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International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 04 Issue: 11 | Nov -2017 www.irjet.net p-ISSN: 2395-0072
© 2017, IRJET | Impact Factor value: 6.171 | ISO 9001:2008 Certified Journal | Page 958
Durability Characteristics of Fiber Reinforced Geopolymer Concrete
Incorporated with Fly-ash and GGBS
D. Naveen Kumar 1 , DR. Kolli Ramujee2
1M.Tech. student Structural Engg, VNR Vignana Jyothi Institute of Engineering and Technology
2
Professor Civil Engineering Department, VNR Vignana Jyothi Institute of Engineering and Technology, Hyderabad,
Telangana-500090, India.
--------------------------------------------------------------------------------***----------------------------------------------------------------------------
Abstract: The growth of geopolymer concrete has increased its demand from past years. The importance of geopolymer concrete
has been boosted up in present trends due to its exhibition of excellent Strength and Durability Properties while compared to
ordinary Portland cement based concrete the geopolymer concrete can be easily taken into consideration by replacement of
cement concrete. As, CO2 the major harmful exponent ejected during cement production which result in deterioration of
environment and effects the global warming in order to reduce this, CO2 content in geopolymer concrete alternate binders like
low calcium based fly ash and GGBS are used which are less hazardous compared to ordinary Portland cement. This experimental
work deals with the tests like sulphate resistances, chloride resistance, water Absorption, Abrasion resistance tests for specimens
have been carried out to determine the durability characteristics as extension of strength properties developed for fiber reinforced
geopolymer concrete at a Standard grade of (G40) by incorporating polypropylene and basalt fibers the dosage of fibers were
varied in volume fractions at 0%, 0.1%, 0.2%, 0.3%, 0.4%,. Basalt fibers were kept constant as 0.05% for all mixes conducted.
Active alkaline liquids like sodium hydroxide (NaOH) of 12 molarity concentration, sodium silicate (Na2SiO3) gel, and naphthalene
based super plasticizer SP 430 were used.
Key words: geopolymer concrete, fly-ash, GGBS, polypropylene fiber, basalt fiber, sodium silicate, sodium hydroxide,
SP430, Compressive strength, Chloride resistance, Sulphate resistance, Water absorption, Abrasion resistance.
I. INTRODUCTION
Concrete usage around the globe is secondary to water. The durability characteristics of concrete are normally one of the
prime issues within in the concrete industry. This phenomenon is even more important for geopolymer concrete. Even then it
is still considered as one of the tough problems in concrete community due to their large scale production and
commercialization. The development of low calcium fly-ash based geopolymer concretes offers promising criterion for bring a
drastic change in producing concrete. However, considering Geopolymer binders as an alternative to ordinary Portland
cement, varies strength related matters of new material should be evaluated for comparative analysis.[5][7][9] The binary
blended geopolymer concrete, concrete made up of GGBS fly ash, fine river sand, Standard sized coarse aggregate, and alkaline
activators like sodium silicate & sodium hydroxide, runs a significant role in its environmental control of green house effect.
The minimising of carbon dioxide from cement producing industries can contribute the deterioration of ecosystem and
prevailing environment. Concrete exposed to environment they are considered as they were subjected to several types of
aggressive materials mechanical agents, such as admixtures water reducers etc, and deterioration due effect of chemical
solutions they attacks due to presence of chlorides and sulphates, with respect to changes in temperature. The damage of
concrete structures happens due to the aggressive agents, such as alkaline activators, In case of fibre reinforced concrete.[9]
Additionally, the durability properties of fiber reinforced geopolymer concrete are independent of its intrinsic qualities it
varies according to the type of exposure in the different environmental conditions and the strategy of immersion. when fiber
reinforced geopolymer Concrete reacts with various chemical solutions consisting sulphates, chlorides, nitrates etc and zinc
magnesium ions impacts the mechanisms like crystallization of salts and precipitation of insoluble particles due to attack of
chemical solutions.[1] Permeability factor is the important phenomenon for the determination of long-term durability
characteristics of fibre reinforced concrete in prevailing environment. The denser the geopolymer concrete will be it becomes
difficult for the deterioration. In the current trends the manufacturing of geopolymer concrete, is done by mixing waste
product exhibited by thermal power plants like fly ash and Ground granulated blast furnace slag which can be completely used
as replacement of ordinary Portland cement. In the Current experimental investigations for durability has been carried out on
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 04 Issue: 11 | Nov -2017 www.irjet.net p-ISSN: 2395-0072
© 2017, IRJET | Impact Factor value: 6.171 | ISO 9001:2008 Certified Journal | Page 959
double fiber incorporated geopolymer concrete are mainly given attention on geopolymer technology to make use of bi
product based geopolymer concrete by determining its physical and chemical properties. [3][5]Typically there are no specific
standard Codal provisions or rules available for judging the durability properties of geopolymer concrete. This paper gives a
brief explanation by investigating the durability properties of binary blended fiber reinforced geopolymer concrete, The
compressive strength, chloride sulphate resistance, abrasion resistance, water absorption tests were performed and
investigated when exposed to natural and standard environmental conditions.
