The crystal structure and quality of ZnO thin films were enhanced by high temperature vacuum annealing. 150 nm thick ZnO films were deposited on a-plane sapphire substrates by RF sputtering at 600°C and then annealed in situ at temperatures from 700°C to 900°C. Higher annealing temperatures produced smoother films with root mean square roughness reaching 0.3 nm at 850°C. Raman spectroscopy showed the A1(TO) mode at all annealing temperatures and the A1(LO) mode appeared above 800°C, indicating improved crystal quality. X-ray diffraction revealed narrower diffraction peaks and a relaxed lattice constant matching bulk ZnO at 900°C annealing, demonstrating high quality c-axis oriented epit
This is a power point presentation of project work on preparing Zinc oxide thin films by using SILAR technique and CBD technique and studying its characteristics.
Rosa alejandra lukaszew tests of the gurenvich odel toward larger field gra...thinfilmsworkshop
SRF properties are inherently a surface phenomenon involving a material thickness of a few microns thus opening up the possibility of using thin film coatings to achieve a desired performance. I will describe our experimental attempts to test the superconducting/insulating/superconducting (SIS) multilayer model proposed by A. Gurevich [1] to shield the bulk of the cavity from vortex penetration and hence enable larger accelerating fields than presently possible.
This paper reports the effect of the different deposition methods towards the ZnO nanostructure crystal quality and film thickness on the polyimide substrate. The ZnO film has been deposited by using the spray pyrolysis technique, sol-gel and RF Sputtering. Different methods give a different nanostructure of the ZnO thin film. Sol gel methods, results of nanoflowers ZnO thin film with the thickness of thin film is 600nm. It also produces the best of the piezoelectric effect in term of electrical performance, which is 5.0 V and 12 MHz of frequency which is higher than other frequency obtained by spray pyrolysis and RF sputtering.
Preparation and Properties of Nanocrystalline Zinc Oxide Thin Filmsijtsrd
Metal oxide is highly important material which possesses many unique optical and electrical properties for applications in many areas such as Solar cells, Gas sensors and so on. With the development of research and applications of Metal oxide thin films, research results are verified that the morphology of Metal oxide thin films are plays an important role in applications of these films. Variety of morphologies, complex structure has been developed by physical or chemical methods. However the work on controlled growth of these films is still in developing state. Therefore in present work we deposited ZnS and ZnO metal oxides thin films on different substrates by Chemical Bath Deposition Technique. Structural, Surface Morphology and Optical properties of as deposited films were investigated by XRD, SEM, and UV VIS Spectrophotometer. The band gap is also calculated from the equation relating absorption co efficient to wavelength. The band gap indicates the film is transmitting within the visible range and the band gaps changes because of the grain size of the films. We also observed that, the change in preparative parameters affects the deposition rate of thin films. From the observation, it is clear that the growth rate increases as the deposition temperature, increases. S. S. Kawar "Preparation and Properties of Nanocrystalline Zinc Oxide Thin Films" Published in International Journal of Trend in Scientific Research and Development (ijtsrd), ISSN: 2456-6470, Volume-4 | Issue-4 , June 2020, URL: https://www.ijtsrd.com/papers/ijtsrd31623.pdf Paper Url :https://www.ijtsrd.com/physics/nanotechnology/31623/preparation-and-properties-of-nanocrystalline-zinc-oxide-thin-films/s-s-kawar
This is a power point presentation of project work on preparing Zinc oxide thin films by using SILAR technique and CBD technique and studying its characteristics.
Rosa alejandra lukaszew tests of the gurenvich odel toward larger field gra...thinfilmsworkshop
SRF properties are inherently a surface phenomenon involving a material thickness of a few microns thus opening up the possibility of using thin film coatings to achieve a desired performance. I will describe our experimental attempts to test the superconducting/insulating/superconducting (SIS) multilayer model proposed by A. Gurevich [1] to shield the bulk of the cavity from vortex penetration and hence enable larger accelerating fields than presently possible.
This paper reports the effect of the different deposition methods towards the ZnO nanostructure crystal quality and film thickness on the polyimide substrate. The ZnO film has been deposited by using the spray pyrolysis technique, sol-gel and RF Sputtering. Different methods give a different nanostructure of the ZnO thin film. Sol gel methods, results of nanoflowers ZnO thin film with the thickness of thin film is 600nm. It also produces the best of the piezoelectric effect in term of electrical performance, which is 5.0 V and 12 MHz of frequency which is higher than other frequency obtained by spray pyrolysis and RF sputtering.
