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6 April 2022 U.Aravind, Lect/Mech, LAPC 1
Lakshmi Ammal Polytechnic College
Department of Mechanical Engineering
Subject Code : 4020340
Year & Semester : II / III
Scheme : N
By…
U.Aravind,
Lecturer/Mechanical Engineering,
LAPC, Kovilpatti.
6 April 2022 U.Aravind, Lect/Mech, LAPC 2
Lakshmi Ammal Polytechnic College
Department of Mechanical Engineering
Subject Code : 4020340
Subject Name : Thermal Engineering I
Year & Semester : II / III
Scheme : N
Unit : 1
Topic: II. Thermodynamics Processes of
Perfect Gases
Thermodynamic Processes
The Study of thermodynamic process
involves the determination of the
Work (W)
Change in Internal energy (∆U)
Change in Entropy (∆S)
The amount of heat transferred (Q)
6 April 2022 U.Aravind, Lect/Mech, LAPC 3
Thermodynamic Processes
•Constant Volume (or) Isochoric Process [V=c]
•Constant Pressure (or) Isobaric Process [p=c]
•Constant Temperature (or) Isothermal (or)
Hyperbolic Process [T=c]
•Reversible adiabatic (or) Isentropic Process
[pvγ
= c]
•Polytropic Process [pv𝑛
= c]
•Free Expansion Process
•Throttling Process
6 April 2022 U.Aravind, Lect/Mech, LAPC 4
6 April 2022 U.Aravind, Lect/Mech, LAPC 5
• m kg of gas taken in a Closed Vessel.
• It is heated or cooled
• Being contained in a closed vessel gas neither
expands nor compressed.
• So volume remains constant.
6 April 2022 U.Aravind, Lect/Mech, LAPC 6
6 April 2022 U.Aravind, Lect/Mech, LAPC 7
6 April 2022 U.Aravind, Lect/Mech, LAPC 8
6 April 2022 U.Aravind, Lect/Mech, LAPC 9
i) General gas equation :
𝐏𝟏𝐕𝟏
𝐓𝟏
=
𝐏𝟐𝐕𝟐
𝐓𝟐
Apply 𝐕𝟏 = 𝐕𝟐 in to General Gas Equation
𝐏𝟏𝐕𝟏
𝐓𝟏
=
𝐏𝟐𝐕𝟐
𝐓𝟐
𝐏𝟏
𝐓𝟏
=
𝐏𝟐
𝐓𝟐
ii) Heat Transferred(Q)
Heat Transferred = mass x specific heat at constant volume
x temperature difference
Q = m 𝐂𝐯 (T2 – T1)
iii) Work done (W)
As gas neither expands nor compressed in a closed vessel, so
work done is Zero.
W = 0
6 April 2022 U.Aravind, Lect/Mech, LAPC 10
iv) Change in Internal Energy (∆U)
Change in Internal Energy= mass x specific heat at constant volume
x temperature difference
∆U = m 𝐂𝐯 (T2 – T1) (Common for all process)
v) By first law of thermodynamics
Q = ∆U + W
= ∆U + 0
Q= ∆U
vi) Change in Entropy (∆S)
∆S = 𝐓𝟏
𝐓𝟐 𝐝𝐐
𝐓
Q = m𝐂𝐯 (T2 – T1)
In differentiate form
dQ = m𝐂𝐯 dT
= 𝐓𝟏
𝐓𝟐 m𝐂𝐯 dT
𝐓
𝟏
𝐱
dx = 𝐥𝐨𝐠𝒆𝒙 = 𝐥𝐧𝐱
∆S = m𝐂𝐯 ln
𝑻𝟐
𝑻𝟏
6 April 2022 U.Aravind, Lect/Mech, LAPC 11
• m kg of gas taken in an engine cylinder.
• To maintain constant pressure some weight is
placed on the piston.
• Gas is heated
• It expands and does work on the pressure.
6 April 2022 U.Aravind, Lect/Mech, LAPC 12
6 April 2022 U.Aravind, Lect/Mech, LAPC 13
6 April 2022 U.Aravind, Lect/Mech, LAPC 14
6 April 2022 U.Aravind, Lect/Mech, LAPC 15
i) General gas equation :
𝐏𝟏𝐕𝟏
𝐓𝟏
=
𝐏𝟐𝐕𝟐
𝐓𝟐
Apply 𝐏𝟏 = 𝐏𝟐 in to General Gas Equation
𝐏𝟏𝐕𝟏
𝐓𝟏
=
𝐏𝟐𝐕𝟐
𝐓𝟐
𝐕𝟏
𝐓𝟏
=
𝐕𝟐
𝐓𝟐
ii) Heat Transferred(Q)
Heat Transferred = mass x specific heat at constant
pressure x temperature difference
Q = m 𝐂𝐏 (T2 – T1)
iii) Work done (W)
Work done = hatched area in PV diagram = height x breadth
W = 𝐏𝟏(𝐕𝟐 - 𝐕𝟏)
6 April 2022 U.Aravind, Lect/Mech, LAPC 16
iv) By first law of thermodynamics
Q= ∆U + W
v) Change in Entropy (∆S)
∆S = 𝐓𝟏
𝐓𝟐 𝐝𝐐
𝐓
Q = m𝐂𝐏 (T2 – T1)
In differentiate form
dQ = m𝐂𝐏 dT
= 𝐓𝟏
𝐓𝟐 m𝐂𝐏 dT
𝐓
𝟏
𝐱
dx = 𝐥𝐨𝐠𝒆𝒙 = 𝐥𝐧𝐱
∆S = m𝐂𝐏 ln
𝑻𝟐
𝑻𝟏
6 April 2022 U.Aravind, Lect/Mech, LAPC 17
• m kg of gas taken in an engine cylinder.
• It is heated slowly by source
• Temperature may tend to raise. But this is
nullified by the expansion of gas.
• So the temperature remains constant.
6 April 2022 U.Aravind, Lect/Mech, LAPC 18
6 April 2022 U.Aravind, Lect/Mech, LAPC 19
6 April 2022 U.Aravind, Lect/Mech, LAPC 20
6 April 2022 U.Aravind, Lect/Mech, LAPC 21
i) General gas equation :
𝐏𝟏𝐕𝟏
𝐓𝟏
=
𝐏𝟐𝐕𝟐
𝐓𝟐
Apply 𝐓𝟏 = 𝐓𝟐 in to General Gas Equation
𝐏𝟏𝐕𝟏
𝐓𝟏
=
𝐏𝟐𝐕𝟐
𝐓𝟐
𝐏𝟏𝐕𝟏 = 𝐏𝟐𝐕𝟐
ii) Change in Internal Energy (∆U)
∆U = m 𝐂𝐯 (T2 – T1)
𝐓𝟏 = 𝐓𝟐
∆U = 0
iii) Change in Enthalpy (∆h)
∆h = m 𝐂𝐏 (T2 – T1)
𝐓𝟏 = 𝐓𝟐
∆h = 0
iv) By first law of thermodynamics
Q = ∆U + W
= 0 + W
Q = W
6 April 2022 U.Aravind, Lect/Mech, LAPC 22
v) Work done (W)
Work done = hatched area in PV diagram = height x breadth
W = 𝐏𝟏𝐕𝟏𝐥𝐧
𝐕𝟐
𝐕𝟏
(or) W = mR 𝐓𝟏 ln
𝐕𝟐
𝐕𝟏
vi) Change in Entropy (∆S)
∆S = 𝐓𝟏
𝐓𝟐 𝐝𝐐
𝐓
T is constant
=
𝟏
𝐓
𝒅𝑸
𝒅𝒙 = x
∆S =
𝐐
𝐓
=
mR 𝐓𝟏ln 𝐕𝟐
𝐕𝟏
𝐓𝟏
∆S = mR ln
𝐕𝟐
𝐕𝟏
6 April 2022 U.Aravind, Lect/Mech, LAPC 23
6 April 2022 U.Aravind, Lect/Mech, LAPC 24
• m kg of gas taken in an engine cylinder.
• It is expanded rapidly.
• To prevent heat transfer, system is fully
covered by insulation.
• No heat transfer takes place during the process.