II. LITERATURE REVIEW
S. S. Patil and A. A. Patil had investigated and reported the Durability characteristics of fly ash based geopolymer concrete
incorporating of silica fume at standard grade of (G40). Geopolymer is a green cementations material which possesses
excellent mechanical characteristics; low amount of heat is liberated and emits less carbon dioxide which is a toxic
environmental pollutant. In this current paper, the study on durability properties of fly ash based geopolymer concrete on
addition of silica fume have been investigated by placing the cubes in two percent of sulphuric acid and five percent of sodium
chloride liquids. The resistance of fly-ash and silica fume based geopolymer specimens to chemical attack was thoroughly
evaluated the modifications in the weights and percentage loss in compressive strength at different durations of time. A
control mix was also casted for M40 grade with normal OPC concrete for comparison. Percent losses in compressive strengths
in the case of control (M40) and GPC in 2% sulphuric acid at 90 days Were found 35 and 9%. Percent loss in compressive
strength for the control mix and GPC in 5% sodium chloride at 90 days were 16% and about 0%.Hence the resistance of fly-ash
based geopolymer concrete incorporating silica fume in sulphuric acid and chloride solution was significantly higher than that
of the OPC concrete mix.[1][3] Ganesan lavanya and Josephraj Began had performed studies on Durability phenomenon of
High Calcium Fly Ash Based Geopolymer Concrete how the geopolymer concrete behaves when it gets reacted with high
calcium contend fly ash along with alkaline liquids when subjected to two percentage of H2SO4 acidic solution and five
percent of MgSO4 at a duration of 90 days. The water absorption and Sorptivity was also measured. The investigations were
carried out for control mix of standard grade such as M20 M40 and M60.the ratio of alkaline liquid was assumed to be
2.50.The molar concentration of sodium hydroxide was chosen as 12.the cubes of standard dimensions 1503 was casted and
circular discs of 100mm x 200mm was casted and cured at ambient condition. The surface wearing, strength, density was
observed at durations of 7 days 14 days and 60 days. [7] The results were detected as the decrease in strength for GPC was
nearly 14% and OPC was 26% for MgSO4 solution. The decrease in compressive strength was about 19% for GPC and 28% for
OPC specimens. The GPC and OPC mixes indicated small changes in weight and strengths when the specimens were immersed
into sulphuric acid and magnesium sulphate solutions. The water absorption and sorptivity of GPC were negligible. Bapugouda
Patil Veranda Kumar M, Dr. H Narendra had done experimental investigation on Durability Studies On Sustainable
Geopolymer Concrete The main focussed in this paper was to retrieve the durability properties of high strength geopolymer
concrete and to comparative differences between normal strength concrete and high strength geopolymer concrete was
focused. The resistance to chloride attack sulphate attack and fire resistance was analysed. Their main aim of the study was to
develop sustainable GPC by using of low calcium based fly ash, GGBS, pond ash obtained from thermal power plants which are
treated to be waste product and M-sand. Compressive strength and durability properties of high strength GPC was compared
with that of Normal strength concrete. The results of compressive strength test of GPC cubes left for ambient curing, reported
that the development of M30 grade through which the compressive strength can be achieved without heat curing. In the
Current experimental program it was noticed that GGBS plays a majestic role in increasing the compressive strength of the fly
ash a based geopolymer concrete with incorporation of GGBS in GPC showed better results in both ambient curing and heat
curing conditions. The compressive strength was slightly higher in heat cured specimens than ambient cured specimens.[8]
The 16M molarity concentration use of sodium hydroxide pellets has resulted in giving optimal condition while compared all
molarities which can be suggested for future geopolymeric applications. Durability of geopolymer concrete is equally to that of
strength parameters of the geopolymer concrete for the structure to have great life. Durability test like acid resistance test
(HCl), chloride resistance test (NaCl), sulphate resistance test (MgSO4), fire resistance test and water absorption test were
conducted on both GPC and normal strength specimens. Gain of mass in GPC specimens immersed in sodium chloride and
Magnesium sulphate solution was noticed while compared to that normal strength concrete specimens.
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
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III. MATERIALS
3.1 Fly-ash:
The fly ash was obtained from navyug thermal plants which are classified as Low calcium, Class F (American Society for
Testing and Materials 2001) dry fly ash which is grey in colour this fly ash contained a very low percentage of carbon as
indicated by the low Loss on Ignition (LOI) values.
3.2 Ground Granulated Blast Furnace Slag:
Ground-granulated blast-furnace slag (GGBS or GGBFS) is obtained by quenching molten iron slag (a by-product of iron
and steel-making) from a blast furnace in water or steam, to produce a glassy, granular product that is then dried and ground
into a fine powder. Ground granulated blast furnace slag is obtained from kakatiya power plant located in Warangal.
(a) (b)
Figure.1 (a) fly-ash & (b) GGBS
Table.2 Chemical Properties of fly-ash & GGBS.
Particulars Class F fly ash GGBS
% Silica(SiO2) 65.6 30.61
% Alumina(Al2O3) 28.0 16.24
% Iron Oxide(Fe2O3) 3.0 0.584
% Lime (CaO) 1.0 34.48
% Magnesia (MgO) 1.0 6.79
% Titanium Oxide (TiO2) 0.5 -
% Sulphur Trioxide (SO3) 0.2 1.85
Loss on Ignition 0.29 2.1
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Table.3 Physical Properties of Fly-ash & GGBS.
Property Fly-ash GGBS
Specific gravity 2.21 2.82
bulk density Kg/m3 540-860 100-1200
appearance grey Grayish white
Particle size 30 microns 25 microns
Fineness(m2/kg) 360 400
3.3 Alkaline Liquids:
A mixture of sodium silicate (Na2SiO3) solution and sodium hydroxide (NaOH) solution are chosen as the alkaline liquid. The
sodium hydroxide material used at a standard grade in the form of pellets form (5mm), with a specific gravity of 2.430, 96.5%
of purity. The sodium hydroxide (NaOH) solution was prepared by dissolving these pellets in water for 24 hours before usage.
Sodium Silicate was obtained from caelmil Industries, Shirag kinch pvt ltd Madhya Pradesh. The chemical composition of the
sodium silicate solution was Na2O=14.33%, SiO2=30.10%, and water 55.57% by mass.
(c) (d)
Figure.2 (b) sodium silicate & (c) Sodium Hydroxide pellets
Table.4 Properties of Sodium Silicate
Specific gravity 1.65
Molar mass 112.06 gram/mol
Na2O 12.80%
SiO2 28.46%
Water ( by mass) 58.70%
Weight ratio (SiO2 to Na2O) 2.5
Molarity ratio 0.94
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Table.5 Properties of Sodium Silicate
3.4 Fine aggregate:
Locally available sand is used. The specific gravity of 2.655 and fineness modulus of 3.682 are used as fine aggregate.
The water absorption is about 1%.
3.5 Coarse Aggregate:
The fine Crushed aggregate available from local sources has been used. The coarse aggregates with maximum size of
20mm having the specific gravity value of nearly 2.82.The water absorption of coarse aggregate was about 0.55 %.
Table.6 Properties of Coarse Aggregates & Fine Aggregates
(e) (f)
Figure.3 (e) fine aggregate & (f) coarse aggregate 20mm
Molar mass 40 gr/mol
Appearance White
Density 2.25 gr/cc
Melting point 315oC
Boiling point 13800C
Amount of heat liberated
when dissolved in water
268 cal/gr
Property Coarse Aggregate Fine Aggregate
Specific gravity 2.86 2.59
Water absorption 0.35% 0.9%
Fineness modulus 6.95 2.42
Bulk density Kg/m3 1660 1585
Source Crushed granite
stone
Sea Shore
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3.6 Fibers:
(a) Polypropylene fibers:
Polypropylene is derived from monomer C3H6 which is purely hydrocarbon. These fibers possess high crystalline
nature. Chemical inertness makes the fibers resistant to most chemicals. [6]The main use of polypropylene fibers is to arrest
crack width which can improve flexural behaviour of geopolymer concrete. In the present experimental investigation
polypropylene fibers of 12mm in length are used for all mixes performed in the experiment. The polypropylene fiber is widely
preferred because it gives an advantage of easy dispersion while concrete mix. In present experiment 12mm monofilament
polypropylene fibers are used.
(b) Basalt fibers:
The basalt fibers are originated from basalt mineral rock these are very fine in nature incorporated with minerals like
plagioclase, pyroxene, and olivine. Basalt fiber used in fiber reinforced composites and structural elements has high potential
to impart tensile strength of geopolymer concrete.[4][2] It can provide good mechanical properties and chemical resistance in
acid & alkali environment. Basalt fibers impart non-corrosive reinforcement High modulus of elasticity and excellent heat
resistance. Basalt fibers in geopolymer concrete helps in increasing tensile strength from 25-30%. In present experimental
work basalt fibers of 12mm are incorporated and were kept constant at 0.05%.