Preparation and Properties of Nanocrystalline Zinc Oxide Thin Filmsijtsrd
Metal oxide is highly important material which possesses many unique optical and electrical properties for applications in many areas such as Solar cells, Gas sensors and so on. With the development of research and applications of Metal oxide thin films, research results are verified that the morphology of Metal oxide thin films are plays an important role in applications of these films. Variety of morphologies, complex structure has been developed by physical or chemical methods. However the work on controlled growth of these films is still in developing state. Therefore in present work we deposited ZnS and ZnO metal oxides thin films on different substrates by Chemical Bath Deposition Technique. Structural, Surface Morphology and Optical properties of as deposited films were investigated by XRD, SEM, and UV VIS Spectrophotometer. The band gap is also calculated from the equation relating absorption co efficient to wavelength. The band gap indicates the film is transmitting within the visible range and the band gaps changes because of the grain size of the films. We also observed that, the change in preparative parameters affects the deposition rate of thin films. From the observation, it is clear that the growth rate increases as the deposition temperature, increases. S. S. Kawar "Preparation and Properties of Nanocrystalline Zinc Oxide Thin Films" Published in International Journal of Trend in Scientific Research and Development (ijtsrd), ISSN: 2456-6470, Volume-4 | Issue-4 , June 2020, URL: https://www.ijtsrd.com/papers/ijtsrd31623.pdf Paper Url :https://www.ijtsrd.com/physics/nanotechnology/31623/preparation-and-properties-of-nanocrystalline-zinc-oxide-thin-films/s-s-kawar
IOSR Journal of Applied Physics (IOSR-JAP) is an open access international journal that provides rapid publication (within a month) of articles in all areas of physics and its applications. The journal welcomes publications of high quality papers on theoretical developments and practical applications in applied physics. Original research papers, state-of-the-art reviews, and high quality technical notes are invited for publications.
Morphological and Optical Study of Sol-Gel SpinCoated Nanostructured CdSThin ...iosrjce
Nanostructured CdS thin films of different thicknesses were deposited on a cleaned glass substrate
using sol-gel spin coating technique. CdS thin films were prepared using cadmium acetate as cadmium source
and thiourea as sulfur source. The Morphological, chemical composition, and optical properties of the spin- coated
CdS thin film were studied using field emission- scanning electron microscopy (FE-SEM), Energy dispersive X –ray
(EDX) spectroscopy, and a UV-Vis-NIR spectrophotometer.The morphological results revealed that the films consist
of agglomerated spherical CdS nanoparticles with diameter < 20 nm, which distributed uniformly on the substrate
surface.The films show high transmittance > 90% and very strong absorption edge at 295 nm.The absorption edge
shifts towards longer wavelength as the film thickness increased.
Synthesis and characterization of zno thin films deposited by chemical bath t...eSAT Journals
Abstract ZnO thin films have been deposited on silica glass substrate using the chemical bath deposition technique. The precursors used were zinc chloride and aqueous ammonia. The solution was stirred continuously with the help of a magnetic stirrer at a bath temperature of 70 oC and a deposition time of 70 minutes. The elemental composition and the surface morphology were studied using energy dispersive and scanning electron microscopy. The band gap was 2.72, 2.66, 2.60 eV for as-deposited, annealed at 200 oC and 300 oC respectively. There was a red shift in the band gap energy as the annealing temperature was increased. This might be due to an improvement in the crystallinity of the ZnO thin films. Index Terms: Zinc oxide, chemical bath, band gap, annealing
Characterization Studies of CdS Nanocrystalline Film Deposited on Teflon Subs...IJLT EMAS
In this article, different substrates for deposition of
CdS material have been discussed. Till date glass, mica, quartz,
ceramic, etc. are commonly employed substrates in thin film
growth. In the present work, CdS is deposited on Teflon
substrate by chemical bath deposition (CBD) method. Also the
films were deposited on different substrates like glass, copper
and zinc and compared with those prepared on Teflon substrate.
The films prepared on Teflon substrate were uniform, stable and
also showed good radiating property. These films were further
characterized by UV-VIS absorption spectral studies, SEM and
EDS studies.
Influence of Thickness on Electrical and Structural Properties of Zinc Oxide ...paperpublications3
Abstract: Zinc Oxide (ZnO) thin films were prepared on corning (7059) glass substrates at a thickness of 75.5 and 130.5nm by RF sputtering technique. The deposition was carried out at room temperature after which the samples were annealed in open air at 1500C. The electrical and structural properties of these films were studied. The electrical properties of the films were monitored by four-point probe method while the structural properties were studied by X-ray diffraction (XRD). It was found that the electrical resistance of the films decreases with increase in the thickness of the films. The XRD analysis of the films showed that the films have a peak located at 〖34.31^0-34.35〗^0with hkl (002). Other parameters calculated include the stress ( ) and the grain size (D).
An Investigation of SILAR Grown Cobalt Selenide Thin Films IIJSRJournal
Nowadays, several deposition techniques have been used to produce thin film materials. The obtained films were characterized by using different tools. These semiconductor materials could be employed in solar cell, laser devices and opto-electronic devices. The main objective of this work is to produce cobalt selenide thin films through successive ionic layer adsorption and reaction method. Advantages of this method include simple procedures, inexpensive equipment, it does not need expensive vacuum system and high quality substrate. During the deposition process, the films were deposited onto soda lime glass under various anionic bath immersion times. The properties of the films were studied for the first time via field emission scanning electron microscopy (FESEM) and UV-visible spectrophotometer. Based on the FESEM analysis, uniform morphology could be observed for the sample produced for 30 seconds (anionic immersion time). The band gap was about 2.6 eV and the optical transmission increased in the visible region could be detected for these samples.
