2395-0072 © 2020, IRJET | Impact Factor value: 7.34 | ISO 9001:2008 Certified Journal | Page 2022 A REVIEW ON FEASIBILITY OF GEOPOLYMER SEA SAND CONCRETE IN INTERLOCKING CONCRETE PAVEMENT BLOCKS Afrin fathima1, Dr.Smitha K K2 1PG student, Civil Engineering Department, Toc H Institute of Science and Technology, Kerala, India 2Associate Professor, Civil Engineering Department, Toc H Institute of Science and Technology, Kerala, India ---------------------------------------------------------------------***--------------------------------------------------------------------- Abstract - Interlocking Block Pavement (IBP) has been extensively used in a number of countries as a problem- solving technique for providing pavement in areas where conventional types of construction are less durable due to many operational and environmental constraints. Portland cement concrete is a major material used in interlocking pavement blocks. It is a composite material comprising Portland cement, coarse aggregate, fine aggregate, and water. But its increased use in construction is exhausting natural resources used in its production and also cause environmental effects, making it necessary to find alternative materials. One potential method is to use sea sand as fine aggregate to produce alkali activated fly ash/GGBS concrete. Sea sand has various advantages, it is more rounded or cubical similar to river sand, the grading is generally good and consistent, contains no organic contaminant or silt and can be mined at a low cost, also the utilization of fly ash and GGBS as an alternative to Portland cement in producing alkali-activated slag concrete (ASC) contributes to environmental protection by reducing CO2 emissions. This study presents a critical review of existing studies on the effects of using sea-sand and alkali activated geopolymer concrete. Key Words: Fly Ash, Ground Granulated Blast Furnace Slag, Alkali Activated Concrete. 1. INTRODUCTION River sand is an essential raw material in construction industry for making concrete. Especially during monsoons the sources of river sand are unpredictable due to the rise in river water table. Also governments have imposed norms on the mining and utilization of river sand for construction purposes. The over collection of river sand from river beds affects our ecological cycle directly or indirectly and so instead of river sand, sea sand that is present at high level in comparison with the river sand in nature at sea shores. Only if the concrete has natural aggregates, the strength and durability would be enhanced. In the current scenario, most of the building agencies and MNC companies adopt artificial sand in their projects. Sea sand is less expensive and reduces the overall construction cost, which also helps to protect river sand from being destruction. Construction has been most important human activity since ancient time. Concrete is widely used and reliable material for construction. Some of challenges in industry are global warming and insufficiency of construction material. One of the methods for replacing concrete constituents is the use of geo-polymer which helps in using very less quantity of cement in concrete. 1.1 Sea Sand in Concrete Sea sand is a potential method is to use as fine aggregate in concrete. It is less expensive and reduces the overall construction cost, which also helps to protect river sand from being destruction. The chloride ions present in sea sand, make its application potentially threatening to the durability of concrete structures made by using it. Therefore, the salt content of the sea sand must be eliminated before it is utilized to avoid the potential hazards. Desalination can be done by the various methods like, water immersion, natural Sunlight exposure, rinsing, mechanical methods etc. , after preliminary treatments chloride analysis are done for maximum chloride content of sand deemed acceptable for concrete works. 1.2 Geopolymer Concrete In 1978, Davidovits proposed that a binder could be produced by a polymerisation process involving a reaction between alkaline liquids and compounds containing aluminium and silicon. The binders created were termed "geopolymers". Unlike ordinary portland/pozzolanic cements, geopolymers do not form calcium-silicate- hydrates (CSHs) for matrix formation and strength, but silica and alumina reacting with an alkaline solution produce an aluminosilicate gel that binds the aggregates and provides the strength of concrete. Source materials and alkaline liquids are the two main constituents of geopolymers, the strengths of which depend on the nature of the materials and the types of liquids. 2. LITERATURE SURVEY In recent years, many studies were conducted by various researchers on environmental friendly concrete materials. Geopolymer concrete is a construction materials that can be used in the construction industry. The goal which is expected from the paper is to study the effect of geopolymer sea sand concrete in interlocking concrete pavement blocks. 2.1 Studies on Interlocking Concrete Pavement Blocks Jamshidi, et.al (2019) conducted comprehensive researches on the State-of-the-art of interlocking concrete