Table.7 Properties of Fibers
Property Polypropylene fibers Basalt fibers
Type Macro filament crimpled
Cut length 12mm 12mm
Diameter 0.0045 Fine(7-15 µm)
Tensile Strength 550-700 MPa 515-580 MPa
Density 0.91 gm/cm3 2.6 gm/cm3
color white brown
Elongation at failure 20% 3.1%
Modulus of
elasticity(GN/m2)
3.5-6.8 100-110
Electric conductivity low medium
(g) (h)
Figure.4 (g) polypropylene fibers & (h) Basalt Fibers
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4. Mix design for Polypropylene and Basalt fiber reinforced geopolymer concrete:
The common difference between Geopolymer concrete and ordinary Portland concrete is the binder. The Al and Si
oxides in low calcium fly ash with react the alkaline solution to form geopolymer paste that binds the coarse aggregate, fine
aggregate and other un-reacted material together to form geopolymer concrete paste in OPC the aggregate occupied 70-80%
of the total mass of concrete. So the assumed aggregate percentage was 77% .The ratio of binder i.e. fly-ash, GGBS to alkaline
solution ratios is assumed to 0.40. The ratio of sodium silicate to sodium hydroxide solution was taken as 2.5 for all the
mixtures because the sodium silicate is cheaper than the sodium hydroxide pellets based solution. The molarity concentration
of NaOH solution was taken as 12M for all consecutive mixes. The water reducer used was naphthalene based super plasticizer
Forsec SP 430(8). Extra water content was added according to demand for settling of geopolymer concrete paste.
5. Experimental Procedure
To prepare 12M molarity concentration of NaOH solution of NaOH pellets was mixed in the water & makes it up to one litre
solution. The NaOH solution should be prepared 24 hours prior to use, because after dissolving pellets of NaOH in water,
solution increases up to 700c to 800c in temperature. Hence for usage it has to be cooled at room temperature. The NaOH
solution prepared was dissolved together with Na2SiO3 solution to get required alkaline solution. The solid constituents of
geopolymer concrete like fly ash, GGBS , fine & course aggregates, were mixed for about four minutes in the pan
mixer.[1][6][7]. Then alkaline solution added to the entire mix thoroughly for three minutes to get homogeneous
geopolymeric concrete paste. For Polypropylene fibers reinforced geopolymer concrete mixes, fibers were added to dry mix in
three different proportions from 0-0.4% by volume and putting basalt fibers constant at 0.05% for all mixes fibers chosen are
of 12mm in length, the mix goes as six different mixes such as the
(0.1PPF+0.05BF),(0.2PPF+0.05BF),(0.3PPF+0.05BF),(0.4PPF+0.05BF), in volume fractions (density ) i.e (910 kg/m3 for
Polypropylene & 2650 kg/m3 Basalt fibers). In this experimental work, 150 X 150 X 150mm size cubes. After 24 hours of
casting all specimens were demoulded & then placed in an oven for Heat (oven) curing at standard temperature of 60 C for 12
hours duration. Then specimens were removed from oven & kept at room temperature. After 28 days, weight of specimens
was taken to determine for compressive strength. Cubes were immersed in 5% HCL solution, 5% MgSO4 solution and 5%
H2SO4 solution.
Table.8 Mix Design Data
Table.9 fiber Dosage
Contents Kg/m3
Fly Ash 197.64
GGBS 197.64
Coarse Aggregate 1201.8
Fine Aggregate 646.8
NaOH 45.06
Na2SiO3 112.65
SP (430) 7.889
Sno Mix id
Polypropylene
Fibers (Kg/m3)
Basalt Fibers
(Kg/m3)
1 M1 (0%) 0 0
2 M2 (0.1%) 0.91 1.325
3 M3 (0.2%) 1.82 1.325
4 M4 (0.3%) 2.73 1.325
5 M5 (0.4%) 3.64 1.325
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6. Results & Discussions
1. Compressive Strength:
Compressive strength is the major property of concrete. The specimens were tested on 2000kN As per IS: 10086-1982. The
geopolymer concrete mixes were formulated in such a way that the fibers were varied replaced partially with 0.1%, 0.2%,
0.3%, and 0.4%. By putting basalt fibers constant at 0.05 %.
Table.10 Compressive Strength Results:
Figure.5 Compressive Strength Variation
1.2. Abrasion Resistance (water method):-
Abrasion resistance refers to the ability of materials and structures to withstand the wearing activity. It is a strategy of erosion
or rubbing away the contact surface of concrete by means of friction. Abrasion resistance resists the wear caused due to
mechanical action. the resistant materials are useful for both at when materials are at motion and static condition. The Moto of
abrasion resistance of concrete is to determine the toughness of aggregate and strength of aggregate bonded together in the
concrete matrix. Abrasion resistance can be controlled by usage of surface hardeners, lubricants covering the material with
coating agents, sliding and impinged or resurfacing the concrete elements. Confined to ASTM code no. 1138. In the present
experimental work abrasion resistance is performed for optimal strength 55.84 N/mm2 .
The Abrasion loss can be calculated as follows:
Volume of the specimen at any time can be computed using
26.75
35.25 37.11
32.06
21.33
45.44
47.4
55.84
49.19
37.5
FRGPC (0%)FRGPC (0.5%)FRGPC (1%)FRGPC (1.5%)FRGPC (2%)
Compressive Strength (N/mm2)
7 days 28 days
Mix id 7 days 28 days
FRGPC (0%) 26.75 45.44
FRGPC (0.1%) 35.25 47.4
FRGPC (0.2%) 37.11 55.84
FRGPC (0.3%) 32.06 49.19
FRGPC (0.4%) 21.33 37.5
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V Vt = (Wair - Wwater)/ Gw
Where Wair is the mass of the specimen in air at the desired time in kg, Wwater is apparent mass of the specimen in water at
the desired time in kg, Gw is the unit weight of water, kg/m
3
The volume of concrete lost at the end of any time increment of
testing as follows:
VLt = Vi – Vt
Where VLt = Volume of material lost by abrasion at the end of the test increment in question, m
3
.