Dye Sensitized Solar Cells Incorporated with Tio2 -ZnO NanoparticlesScientific Review SR
We demonstrated an improvement in efficiency of Dye sensitized solar cells (DSSCs) decorated with
zinc oxide (ZnO) nanoparticles (NPs) through successive ionic layer adsorption and reaction (SILAR). A series of
ZnO with different SILAR cycles were synthesized on TiO
2 that has been pre-grown on fluorine tin oxide (FTO)
glass slides. The performance of DSSCs containing ZnO NPs was significantly affected. The photovoltaic (PV)
performance decreased with increasing number of SILAR cycles from two SILAR cycles to four SILAR cycles,
the best performance was achieved using the anodes prepared with two SILAR cycles. The best cell shows a
conversion efficiency (η) of 0.0064 %. The cell exhibits ~ 2.13 improvement over the performance (0.0030 %) of
bare FTO-based device. The related PV performance enhancement mechanism is discussed
Enhanced field electron emission of flower like zinc oxide on zinc oxide nano...Suhufa Alfarisa
For the first time, zinc oxide (ZnO) nanoflowers on ZnO nanorods were produced on carbon nanotubes
(CNTs) synthesised from waste cooking palm oil precursor. First, CNTs were grown using thermal chemical vapour deposition method. Next, ZnO nanostructures were deposited using the sonicated sol-gel immersion method
From Design to Production - How to work with UK manufacturersKate Hills
These are the slides from a talk that I did at the Breakthrough in fashion event on Monday 21st March.
They are my top tips for brands looking to source production from UK fashion and textile manufacturers. If you want to find out more then you may want to visit our Meet the Manufacturer event. Go to www.meetthemanufacturer.co.uk for more details.
Presentation given at the International Research-Center Summer School in Cognitive System and Interactive Robotics, Data and content Analysis - Athens 29 July 2014
IOSR Journal of Applied Physics (IOSR-JAP) is an open access international journal that provides rapid publication (within a month) of articles in all areas of physics and its applications. The journal welcomes publications of high quality papers on theoretical developments and practical applications in applied physics. Original research papers, state-of-the-art reviews, and high quality technical notes are invited for publications.
Morphological and Optical Study of Sol-Gel SpinCoated Nanostructured CdSThin ...iosrjce
Nanostructured CdS thin films of different thicknesses were deposited on a cleaned glass substrate
using sol-gel spin coating technique. CdS thin films were prepared using cadmium acetate as cadmium source
and thiourea as sulfur source. The Morphological, chemical composition, and optical properties of the spin- coated
CdS thin film were studied using field emission- scanning electron microscopy (FE-SEM), Energy dispersive X –ray
(EDX) spectroscopy, and a UV-Vis-NIR spectrophotometer.The morphological results revealed that the films consist
of agglomerated spherical CdS nanoparticles with diameter < 20 nm, which distributed uniformly on the substrate
surface.The films show high transmittance > 90% and very strong absorption edge at 295 nm.The absorption edge
shifts towards longer wavelength as the film thickness increased.
Synthesis and characterization of zno thin films deposited by chemical bath t...eSAT Journals
Abstract ZnO thin films have been deposited on silica glass substrate using the chemical bath deposition technique. The precursors used were zinc chloride and aqueous ammonia. The solution was stirred continuously with the help of a magnetic stirrer at a bath temperature of 70 oC and a deposition time of 70 minutes. The elemental composition and the surface morphology were studied using energy dispersive and scanning electron microscopy. The band gap was 2.72, 2.66, 2.60 eV for as-deposited, annealed at 200 oC and 300 oC respectively. There was a red shift in the band gap energy as the annealing temperature was increased. This might be due to an improvement in the crystallinity of the ZnO thin films. Index Terms: Zinc oxide, chemical bath, band gap, annealing
Characterization Studies of CdS Nanocrystalline Film Deposited on Teflon Subs...IJLT EMAS
In this article, different substrates for deposition of
CdS material have been discussed. Till date glass, mica, quartz,
ceramic, etc. are commonly employed substrates in thin film
growth. In the present work, CdS is deposited on Teflon
substrate by chemical bath deposition (CBD) method. Also the
films were deposited on different substrates like glass, copper
and zinc and compared with those prepared on Teflon substrate.
The films prepared on Teflon substrate were uniform, stable and
also showed good radiating property. These films were further
characterized by UV-VIS absorption spectral studies, SEM and
EDS studies.
Influence of Thickness on Electrical and Structural Properties of Zinc Oxide ...paperpublications3
Abstract: Zinc Oxide (ZnO) thin films were prepared on corning (7059) glass substrates at a thickness of 75.5 and 130.5nm by RF sputtering technique. The deposition was carried out at room temperature after which the samples were annealed in open air at 1500C. The electrical and structural properties of these films were studied. The electrical properties of the films were monitored by four-point probe method while the structural properties were studied by X-ray diffraction (XRD). It was found that the electrical resistance of the films decreases with increase in the thickness of the films. The XRD analysis of the films showed that the films have a peak located at 〖34.31^0-34.35〗^0with hkl (002). Other parameters calculated include the stress ( ) and the grain size (D).