• So the entropy of the gas remains constant.
6 April 2022 U.Aravind, Lect/Mech, LAPC 25
6 April 2022 U.Aravind, Lect/Mech, LAPC 26
6 April 2022 U.Aravind, Lect/Mech, LAPC 27
i) Pressure, Volume, Temperature
Relation:
i) Pressure Volume Relations
𝐏𝟏
𝐏𝟐
= [
𝐕𝟐
𝐕𝟏
]𝛄
ii. Temperature Volume Relations
𝐓𝟏
𝐓𝟐
= [
𝐕𝟐
𝐕𝟏
]𝛄−𝟏
ii. Temperature Pressure Relations
𝐓𝟏
𝐓𝟐
= [
𝐏𝟏
𝐏𝟐
]
𝜸−𝟏
𝜸
6 April 2022 U.Aravind, Lect/Mech, LAPC 28
ii) Heat Transferred(Q)
Q = 0
iii) Work done (W)
W =
𝑷𝟏𝑽𝟏−𝑷𝟐𝑽𝟐
𝜸−𝟏
iv) Change in Internal Energy (∆U)
∆U = m 𝐂𝐯 (T2 – T1)
v) By first law of thermodynamics
Q = ∆U + W
0 = ∆U + W
∆U = - W
vi) Change in Entropy (∆S)
∆S = 𝐓𝟏
𝐓𝟐 𝐝𝐐
𝐓
Q is 0
∆S = 𝟎
6 April 2022 U.Aravind, Lect/Mech, LAPC 29
6 April 2022 U.Aravind, Lect/Mech, LAPC 30
6 April 2022 U.Aravind, Lect/Mech, LAPC 31
i) Pressure, Volume, Temperature
Relation:
i) Pressure Volume Relations
𝐏𝟏
𝐏𝟐
= [
𝐕𝟐
𝐕𝟏
]𝒏
ii. Temperature Volume Relations
𝐓𝟏
𝐓𝟐
= [
𝐕𝟐
𝐕𝟏
]𝐧−𝟏
ii. Temperature Pressure Relations
𝐓𝟏
𝐓𝟐
= [
𝐏𝟏
𝐏𝟐
]
𝒏−𝟏
𝒏
6 April 2022 U.Aravind, Lect/Mech, LAPC 32
ii) Heat Transferred(Q)
Q =
𝛄−𝐧
𝛄−𝟏
x W
iii) Work done (W)
W =
𝐏𝟏𝐕𝟏−𝐏𝟐𝐕𝟐
𝐧−𝟏
iv) Change in Internal Energy (∆U)
∆U = m 𝐂𝐯 (T2 – T1)
v) Change in Entropy (∆S)
∆S =
𝛄−𝐧
𝛄−𝟏
mR ln
𝐕𝟐
𝐕𝟏
6 April 2022 U.Aravind, Lect/Mech, LAPC 33
6 April 2022 U.Aravind, Lect/Mech, LAPC 34
6 April 2022 U.Aravind, Lect/Mech, LAPC 35
6 April 2022 U.Aravind, Lect/Mech, LAPC 36
Isothermal Process Isentropic Process
Temperature is Constant Entropy is Constant
Heat Transfer takes place No Heat Transfer takes place
Slow Process Fast Process
Change in Internal Energy is
Zero
Change in Internal Energy is
not Zero
Change in enthalpy is Zero Change in enthalpy is not Zero
Ex: Stirling Cycle Ex: Otto cycle
6 April 2022 U.Aravind, Lect/Mech, LAPC 37
Problems on
Thermodynamic
Processes
6 April 2022 U.Aravind, Lect/Mech, LAPC 38
Problems on Constant
Volume Processes
6 April 2022 U.Aravind, Lect/Mech, LAPC 39
1. Determine the final temperature, external work done, change in
internal energy, change in enthalpy, change in entropy in the case of
2kg of gas at 50°C being heated at constant volume until the
pressure is doubled.
Given Data:
• Type of Process:
• Mass, m = 2 kg
• Initial Temperature, T1 = 50°C = 50 + 273 = 323 K
• Pressure is Doubled
To Find:
• Final Temperature, T2
• Work Done, W
• Change in Internal Energy, ∆U
• Change in Enthalpy, ∆h
• Change in Entropy, ∆S
40
Constant Volume Process
𝐏𝟐= 2 𝑷𝟏
6 April 2022 U.Aravind, Lect/Mech, LAPC
Solution:-
I. To Find Final Temperature, 𝐓𝟐
From General gas equation :
𝐏𝟏𝐕𝟏
𝐓𝟏
=
𝐏𝟐𝐕𝟐
𝐓𝟐
𝐏𝟏
𝐓𝟏
=
𝐏𝟐
𝐓𝟐
∴ 𝐓𝟐 =
𝐏𝟐𝐓𝟏
𝐏𝟏
𝑇2 =
2P1x 323
P1
= 646
41
𝐓𝟐 = 646 K
𝐅𝐨𝐫 𝐂𝐨𝐧𝐬𝐭𝐚𝐧𝐭 𝐕𝐨𝐥𝐮𝐦𝐞 𝐏𝐫𝐨𝐜𝐞𝐬𝐬
𝐕𝟏 = 𝐕𝟐
6 April 2022 U.Aravind, Lect/Mech, LAPC
II. To Find Work done, W
III. To Find Change in Internal Energy,
∆U
We Know ∆U = m 𝐂𝐕 (T2 – T1)
= 2 x 0.718 (646 - 323)
= 463.82
42
W = 0
𝐀𝐬𝐬𝐮𝐦𝐞, CV = 0.718
∆U = 463.82 kJ
6 April 2022 U.Aravind, Lect/Mech, LAPC
IV. To Find Change in Enthalpy, ∆h
We Know ∆h = m 𝐂𝐏 (T2 – T1)
= 2 x 1.005 (646 - 323)
= 649.23
V. To Find Change in Entropy, ∆S
We Know ∆S = m𝐂𝐯 ln
𝐓𝟐
𝐓𝟏
= 2 x 0.718 ln
𝟔𝟒𝟔
𝟑𝟐𝟑
= 0.9953
43
𝐀𝐬𝐬𝐮𝐦𝐞, CP = 1.005
∆𝐡 = 649.23 kJ
∆𝐒 = 0.9953 kJ/K
6 April 2022 U.Aravind, Lect/Mech, LAPC
Results:-
I. Final Temperature, 𝐓𝟐 = 646 K
II. Work done, W = 0
III. Change in Internal Energy, ∆U = 463.82 kJ
IV. Change in Enthalpy, ∆h = 649.23 kJ
V. Change in Entropy, ∆S = 0.9953 kJ/K
44
6 April 2022 U.Aravind, Lect/Mech, LAPC
2. A Mass of 2.25 kg of nitrogen occupying 1.5𝐦𝟑
is heated from
25°C to 200°C at constant volume. Molecular weight of nitrogen is
28 and universal gas constant is 8.314 KJ/kg.mole.K. Calculate the
initial and final pressure of the gas and Change in internal energy
and change in entropy.