V = volume of specimen before testing, m
3
and
Vt = volume of the specimen at the end of the test increment in question, m
3
Figure.6 (i) GPC after wearing (j) FRGPC after wearing action
Table.11 Mix design for Abrasion Resistance:
Grade of concrete GPC FRGPC
Fly-Ash (Kg/m3) 197.64 197.64
GGBS 197.64 197.64
Fine Aggregate (Kg/m3) 646.8 646.8
Coarse Aggregate (Kg/m3) 1201.2 1201.2
Water (Kg/m3) 20 15
S.P (Kg/m3) 3.5 3.5
W/C Ratio 0.4 0.4
Polypropylene Fibers 0 0.20%
Basalt Fibers 0 0.05%
Table.12 Abrasion Results for plain GPC:
duration mass Air mass water Vt VLt Avg. depth of abrasion(mm)
0 15.98 11.862 4.118 - -
12 14.81 11.486 3.324 0.794 2.53
24 14.486 11.296 3.19 0.134 3.056
36 14.142 11.118 3.024 0.166 2.858
48 13.789 10.909 2.88 0.144 2.736
60 13.486 10.742 2.744 0.136 2.608
72 13 10.568 2.432 0.312 2.12
15.908
Total abrasion loss is 15.908 mm
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Table.12 Abrasion Results for fiber reinforced optimal mix:
duration mass Air mass water Vt VLt Avg. depth of abrasion(mm)
0 13.825 11.852 1.973 - -
12 13.428 11.645 1.783 0.19 1.593
24 13.176 11.566 1.61 0.173 1.437
36 12.942 11.498 1.444 0.166 1.278
48 12.623 11.335 1.288 0.156 1.132
60 12.482 11.332 1.15 0.138 1.012
72 12.202 11.168 1.034 0.116 0.918
7.37
Total abrasion loss for fibers incorporated mould is 7.37 mm
1.3. Sulphate Resistance Test (MgSO4)-
The sulphate resistance test was performed to study the performance of geopolymer concrete subjected to 5% of MgSO4
solution Sulphates may be present in constituents which develop the contact of geopolymer matrix and affect it.
Figure.7 Specimens in MgSO4 & NaCL
Table.13 shows the average weight gain in (%) for the cubes immersed in MgSO4
mix id 60DAYS 90 DAYS
M1 (0%) 1.11 1.25
M2 (0.2%) 1.32 1.38
M3 (0.3%) 1.37 1.42
1.4 Acid Resistance test (H2SO4):
Acid resistance property of geo polymer concrete mixes has been studied by exposing the concrete specimens in 5% of
sulphuric acid for 60 and 90 days. Various parameter evaluated are visual appearance, change in mass and change in
compressive strength after the exposure period of both type of concrete. pH value of the solution was checked at 20 days
interval and maintained throughout the test period.
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Table.14 shows weight loss of specimens when exposed to 5% of H2SO4
MIX ID Initial weight Final weight % loss 60 days % loss 90 days
M1 (0%) 8.78 8.64 1.59 6.30
M2(0.2%) 8.46 8.37 1.06 4.20
M3(0.3%) 8.42 8.35 0.83 7.44
1.5 Chloride Resistance Test-
Test specimens for Sodium chloride resistance and change in mass test were 150X150X150mm cubes of geopolymer
concrete each. 3 specimens for each test were prepared for chloride resistance test to take average result of the specimen.
Table.15 shows the average weight gain for the cubes immersed in NaCl for 60& 90 days
MIX ID
Initial
weight kgs
Final weight
kgs
% gain in 60
days
% gain in 90
days
M1 (0%) 8.59 8.82 2.68 0.46
M2(0.2%) 8.46 8.64 2.13 0.70
M3(0.3%) 8.42 8.54 1.43 0.24
1.6 Water Absorption test:-
Water absorption tests for the GPC & FRGPC cubes were carried out for water Absorption test. The cubes once sufficiently
dried were weighed to find their initial weights and then immersed completely in water for 24 hours. After the 24 hour
duration, the specimens are removed and its saturated surface dry weight was recorded as the final weight. Water absorption
of specimens is reported as the percentage increase in weight.
Water Absorption in % can be determined using the formula give below
Water absorption =
Table.16 shows the percentage % saturated water absorption after 60 & 90 days
MIX ID 60 days 90 days
M1 (0%) 5.62 6.15
M3(0.2%) 2.81 3.23
M5(0.3%) 3.45 4.15
Conclusions
After performing various tests on fiber reinforce geopolymer concrete the compressive strength resulted optimal strength at
1% of fiber inclusions so, the durability tests are carried out for two consecutive optimal strength obtained mixes i.e. is volume
fractions of 0.2 % and 0.3% of incorporation of Polypropylene fibers and 0.05% of basalt fibers. The fiber reinforced
composites has performed better results in Abrasion, resistance against sulphate, acid resistance, water absorption tests As
compared to control mix i.e. without fibers. Addition of fly-ash & GGBS has improved the performance of fiber reinforced
geopolymer concrete. The fiber reinforced geopolymer concrete has low demand for water as compared to control.
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[8] Kolli Ramujee et al(2014) “ Permeability and Abrasion resistance of geopolymer concrete” Indian Concrete Journal (ICJ),
vol 88,issue no 12.
[9] Shalika Sharma, Dr Hemant Sood Abrasion Resistance of Geopolymer Concrete at Varying Temperature. IOSR Journal of
Mechanical and Civil Engineering (IOSR-JMCE) e-ISSN: 2278-1684,p-ISSN: 2320-334X, Volume 13, Issue 1 Ver. I (Jan. - Feb.
2016), PP 22-25.
[10] P Abhilash1, C Sashidhar2 and I V Ramana Reddy3Evaluation of performance of Geopolymer Concrete in acid
environment. International Research Journal of Engineering and Technology (IRJET) Volume: 04 Issue: 07 | July -2017.
