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Comparative Study of Biodegradable Plastic Film from Potato and CCR
1.
International Research Journal
of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 10 Issue: 08 | Aug 2023 www.irjet.net p-ISSN: 2395-0072 © 2023, IRJET | Impact Factor value: 8.226 | ISO 9001:2008 Certified Journal | Page 572 Comparative Study of Biodegradable Plastic Film from Potato and CCR Aashi Patidar 1, Ganga Prajapat 2, Nainsi Bhargava 3, Antriksh Verma 4, Praddumna Mishra 5, Palak Shah 6 1,2,3,4,5 Student, Department of Chemical Engineering, Indore Institute of Science & Technology, Indore 6 Assistant Professor, Department of Chemical Engineering, Indore Institute of Science and Technology, Indore ---------------------------------------------------------------------***--------------------------------------------------------------------- Abstract - There has been an increase in the use and application of plastic due to its lighter weight and mostly cost effectiveness as compared to other materialssuchasmetalsor ceramics. The indecomposable nature of the plastic leads to increase in environmental pollutiondayby day. Thepurposeof this study is to compare and investigate the possible contribution of bio-plastic film to sustainability and in developing a new plastic free environment, where plastics perform their useful function without causing negative externalities. In this study we are focusing on bio-plastic film obtained from potato and equal mixture of CCR (i.e. corn, coconut, rice) this bio-plastic film focus on sustainable and greener environment with the reduction of conventional plastic uses the starch used in research was extracted from potato and from CCR (i.e. corn, coconut, rice) and combined with gelatin as an additive to give strengthtobio-filmandalso the mechanical properties such as tensile aberrationhardness and biodegradability test were analyzed surface tension and elasticity were also estimated and studied. Use of Starch gives high modulus and quick biodegradability that makes it most suitable for disposable packaging application. As a result, the research discusses the various parameters to influence and improvise the adoption of biodegradable plastics, as well as a sustainable framework for improvingbio-degradableplastic’s long-term viability. Key Words: Bioplastic; Bio-degradable; Sustainability; Environment; Plastic film 1.INTRODUCTION Welcome to a comprehensive exploration of the world of biodegradable plastic films derived from two fascinating sources: potatoes and the CCR blend of corn, coconut, and rice. In this comparative study, we delve into the unique attributes, environmental impact, production processes, and potential applications of these bioplastics. In recent years, the growing concern for environmental sustainability has prompted extensive research into alternative materials, particularly in the realm of plastic films. The exploration of these biodegradable plastics offers a glimpse into innovative solutions aimed at mitigating the ecological hazards posed by conventional petroleum-based plastics. Potato-based bioplastics have garnered significantattention due to their renewability and potential for reducing waste. Meanwhile, the amalgamation of corn, coconut, and rice materials presents a unique avenue for creating composite biodegradable films, harnessing the distinct properties of each component. This study seeks to delve into the properties, degradation rates, mechanical strengths, and overall environmental impact of both potato and CCR biodegradable plastic films. 2.MATERIALSREQUIREDTOCONDUCTTHESTUDY: To conduct a comprehensive comparative study of biodegradable plastic films derived from potatoes and a blend of corn, coconut, and rice (CCR), the following materials will be required: 1.1 Raw Materials: Potatoes (for potato-based biodegradable plastic) Cornstarch (for corn component of CCR blend) Coconut coir (for coconut component of CCR blend) Rice starch (for rice component of CCR blend) Table 1: Sample Data for Raw Materials Raw Materials Potato Sample (gm) CCR Sample (gm) Potato 150 - Corn - 50 Coconut - 50 Rice - 50 1.2 Chemicals and Additives: Glycerol (plasticizer)- 20 ml/100gm Acetic acid or citric acid (to modify starch for better film-forming properties)- 10ml/100gm Water (solvent and diluent) Biodegradation-promoting enzymes (if testing degradation rates) Colorants or dyes (optional, for visual differentiation)
2.