  • 2. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 07 Issue: 02 | Feb 2020 www.irjet.net p-ISSN: 2395-0072 © 2020, IRJET | Impact Factor value: 7.34 | ISO 9001:2008 Certified Journal | Page 2023 block pavement technology in Japan as a post-modern pavement (PMP). They studied the relevant literature in English and Japanese, including journals, conference proceedings, technical reports, books, and theses, over a span of 47 years (1971–2018), and found the structural and functional performances of the ICBP in different facilities. Also examines its waste material use, less noise emission, air purifying characteristics, and heat island reduction, the environmental performance of ICBP was in harmony with sustainable practices. In addition, pavements users, both able and differently abled, rated the ICBP as a more appropriate pavement system owing to its physical appearance, serviceability, aesthetic features, lower heat island effect, rapid maintenance, and positive psychologic effects after earthquake and tsunami events. From all the studies they concluded that, the ICBP can be recommended as a PMP for the design and development of resilient transportation infrastructure assets in Japan. Sadek, et.al (2017) evaluating the physico-mechanical and durability-related properties of concrete paving blocks containing cement kiln dust (CKD) used as a partial replacement or as an addition to cement. Hexagonal- shaped metallic moulds with approximately 34,000 mm2 area and 80 mm thickness was selected here. From the study they concluded that, It is possible to use high volumes of CKD in the production of environmental- friendly interlocking paving blocks. The quality of paving blocks depends on both of method of using CKD (i.e., addition or replacement of cement) and its percentage in the mix. At the same CKD percentage, using CKD as an addition is better than being used as a partial replacement of cement. Paving blocks containing 20% CKD as an addition to cement have comparable properties to the control blocks without CKD. Up to 40% CKD can be used in the production of paving blocks for heavy traffic applications, while 60% CKD blocks are suitable for areas subjected to medium traffic applications such as in city streets. Also, it is recommended to use the control blocks and 20% CKD blocks (as addition) in heavy traffic applications, even after 11 months of exposure to 1% HCl. 2.2 Studies on Concrete Made With Sea Sand Cheng, et.al (2018) investigate the durability performances of coral sand concrete (CSC) produced by using porous coral sand aggregate and supplementary cementitious materials compared to river sand concrete (RSC). The durability properties of CSC were evaluated in terms of chloride penetration, water absorption, drying shrinkage, accelerated carbonation, and sulphate drying-wetting cycle. The results indicated that the CSC exhibited higher drying shrinkage, capillary water absorption, carbonation depths, and a slightly lower later compressive strength compared with RSC. However, porous coral aggregate provided a more rapid early age strength, better resistance to chloride ion penetration, and sulphate drying wetting cycle than the RSC due to its internal curing. Additionally, the combinations of internal curing and pozzolanic reaction contributed to the microstructure improvement of CSC, which conformed good durability properties of CSC containing SCMs. Moreover, the ecological evaluation demonstrated that the CSC incorporation of SCMs resulted in a significant reduction of CO2 emission. Xiao, et.al (2017) provide a critical review of existing studies on the effects of using sea-sand and/or seawater as raw materials of concrete on the properties of the resulting concrete, including its workability, short and long-term strength as well as durability. Both sea-sand and seawater are likely to accelerate the strength development of concrete during early stages due to the rich chloride content in sea-sand and seawater. Concrete made with sea- sand and/ or seawater has a significantly higher 7-day compressive strength, a comparable 28-day compressive strength and a similar long-term compressive strength to ordinary concrete. Also it is shown that the use of sea-sand and seawater may have a significant effect on chloride induced steel