Given Data:
• Type of Process:
• Mass, m = 2.25 kg
• Volume, V1 = V2 = 1.5m3
• Initial Temperature, T1 = 25°C= 25 + 273 = 298 K
• Final Temperature, T2 = 200°C= 200 + 273 = 473 K
• Molecular Weight, M = 28
• Universal Gas Constant, RU = 8.314 KJ/kg.K
To Find:
i) Initial Pressure, P1 ii) Final Pressure, P2
iii) `Change in Internal Energy, ∆U iv)Change in Entropy, ∆S 45
Constant Volume Process
6 April 2022 U.Aravind, Lect/Mech, LAPC
Solution:-
I. To Find Initial Pressure, 𝐏𝟏
From Characteristic gas equation :𝐏𝟏𝐕𝟏 = 𝐦𝐑𝐓𝟏
We have to find R
We know R =
RU
M
=
8.314
28
R = 0.2969
∴ 𝐏𝟏 =
𝐦𝐑𝐓𝟏
𝐕𝟏
=
2.25 x 0.2969 x 298
1.5
= 132.714
46
𝐏𝟏 = 132.714 kN/ 𝐦𝟐
6 April 2022 U.Aravind, Lect/Mech, LAPC
II. To Find Final Pressure, 𝐏𝟐
From Characteristic gas equation :𝐏𝟐𝐕𝟐 = 𝐦𝐑𝐓𝟐
∴ 𝐏𝟐 =
𝐦𝐑𝐓𝟐
𝐕𝟐
=
2.25 x 0.2969 x 473
1.5
= 210.65
III. To Find Change in Internal Energy, ∆U
We Know ∆U = m 𝐂𝐕 (T2 – T1)
= 2.25 x 0.718 (473-298)
= 282.71
47
𝐏𝟐= 210.65 kN/ 𝐦𝟐
𝐀𝐬𝐬𝐮𝐦𝐞, CV = 0.718
∆U = 282.71 kJ
6 April 2022 U.Aravind, Lect/Mech, LAPC
IV. To Find Change in Entropy, ∆S
We Know ∆S = m𝐂𝐯 ln
𝐓𝟐
𝐓𝟏
= 2.25 x 0.718 ln
473
298
= 0.7463
Results:-
I. Initial Pressure, 𝐏𝟏 = 132.714 kN/ 𝐦𝟐
II. Final Pressure, 𝐏𝟐 = 210.65 kN/ 𝐦𝟐
III. Change in Internal Energy, ∆U =282.71 kJ
IV.Change in Entropy, ∆S =0.7463 kJ/K
48
∆𝐒 = 0.7163 kJ/K
6 April 2022 U.Aravind, Lect/Mech, LAPC
Problems on Constant
Pressure Process
6 April 2022 U.Aravind, Lect/Mech, LAPC 49
3. A gas whose pressure, volume and temperature are 5 bar,
0.23𝐦𝟑and 185°C respectively has changed its state at constant
pressure until its temperature becomes 70°C. Determine (i) Mass (ii)
Work done (iii) Change in Internal Energy (iv) Heat Transferred
during the process. Take R = 0.29 kJ/kg.K and CP = 1.005 kJ/kg. K
Given Data:
• Type of Process:
• Pressure, P1 = P2 = 5 bar = 5 x 100 = 500 kN/ m2
• Initial Volume, V1 = 0.23 m3
• Initial Temperature, T1 = 185°C= 185 + 273 = 458 K
• Final Temperature, T2 = 70°C= 70 + 273 = 343 K
• Gas Constant, R = 0.29 KJ/kg.K
• CP = 1.005 kJ/kg. K
To Find:
i) Mass, M ii) Work done, W
iii) Change in Internal Energy, ∆U iv) Heat Transferred, Q 50
Constant Pressure Process
6 April 2022 U.Aravind, Lect/Mech, LAPC
Solution:-
I. To Find Mass, m
From Characteristic gas equation :𝐏𝟏𝐕𝟏 = 𝐦𝐑𝐓𝟏
∴ m =
𝐏𝟏𝐕𝟏
𝐑𝐓𝟏
=
500 x 0.23
0.29 x 458
= 0.8658
II. To Find Change in Internal Energy, ∆U
We Know ∆U = m 𝐂𝐕 (T2 – T1)
= 0.8658 x 0.718 (343-458)
= - 71.19 kJ
51
𝐦 = 𝟎. 𝟖𝟔𝟓𝟖 𝐤𝐠
𝐀𝐬𝐬𝐮𝐦𝐞, CV = 0.718
∆U = −71.19 kJ
6 April 2022 U.Aravind, Lect/Mech, LAPC
III. To Find Heat Transferred, Q
We Know Q= m 𝐂𝐏 (T2 – T1)
= 0.8658 x 1.005 (343-458)
= - 100.064 kJ
IV. To Find Work done, W
By First law of Thermodynamics
Q = ∆U + W
∴ 𝐖 = Q - ∆U
= - 100.064 - (-71.19)
= -28.874
52
𝐐 = −𝟏𝟎𝟎. 𝟎𝟔𝟒 𝐤𝐉
𝐖 = −28.874 kJ
6 April 2022 U.Aravind, Lect/Mech, LAPC
4. One kg of air at a pressure of 5 bar and volume 0.3𝐦𝟑
and
temperature 627°C is supplied with heat at constant pressure till the
volume is doubled. Calculate (i) Work done (ii) Change in Internal
Energy (iii) Heat Transferred (iv) Change in Entropy (v) Change in
Enthalpy. Take R = 0.287 kJ/kg.K and CP = 1.005 kJ/kg. K , Cv =
0.718 kJ/kg. K
Given Data:
• Type of Process:
• Mass of air, m = 1kg
• Pressure, P1 = P2 = 9 bar = 9 x 100 = 900 kN/ m2
• Initial Volume, V1 = 0.3 m3
• Initial Temperature, T1 = 627°C= 627 + 273 = 900 K
• Volume is Doubled
• Gas Constant, R = 0.29 KJ/kg.K
• CP = 1.005 kJ/kg. K
• Cv = 0.718 kJ/kg. K
53
Constant Pressure Process
𝐕𝟐= 2 𝐕𝟏 = 2 x 0.3 = 0.6 m3
6 April 2022 U.Aravind, Lect/Mech, LAPC
To Find:
• Final Temperature, T2
• Work Done, W
• Change in Internal Energy, ∆U
• Change in Entropy, ∆S
• Change in Enthalpy, ∆h
• Heat Transferred, Q
Solution:-
I. To Find Final Temperature, 𝐓𝟐
From General gas equation :
𝐏𝟏𝐕𝟏
𝐓𝟏
=
𝐏𝟐𝐕𝟐
𝐓𝟐
𝐕𝟏
𝐓𝟏
=
𝐕𝟐
𝐓𝟐
∴ 𝐓𝟐 =
𝐕𝟐𝐓𝟏
𝐕𝟏
T2 =
0.6 x 900
0.3
= 1800 54
𝐅𝐨𝐫 𝐂𝐨𝐧𝐬𝐭𝐚𝐧𝐭 𝐏𝐫𝐞𝐬𝐬𝐮𝐫𝐞 𝐏𝐫𝐨𝐜𝐞𝐬𝐬
𝑷𝟏 = 𝑷𝟐
𝐓𝟐 = 𝟏𝟖𝟎𝟎 𝐊
6 April 2022 U.Aravind, Lect/Mech, LAPC
II. To Find Work done
We know :𝐖 = 𝐏𝟏(𝐕𝟐 - 𝐕𝟏)
= 900 (0.6-0.3)
= 270
III. To Find Change in Internal Energy, ∆U
We Know ∆U = m 𝐂𝐕 (T2 – T1)
= 1 x 0.718 (1800-900)
= 646.2
55
∆U = 646.2 kJ
W = 𝟐𝟕𝟎 kJ
6 April 2022 U.Aravind, Lect/Mech, LAPC
IV. To Find Change in Entropy, ∆S
We Know ∆S = m𝐂𝐏 ln
𝐓𝟐
𝐓𝟏
= 1 x 1.005 ln
1800
900
= 0.6969
V. To Find Change in Enthalpy , ∆h
We Know ∆h = m 𝐂𝐏 (T2 – T1)
= 1 x 1.005 1800 − 900
= 904.5
56
∆𝐒 = 0.6969 kJ/K
∆𝐡 = 904.5 kJ
6 April 2022 U.Aravind, Lect/Mech, LAPC
VI. To Find Heat Transferred, Q
We Know Q= m 𝐂𝐏 (T2 – T1)
= 1 x 1.005 1800 − 900
= 904.5
57
𝐐 = 904.5 kJ
6 April 2022 U.Aravind, Lect/Mech, LAPC
Problems on Constant Temperature
Process (or) Isothermal Process
6 April 2022 U.Aravind, Lect/Mech, LAPC 58
5. 0.2 kg of air at a pressure of 1.1 bar and 15°C is
compressed to isothermally to a pressure of 5.5 bar.