An Investigation of SILAR Grown Cobalt Selenide Thin Films IIJSRJournal
Nowadays, several deposition techniques have been used to produce thin film materials. The obtained films were characterized by using different tools. These semiconductor materials could be employed in solar cell, laser devices and opto-electronic devices. The main objective of this work is to produce cobalt selenide thin films through successive ionic layer adsorption and reaction method. Advantages of this method include simple procedures, inexpensive equipment, it does not need expensive vacuum system and high quality substrate. During the deposition process, the films were deposited onto soda lime glass under various anionic bath immersion times. The properties of the films were studied for the first time via field emission scanning electron microscopy (FESEM) and UV-visible spectrophotometer. Based on the FESEM analysis, uniform morphology could be observed for the sample produced for 30 seconds (anionic immersion time). The band gap was about 2.6 eV and the optical transmission increased in the visible region could be detected for these samples.
Dye Sensitized Solar Cells Incorporated with Tio2 -ZnO NanoparticlesScientific Review SR
We demonstrated an improvement in efficiency of Dye sensitized solar cells (DSSCs) decorated with
zinc oxide (ZnO) nanoparticles (NPs) through successive ionic layer adsorption and reaction (SILAR). A series of
ZnO with different SILAR cycles were synthesized on TiO
2 that has been pre-grown on fluorine tin oxide (FTO)
glass slides. The performance of DSSCs containing ZnO NPs was significantly affected. The photovoltaic (PV)
performance decreased with increasing number of SILAR cycles from two SILAR cycles to four SILAR cycles,
the best performance was achieved using the anodes prepared with two SILAR cycles. The best cell shows a
conversion efficiency (η) of 0.0064 %. The cell exhibits ~ 2.13 improvement over the performance (0.0030 %) of
bare FTO-based device. The related PV performance enhancement mechanism is discussed
Enhanced field electron emission of flower like zinc oxide on zinc oxide nano...Suhufa Alfarisa
For the first time, zinc oxide (ZnO) nanoflowers on ZnO nanorods were produced on carbon nanotubes
(CNTs) synthesised from waste cooking palm oil precursor. First, CNTs were grown using thermal chemical vapour deposition method. Next, ZnO nanostructures were deposited using the sonicated sol-gel immersion method
From Design to Production - How to work with UK manufacturersKate Hills
These are the slides from a talk that I did at the Breakthrough in fashion event on Monday 21st March.
They are my top tips for brands looking to source production from UK fashion and textile manufacturers. If you want to find out more then you may want to visit our Meet the Manufacturer event. Go to www.meetthemanufacturer.co.uk for more details.
Presentation given at the International Research-Center Summer School in Cognitive System and Interactive Robotics, Data and content Analysis - Athens 29 July 2014
The Ten slides you need to see to understand the manufacturing recovery in th...John Ashcroft
The Ten slides you need to see to understand the manufacturing recovery in the UK : The Saturday Economist October 2014.
Superstars : Engineering, Automotive, Transport, Aerospace, Marine and Capital Investment; Products;
Steady State : Food, Drink and Utilities e.g. water and energy.
Sectors Recovering : Paper, Plastics, Furniture, Basic Metals;
The Terminals : Textiles, tobacco;
Overall …Still too many sectors, including building products
awaiting recovery.
Developing a social media strategy to enhance your research profileGilles Couzin
These are the slides I used on a workshop given to researchers and doctoral students at the University of Bristol, UK on 17th June 2015.
The aim of this practical 2-hour workshop was to help researchers engage with social media more effectively to support their research and career.
WINNING IN GROWTH CITIES /ACushman & Wakefield Capital Markets Research Publi...Guy Masse
This report has been prepared by the Research and
Capital Markets teams at Cushman & Wakefield to
identify the winning cities in today’s international real
estate investment market. The executive summary
looks at the largest and fastest growing cities in
investment terms and the differences in pricing,
as well as demand and activity between sectors.
Brief summary of Mitch Goodwin's teaching experience between 2004 and 2013. Brief description of his PhD project Dark Euphoria : The Neo Gothic Narrative of MillennialTechnoculture". Practice led reserach outcomes from his recent period of Special Studies Leave.
2015 Manufacturing and Industrials M&A Predictions Cautiously optimisticDeloitte UK
Deloitte examine manufacturing and industrial M&A trends over the last eighteen months. Offering analysis and commentary on themes such as expectations for M&A and changes in strategies.
Based on interviews with senior decision makers at large UK manufacturers, this report aims to explore some of the challenges faced by the manufacturing sector through the analysis of first hand experiences of internationalisation.
Lessons from Jerry Seinfeld to Comedians and PresentersMonkeyBusiness
Presentation with the tips of Jerry Seinfeld for comedians and presenters.
Based on the movie "Comedian: Behind the Scenes of Comedy."
Creative Director: Alexandre Franzolim
Art Director: Fernando Zornoff
Screenplay: Michel Geraissate
Design: Fernando Zornoff
// MonkeyBusiness is an brazilian agency that is specialized in presentations. All our energy is focused on creating memorable slides, which hold the attention of your audience and express your ideas.
MonkeyBusiness
www.monkeybusiness.com.br
www.macacosmebloguem.com.br
www.facebook.com/mkbusiness
www.twitter.com/mkbusiness
A Blessing of unicorns: Edinburgh's Entrepreneurial EcosystemBen Spigel
Edinburgh has one of the strongest entrepreneurial ecosystems in the world, but it remains hidden. This presentation talks about what entrepreneurial ecosystems are, why they matter, and the features of Edinburgh's ecosystem.