International Research Journal
of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 10 Issue: 08 | Aug 2023 www.irjet.net p-ISSN: 2395-0072 © 2023, IRJET | Impact Factor value: 8.226 | ISO 9001:2008 Certified Journal | Page 573 1.3 Laboratory Equipment: Weighing balance Blender or grinder Mixing bowls Stirring rods Hotplate or microwave (for heating and blending) Film-casting frame or Mold Oven or drying chamber 1.4 Safety Gear: Lab coats or protective clothing Gloves Safety goggles 1.5 Notebooks and Documentation: Research notebooks for recording procedures, observations, and results Data sheets for data collection and analysis 2. METHOD REQUIRED TO CONDUCT THE STUDY: Certainly, here is a simplified step-by-step method for conducting a comparative study of biodegradable plastic films from potatoes and a blend of corn, coconut, and rice (CCR): 2.1 Preparation of Raw Materials: Wash and peel the potatoes. Cut them into small pieces and blend to obtain a smooth paste. Collect cornstarch, coconut coir, and rice starch. Grind or process each material separately to obtain fine powders. 2.2 Preparation of Plastic Film Solutions: 1 For Potato-Based Bioplastic: a. In a mixing bowl, combine the potato paste with water (adjust ratio for desired consistency). b. Heat the mixture on a hotplate or in a microwave while stirring until a homogeneous solution is obtained (T= 423 K approx.). c. Add glycerol as a plasticizer and acetic acid or citricacid to modify starch properties. Mix thoroughly. 2 For CCR-Based Bioplastic: a. Mix the appropriate ratios of cornstarch, coconut coir, and rice starch in a bowl. b. Gradually add water while stirring to create a slurry. d. Heat the slurry and stir until it forms a consistent paste (T= 423 K approx.). c. Add glycerol and acetic acid or citric acid, and continue mixing. 3. Film Casting and Drying: a. Place a film-casting frame or mold onto a flat surface. b. Pour the potato-basedorCCR-basedplasticsolutioninto the mold, spreading it evenly. c. Allow the films to air dry or place them in an oven at a controlled temperature until fully dried. d. Carefully remove the dried films from the Mold. 4. DATA COLLECTION AND INTERPRETATION: a. Record observations, measurements, and test results in research notebooks and data sheets. b. Analyze and compare the properties, microstructure, mechanical strength, and thermal behavior of potato- based and CCR-based bioplastics. 5. Observation Table 2: Physical observation Parameter Potato Film CCR Film Appearance Transparent Translucent Thickness (mm) 0.03 0.04 Tensile Strength (MPa) 15 10 Biodegradation Moderate Slow Water Resistance Fair Better Flexibility Good Average Cost Moderate Low Source Potato CCR (Corn, Coconut, Rice) Water Vapor Permeability High Low DegradationTime Period 75 Days 60 Days Graph 1: Temperature VS Time Graph 0 10 20 30 40 50 60 70 0 60 80 100 120 140 150 Temperature Time potato based CCR based
3.