Calculate (i) Initial & Final Volume (ii) Work done (iii)
Change in Internal Energy (iv) Heat Rejected (v)
Change in Entropy (vi) Change in Enthalpy. Take R =
0.292 kJ/kg.K
Given Data:
•Type of Process:
•Mass of air, m = 0.2 kg
•Initial Pressure, P1 = 1.1 bar = 1.1 x 100 = 110 kN/ m2
•Final Pressure, P2 = 5.5 bar = 5.5 x 100 = 550 kN/ m2
•Temperature, T1 = T2 = 15°C= 15 + 273 = 288 K
•Gas Constant, R = 0.29 KJ/kg.K
59
Constant Thermal Process
6 April 2022 U.Aravind, Lect/Mech, LAPC
To Find:
• Initial Volume, V1
• Final Volume, V2
• Work Done, W
• Change in Internal Energy, ∆U
• Change in Enthalpy, ∆h
• Change in Entropy, ∆S
• Heat Rejected, Q
Solution:-
I. To Find Initial Volume, 𝐕𝟏
From Characteristic gas equation :𝐏𝟏𝐕𝟏 = 𝐦𝐑𝐓𝟏
𝐕𝟏 =
𝐦𝐑𝐓𝟏
𝐏𝟏
𝐕𝟏 =
0.2 x 0.292 x 288
110
= 0.1529
60
𝐅𝐨𝐫 𝐂𝐨𝐧𝐬𝐭𝐚𝐧𝐭 𝐓𝐞𝐦𝐩𝐞𝐫𝐚𝐭𝐮𝐫𝐞 𝐏𝐫𝐨𝐜𝐞𝐬𝐬
𝐓𝟏 = 𝐓𝟐
𝐕𝟏 = 𝟎. 𝟏𝟓𝟐𝟗 𝐦𝟑
6 April 2022 U.Aravind, Lect/Mech, LAPC
II. To Find Final Volume, 𝐕𝟐
From Characteristic gas equation :𝐏𝟐𝐕𝟐 = 𝐦𝐑𝐓𝟐
𝐕𝟐 =
𝐦𝐑𝐓𝟐
𝐏𝟐
𝐕𝟐 =
0.2 x 0.292 x 288
550
= 0.0305
III. To Find Work done, W
We know :W = 𝐏𝟏𝐕𝟏𝐥𝐧
𝐕𝟐
𝐕𝟏
= 110 x 0.1529 ln
0.0305
0.1529
= - 27.113
61
𝐕𝟐 = 𝟎. 𝟎𝟑𝟎𝟓 𝐦𝟑
𝐖 = −27.113 kJ
6 April 2022 U.Aravind, Lect/Mech, LAPC
IV. To Find Change in Internal Energy, ∆U
We Know ∆U = m 𝐂𝐕 (T2 – T1)
= 0.2 x 0.718 (288-288)
= 0
V. To Find Change in Enthalpy , ∆h
We Know ∆h = m 𝐂𝐏 (T2 – T1)
= 0.2 x 1.005 288 − 288
= 0
62
∆U = 0
∆𝐡 = 𝟎
6 April 2022 U.Aravind, Lect/Mech, LAPC
V. To Find Change in Entropy, ∆S
We Know ∆S = m𝐑ln
𝐕𝟐
𝐕𝟏
= 0.2 x 0.292 ln
0.0305
0.1529
= -0.094
VII. To Find Heat Transferred, Q
We know :Q = 𝐏𝟏𝐕𝟏𝐥𝐧
𝐕𝟐
𝐕𝟏
= 110 x 0.1529 ln
0.0305
0.1529
= - 27.113
63
∆𝐒 = −0.094 kJ/K
𝐐 = −27.113 kJ
6 April 2022 U.Aravind, Lect/Mech, LAPC
Problems on Adiabatic Process
(or) Isentropic Process
6 April 2022 U.Aravind, Lect/Mech, LAPC 64
6. Air at 1 bar and 40°C is compressed to 1/10th original
volume isentropically. Calculate Final pressure and
Temperature & Work done on 1𝐦𝟑of air. Assume R =
0.287 kJ/kg.K and γ = 1.41
Given Data:
•Type of Process:
•Mass of air, m = 1kg
•Initial Pressure, P1 = 1 bar = 1 x 100 = 100 kN/ m2
•Initial Temperature, T1 = 40°C= 40 + 273 = 313 K
•Initial Volume, V1 = 1 m3
•Final volume V2 =
•Gas Constant, R = 0.29 KJ/kg.K
•γ = 1.41 65
Isentropic Process
1/10th 𝐭𝐡𝐞 𝐨𝐫𝐢𝐠𝐢𝐧𝐚𝐥 𝐯𝐨𝐥𝐮𝐦𝐞
=
1
10
x V1
6 April 2022 U.Aravind, Lect/Mech, LAPC
=
1
10
x 1 = 0.1m3
To Find:
• Final Pressure, P2
• Final Temperature, T2
• Work Done, W
Solution:-
I. To Find Final Pressure, P2
Pressure Volume Relationship:
Writing Inversely,
∴ P2 = P1 x
V1
V2
γ
= 100 x
1
0.1
1.41
= 2570.395
66
𝐏𝟏
𝐏𝟐
=
𝐕𝟐
𝐕𝟏
𝛄
6 April 2022 U.Aravind, Lect/Mech, LAPC
𝐏𝟐
𝐏𝟏
=
𝐕𝟏
𝐕𝟐
𝛄
𝐏𝟐 = 2570.395 kN/ 𝐦𝟐
II. To Find Final Temperature, T2
Pressure Volume Relationship:
Writing Inversely,
∴ T2 = T1 x
V1
V2
γ−1
= 313 x
1
0.1
1.41−1
= 804.53
67
𝐓𝟏
𝐓𝟐
=
𝐕𝟐
𝐕𝟏
𝛄−𝟏
6 April 2022 U.Aravind, Lect/Mech, LAPC
𝐓𝟐
𝐓𝟏
=
𝐕𝟏
𝐕𝟐
𝛄−𝟏
𝐓𝟐 = 804.53 K
III. To Find Work done, W
We know :
=
(100 x 1) – (2570.395 x 0.1)
1.41 − 1
= -383.02
68
W =
𝐏𝟏𝐕𝟏−𝐏𝟐𝐕𝟐
𝛄−𝟏
6 April 2022 U.Aravind, Lect/Mech, LAPC
W = -383.02 kJ
7. 0.5 kg of a certain gas occupies 0.3 𝐦𝟑
at 20°C
and 140 kN/𝐦𝟐
and after adiabatic compression to
0.15𝐦𝟑
, the pressure is 370 kN/𝐦𝟐
. Find the value
of gas constant and two specific heats. Take γ = 1.4
Given Data:
•Type of Process:
•Mass of air, m = 0.5 kg
•Initial Volume, V1 = 0.3 m3
•Initial Temperature, T1 = 20°C= 20 + 273 = 293 K
•Initial Pressure, P1 = 140 kN/m2
•Final volume V2 = 0.15 m3
•Final Pressure, P2 = 370 kN/m2
• γ = 1.4 69
Isentropic Process
U.Aravind, Lect/Mech, LAPC
To Find:
•Gas Constant, R
•Specific Heat, CP
•Specific Heat, Cv
Solution:-
I. To Find Gas Constant, R
From Characteristic gas equation :𝐏𝟏𝐕𝟏 = 𝐦𝐑𝐓𝟏
∴ R =
P1V1
mT1
=
140 x 0.3
0.5 x 293
= 0.2866
70
6 April 2022 U.Aravind, Lect/Mech, LAPC
R = 0.2866 kJ/kg.K
II. To Find Specific Heat, 𝐂𝐯
We know :𝐏𝟏𝐕𝟏 = 𝐦𝐑𝐓𝟏
∴ R =
P1V1
mT1
=
140 x 0.3
0.5 x 293
= 0.2866
71
6 April 2022 U.Aravind, Lect/Mech, LAPC
R = 0.2866 kJ/kg.K
6 April 2022 U.Aravind, Lect/Mech, LAPC 72

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Thermal Engineering - I - Unit 1 Thermodynamics Process of Perfect Gases - N Scheme III Sem Diploma Mech

  • 1. 6 April 2022 U.Aravind, Lect/Mech, LAPC 1 Lakshmi Ammal Polytechnic College Department of Mechanical Engineering Subject Code : 4020340 Year & Semester : II / III Scheme : N By… U.Aravind, Lecturer/Mechanical Engineering, LAPC, Kovilpatti.