Presentation (Dutch): https://www.youtube.com/watch?v=aqcc0C-qBhA
A short presentation in PechaKucha format (20 slides, who are each 20 seconds visible) about Apple HomeKit.
17 Seinfeld Quotes to Inspire your Marketing StrategyWishpond
From puffy shirts to soup nazis, Festivus to yada, yada, yada, Seinfeld gave us some of the most memorable pop-culture moments of the 90s.
In this fun and entertaining Slideshare, we take a look at 17 of the most iconic Seinfeld quotes, and reframe them to inspire your businesses' 2015 marketing strategy.
Grab some pretzels (remember they make you thirsty) and check it out!
The International Journal of Engineering & Science is aimed at providing a platform for researchers, engineers, scientists, or educators to publish their original research results, to exchange new ideas, to disseminate information in innovative designs, engineering experiences and technological skills. It is also the Journal's objective to promote engineering and technology education. All papers submitted to the Journal will be blind peer-reviewed. Only original articles will be published.
The papers for publication in The International Journal of Engineering& Science are selected through rigorous peer reviews to ensure originality, timeliness, relevance, and readability.
EFFECT OF ULTRAVIOLET RADIATION ON STRUCTURAL PROPERTIES OF NANOWIRESijoejournal
Copper nanowires were prepared through electrochemical template synthesis using Nucleopore polycarbonate membranes having nominal pore sizes of 800nm and 15nm diameter. The 800nm and 15nm nanowires thus grown were viewed under SEM and TEM respectively, while their FCC crystallographic structure was confirmed through X-ray and electron diffraction patterns. The X-ray diffraction peaks indicated strong texturing for (200). The texturing was found to reduce significantly upon exposure to ultraviolet radiation.
Effect of Temperature on Structural, Morphological and Optical Properties of ...RSIS International
The Pure zinc oxide (ZnO) thin films of different substrate temperature have been prepared on well cleaned glass substrate by improved spray pyrolysis technique. The gross structure of the annealed films have been examined by X- ray diffraction (XRD) technique using powder X- ray diffractometer which reveals the enhancement of crystallinity with increase in the deposition temperature. Surface morphology of the synthesized ZnO thin films have been analyzed by means of atomic force microscopy (AFM) which reveals average particle size of as synthesize ZnO thin films has been found to be 79 nm. The band gap as deposited ZnO have been examined by UV-Vis spectroscopy carried out in absorption mode by Double Beam UV- VIS Spectrophotometer with radiations in the range of 훌= 190 nm to 1100 nm which is in the range of 3.03 eV to 3.16 eV.
Characterization of Manganese doped ZnO (MZO) thin films by Spin Coating Tech...IOSR Journals
Doping is a widely used to improve the structural and optical properties of semiconductors. However deposition route is also very important to get nanostructure with different properties. ZnO nanostructures doped with Mn having 5% doping concentrations by weight percentage have been synthesized in the laboratory using Spin coating technique. Scanning Electron Microscope (SEM) image shows the around one millimeter and X-ray diffractometer studies shows that the average diameter of the particles is 25 nm. From the UV-Vis studies the annealing temperature increases the crystal size decreases and the bandgap values increases accordingly.
Fabrication and characterization of nickelijoejournal
This paper shows that nickel nanowires of length 11μm and diameters 800 and 15nm were grown within
the pores of nuclear track polycarbonate membrane by electrodepositing nickel. Surface morphology and
crystallographic structure of the deposited nanowires was investigated using SEM, TEM and XRD
respectively. It is found that low current density gives good result, while high current density leads to the
formation of curled nanowires. Fabricated nanowires were further investigated for electrical properties
and found that nanowires obey ohm’s law. Through structural characterization it has been observed that
the fabricated nanowires posses FCC lattice structure.
EFFECT OF ZN CONCENTRATION ON STRUCTURAL AND OPTICAL PROPRIETIES OF ZNO THIN ...AEIJjournal2
ZnO thin film were deposited by spray pyrolysis on glass substrates, using zinc nitrate as precursor with
different molar concentrations varying from 0.05M to 0.2 M. To study the structural proprieties of the film ,
the different technique was used as the X-ray diffraction, atomic force microscopy (AFM), Raman
scattering , and FTIR . The optical properties were explored by transmission, reflectivity and
Photoluminescence techniques. The ZnO thin films obtained in this paper are polycrystallines, the grain
size increases when the molar concentration of Zn precursor was increasing. The films are transparent in
visible region, this transmission values decreases when the molar concentration increase caused by the
increasing of surface roughness
Effect of Zn Concentration On Structural and Optical Proprieties Of ZNO Thin ...AEIJjournal2
ZnO thin film were deposited by spray pyrolysis on glass substrates, using zinc nitrate as precursor with
different molar concentrations varying from 0.05M to 0.2 M. To study the structural proprieties of the film ,
the different technique was used as the X-ray diffraction, atomic force microscopy (AFM), Raman
scattering , and FTIR . The optical properties were explored by transmission, reflectivity and
Photoluminescence techniques. The ZnO thin films obtained in this paper are polycrystallines, the grain
size increases when the molar concentration of Zn precursor was increasing. The films are transparent in
visible region, this transmission values decreases when the molar concentration increase caused by the
increasing of surface roughness
Potentiostatic Deposition of ZnO Nanowires: Effect of Applied Potential and Z...IJRES Journal
In this work we report on potentiostatic deposition of Zinc oxide (ZnO) nanowires on fluorine-doped tin oxide (FTO) covered glass substrates from electroreduction of molecular oxygen. The influence of applied deposition potential, and the concentrations of zinc precursor (ZnCl2) on the properties of ZnO nanowires was investigated.SEM results revealed that ZnO nanowires electrodeposited at applied potential -0.85Vhave high density and good alignment. The diameters and densities of the electrodeposited ZnO nanowires are strongly dependent on the zinc ion concentrations and well aligned nanowires with uniform diameter can be obtained when the concentration of zinc ions is between 0.5 mM and 1 mM.