corrosion but has only a negligible effect on the carbonation process of concrete. Strong evidence exists that a combination of mineral admixtures for the concrete and reinforcement with fiber reinforced polymer can effectively solve the durability problem associated with the abundance of chloride ions in sea-sand seawater concrete. Erdogan, et.al (2016) studied the potential beneficial use of untreated and treated marine dredged material (DM) in ready-mix concrete (RMC) as a fine aggregate. For this study DMs collected from four Turkish ports/harbours. Here silica sand was replaced with untreated- and treated- composites of marine at five ratios, 0%, 25%, 50%, 75%, and 100%, respectively. For all the mixes Mechanical, durability, leaching, mineralogical/micro-structural properties are analysed. Test results shows that, concretes having 50% untreated dredged materials and 100% treated dredged materials met the minimum requirement of control mix. Therefore Marine DM can be beneficially used in RMC production after pre-treatment. Sun, et.al (2014) analyse the micro structure of sea sand concrete by the Accelerated Surface Area and Porosimetry System (ASAPS) to detect the concrete micro-prorous structure distribution, the Tabletop Scanning Electron Micro-scope (TSEM) to analysis the sea sand concrete internal microstructure, as well as the X-Ray Diffractometer (XRD) and the Thermal gravimetric/Differemtial Thermal Anylyzer (TG/DTA)to observe the composition of concrete. The influence on hydration processes of concrete caused by sea sand was reseached from four aspects which are the influences of fly ash on concrete, chlorine salts on sea sand concrete, chlorine salt on fly ash added sea sand concrete and desalination sea sand and not desalination sea sand concrete micro structure eatures to evaluate the effect of sea sand on regular sea sand concrete and fly ash added sea sand concrete micro structure features and chemical composition. Test results shows that, 20%fly ash added concrete is rich in hydration products and the content of C-
  • 3. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 07 Issue: 02 | Feb 2020 www.irjet.net p-ISSN: 2395-0072 © 2020, IRJET | Impact Factor value: 7.34 | ISO 9001:2008 Certified Journal | Page 2024 S-H gels coming from the secondary hydration are more than the concrete without fly ash added. In XRD picture both of Ca(OH)2 crystal’s diffraction peaks are not high and the endothermic peaks of Ca crystal are similar in TG/DTA picture. 2.3 Studies on Alkali Activated Slag Concrete Thunuguntla, et.al, (2018) studies the mechanical and durability performance of Alkali Activated Slag Concrete (AASC) prepared using ground granulated blast furnace slag as the sole binder material. The influence of sodium hydroxide concentration (1 M and 8 M), binder content (300 kg/m3 and 450 kg/m3) and alkaline solution/ binder ratio (0.4 and 0.55) on the mechanical and durability properties of alkali activated slag concrete (AASC) were reported. From the study they concluded that, NaOH concentration is found to be the most influential parameter on mechanical and durability characteristics of AASC. The capillary sorptivity of AASC is low, which indicates it offers high resistance to water absorption, also offers high resistance to nitrates and chlorides compared to sulfates. The deterioration of AASC specimens immersed in sulfuric acid started at corners and progresses inwards, few pop outs were also observed on the surface of specimens. AASC mixes with higher NaOH concentration exhibited better resistance to acid attack as compared to mixes with lower NaOH concentration, which may be attributed to high alkalinity and strong porous structure of concrete. Puertas, et.al, (2018) studied the behaviour of fresh and hardened alkali-activated slag (AAS) and OPC concretes and was compared and the effect of mixing time assessed. Two mixing protocols was deployed to prepare both the OPCC and AASC systems. Protocol 1 corresponds to AAS concrete dosage previously determine in RILEM TC 247- DTA. In protocol 2 a longer mixing time of all concrete components was considered according to previous rheological studies. From the study they concluded that, the slump and rheological behaviour of OPCC and AASC differed, particularly where AASC was activated with water glass. It has been demonstrated that the nature of the alkaline activator is the key determinant in AAS concrete rheology. Longer mixing times had an adverse effect on dynamic and static yield stress and prompted significant and irreversible coagulation among cement particles (decline in workability) in OPC and AAS N concretes. In contrast, longer mixing times were favourable in AAS-WG concrete, in which they would be