BIOGRAPHY:
D.Naveen Kumar
PG Student VNR VJIET
DR. K. Ramujee
PROFESSOR & DEAN civil Dept.VNR VJIET

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Durability Characteristics of Fiber Reinforced Geopolymer Concrete Incorporated with Fly-ash and GGBS (38 characters

  • 1. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 04 Issue: 11 | Nov -2017 www.irjet.net p-ISSN: 2395-0072 © 2017, IRJET | Impact Factor value: 6.171 | ISO 9001:2008 Certified Journal | Page 958 Durability Characteristics of Fiber Reinforced Geopolymer Concrete Incorporated with Fly-ash and GGBS D. Naveen Kumar 1 , DR. Kolli Ramujee2 1M.Tech. student Structural Engg, VNR Vignana Jyothi Institute of Engineering and Technology 2 Professor Civil Engineering Department, VNR Vignana Jyothi Institute of Engineering and Technology, Hyderabad, Telangana-500090, India. --------------------------------------------------------------------------------***---------------------------------------------------------------------------- Abstract: The growth of geopolymer concrete has increased its demand from past years. The importance of geopolymer concrete has been boosted up in present trends due to its exhibition of excellent Strength and Durability Properties while compared to ordinary Portland cement based concrete the geopolymer concrete can be easily taken into consideration by replacement of cement concrete. As, CO2 the major harmful exponent ejected during cement production which result in deterioration of environment and effects the global warming in order to reduce this, CO2 content in geopolymer concrete alternate binders like low calcium based fly ash and GGBS are used which are less hazardous compared to ordinary Portland cement. This experimental work deals with the tests like sulphate resistances, chloride resistance, water Absorption, Abrasion resistance tests for specimens have been carried out to determine the durability characteristics as extension of strength properties developed for fiber reinforced geopolymer concrete at a Standard grade of (G40) by incorporating polypropylene and basalt fibers the dosage of fibers were varied in volume fractions at 0%, 0.1%, 0.2%, 0.3%, 0.4%,. Basalt fibers were kept constant as 0.05% for all mixes conducted. Active alkaline liquids like sodium hydroxide (NaOH) of 12 molarity concentration, sodium silicate (Na2SiO3) gel, and naphthalene based super plasticizer SP 430 were used. Key words: geopolymer concrete, fly-ash, GGBS, polypropylene fiber, basalt fiber, sodium silicate, sodium hydroxide, SP430, Compressive strength, Chloride resistance, Sulphate resistance, Water absorption, Abrasion resistance. I. INTRODUCTION Concrete usage around the globe is secondary to water. The durability characteristics of concrete are normally one of the prime issues within in the concrete industry. This phenomenon is even more important for geopolymer concrete. Even then it is still considered as one of the tough problems in concrete community due to their large scale production and commercialization. The development of low calcium fly-ash based geopolymer concretes offers promising criterion for bring a drastic change in producing concrete. However, considering Geopolymer binders as an alternative to ordinary Portland cement, varies strength related matters of new material should be evaluated for comparative analysis.[5][7][9] The binary blended geopolymer concrete, concrete made up of GGBS fly ash, fine river sand, Standard sized coarse aggregate, and alkaline activators like sodium silicate & sodium hydroxide, runs a significant role in its environmental control of green house effect. The minimising of carbon dioxide from cement producing industries can contribute the deterioration of ecosystem and prevailing environment. Concrete exposed to environment they are considered as they were subjected to several types of aggressive materials mechanical agents, such as admixtures water reducers etc, and deterioration due effect of chemical solutions they attacks due to presence of chlorides and sulphates, with respect to changes in temperature. The damage of concrete structures happens due to the aggressive agents, such as alkaline activators, In case of fibre reinforced concrete.[9] Additionally, the durability properties of fiber reinforced geopolymer concrete are independent of its intrinsic qualities it varies according to the type of exposure in the different environmental conditions and the strategy of immersion. when fiber reinforced geopolymer Concrete reacts with various chemical solutions consisting sulphates, chlorides, nitrates etc and zinc magnesium ions impacts the mechanisms like crystallization of salts and precipitation of insoluble particles due to attack of chemical solutions.[1] Permeability factor is the important phenomenon for the determination of long-term durability characteristics of fibre reinforced concrete in prevailing environment. The denser the geopolymer concrete will be it becomes difficult for the deterioration. In the current trends the manufacturing of geopolymer concrete, is done by mixing waste product exhibited by thermal power plants like fly ash and Ground granulated blast furnace slag which can be completely used as replacement of ordinary Portland cement. In the Current experimental investigations for durability has been carried out on
  • 2. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 04 Issue: 11 | Nov -2017 www.irjet.net p-ISSN: 2395-0072 © 2017, IRJET | Impact Factor value: 6.171 | ISO 9001:2008 Certified Journal | Page 959 double fiber incorporated geopolymer concrete are mainly given attention on geopolymer technology to make use of bi product based geopolymer concrete by determining its physical and chemical properties. [3][5]Typically there are no specific standard Codal provisions or rules available for judging the durability properties of geopolymer concrete. This paper gives a brief explanation by investigating the durability properties of binary blended fiber reinforced geopolymer concrete, The compressive strength, chloride sulphate resistance, abrasion resistance, water absorption tests were performed and investigated when exposed to natural and standard environmental conditions. II. LITERATURE REVIEW S. S. Patil and A. A. Patil had investigated and reported the Durability characteristics of fly ash based geopolymer concrete incorporating of silica fume at standard grade of (G40). Geopolymer is a green cementations material which possesses excellent mechanical characteristics; low amount of heat is liberated and emits less carbon dioxide which is a toxic environmental pollutant. In this current paper, the study on durability properties of fly ash based geopolymer concrete on addition of silica fume have been investigated by placing the cubes in two percent of sulphuric acid and five percent of sodium chloride liquids. The resistance of fly-ash and silica fume based geopolymer specimens to chemical attack was thoroughly evaluated the modifications in the weights and percentage loss in compressive strength at different durations of time. A control mix was also casted for M40 grade with normal OPC concrete for comparison. Percent losses in compressive strengths in the case of control (M40) and GPC in 2% sulphuric acid at 90 days Were found 35 and 9%. Percent loss in compressive strength for the control mix and GPC in 5% sodium chloride at 90 days were 16% and about 0%.Hence the resistance of fly-ash based geopolymer concrete incorporating silica fume in sulphuric acid and chloride solution was significantly higher than that of the OPC concrete mix.[1][3] Ganesan lavanya and Josephraj Began had performed studies on Durability phenomenon of High Calcium Fly Ash Based Geopolymer Concrete how the geopolymer concrete behaves when it gets reacted with high calcium contend fly ash along with alkaline liquids when subjected to two percentage of H2SO4 acidic solution and five percent of MgSO4 at a duration of 90 days. The water absorption and Sorptivity was also measured. The investigations were carried out for control mix of standard grade such as M20 M40 and M60.the ratio of alkaline liquid was assumed to be 2.50.The molar concentration of sodium hydroxide was chosen as 12.the cubes of standard dimensions 1503 was casted and circular discs of 100mm x 200mm was casted and cured at ambient condition. The surface wearing, strength, density was observed at durations of 7 days 14 days and 60 days. [7] The results were detected as the decrease in strength for GPC was nearly 14% and OPC was 26% for MgSO4 solution. The decrease in compressive strength was about 19% for GPC and 28% for OPC specimens. The GPC and OPC mixes indicated small changes in weight and strengths when the specimens were immersed into sulphuric acid and magnesium sulphate solutions. The water absorption and sorptivity of GPC were negligible. Bapugouda Patil Veranda Kumar M, Dr. H Narendra had done experimental investigation on Durability Studies On Sustainable Geopolymer Concrete The main focussed in this paper was to retrieve the durability properties of high strength geopolymer concrete and to comparative differences between normal strength concrete and high strength geopolymer concrete was focused. The resistance to chloride attack sulphate attack and fire resistance was analysed. Their main aim of the study was to develop sustainable GPC by using of low calcium based fly ash, GGBS, pond ash obtained from thermal power plants which are treated to be waste product and M-sand. Compressive strength and durability properties of high strength GPC was compared with that of Normal strength concrete. The results of compressive strength test of GPC cubes left for ambient curing, reported that the development of M30 grade through which the compressive strength can be achieved without heat curing. In the Current experimental program it was noticed that GGBS plays a majestic role in increasing the compressive strength of the fly ash a based geopolymer concrete with incorporation of GGBS in GPC showed better results in both ambient curing and heat curing conditions. The compressive strength was slightly higher in heat cured specimens than ambient cured specimens.[8] The 16M molarity concentration use of sodium hydroxide pellets has resulted in giving optimal condition while compared all molarities which can be suggested for future geopolymeric applications. Durability of geopolymer concrete is equally to that of strength parameters of the geopolymer concrete for the structure to have great life. Durability test like acid resistance test (HCl), chloride resistance test (NaCl), sulphate resistance test (MgSO4), fire resistance test and water absorption test were conducted on both GPC and normal strength specimens. Gain of mass in GPC specimens immersed in sodium chloride and Magnesium sulphate solution was noticed while compared to that normal strength concrete specimens.