An Research Article on Fabrication and Characterization of Nickel Oxide Coate...ijtsrd
In this paper we have produced NiO thin film based solar cells. The NiO thin film was then studied for their structural, optical and electrical properties. By the help of these results we have capable to know about the structure of NiO the phase purity of the thin film X ray diffraction XRD pattern of NiO showed the diffraction planes corresponding to cubic phase respectively. The optical properties showed that with the increase in the deposition time of NiO the energy band gap varied between 3.1 to 3.24 eV. In the end, IV characteristics of the thin films were obtained by the help of matlab in the presence of light as will as dark region. Vijay Aithekar "An Research Article on Fabrication and Characterization of Nickel Oxide Coated Solar Cell" Published in International Journal of Trend in Scientific Research and Development (ijtsrd), ISSN: 2456-6470, Volume-3 | Issue-5 , August 2019, URL: https://www.ijtsrd.com/papers/ijtsrd25300.pdfPaper URL: https://www.ijtsrd.com/physics/nanotechnology/25300/an-research-article-on-fabrication-and-characterization-of-nickel-oxide-coated-solar-cell/vijay-aithekar
Effect of Sn Doping on Structural and Electrical Properties of ZnO Thin Films...journal ijrtem
Abstract: Un-doped and tin (Sn) doped ZnO films were deposited on heated glass substrates by chemical spray pyrolysis method
(CSP). The effect of Sn concentration on the structural, surface morphological and electrical properties of the SnO2 films was
investigated. XRD analyses showed that the obtained films are polycrystalline in nature with hexagonal structure with preferred
orientation of (101). Doping with tin (Sn) causes increase in the grain size. Atomic force microscopy images showed that the root
mean square of the average surface roughness's varied from (1.48 to 3.58) as dopant concentration increased from 0 to 5 wt.%. The
electrical properties of the Sn ZnO films were strongly influenced by doping concentration. The electrical resistance of the films was
sharply decreased as dopant concentration increased.
Keywords: (ZnO) thin films, Sn Doping, Structural and electrical Properties
Studies on in-Doped Zno Transparent Conducting thin FilmsIJRESJOURNAL
ABSTRACT: In this manuscript we have investigated the influences of indium dopants on zinc oxide (ZnO) thin films regarding physico-chemical properties for application in modern conducting devices. As a starting material, Indium (III) chloride, and Zn(CH3COO)2⋅2H2O were used. The complex TSDC spectrum was obtained by submitting the sample to a constant electrical field Ep = 10M V/m during 2 min at a varing polarization temperature of Tmax = 1500C. A minimal sheet resistance with electrical resistivity as low in the range of 10-3 Ω·cm was found for this thin film.
Synthesis Of Nanostructured TiO2 Thin Films By Pulsed Laser Deposition (PLD) ...sarmad
Sarmad Sabih Al-Obaidi
Ali Ahmed Yousif
Abstract
In this work, nanostructured TiO2 thin films were grown by pulsed laser deposition (PLD) technique on glass substrates. TiO2 thin films then were annealed at 400-600 °C in air for a period of 2 hours. Effect of annealing on the structural and morphological were studied. Many growth parameters have been considered to specify the optimum conditions, namely substrate temperature (300 °C), oxygen pressure (10-2 Torr), laser fluence energy density (0.4 J/cm2), using double frequency Q-switching Nd:YAG laser beam (wavelength 532nm), repetition rate (1-6 Hz) and the pulse duration of 10 ns. The results of the X-ray test show that all nanostructures tetragonal are polycrystalline. These results show that grain size increase from 19.5 nm to 29.5 with the increase of annealing temperature. The XRD results also reveal that the deposited thin film, annealed at 400 °C of TiO2 have anatase phase. Thin films annealed at 500 °C and 600 °C have mixed anatase and rutile phases. Full Width at Half Maximum (FWHM) values of the (101) peaks of these films decrease from 0.450° to 0.301° with the increase of annealing temperature. Surface morphology of the thin films have been studied by using atomic force microscopes (AFM). AFM measurements confirmed that the films have good crystalline and homogeneous surface. The Root Mean Square (RMS) value of thin films surface roughness are increased with the increase of annealing temperature.