required to break down the microstructure to enhance rheological behaviour. These results proved that for AAS-WG concrete preparation is recommended to longer mixing time. That would have effect on future standardization of these eco- efficient building materials. Mohebi, et.al (2015) studied the abrasion resistance of Alkali-Activated Slag (AAS) concrete. Four affecting factors including curing temperature, alkaline solution to slag weight ratio, concentration of sodium hydroxide solution and sodium hydroxide to sodium silicate weight ratio was considered to achieve the maximum compressive strength and abrasion resistance of AAS concrete using the Taguchi design of experiment method. From all the results and discussions they concluded that, the mixture with alkaline solution to slag weight ratio of 0.45, curing temperature of 95oC, sodium hydroxide concentration of 6 M and sodium hydroxide to sodium silicate weight ratio of 3 resulted in the maximum compressive strength and also, the mixture with alkaline solution to slag weight ratio of 0.4, sodium hydroxide concentration of 6M, sodium hydroxide to sodium silicate weight ratio of 3, which had been cured at 25oC, was found as optimal mixture for the maximum abrasion resistance. Water curing regime improved the surface condition and considerably increased the abrasion resistance of AAS concrete. Comparison between alkali- activated slag concrete and ordinary Portland concrete efficiency showed that the CO2 footprint of alkali-activated slag concrete was approximately 51% less than that of comparable concrete containing 100% ordinary Portland concrete binder and the eco-mechanical performance of alkali-activated slag concrete was superior than that of ordinary concrete. 2.4 Studies on Alkali Activated Slag Sea Sand Concrete Yang, et.al (2019) studied the mechanical properties of alkali-activated slag concrete (ASC) mixed by seawater and sea sand. Four types of ASC are prepared by considering the effects of seawater, sea sand and combination of the two constituents, respectively. Based on the SEM (scanning electron microscope) and XRD (X-ray diffraction) analysis, the seawater and sea sand are found to have some effect on the morphology and hydration products of the ASC. The strengths of the four ASC are close to each other. The ASC with seawater or sea sand has slightly higher drying shrinkage but better resistance to chloride ion permeability. Bond performance of FRP (fiber-reinforced polymer) and steel bars to ASC is studied using pull-out tests. The short-term bond strength, interfacial shear rigidity and shear fracture energy of steel bars with ASC are apparently higher than those of FRP bars with ASC. But the ratios of the residual frictional stress to the bond strength are larger for the FRP bars. The bond strength and residual frictional stress in the ASC with sea water or sea sand are slightly higher and the largest shear fracture energy is observed in the ASC with the combination of sea water and sea sand. Nguyen, et.al (2018) studies the mechanical properties of geopolymer concrete prepared with sea sand as the fine aggregate, and the corrosion of steel bar embedded in the concrete subjected to accelerated corrosion tests. From all the results and discussions they concluded that, the compressive strength of geopolymer concrete using sea sand as fine aggregate reached its highest value at an alkaline to fly ash ratio of 0.35–0.45. This range is similar to that of normal geopolymer concrete. For sea sand geopolymer concrete, the effect of aggregate to fly ash ratio
  • 4. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 07 Issue: 02 | Feb 2020 www.irjet.net p-ISSN: 2395-0072 © 2020, IRJET | Impact Factor value: 7.34 | ISO 9001:2008 Certified Journal | Page 2025 is the same as aggregate to cement (A/C) in conventional concrete. When this ratio is low, the geopolymer paste tends to cover the aggregate, and fill the voids inside the concrete specimens. As a result, the geopolymer concrete has enhanced high compressive strength. There was a regular increase in compressive strength, when the Si/Al ratio changed from 1.16 to 1.52. And then, the compressive strength slightly went up as the Si/Al increased from 1.52 to 1.67. Under accelerated corrosion conditions, the potential of steel bar in the geopolymer concrete using sea sand as fine aggregate was higher than in Portland cement concrete, result shows that it takes more time for steel bar in geopolymer concrete using sea sand to be attacked and corroded, compared to the steel bar in normal concrete. In conclusion, geopolymer concrete using sea sand as fine aggregate shows good potential as an alternative material to traditional Portland cement concrete. 