  • 2. 6 April 2022 U.Aravind, Lect/Mech, LAPC 2 Lakshmi Ammal Polytechnic College Department of Mechanical Engineering Subject Code : 4020340 Subject Name : Thermal Engineering I Year & Semester : II / III Scheme : N Unit : 1 Topic: II. Thermodynamics Processes of Perfect Gases
  • 3. Thermodynamic Processes The Study of thermodynamic process involves the determination of the Work (W) Change in Internal energy (∆U) Change in Entropy (∆S) The amount of heat transferred (Q) 6 April 2022 U.Aravind, Lect/Mech, LAPC 3
  • 4. Thermodynamic Processes •Constant Volume (or) Isochoric Process [V=c] •Constant Pressure (or) Isobaric Process [p=c] •Constant Temperature (or) Isothermal (or) Hyperbolic Process [T=c] •Reversible adiabatic (or) Isentropic Process [pvγ = c] •Polytropic Process [pv𝑛 = c] •Free Expansion Process •Throttling Process 6 April 2022 U.Aravind, Lect/Mech, LAPC 4
  • 5. 6 April 2022 U.Aravind, Lect/Mech, LAPC 5
  • 6. • m kg of gas taken in a Closed Vessel. • It is heated or cooled • Being contained in a closed vessel gas neither expands nor compressed. • So volume remains constant. 6 April 2022 U.Aravind, Lect/Mech, LAPC 6
  • 7. 6 April 2022 U.Aravind, Lect/Mech, LAPC 7
  • 8. 6 April 2022 U.Aravind, Lect/Mech, LAPC 8
  • 9. 6 April 2022 U.Aravind, Lect/Mech, LAPC 9 i) General gas equation : 𝐏𝟏𝐕𝟏 𝐓𝟏 = 𝐏𝟐𝐕𝟐 𝐓𝟐 Apply 𝐕𝟏 = 𝐕𝟐 in to General Gas Equation 𝐏𝟏𝐕𝟏 𝐓𝟏 = 𝐏𝟐𝐕𝟐 𝐓𝟐 𝐏𝟏 𝐓𝟏 = 𝐏𝟐 𝐓𝟐 ii) Heat Transferred(Q) Heat Transferred = mass x specific heat at constant volume x temperature difference Q = m 𝐂𝐯 (T2 – T1) iii) Work done (W) As gas neither expands nor compressed in a closed vessel, so work done is Zero. W = 0
  • 10. 6 April 2022 U.Aravind, Lect/Mech, LAPC 10 iv) Change in Internal Energy (∆U) Change in Internal Energy= mass x specific heat at constant volume x temperature difference ∆U = m 𝐂𝐯 (T2 – T1) (Common for all process) v) By first law of thermodynamics Q = ∆U + W = ∆U + 0 Q= ∆U vi) Change in Entropy (∆S) ∆S = 𝐓𝟏 𝐓𝟐 𝐝𝐐 𝐓 Q = m𝐂𝐯 (T2 – T1) In differentiate form dQ = m𝐂𝐯 dT = 𝐓𝟏 𝐓𝟐 m𝐂𝐯 dT 𝐓 𝟏 𝐱 dx = 𝐥𝐨𝐠𝒆𝒙 = 𝐥𝐧𝐱 ∆S = m𝐂𝐯 ln 𝑻𝟐 𝑻𝟏
  • 11. 6 April 2022 U.Aravind, Lect/Mech, LAPC 11
  • 12. • m kg of gas taken in an engine cylinder. • To maintain constant pressure some weight is placed on the piston. • Gas is heated • It expands and does work on the pressure. 6 April 2022 U.Aravind, Lect/Mech, LAPC 12
  • 13. 6 April 2022 U.Aravind, Lect/Mech, LAPC 13
  • 14. 6 April 2022 U.Aravind, Lect/Mech, LAPC 14
  • 15. 6 April 2022 U.Aravind, Lect/Mech, LAPC 15 i) General gas equation : 𝐏𝟏𝐕𝟏 𝐓𝟏 = 𝐏𝟐𝐕𝟐 𝐓𝟐 Apply 𝐏𝟏 = 𝐏𝟐 in to General Gas Equation 𝐏𝟏𝐕𝟏 𝐓𝟏 = 𝐏𝟐𝐕𝟐 𝐓𝟐 𝐕𝟏 𝐓𝟏 = 𝐕𝟐 𝐓𝟐 ii) Heat Transferred(Q) Heat Transferred = mass x specific heat at constant pressure x temperature difference Q = m 𝐂𝐏 (T2 – T1) iii) Work done (W) Work done = hatched area in PV diagram = height x breadth W = 𝐏𝟏(𝐕𝟐 - 𝐕𝟏)
  • 16. 6 April 2022 U.Aravind, Lect/Mech, LAPC 16 iv) By first law of thermodynamics Q= ∆U + W v) Change in Entropy (∆S) ∆S = 𝐓𝟏 𝐓𝟐 𝐝𝐐 𝐓 Q = m𝐂𝐏 (T2 – T1) In differentiate form dQ = m𝐂𝐏 dT = 𝐓𝟏 𝐓𝟐 m𝐂𝐏 dT 𝐓 𝟏 𝐱 dx = 𝐥𝐨𝐠𝒆𝒙 = 𝐥𝐧𝐱 ∆S = m𝐂𝐏 ln 𝑻𝟐 𝑻𝟏
  • 17. 6 April 2022 U.Aravind, Lect/Mech, LAPC 17
  • 18. • m kg of gas taken in an engine cylinder. • It is heated slowly by source • Temperature may tend to raise. But this is nullified by the expansion of gas. • So the temperature remains constant. 6 April 2022 U.Aravind, Lect/Mech, LAPC 18
  • 19. 6 April 2022 U.Aravind, Lect/Mech, LAPC 19
  • 20. 6 April 2022 U.Aravind, Lect/Mech, LAPC 20
  • 21. 6 April 2022 U.Aravind, Lect/Mech, LAPC 21 i) General gas equation : 𝐏𝟏𝐕𝟏 𝐓𝟏 = 𝐏𝟐𝐕𝟐 𝐓𝟐 Apply 𝐓𝟏 = 𝐓𝟐 in to General Gas Equation 𝐏𝟏𝐕𝟏 𝐓𝟏 = 𝐏𝟐𝐕𝟐 𝐓𝟐 𝐏𝟏𝐕𝟏 = 𝐏𝟐𝐕𝟐 ii) Change in Internal Energy (∆U) ∆U = m 𝐂𝐯 (T2 – T1) 𝐓𝟏 = 𝐓𝟐 ∆U = 0 iii) Change in Enthalpy (∆h) ∆h = m 𝐂𝐏 (T2 – T1) 𝐓𝟏 = 𝐓𝟐 ∆h = 0 iv) By first law of thermodynamics Q = ∆U + W = 0 + W Q = W
  • 22. 6 April 2022 U.Aravind, Lect/Mech, LAPC 22 v) Work done (W) Work done = hatched area in PV diagram = height x breadth W = 𝐏𝟏𝐕𝟏𝐥𝐧 𝐕𝟐 𝐕𝟏 (or) W = mR 𝐓𝟏 ln 𝐕𝟐 𝐕𝟏 vi) Change in Entropy (∆S) ∆S = 𝐓𝟏 𝐓𝟐 𝐝𝐐 𝐓 T is constant = 𝟏 𝐓 𝒅𝑸 𝒅𝒙 = x ∆S = 𝐐 𝐓 = mR 𝐓𝟏ln 𝐕𝟐 𝐕𝟏 𝐓𝟏 ∆S = mR ln 𝐕𝟐 𝐕𝟏
  • 23. 6 April 2022 U.Aravind, Lect/Mech, LAPC 23
  • 24. 6 April 2022 U.Aravind, Lect/Mech, LAPC 24