  • 3. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 04 Issue: 11 | Nov -2017 www.irjet.net p-ISSN: 2395-0072 © 2017, IRJET | Impact Factor value: 6.171 | ISO 9001:2008 Certified Journal | Page 960 III. MATERIALS 3.1 Fly-ash: The fly ash was obtained from navyug thermal plants which are classified as Low calcium, Class F (American Society for Testing and Materials 2001) dry fly ash which is grey in colour this fly ash contained a very low percentage of carbon as indicated by the low Loss on Ignition (LOI) values. 3.2 Ground Granulated Blast Furnace Slag: Ground-granulated blast-furnace slag (GGBS or GGBFS) is obtained by quenching molten iron slag (a by-product of iron and steel-making) from a blast furnace in water or steam, to produce a glassy, granular product that is then dried and ground into a fine powder. Ground granulated blast furnace slag is obtained from kakatiya power plant located in Warangal. (a) (b) Figure.1 (a) fly-ash & (b) GGBS Table.2 Chemical Properties of fly-ash & GGBS. Particulars Class F fly ash GGBS % Silica(SiO2) 65.6 30.61 % Alumina(Al2O3) 28.0 16.24 % Iron Oxide(Fe2O3) 3.0 0.584 % Lime (CaO) 1.0 34.48 % Magnesia (MgO) 1.0 6.79 % Titanium Oxide (TiO2) 0.5 - % Sulphur Trioxide (SO3) 0.2 1.85 Loss on Ignition 0.29 2.1
  • 4. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 04 Issue: 11 | Nov -2017 www.irjet.net p-ISSN: 2395-0072 © 2017, IRJET | Impact Factor value: 6.171 | ISO 9001:2008 Certified Journal | Page 961 Table.3 Physical Properties of Fly-ash & GGBS. Property Fly-ash GGBS Specific gravity 2.21 2.82 bulk density Kg/m3 540-860 100-1200 appearance grey Grayish white Particle size 30 microns 25 microns Fineness(m2/kg) 360 400 3.3 Alkaline Liquids: A mixture of sodium silicate (Na2SiO3) solution and sodium hydroxide (NaOH) solution are chosen as the alkaline liquid. The sodium hydroxide material used at a standard grade in the form of pellets form (5mm), with a specific gravity of 2.430, 96.5% of purity. The sodium hydroxide (NaOH) solution was prepared by dissolving these pellets in water for 24 hours before usage. Sodium Silicate was obtained from caelmil Industries, Shirag kinch pvt ltd Madhya Pradesh. The chemical composition of the sodium silicate solution was Na2O=14.33%, SiO2=30.10%, and water 55.57% by mass. (c) (d) Figure.2 (b) sodium silicate & (c) Sodium Hydroxide pellets Table.4 Properties of Sodium Silicate Specific gravity 1.65 Molar mass 112.06 gram/mol Na2O 12.80% SiO2 28.46% Water ( by mass) 58.70% Weight ratio (SiO2 to Na2O) 2.5 Molarity ratio 0.94
  • 5. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 04 Issue: 11 | Nov -2017 www.irjet.net p-ISSN: 2395-0072 © 2017, IRJET | Impact Factor value: 6.171 | ISO 9001:2008 Certified Journal | Page 962 Table.5 Properties of Sodium Silicate 3.4 Fine aggregate: Locally available sand is used. The specific gravity of 2.655 and fineness modulus of 3.682 are used as fine aggregate. The water absorption is about 1%. 3.5 Coarse Aggregate: The fine Crushed aggregate available from local sources has been used. The coarse aggregates with maximum size of 20mm having the specific gravity value of nearly 2.82.The water absorption of coarse aggregate was about 0.55 %. Table.6 Properties of Coarse Aggregates & Fine Aggregates (e) (f) Figure.3 (e) fine aggregate & (f) coarse aggregate 20mm Molar mass 40 gr/mol Appearance White Density 2.25 gr/cc Melting point 315oC Boiling point 13800C Amount of heat liberated when dissolved in water 268 cal/gr Property Coarse Aggregate Fine Aggregate Specific gravity 2.86 2.59 Water absorption 0.35% 0.9% Fineness modulus 6.95 2.42 Bulk density Kg/m3 1660 1585 Source Crushed granite stone Sea Shore
  • 6. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 04 Issue: 11 | Nov -2017 www.irjet.net p-ISSN: 2395-0072 © 2017, IRJET | Impact Factor value: 6.171 | ISO 9001:2008 Certified Journal | Page 963 3.6 Fibers: (a) Polypropylene fibers: Polypropylene is derived from monomer C3H6 which is purely hydrocarbon. These fibers possess high crystalline nature. Chemical inertness makes the fibers resistant to most chemicals. [6]The main use of polypropylene fibers is to arrest crack width which can improve flexural behaviour of geopolymer concrete. In the present experimental investigation polypropylene fibers of 12mm in length are used for all mixes performed in the experiment. The polypropylene fiber is widely preferred because it gives an advantage of easy dispersion while concrete mix. In present experiment 12mm monofilament polypropylene fibers are used. (b) Basalt fibers: The basalt fibers are originated from basalt mineral rock these are very fine in nature incorporated with minerals like plagioclase, pyroxene, and olivine. Basalt fiber used in fiber reinforced composites and structural elements has high potential to impart tensile strength of geopolymer concrete.[4][2] It can provide good mechanical properties and chemical resistance in acid & alkali environment. Basalt fibers impart non-corrosive reinforcement High modulus of elasticity and excellent heat resistance. Basalt fibers in geopolymer concrete helps in increasing tensile strength from 25-30%. In present experimental work basalt fibers of 12mm are incorporated and were kept constant at 0.05%. Table.7 Properties of Fibers Property Polypropylene fibers Basalt fibers Type Macro filament crimpled Cut length 12mm 12mm Diameter 0.0045 Fine(7-15 µm) Tensile Strength 550-700 MPa 515-580 MPa Density 0.91 gm/cm3 2.6 gm/cm3 color white brown Elongation at failure 20% 3.1% Modulus of elasticity(GN/m2) 3.5-6.8 100-110 Electric conductivity low medium (g) (h) Figure.4 (g) polypropylene fibers & (h) Basalt Fibers
  • 7. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 04 Issue: 11 | Nov -2017 www.irjet.net p-ISSN: 2395-0072 © 2017, IRJET | Impact Factor value: 6.171 | ISO 9001:2008 Certified Journal | Page 964 4. Mix design for Polypropylene and Basalt fiber reinforced geopolymer concrete: The common difference between Geopolymer concrete and ordinary Portland concrete is the binder. The Al and Si oxides in low calcium fly ash with react the alkaline solution to form geopolymer paste that binds the coarse aggregate, fine aggregate and other un-reacted material together to form geopolymer concrete paste in OPC the aggregate occupied 70-80% of the total mass of concrete. So the assumed aggregate percentage was 77% .The ratio of binder i.e. fly-ash, GGBS to alkaline solution ratios is assumed to 0.40. The ratio of sodium silicate to sodium hydroxide solution was taken as 2.5 for all the mixtures because the sodium silicate is cheaper than the sodium hydroxide pellets based solution. The molarity concentration of NaOH solution was taken as 12M for all consecutive mixes. The water reducer used was naphthalene based super plasticizer Forsec SP 430(8). Extra water content was added according to demand for settling of geopolymer concrete paste. 