الخلاصة
على (PLD) النانویة بوساطة تقنیة ترسیب اللیزر النبضي (TiO في ھذا البحث، تم انماء أغشیة اوكسید التیتانیوم ( 2
الرقیقة من 400 الى 600 درجة مئویة في الھواء مدة ساعتین . ودرس تأثیر TiO قواعد زجاجیة. ومن ثم لدنت أغشیة 2
التلدین في الخصائص التركیبیة والطبوغرافیة. عوامل عدیدة لأنماء الأغشیة اخذت بنظر الاعتبار لتحدید الحالة المثلى مثل
0.4 ) باستخدام J/cm 10-2 ) ،كثافة طاقة الفیض اللیزري( 2 Torr) 300 ) ،ضغط الأوكسجین ºC) درجة حرارة القاعدة
532 بمعدل تكراریة - 1 nm التردد المضاعف للیزر النیدیمیوم- یاك الذي یعمل بتقنیة عامل النوعیة عند الطول الموجي
6 ھرتز) وامد نبضة 10 نانوثانیة. تظُھر نتائج فحوصات الأشعة السینیة أن جمیع التراكیب النانویة رباعیة متعددة )
التبلور. وان ھذه النتائج تظھر زیادة في حجم الحبیبات من 19.5 نانومتر الى 29.5 نانومترمع زیادة درجة حرارة التلدین.
نتائج الأشعة السینیة اظھرت ایضا ان الغشاء المرسب والملدن في 400 درجة مئویة لثنائي اوكسید
Annealing and Microstructural Characterization of Tin-Oxide Based Thick Film ...Anis Rahman
Abstract. The sheet resistance of tin oxide based thick-film resistors exhibits two regions of temperature dependence,
described by hopping (23°C-200°C) and diffusion mechanisms (200°C-350°C), respectively.
Annealing these samples causes the sheet resistance to increase in both regions. In the post-annealed samples,
the hopping conduction range is extended by 50°C (23°C-250°C) while the hopping parameter, To, is decreased by
more than 50%. The activation energy of diffusion (0.60 eV) is the same for both pre- and post annealed samples, but
the magnitude of resistance in the diffusion controlled region is increased significantly as a result of annealing. These
changes are explained in terms of a net decrease in the concentration of tin ions in the glass matrix. From a careful
microstructural study it was found that a conduction path composed of tin-oxide grains or their clusters in contact
with each other does not exist in the present system. HREM micrographs showed the presence of nanocrystalline
tin-oxide particles in the glass phase separating the tin-oxide grain clusters. Estimated average separation between
the nanocrystals in 4 nm, consistent with a variable-range hopping conduction via the dissolved tin ions in the glass
matrix.
Courier management system project report.pdfKamal Acharya
It is now-a-days very important for the people to send or receive articles like imported furniture, electronic items, gifts, business goods and the like. People depend vastly on different transport systems which mostly use the manual way of receiving and delivering the articles. There is no way to track the articles till they are received and there is no way to let the customer know what happened in transit, once he booked some articles. In such a situation, we need a system which completely computerizes the cargo activities including time to time tracking of the articles sent. This need is fulfilled by Courier Management System software which is online software for the cargo management people that enables them to receive the goods from a source and send them to a required destination and track their status from time to time.
Welcome to WIPAC Monthly the magazine brought to you by the LinkedIn Group Water Industry Process Automation & Control.
In this month's edition, along with this month's industry news to celebrate the 13 years since the group was created we have articles including
A case study of the used of Advanced Process Control at the Wastewater Treatment works at Lleida in Spain
A look back on an article on smart wastewater networks in order to see how the industry has measured up in the interim around the adoption of Digital Transformation in the Water Industry.
Industrial Training at Shahjalal Fertilizer Company Limited (SFCL)MdTanvirMahtab2
This presentation is about the working procedure of Shahjalal Fertilizer Company Limited (SFCL). A Govt. owned Company of Bangladesh Chemical Industries Corporation under Ministry of Industries.
Event Management System Vb Net Project Report.pdfKamal Acharya
In present era, the scopes of information technology growing with a very fast .We do not see any are untouched from this industry. The scope of information technology has become wider includes: Business and industry. Household Business, Communication, Education, Entertainment, Science, Medicine, Engineering, Distance Learning, Weather Forecasting. Carrier Searching and so on.
My project named “Event Management System” is software that store and maintained all events coordinated in college. It also helpful to print related reports. My project will help to record the events coordinated by faculties with their Name, Event subject, date & details in an efficient & effective ways.
In my system we have to make a system by which a user can record all events coordinated by a particular faculty. In our proposed system some more featured are added which differs it from the existing system such as security.
NO1 Uk best vashikaran specialist in delhi vashikaran baba near me online vas...Amil Baba Dawood bangali
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Cosmetic shop management system project report.pdfKamal Acharya
Buying new cosmetic products is difficult. It can even be scary for those who have sensitive skin and are prone to skin trouble. The information needed to alleviate this problem is on the back of each product, but it's thought to interpret those ingredient lists unless you have a background in chemistry.
Instead of buying and hoping for the best, we can use data science to help us predict which products may be good fits for us. It includes various function programs to do the above mentioned tasks.
Data file handling has been effectively used in the program.