  • 25. • m kg of gas taken in an engine cylinder. • It is expanded rapidly. • To prevent heat transfer, system is fully covered by insulation. • No heat transfer takes place during the process. • So the entropy of the gas remains constant. 6 April 2022 U.Aravind, Lect/Mech, LAPC 25
  • 26. 6 April 2022 U.Aravind, Lect/Mech, LAPC 26
  • 27. 6 April 2022 U.Aravind, Lect/Mech, LAPC 27 i) Pressure, Volume, Temperature Relation: i) Pressure Volume Relations 𝐏𝟏 𝐏𝟐 = [ 𝐕𝟐 𝐕𝟏 ]𝛄 ii. Temperature Volume Relations 𝐓𝟏 𝐓𝟐 = [ 𝐕𝟐 𝐕𝟏 ]𝛄−𝟏 ii. Temperature Pressure Relations 𝐓𝟏 𝐓𝟐 = [ 𝐏𝟏 𝐏𝟐 ] 𝜸−𝟏 𝜸
  • 28. 6 April 2022 U.Aravind, Lect/Mech, LAPC 28 ii) Heat Transferred(Q) Q = 0 iii) Work done (W) W = 𝑷𝟏𝑽𝟏−𝑷𝟐𝑽𝟐 𝜸−𝟏 iv) Change in Internal Energy (∆U) ∆U = m 𝐂𝐯 (T2 – T1) v) By first law of thermodynamics Q = ∆U + W 0 = ∆U + W ∆U = - W vi) Change in Entropy (∆S) ∆S = 𝐓𝟏 𝐓𝟐 𝐝𝐐 𝐓 Q is 0 ∆S = 𝟎
  • 29. 6 April 2022 U.Aravind, Lect/Mech, LAPC 29
  • 30. 6 April 2022 U.Aravind, Lect/Mech, LAPC 30
  • 31. 6 April 2022 U.Aravind, Lect/Mech, LAPC 31 i) Pressure, Volume, Temperature Relation: i) Pressure Volume Relations 𝐏𝟏 𝐏𝟐 = [ 𝐕𝟐 𝐕𝟏 ]𝒏 ii. Temperature Volume Relations 𝐓𝟏 𝐓𝟐 = [ 𝐕𝟐 𝐕𝟏 ]𝐧−𝟏 ii. Temperature Pressure Relations 𝐓𝟏 𝐓𝟐 = [ 𝐏𝟏 𝐏𝟐 ] 𝒏−𝟏 𝒏
  • 32. 6 April 2022 U.Aravind, Lect/Mech, LAPC 32 ii) Heat Transferred(Q) Q = 𝛄−𝐧 𝛄−𝟏 x W iii) Work done (W) W = 𝐏𝟏𝐕𝟏−𝐏𝟐𝐕𝟐 𝐧−𝟏 iv) Change in Internal Energy (∆U) ∆U = m 𝐂𝐯 (T2 – T1) v) Change in Entropy (∆S) ∆S = 𝛄−𝐧 𝛄−𝟏 mR ln 𝐕𝟐 𝐕𝟏
  • 33. 6 April 2022 U.Aravind, Lect/Mech, LAPC 33
  • 34. 6 April 2022 U.Aravind, Lect/Mech, LAPC 34
  • 35. 6 April 2022 U.Aravind, Lect/Mech, LAPC 35
  • 36. 6 April 2022 U.Aravind, Lect/Mech, LAPC 36
  • 37. Isothermal Process Isentropic Process Temperature is Constant Entropy is Constant Heat Transfer takes place No Heat Transfer takes place Slow Process Fast Process Change in Internal Energy is Zero Change in Internal Energy is not Zero Change in enthalpy is Zero Change in enthalpy is not Zero Ex: Stirling Cycle Ex: Otto cycle 6 April 2022 U.Aravind, Lect/Mech, LAPC 37
  • 38. Problems on Thermodynamic Processes 6 April 2022 U.Aravind, Lect/Mech, LAPC 38
  • 39. Problems on Constant Volume Processes 6 April 2022 U.Aravind, Lect/Mech, LAPC 39
  • 40. 1. Determine the final temperature, external work done, change in internal energy, change in enthalpy, change in entropy in the case of 2kg of gas at 50°C being heated at constant volume until the pressure is doubled. Given Data: • Type of Process: • Mass, m = 2 kg • Initial Temperature, T1 = 50°C = 50 + 273 = 323 K • Pressure is Doubled To Find: • Final Temperature, T2 • Work Done, W • Change in Internal Energy, ∆U • Change in Enthalpy, ∆h • Change in Entropy, ∆S 40 Constant Volume Process 𝐏𝟐= 2 𝑷𝟏 6 April 2022 U.Aravind, Lect/Mech, LAPC
  • 41. Solution:- I. To Find Final Temperature, 𝐓𝟐 From General gas equation : 𝐏𝟏𝐕𝟏 𝐓𝟏 = 𝐏𝟐𝐕𝟐 𝐓𝟐 𝐏𝟏 𝐓𝟏 = 𝐏𝟐 𝐓𝟐 ∴ 𝐓𝟐 = 𝐏𝟐𝐓𝟏 𝐏𝟏 𝑇2 = 2P1x 323 P1 = 646 41 𝐓𝟐 = 646 K 𝐅𝐨𝐫 𝐂𝐨𝐧𝐬𝐭𝐚𝐧𝐭 𝐕𝐨𝐥𝐮𝐦𝐞 𝐏𝐫𝐨𝐜𝐞𝐬𝐬 𝐕𝟏 = 𝐕𝟐 6 April 2022 U.Aravind, Lect/Mech, LAPC
  • 42. II. To Find Work done, W III. To Find Change in Internal Energy, ∆U We Know ∆U = m 𝐂𝐕 (T2 – T1) = 2 x 0.718 (646 - 323) = 463.82 42 W = 0 𝐀𝐬𝐬𝐮𝐦𝐞, CV = 0.718 ∆U = 463.82 kJ 6 April 2022 U.Aravind, Lect/Mech, LAPC
  • 43. IV. To Find Change in Enthalpy, ∆h We Know ∆h = m 𝐂𝐏 (T2 – T1) = 2 x 1.005 (646 - 323) = 649.23 V. To Find Change in Entropy, ∆S We Know ∆S = m𝐂𝐯 ln 𝐓𝟐 𝐓𝟏 = 2 x 0.718 ln 𝟔𝟒𝟔 𝟑𝟐𝟑 = 0.9953 43 𝐀𝐬𝐬𝐮𝐦𝐞, CP = 1.005 ∆𝐡 = 649.23 kJ ∆𝐒 = 0.9953 kJ/K 6 April 2022 U.Aravind, Lect/Mech, LAPC
  • 44. Results:- I. Final Temperature, 𝐓𝟐 = 646 K II. Work done, W = 0 III. Change in Internal Energy, ∆U = 463.82 kJ IV. Change in Enthalpy, ∆h = 649.23 kJ V. Change in Entropy, ∆S = 0.9953 kJ/K 44 6 April 2022 U.Aravind, Lect/Mech, LAPC
  • 45. 2. A Mass of 2.25 kg of nitrogen occupying 1.5𝐦𝟑 is heated from 25°C to 200°C at constant volume. Molecular weight of nitrogen is 28 and universal gas constant is 8.314 KJ/kg.mole.K. Calculate the initial and final pressure of the gas and Change in internal energy and change in entropy. Given Data: • Type of Process: • Mass, m = 2.25 kg • Volume, V1 = V2 = 1.5m3 • Initial Temperature, T1 = 25°C= 25 + 273 = 298 K • Final Temperature, T2 = 200°C= 200 + 273 = 473 K • Molecular Weight, M = 28 • Universal Gas Constant, RU = 8.314 KJ/kg.K To Find: i) Initial Pressure, P1 ii) Final Pressure, P2 iii) `Change in Internal Energy, ∆U iv)Change in Entropy, ∆S 45 Constant Volume Process 6 April 2022 U.Aravind, Lect/Mech, LAPC