5. Experimental Procedure To prepare 12M molarity concentration of NaOH solution of NaOH pellets was mixed in the water & makes it up to one litre solution. The NaOH solution should be prepared 24 hours prior to use, because after dissolving pellets of NaOH in water, solution increases up to 700c to 800c in temperature. Hence for usage it has to be cooled at room temperature. The NaOH solution prepared was dissolved together with Na2SiO3 solution to get required alkaline solution. The solid constituents of geopolymer concrete like fly ash, GGBS , fine & course aggregates, were mixed for about four minutes in the pan mixer.[1][6][7]. Then alkaline solution added to the entire mix thoroughly for three minutes to get homogeneous geopolymeric concrete paste. For Polypropylene fibers reinforced geopolymer concrete mixes, fibers were added to dry mix in three different proportions from 0-0.4% by volume and putting basalt fibers constant at 0.05% for all mixes fibers chosen are of 12mm in length, the mix goes as six different mixes such as the (0.1PPF+0.05BF),(0.2PPF+0.05BF),(0.3PPF+0.05BF),(0.4PPF+0.05BF), in volume fractions (density ) i.e (910 kg/m3 for Polypropylene & 2650 kg/m3 Basalt fibers). In this experimental work, 150 X 150 X 150mm size cubes. After 24 hours of casting all specimens were demoulded & then placed in an oven for Heat (oven) curing at standard temperature of 60 C for 12 hours duration. Then specimens were removed from oven & kept at room temperature. After 28 days, weight of specimens was taken to determine for compressive strength. Cubes were immersed in 5% HCL solution, 5% MgSO4 solution and 5% H2SO4 solution. Table.8 Mix Design Data Table.9 fiber Dosage Contents Kg/m3 Fly Ash 197.64 GGBS 197.64 Coarse Aggregate 1201.8 Fine Aggregate 646.8 NaOH 45.06 Na2SiO3 112.65 SP (430) 7.889 Sno Mix id Polypropylene Fibers (Kg/m3) Basalt Fibers (Kg/m3) 1 M1 (0%) 0 0 2 M2 (0.1%) 0.91 1.325 3 M3 (0.2%) 1.82 1.325 4 M4 (0.3%) 2.73 1.325 5 M5 (0.4%) 3.64 1.325
  • 8. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 04 Issue: 11 | Nov -2017 www.irjet.net p-ISSN: 2395-0072 © 2017, IRJET | Impact Factor value: 6.171 | ISO 9001:2008 Certified Journal | Page 965 6. Results & Discussions 1. Compressive Strength: Compressive strength is the major property of concrete. The specimens were tested on 2000kN As per IS: 10086-1982. The geopolymer concrete mixes were formulated in such a way that the fibers were varied replaced partially with 0.1%, 0.2%, 0.3%, and 0.4%. By putting basalt fibers constant at 0.05 %. Table.10 Compressive Strength Results: Figure.5 Compressive Strength Variation 1.2. Abrasion Resistance (water method):- Abrasion resistance refers to the ability of materials and structures to withstand the wearing activity. It is a strategy of erosion or rubbing away the contact surface of concrete by means of friction. Abrasion resistance resists the wear caused due to mechanical action. the resistant materials are useful for both at when materials are at motion and static condition. The Moto of abrasion resistance of concrete is to determine the toughness of aggregate and strength of aggregate bonded together in the concrete matrix. Abrasion resistance can be controlled by usage of surface hardeners, lubricants covering the material with coating agents, sliding and impinged or resurfacing the concrete elements. Confined to ASTM code no. 1138. In the present experimental work abrasion resistance is performed for optimal strength 55.84 N/mm2 . The Abrasion loss can be calculated as follows: Volume of the specimen at any time can be computed using 26.75 35.25 37.11 32.06 21.33 45.44 47.4 55.84 49.19 37.5 FRGPC (0%)FRGPC (0.5%)FRGPC (1%)FRGPC (1.5%)FRGPC (2%) Compressive Strength (N/mm2) 7 days 28 days Mix id 7 days 28 days FRGPC (0%) 26.75 45.44 FRGPC (0.1%) 35.25 47.4 FRGPC (0.2%) 37.11 55.84 FRGPC (0.3%) 32.06 49.19 FRGPC (0.4%) 21.33 37.5
  • 9. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 04 Issue: 11 | Nov -2017 www.irjet.net p-ISSN: 2395-0072 © 2017, IRJET | Impact Factor value: 6.171 | ISO 9001:2008 Certified Journal | Page 966 V Vt = (Wair - Wwater)/ Gw Where Wair is the mass of the specimen in air at the desired time in kg, Wwater is apparent mass of the specimen in water at the desired time in kg, Gw is the unit weight of water, kg/m 3 The volume of concrete lost at the end of any time increment of testing as follows: VLt = Vi – Vt Where VLt = Volume of material lost by abrasion at the end of the test increment in question, m 3 . V = volume of specimen before testing, m 3 and Vt = volume of the specimen at the end of the test increment in question, m 3 Figure.6 (i) GPC after wearing (j) FRGPC after wearing action Table.11 Mix design for Abrasion Resistance: Grade of concrete GPC FRGPC Fly-Ash (Kg/m3) 197.64 197.64 GGBS 197.64 197.64 Fine Aggregate (Kg/m3) 646.8 646.8 Coarse Aggregate (Kg/m3) 1201.2 1201.2 Water (Kg/m3) 20 15 S.P (Kg/m3) 3.5 3.5 W/C Ratio 0.4 0.4 Polypropylene Fibers 0 0.20% Basalt Fibers 0 0.05% Table.12 Abrasion Results for plain GPC: duration mass Air mass water Vt VLt Avg. depth of abrasion(mm) 0 15.98 11.862 4.118 - - 12 14.81 11.486 3.324 0.794 2.53 24 14.486 11.296 3.19 0.134 3.056 36 14.142 11.118 3.024 0.166 2.858 48 13.789 10.909 2.88 0.144 2.736 60 13.486 10.742 2.744 0.136 2.608 72 13 10.568 2.432 0.312 2.12 15.908 Total abrasion loss is 15.908 mm
  • 10. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 04 Issue: 11 | Nov -2017 www.irjet.net p-ISSN: 2395-0072 © 2017, IRJET | Impact Factor value: 6.171 | ISO 9001:2008 Certified Journal | Page 967 Table.12 Abrasion Results for fiber reinforced optimal mix: duration mass Air mass water Vt VLt Avg. depth of abrasion(mm) 0 13.825 11.852 1.973 - - 12 13.428 11.645 1.783 0.19 1.593 24 13.176 11.566 1.61 0.173 1.437 36 12.942 11.498 1.444 0.166 1.278 48 12.623 11.335 1.288 0.156 1.132 60 12.482 11.332 1.15 0.138 1.012 72 12.202 11.168 1.034 0.116 0.918 7.37 Total abrasion loss for fibers incorporated mould is 7.37 mm 1.3. Sulphate Resistance Test (MgSO4)- The sulphate resistance test was performed to study the performance of geopolymer concrete subjected to 5% of MgSO4 solution Sulphates may be present in constituents which develop the contact of geopolymer matrix and affect it. Figure.7 Specimens in MgSO4 & NaCL Table.13 shows the average weight gain in (%) for the cubes immersed in MgSO4 mix id 60DAYS 90 DAYS M1 (0%) 1.11 1.25 M2 (0.2%) 1.32 1.38 M3 (0.3%) 1.37 1.42 1.4 Acid Resistance test (H2SO4): Acid resistance property of geo polymer concrete mixes has been studied by exposing the concrete specimens in 5% of sulphuric acid for 60 and 90 days. Various parameter evaluated are visual appearance, change in mass and change in compressive strength after the exposure period of both type of concrete. pH value of the solution was checked at 20 days interval and maintained throughout the test period.