3. CONCLUSIONS To avoid scarcity of river sand, sea sand is used as a fine aggregate in concrete batching. Researchers say that using sea sand as a replacement for river sand would increase the bonding between cement and sand because of lesser amount of silt content present in the sea sand .Sea sand and seawater develops its early strength faster than that of ordinary concrete, but the former achieves a similar long- term strength to the latter. Many researches shows that use of mineral admixtures can improve the properties. In the context of reducing CO2 emissions, the one prospect currently practiced is replacing Portland cement with high volumes of supplementary cementitious materials (SCMs). Effective use of locally available SCMs like fly ash and ground granulated blast furnace slag (GGBFS) in producing concrete reduces the burden on the landfills and environmental pollution. AASC has numerous advantages over OPCC like low environmental impact, high strength, and rapid gain in strength and better durability characteristics. The type and nature of binding material, quantity and nature of alkaline activator solution and curing conditions strongly influence the mechanical and durability properties of AASC. Sodium silicate and sodium hydroxide based activators are suitable considering the mechanical properties of GBFS and FA geopolymer. GBFS is a glassy phase material, it is, therefore, easier to activate than fly ash. Fly ash contains a larger portion of crystalline phase and usually requires temperature between 40 and 85 oC to accelerate the reaction. The mixtures with alkaline solution to slag weight ratio of 0.45, sodium hydroxide concentration of 6M and sodium hydroxide to sodium silicate weight ratio of 3, which had been cured at 95 oC , was chosen as the optimal mixture given the maximum compressive strength. AASC using sea sand as fine aggregate shows good potential as an alternative material to traditional Portland cement concrete. The compressive strength of geopolymer concrete using sea sand as fine aggregate reached its highest value at an alkaline to fly ash ratio of 0.35–0.45. This range is similar to that of normal geopolymer concrete. The ASC with seawater or sea sand has slightly higher drying shrinkage but better resistance to chloride ion permeability. REFERENCES [1] Cheng S, Shui Z, Sun T, Rui Y, Zhang G, “Durability and microstructure of coral sand concrete incorporating supplementary cementitious materials”, Construction and Building Materials, vol.171, 2018, pp.44 – 53. [2] Erdogan P.O, Basar H.M, Erden I, Tolun L, “Beneficial use of marine dredged materials as a fine aggregate in ready-mixed concrete: Turkey example”, Construction and Building Materials, vol.124, 2016, pp.690 – 704. [3] Jamshidi A, Kurumisawa K, White G, Nishizawa T, Igarashi T, Nawa T, Mao J,”State-of-the-art of interlocking concrete block pavement technology in Japan as a post-modern pavement”, Construction and Building Materials, vol.200, 2019, pp.713 – 755. [4] Mohebi R, Behfarnia K, Shojaei M, “Abrasion resistance of alkali-activated slag concrete designed by Taguchi method”, Construction and Building Materials, vol.98, 2015, pp.792 – 798. [5] Nguyen K.T, Tuan A.L, Lee K,”Evaluation of the mechanical properties of sea sand-based geopolymer concrete and the corrosion of embedded steel bar”, Construction and Building Materials, vol.169, 2018, pp. 462 – 472. [6] Puertas F, Fonteboa B.G, Taboada I.G, Alonso M.M, “Alkali-activated slag concrete: Fresh and hardened behavior”, Cement and Concrete Composites, vol.85, 2018, pp.22 – 31. [7] Sadek D.M, Attar M, Ali A.M, “Physico-mechanical and durability characteristics of concrete paving blocks incorporating cement kiln dust”, Construction and Building Materials, vol.157, 2017, pp.300 – 312. [8] Sun W, Jiang Y, Liu J, “Analysing the micro structure of sea sand concrete”, Applied Mechanics and Materials, vol.586, 2014, pp.1076 - 1080. [9] Thunuguntla C.S, Gunneswara Rao T.D, “Effect of mix design parameters on mechanical and durability properties of alkali activated slag concrete”, Construction and Building Materials, vol.193, 2018, pp.173 – 188. [10] Xiao J, Qiang C, Nanni A, Zhang K, “Use of sea sand and seawater in concrete construction: Current status and future opportunities”, Construction and Building Materials, vol.155, 2017, pp.1101 - 1111.
  • 5. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 07 Issue: 02 | Feb 2020 www.irjet.net p-ISSN: 2395-0072 © 2020, IRJET | Impact Factor value: 7.34 | ISO 9001:2008 Certified Journal | Page 2026 [11] Yang S, Xu J, Zang C, Rui L, Yang Q, Sun S, “Mechanical properties of alkali-activated slag concrete mixed by seawater and sea sand”, Construction and Building Materials, vol.196, 2019, pp.395 - 410.