  • 46. Solution:- I. To Find Initial Pressure, 𝐏𝟏 From Characteristic gas equation :𝐏𝟏𝐕𝟏 = 𝐦𝐑𝐓𝟏 We have to find R We know R = RU M = 8.314 28 R = 0.2969 ∴ 𝐏𝟏 = 𝐦𝐑𝐓𝟏 𝐕𝟏 = 2.25 x 0.2969 x 298 1.5 = 132.714 46 𝐏𝟏 = 132.714 kN/ 𝐦𝟐 6 April 2022 U.Aravind, Lect/Mech, LAPC
  • 47. II. To Find Final Pressure, 𝐏𝟐 From Characteristic gas equation :𝐏𝟐𝐕𝟐 = 𝐦𝐑𝐓𝟐 ∴ 𝐏𝟐 = 𝐦𝐑𝐓𝟐 𝐕𝟐 = 2.25 x 0.2969 x 473 1.5 = 210.65 III. To Find Change in Internal Energy, ∆U We Know ∆U = m 𝐂𝐕 (T2 – T1) = 2.25 x 0.718 (473-298) = 282.71 47 𝐏𝟐= 210.65 kN/ 𝐦𝟐 𝐀𝐬𝐬𝐮𝐦𝐞, CV = 0.718 ∆U = 282.71 kJ 6 April 2022 U.Aravind, Lect/Mech, LAPC
  • 48. IV. To Find Change in Entropy, ∆S We Know ∆S = m𝐂𝐯 ln 𝐓𝟐 𝐓𝟏 = 2.25 x 0.718 ln 473 298 = 0.7463 Results:- I. Initial Pressure, 𝐏𝟏 = 132.714 kN/ 𝐦𝟐 II. Final Pressure, 𝐏𝟐 = 210.65 kN/ 𝐦𝟐 III. Change in Internal Energy, ∆U =282.71 kJ IV.Change in Entropy, ∆S =0.7463 kJ/K 48 ∆𝐒 = 0.7163 kJ/K 6 April 2022 U.Aravind, Lect/Mech, LAPC
  • 49. Problems on Constant Pressure Process 6 April 2022 U.Aravind, Lect/Mech, LAPC 49
  • 50. 3. A gas whose pressure, volume and temperature are 5 bar, 0.23𝐦𝟑and 185°C respectively has changed its state at constant pressure until its temperature becomes 70°C. Determine (i) Mass (ii) Work done (iii) Change in Internal Energy (iv) Heat Transferred during the process. Take R = 0.29 kJ/kg.K and CP = 1.005 kJ/kg. K Given Data: • Type of Process: • Pressure, P1 = P2 = 5 bar = 5 x 100 = 500 kN/ m2 • Initial Volume, V1 = 0.23 m3 • Initial Temperature, T1 = 185°C= 185 + 273 = 458 K • Final Temperature, T2 = 70°C= 70 + 273 = 343 K • Gas Constant, R = 0.29 KJ/kg.K • CP = 1.005 kJ/kg. K To Find: i) Mass, M ii) Work done, W iii) Change in Internal Energy, ∆U iv) Heat Transferred, Q 50 Constant Pressure Process 6 April 2022 U.Aravind, Lect/Mech, LAPC
  • 51. Solution:- I. To Find Mass, m From Characteristic gas equation :𝐏𝟏𝐕𝟏 = 𝐦𝐑𝐓𝟏 ∴ m = 𝐏𝟏𝐕𝟏 𝐑𝐓𝟏 = 500 x 0.23 0.29 x 458 = 0.8658 II. To Find Change in Internal Energy, ∆U We Know ∆U = m 𝐂𝐕 (T2 – T1) = 0.8658 x 0.718 (343-458) = - 71.19 kJ 51 𝐦 = 𝟎. 𝟖𝟔𝟓𝟖 𝐤𝐠 𝐀𝐬𝐬𝐮𝐦𝐞, CV = 0.718 ∆U = −71.19 kJ 6 April 2022 U.Aravind, Lect/Mech, LAPC
  • 52. III. To Find Heat Transferred, Q We Know Q= m 𝐂𝐏 (T2 – T1) = 0.8658 x 1.005 (343-458) = - 100.064 kJ IV. To Find Work done, W By First law of Thermodynamics Q = ∆U + W ∴ 𝐖 = Q - ∆U = - 100.064 - (-71.19) = -28.874 52 𝐐 = −𝟏𝟎𝟎. 𝟎𝟔𝟒 𝐤𝐉 𝐖 = −28.874 kJ 6 April 2022 U.Aravind, Lect/Mech, LAPC
  • 53. 4. One kg of air at a pressure of 5 bar and volume 0.3𝐦𝟑 and temperature 627°C is supplied with heat at constant pressure till the volume is doubled. Calculate (i) Work done (ii) Change in Internal Energy (iii) Heat Transferred (iv) Change in Entropy (v) Change in Enthalpy. Take R = 0.287 kJ/kg.K and CP = 1.005 kJ/kg. K , Cv = 0.718 kJ/kg. K Given Data: • Type of Process: • Mass of air, m = 1kg • Pressure, P1 = P2 = 9 bar = 9 x 100 = 900 kN/ m2 • Initial Volume, V1 = 0.3 m3 • Initial Temperature, T1 = 627°C= 627 + 273 = 900 K • Volume is Doubled • Gas Constant, R = 0.29 KJ/kg.K • CP = 1.005 kJ/kg. K • Cv = 0.718 kJ/kg. K 53 Constant Pressure Process 𝐕𝟐= 2 𝐕𝟏 = 2 x 0.3 = 0.6 m3 6 April 2022 U.Aravind, Lect/Mech, LAPC
  • 54. To Find: • Final Temperature, T2 • Work Done, W • Change in Internal Energy, ∆U • Change in Entropy, ∆S • Change in Enthalpy, ∆h • Heat Transferred, Q Solution:- I. To Find Final Temperature, 𝐓𝟐 From General gas equation : 𝐏𝟏𝐕𝟏 𝐓𝟏 = 𝐏𝟐𝐕𝟐 𝐓𝟐 𝐕𝟏 𝐓𝟏 = 𝐕𝟐 𝐓𝟐 ∴ 𝐓𝟐 = 𝐕𝟐𝐓𝟏 𝐕𝟏 T2 = 0.6 x 900 0.3 = 1800 54 𝐅𝐨𝐫 𝐂𝐨𝐧𝐬𝐭𝐚𝐧𝐭 𝐏𝐫𝐞𝐬𝐬𝐮𝐫𝐞 𝐏𝐫𝐨𝐜𝐞𝐬𝐬 𝑷𝟏 = 𝑷𝟐 𝐓𝟐 = 𝟏𝟖𝟎𝟎 𝐊 6 April 2022 U.Aravind, Lect/Mech, LAPC
  • 55. II. To Find Work done We know :𝐖 = 𝐏𝟏(𝐕𝟐 - 𝐕𝟏) = 900 (0.6-0.3) = 270 III. To Find Change in Internal Energy, ∆U We Know ∆U = m 𝐂𝐕 (T2 – T1) = 1 x 0.718 (1800-900) = 646.2 55 ∆U = 646.2 kJ W = 𝟐𝟕𝟎 kJ 6 April 2022 U.Aravind, Lect/Mech, LAPC
  • 56. IV. To Find Change in Entropy, ∆S We Know ∆S = m𝐂𝐏 ln 𝐓𝟐 𝐓𝟏 = 1 x 1.005 ln 1800 900 = 0.6969 V. To Find Change in Enthalpy , ∆h We Know ∆h = m 𝐂𝐏 (T2 – T1) = 1 x 1.005 1800 − 900 = 904.5 56 ∆𝐒 = 0.6969 kJ/K ∆𝐡 = 904.5 kJ 6 April 2022 U.Aravind, Lect/Mech, LAPC
  • 57. VI. To Find Heat Transferred, Q We Know Q= m 𝐂𝐏 (T2 – T1) = 1 x 1.005 1800 − 900 = 904.5 57 𝐐 = 904.5 kJ 6 April 2022 U.Aravind, Lect/Mech, LAPC