  • 11. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 04 Issue: 11 | Nov -2017 www.irjet.net p-ISSN: 2395-0072 © 2017, IRJET | Impact Factor value: 6.171 | ISO 9001:2008 Certified Journal | Page 968 Table.14 shows weight loss of specimens when exposed to 5% of H2SO4 MIX ID Initial weight Final weight % loss 60 days % loss 90 days M1 (0%) 8.78 8.64 1.59 6.30 M2(0.2%) 8.46 8.37 1.06 4.20 M3(0.3%) 8.42 8.35 0.83 7.44 1.5 Chloride Resistance Test- Test specimens for Sodium chloride resistance and change in mass test were 150X150X150mm cubes of geopolymer concrete each. 3 specimens for each test were prepared for chloride resistance test to take average result of the specimen. Table.15 shows the average weight gain for the cubes immersed in NaCl for 60& 90 days MIX ID Initial weight kgs Final weight kgs % gain in 60 days % gain in 90 days M1 (0%) 8.59 8.82 2.68 0.46 M2(0.2%) 8.46 8.64 2.13 0.70 M3(0.3%) 8.42 8.54 1.43 0.24 1.6 Water Absorption test:- Water absorption tests for the GPC & FRGPC cubes were carried out for water Absorption test. The cubes once sufficiently dried were weighed to find their initial weights and then immersed completely in water for 24 hours. After the 24 hour duration, the specimens are removed and its saturated surface dry weight was recorded as the final weight. Water absorption of specimens is reported as the percentage increase in weight. Water Absorption in % can be determined using the formula give below Water absorption = Table.16 shows the percentage % saturated water absorption after 60 & 90 days MIX ID 60 days 90 days M1 (0%) 5.62 6.15 M3(0.2%) 2.81 3.23 M5(0.3%) 3.45 4.15 Conclusions After performing various tests on fiber reinforce geopolymer concrete the compressive strength resulted optimal strength at 1% of fiber inclusions so, the durability tests are carried out for two consecutive optimal strength obtained mixes i.e. is volume fractions of 0.2 % and 0.3% of incorporation of Polypropylene fibers and 0.05% of basalt fibers. The fiber reinforced composites has performed better results in Abrasion, resistance against sulphate, acid resistance, water absorption tests As compared to control mix i.e. without fibers. Addition of fly-ash & GGBS has improved the performance of fiber reinforced geopolymer concrete. The fiber reinforced geopolymer concrete has low demand for water as compared to control.
  • 12. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 04 Issue: 11 | Nov -2017 www.irjet.net p-ISSN: 2395-0072 © 2017, IRJET | Impact Factor value: 6.171 | ISO 9001:2008 Certified Journal | Page 969 References [1] Mehta, P. K. (1989). Pozzolanic and Cementitious By-Products in Concrete - Another Look. Paper presented at the third international conference on fly ash, silica fume, slag, and natural pozzolans in concrete, Trondheim, Norway. [2] Rangan, B. V. (2008). Fly Ash-Based Geopolymer Concrete. Retrieved 19 November 2008: [3] Wallah, S. E., &Rangan, B. V. (2006). Low-Calcium Fly Ash-Based Geopolymer Concrete : Long-Term. [4] Properties (Research Report GC 2). Perth: Faculty of Engineering Curtin University of Technology. [5] Davidovits, J. (2005). Geopolymer Chemistry and Sustainable Development. The Poly(sialate) Trminology : A Very Useful and Simple Model for the Promotion and Understanding of Green-Chemistry. In J. Davidovits (Ed.), Geopolymer, Green Chemistry and Sustainable Development Solutions (pp. 9-15). Saint-Quentin, France: InstitutGéopolymère. [6] Hall, C. (1981). Water Movement in Porous Building Materials. 4. The Initial Surface Absorption and the Sorptivity. Building and Environment, 16(3), 201-207. Hall, C. (1989). Water sorptivity of mortars and concretes: a review. Magazine of Concrete Research 41(147), 51-61. [7] KolliRamujee et al(2013). “Development of mix design for low calcium based Geopolymer concrete in Ordinary,standard and High strength grade concretes” Indian concrete Institute (ICI), Vol 14, issue no 2, pp 29-34. [8] Kolli Ramujee et al(2014) “ Permeability and Abrasion resistance of geopolymer concrete” Indian Concrete Journal (ICJ), vol 88,issue no 12. [9] Shalika Sharma, Dr Hemant Sood Abrasion Resistance of Geopolymer Concrete at Varying Temperature. IOSR Journal of Mechanical and Civil Engineering (IOSR-JMCE) e-ISSN: 2278-1684,p-ISSN: 2320-334X, Volume 13, Issue 1 Ver. I (Jan. - Feb. 2016), PP 22-25. [10] P Abhilash1, C Sashidhar2 and I V Ramana Reddy3Evaluation of performance of Geopolymer Concrete in acid environment. International Research Journal of Engineering and Technology (IRJET) Volume: 04 Issue: 07 | July -2017. BIOGRAPHY: D.Naveen Kumar PG Student VNR VJIET DR. K. Ramujee PROFESSOR & DEAN civil Dept.VNR VJIET