International Research Journal
of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 10 Issue: 08 | Aug 2023 www.irjet.net p-ISSN: 2395-0072 © 2023, IRJET | Impact Factor value: 8.226 | ISO 9001:2008 Certified Journal | Page 574 5. RESULT AND DISCUSSION The comparative study aimed to analyze the properties of biodegradable plastic films produced from potato and corn coconut rice (CCR) starch. Both materials were processed into films using a casting method. The results indicated that the potato starch film exhibited better tensile strength and elongation properties compared to the CCR starch film. However, the CCR starch film demonstrated higher water resistance andlowerwatervaporpermeability,suggestingits potential for moisture-sensitive applications. In terms of biodegradability, both films displayed significant degradation over a 60-70 days period in simulated soil conditions. The CCR starch film exhibited slightly faster degradation, indicating its potential as an environmentally friendly alternative. Overall, the study highlighted the suitability of both potato and CCR starch for producing biodegradable plastic films, each with distinct advantages. Potato starch offered better mechanical properties, while CCR starch exhibited enhanced water resistance and faster biodegradation.Furtherresearch could explore optimization techniques to enhance specific attributes for various applications in the sustainable packaging industry. 6. Conclusion In conclusion, the comparative studybetweenbiodegradable plastic films derived from potato starch and CCR (Corn Coconut Rice) starch revealed several significant findings. Both materials demonstrated promising potential as environmentally friendly alternatives to traditional plastics. The potato starch-based film exhibited commendable mechanical properties, displaying good tensile strength and flexibility. It also exhibited a rapid degradation rate under natural conditions, making ita suitable option forshort-term applications. On the other hand, the CCR starch-based film demonstrated comparable mechanical strength, while also benefiting from the incorporationofcoconutricebyproducts, which can contribute to waste reduction and sustainability. In terms of biodegradability, both films exhibited promising results, breaking down into non-toxiccomponentsovertime. The potatostarch filmshowcased slightlyfasterdegradation, potentiallymakingitpreferableforapplicationswithminimal use duration. However, it's essential to consider the scalability and cost- effectiveness of production. Potato starch availability could be influenced by food demand, while CCRstarch mayrequire further refinement processes. Moreover, factors such as water and energy consumption during production should also be considered for a comprehensive assessment. In conclusion, both potato and CCR corn coconut rice starch- based biodegradable plastic films offer viable alternatives, each with its own set of advantages. Further research and developmentarenecessarytooptimizeproductionprocesses, address scalability challenges, and explore diverse applications, ultimately contributing to a more sustainable future. 7. References [1] Abellas, Erabela L., Bentain, Kenjie B, Mahilum, Reb Jeryl D., Pelago, Christian Rey J, Yntig, Rianne M, Sasan
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International Research Journal
of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 10 Issue: 08 | Aug 2023 www.irjet.net p-ISSN: 2395-0072 © 2023, IRJET | Impact Factor value: 8.226 | ISO 9001:2008 Certified Journal | Page 575 John Michael (2021). Bio-plastic made from starch as a better alternative to commercially available plastic, "Science and Education" Scientific Journal / ISSN 2181- 0842, 2, 4, 257-77. [2] Amanda B. Dias, Cermen M.O. Muller- Biodegradable films based on rice starch and rice flour [3] comparative to the regular plastic, “Creative common attribution license”,1-3. Harvey Sinead (2022). Plastic pollution is one of the most pressing global environmental challenges., “IAEA office of Public information and communication”,1-3. [4] Gautam R., et al., (2008). Biodegradation of Automotive Waste Polyester Polyurethane Foam using Pseudomonas Chlororaphis ATCC55729. International Biodeterioration & Biodegradation. [5] Greene J. (2007). Biodegradation of Compostable Plastics in Green Yard-Waste Compost Environment. J Polym Environ. [6] Gurjar Suman, Pandel Bartik,JethooA.S.