  • 58. Problems on Constant Temperature Process (or) Isothermal Process 6 April 2022 U.Aravind, Lect/Mech, LAPC 58
  • 59. 5. 0.2 kg of air at a pressure of 1.1 bar and 15°C is compressed to isothermally to a pressure of 5.5 bar. Calculate (i) Initial & Final Volume (ii) Work done (iii) Change in Internal Energy (iv) Heat Rejected (v) Change in Entropy (vi) Change in Enthalpy. Take R = 0.292 kJ/kg.K Given Data: •Type of Process: •Mass of air, m = 0.2 kg •Initial Pressure, P1 = 1.1 bar = 1.1 x 100 = 110 kN/ m2 •Final Pressure, P2 = 5.5 bar = 5.5 x 100 = 550 kN/ m2 •Temperature, T1 = T2 = 15°C= 15 + 273 = 288 K •Gas Constant, R = 0.29 KJ/kg.K 59 Constant Thermal Process 6 April 2022 U.Aravind, Lect/Mech, LAPC
  • 60. To Find: • Initial Volume, V1 • Final Volume, V2 • Work Done, W • Change in Internal Energy, ∆U • Change in Enthalpy, ∆h • Change in Entropy, ∆S • Heat Rejected, Q Solution:- I. To Find Initial Volume, 𝐕𝟏 From Characteristic gas equation :𝐏𝟏𝐕𝟏 = 𝐦𝐑𝐓𝟏 𝐕𝟏 = 𝐦𝐑𝐓𝟏 𝐏𝟏 𝐕𝟏 = 0.2 x 0.292 x 288 110 = 0.1529 60 𝐅𝐨𝐫 𝐂𝐨𝐧𝐬𝐭𝐚𝐧𝐭 𝐓𝐞𝐦𝐩𝐞𝐫𝐚𝐭𝐮𝐫𝐞 𝐏𝐫𝐨𝐜𝐞𝐬𝐬 𝐓𝟏 = 𝐓𝟐 𝐕𝟏 = 𝟎. 𝟏𝟓𝟐𝟗 𝐦𝟑 6 April 2022 U.Aravind, Lect/Mech, LAPC
  • 61. II. To Find Final Volume, 𝐕𝟐 From Characteristic gas equation :𝐏𝟐𝐕𝟐 = 𝐦𝐑𝐓𝟐 𝐕𝟐 = 𝐦𝐑𝐓𝟐 𝐏𝟐 𝐕𝟐 = 0.2 x 0.292 x 288 550 = 0.0305 III. To Find Work done, W We know :W = 𝐏𝟏𝐕𝟏𝐥𝐧 𝐕𝟐 𝐕𝟏 = 110 x 0.1529 ln 0.0305 0.1529 = - 27.113 61 𝐕𝟐 = 𝟎. 𝟎𝟑𝟎𝟓 𝐦𝟑 𝐖 = −27.113 kJ 6 April 2022 U.Aravind, Lect/Mech, LAPC
  • 62. IV. To Find Change in Internal Energy, ∆U We Know ∆U = m 𝐂𝐕 (T2 – T1) = 0.2 x 0.718 (288-288) = 0 V. To Find Change in Enthalpy , ∆h We Know ∆h = m 𝐂𝐏 (T2 – T1) = 0.2 x 1.005 288 − 288 = 0 62 ∆U = 0 ∆𝐡 = 𝟎 6 April 2022 U.Aravind, Lect/Mech, LAPC
  • 63. V. To Find Change in Entropy, ∆S We Know ∆S = m𝐑ln 𝐕𝟐 𝐕𝟏 = 0.2 x 0.292 ln 0.0305 0.1529 = -0.094 VII. To Find Heat Transferred, Q We know :Q = 𝐏𝟏𝐕𝟏𝐥𝐧 𝐕𝟐 𝐕𝟏 = 110 x 0.1529 ln 0.0305 0.1529 = - 27.113 63 ∆𝐒 = −0.094 kJ/K 𝐐 = −27.113 kJ 6 April 2022 U.Aravind, Lect/Mech, LAPC
  • 64. Problems on Adiabatic Process (or) Isentropic Process 6 April 2022 U.Aravind, Lect/Mech, LAPC 64
  • 65. 6. Air at 1 bar and 40°C is compressed to 1/10th original volume isentropically. Calculate Final pressure and Temperature & Work done on 1𝐦𝟑of air. Assume R = 0.287 kJ/kg.K and γ = 1.41 Given Data: •Type of Process: •Mass of air, m = 1kg •Initial Pressure, P1 = 1 bar = 1 x 100 = 100 kN/ m2 •Initial Temperature, T1 = 40°C= 40 + 273 = 313 K •Initial Volume, V1 = 1 m3 •Final volume V2 = •Gas Constant, R = 0.29 KJ/kg.K •γ = 1.41 65 Isentropic Process 1/10th 𝐭𝐡𝐞 𝐨𝐫𝐢𝐠𝐢𝐧𝐚𝐥 𝐯𝐨𝐥𝐮𝐦𝐞 = 1 10 x V1 6 April 2022 U.Aravind, Lect/Mech, LAPC = 1 10 x 1 = 0.1m3
  • 66. To Find: • Final Pressure, P2 • Final Temperature, T2 • Work Done, W Solution:- I. To Find Final Pressure, P2 Pressure Volume Relationship: Writing Inversely, ∴ P2 = P1 x V1 V2 γ = 100 x 1 0.1 1.41 = 2570.395 66 𝐏𝟏 𝐏𝟐 = 𝐕𝟐 𝐕𝟏 𝛄 6 April 2022 U.Aravind, Lect/Mech, LAPC 𝐏𝟐 𝐏𝟏 = 𝐕𝟏 𝐕𝟐 𝛄 𝐏𝟐 = 2570.395 kN/ 𝐦𝟐
  • 67. II. To Find Final Temperature, T2 Pressure Volume Relationship: Writing Inversely, ∴ T2 = T1 x V1 V2 γ−1 = 313 x 1 0.1 1.41−1 = 804.53 67 𝐓𝟏 𝐓𝟐 = 𝐕𝟐 𝐕𝟏 𝛄−𝟏 6 April 2022 U.Aravind, Lect/Mech, LAPC 𝐓𝟐 𝐓𝟏 = 𝐕𝟏 𝐕𝟐 𝛄−𝟏 𝐓𝟐 = 804.53 K
  • 68. III. To Find Work done, W We know : = (100 x 1) – (2570.395 x 0.1) 1.41 − 1 = -383.02 68 W = 𝐏𝟏𝐕𝟏−𝐏𝟐𝐕𝟐 𝛄−𝟏 6 April 2022 U.Aravind, Lect/Mech, LAPC W = -383.02 kJ
  • 69. 7. 0.5 kg of a certain gas occupies 0.3 𝐦𝟑 at 20°C and 140 kN/𝐦𝟐 and after adiabatic compression to 0.15𝐦𝟑 , the pressure is 370 kN/𝐦𝟐 . Find the value of gas constant and two specific heats. Take γ = 1.4 Given Data: •Type of Process: •Mass of air, m = 0.5 kg •Initial Volume, V1 = 0.3 m3 •Initial Temperature, T1 = 20°C= 20 + 273 = 293 K •Initial Pressure, P1 = 140 kN/m2 •Final volume V2 = 0.15 m3 •Final Pressure, P2 = 370 kN/m2 • γ = 1.4 69 Isentropic Process U.Aravind, Lect/Mech, LAPC
  • 70. To Find: •Gas Constant, R •Specific Heat, CP •Specific Heat, Cv Solution:- I. To Find Gas Constant, R From Characteristic gas equation :𝐏𝟏𝐕𝟏 = 𝐦𝐑𝐓𝟏 ∴ R = P1V1 mT1 = 140 x 0.3 0.5 x 293 = 0.2866 70 6 April 2022 U.Aravind, Lect/Mech, LAPC R = 0.2866 kJ/kg.K
  • 71. II. To Find Specific Heat, 𝐂𝐯 We know :𝐏𝟏𝐕𝟏 = 𝐦𝐑𝐓𝟏 ∴ R = P1V1 mT1 = 140 x 0.3 0.5 x 293 = 0.2866 71 6 April 2022 U.Aravind, Lect/Mech, LAPC R = 0.2866 kJ/kg.K
  • 72. 6 April 2022 U.Aravind, Lect/Mech, LAPC 72