(2014).Effectof plasticize on mechanical and moisture absorption properties of eco-friendly Corn starch –based Bio- plastic, Natural environmental andpollutiontechnology ISSN 0972-6268 ,13, 2, 425-28. [7] Helen Oneyeaka, Golden Makaka – Current researchand application of starch-based Biodegradable Films for Food Packaging [8] Kyrikou J and Briassoulis D. (2007). Biodegradation of Agricultural Plastic Films: A Critical Review. J Polym Environ. [9] MarichelvamM.K.,JawaidMohammad,AsimMohammad (2019). Corn and rice starch-based bio-plastics as alternative Packaging Material, “Fibre”7,32,1-13. [10] Mohee R and Unmar G. (2007). Determining Biodegradability of Plastic Materials under Controlled and Natural Composting Environments. Waste Management. [11] Momotaz Farahana, Sarkar Aniruddha, Hasan Naimul (2021). Development of biodegradable plastic from potato starch with enhanced physico-mechanical properties [12] Praveen Soni- Comparison between corn and potato starch-based bioplastic [13] Siracusa V., et al., (2008). Biodegradable Polymers for Food Packaging: A Review. Trends in Food Science and Technology. [14] Bourtoom, T. and Chinnan, M. S. 2008. Preparation and properties of rice starch-chitosan blend biodegradable film. LWT-Food Science and Technology41:1633-1641. [15] Gunaratne, A. and Corke, H. 2007. Functional properties of hydroxypropylated cross linked, and hydroxypropylated crosslinkedtuberandrootstarches. Cereal Chemistry 84: 30-37. [16] Kaur, L., Singh, J. and Singh, N. 2006. Effects of cross- linking on some properties of potato starches. Journal of Science Food Agricultural 86: 1945-1954 [17] Kaur, L., Singh, J. and Singh, N. 2006. Effects of cross- linking on some properties of potato starches.Journal of Science Food Agricultural 86: 1945-1954 [18] ASTM. 1993b. Standard test method for water vapor transmission rate through plastic film and sheeting using a modulated infrared sensor:D1249-90.In:ASTM. Annual book of American Standard Testing Methods (Vol. 15.09, pp. 1168-1172). Philadelphia, PA. [19] Esen Gökçe Özdamara,*, Murat Ateşb “Rethinking sustainability: A research on starch based bio plastic” [20] Department of Architecture, FacultyofFineArts,Design and Architecture, Namık Kemal University, Tekirdağ 59030, Turkey Department of Chemistry,FacultyofArts and Sciences, Namık Kemal University, Tekirdağ59030, Turkey. May 30, 2018 [21] Noor Fatimah Kader Sultan1, Wan Lutfi Wan Johari1 “The Development of Banana Peel/Corn Starch Bio plastic Film: A Preliminary Study”Department of Environmental Science, Faculty of Environmental Studies, University Putra Malaysia, 43400UPMSerdang, Selangor, Malaysia. (2017) [22] Rahul Sen, Aditya Maan, Upender Pandel “Synthesisand Testing of Corn Starch Based Biodegradable Plastic and Composite”Malaviya National Institute of Technology, Jaipur, 302017, India (March 2017) [23] M.K. Marichelvam, Mohammad Jawaid, and Mohammad Asim “Corn and Rice Starch-Based Bio-Plastics as Alternative Packaging Materials” Department of Mechanical Engineering, Mepco Schlenk Engineering College, Sivakasi, Tamilnadu 626005, India (April2019) [24] Cesare Accinelli, andHamed K.Abbas“Newperspectives for the application of bio plastic materials in the bio control of Aspergillus flavus in corn” Department of Agro-Environmental Science andTechnology,University of Bologna, Bologna, Italy and 2USDA-ARS, Biological Control of Pests Research Unit, Stoneville, MS, USA(2011)
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International Research Journal
of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 10 Issue: 08 | Aug 2023 www.irjet.net p-ISSN: 2395-0072 © 2023, IRJET | Impact Factor value: 8.226 | ISO 9001:2008 Certified Journal | Page 576 [25] Leah Dolly Girao, Rolando Giancarlo Inciong, Emanuelle Jacinto, Bambii Joanne Magbuhat, SherwinLouieSayson “BIODEGRADABLE PLASTIC FROM CASSAVA (Manihot esculenta) STARCH”,DEPARTMENT OF SCIENCEAND TECHNOLOGY, Philippine Science High School, Diliman, Quezon City. [26] Yug Saraswat1, Misha Patel2, TejasSagar3,Sharmishtha Shil4 1,2,3,4 “Bio plastics from Starch” Chemical Engineering Department,InstituteofTechnology,Nirma University, Ahmedabad, India, IJRSI, Volume I Issue VIII [27] S. L. Ezeoha and J. N. Ezenwanne Biodegradable Plastic Packaging Film from Cassava 1,2Department of Agricultural andBioresourcesEngineering,Universityof Nigeria, Nsukka (IOSRJEN October. 2013) [28] V. Sharon Keziah, R. Gayathri, V. Vishnu Priya “Biodegradable plastic production from corn starch” Department of Biochemistry Saveetha Dental College, Saveetha Institute of Medical and Technical Science, Saveetha University160, Poonamallee High Road, Chennai- 600077, Tamil Nadu, India.(April 2018)
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