The automated cosmetic shop management system should deal with the automation of general workflow and administration process of the shop. The main processes of the system focus on customer's request where the system is able to search the most appropriate products and deliver it to the customers. It should help the employees to quickly identify the list of cosmetic product that have reached the minimum quantity and also keep a track of expired date for each cosmetic product. It should help the employees to find the rack number in which the product is placed.It is also Faster and more efficient way.
Hybrid optimization of pumped hydro system and solar- Engr. Abdul-Azeez.pdffxintegritypublishin
Advancements in technology unveil a myriad of electrical and electronic breakthroughs geared towards efficiently harnessing limited resources to meet human energy demands. The optimization of hybrid solar PV panels and pumped hydro energy supply systems plays a pivotal role in utilizing natural resources effectively. This initiative not only benefits humanity but also fosters environmental sustainability. The study investigated the design optimization of these hybrid systems, focusing on understanding solar radiation patterns, identifying geographical influences on solar radiation, formulating a mathematical model for system optimization, and determining the optimal configuration of PV panels and pumped hydro storage. Through a comparative analysis approach and eight weeks of data collection, the study addressed key research questions related to solar radiation patterns and optimal system design. The findings highlighted regions with heightened solar radiation levels, showcasing substantial potential for power generation and emphasizing the system's efficiency. Optimizing system design significantly boosted power generation, promoted renewable energy utilization, and enhanced energy storage capacity. The study underscored the benefits of optimizing hybrid solar PV panels and pumped hydro energy supply systems for sustainable energy usage. Optimizing the design of solar PV panels and pumped hydro energy supply systems as examined across diverse climatic conditions in a developing country, not only enhances power generation but also improves the integration of renewable energy sources and boosts energy storage capacities, particularly beneficial for less economically prosperous regions. Additionally, the study provides valuable insights for advancing energy research in economically viable areas. Recommendations included conducting site-specific assessments, utilizing advanced modeling tools, implementing regular maintenance protocols, and enhancing communication among system components.
Explore the innovative world of trenchless pipe repair with our comprehensive guide, "The Benefits and Techniques of Trenchless Pipe Repair." This document delves into the modern methods of repairing underground pipes without the need for extensive excavation, highlighting the numerous advantages and the latest techniques used in the industry.
Learn about the cost savings, reduced environmental impact, and minimal disruption associated with trenchless technology. Discover detailed explanations of popular techniques such as pipe bursting, cured-in-place pipe (CIPP) lining, and directional drilling. Understand how these methods can be applied to various types of infrastructure, from residential plumbing to large-scale municipal systems.
Ideal for homeowners, contractors, engineers, and anyone interested in modern plumbing solutions, this guide provides valuable insights into why trenchless pipe repair is becoming the preferred choice for pipe rehabilitation. Stay informed about the latest advancements and best practices in the field.
Automobile Management System Project Report.pdfKamal Acharya
The proposed project is developed to manage the automobile in the automobile dealer company. The main module in this project is login, automobile management, customer management, sales, complaints and reports. The first module is the login. The automobile showroom owner should login to the project for usage. The username and password are verified and if it is correct, next form opens. If the username and password are not correct, it shows the error message.
When a customer search for a automobile, if the automobile is available, they will be taken to a page that shows the details of the automobile including automobile name, automobile ID, quantity, price etc. “Automobile Management System” is useful for maintaining automobiles, customers effectively and hence helps for establishing good relation between customer and automobile organization. It contains various customized modules for effectively maintaining automobiles and stock information accurately and safely.
When the automobile is sold to the customer, stock will be reduced automatically. When a new purchase is made, stock will be increased automatically. While selecting automobiles for sale, the proposed software will automatically check for total number of available stock of that particular item, if the total stock of that particular item is less than 5, software will notify the user to purchase the particular item.
Also when the user tries to sale items which are not in stock, the system will prompt the user that the stock is not enough. Customers of this system can search for a automobile; can purchase a automobile easily by selecting fast. On the other hand the stock of automobiles can be maintained perfectly by the automobile shop manager overcoming the drawbacks of existing system.
Vaccine management system project report documentation..pdfKamal Acharya
The Division of Vaccine and Immunization is facing increasing difficulty monitoring vaccines and other commodities distribution once they have been distributed from the national stores. With the introduction of new vaccines, more challenges have been anticipated with this additions posing serious threat to the already over strained vaccine supply chain system in Kenya.
Forklift Classes Overview by Intella PartsIntella Parts
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Ultra smooth and lattice relaxed zn o thin films [eid]
1. Superlattices and Microstructures 73 (2014) 268–274
Contents lists available at ScienceDirect
Superlattices and Microstructures
journal homepage: www.elsevier. com/locate/superlattices
Ultra-smooth and lattice relaxed ZnO thin films
A.N. Fouda a,⇑, El Shazly M. Duraia a,b,⇑, E.A. Eid c
a Physics Department, Faculty of Science, Suez Canal University, 41522 Ismailia, Egypt
b Texas State University-San Marcos, Department of Chemistry and Biochemistry, 601 University Dr., San Marcos, TX 78666, USA
c Department of Basic Science, Higher Technological Institute, 44629 10th of Ramadan City, Egypt
a r t i c l e i n f o
Article history:
Received 24 April 2014
Received in revised form 3 May 2014
Accepted 6 May 2014
Available online 5 June 2014
Keywords:
Zinc oxide thin films
Vacuum annealing
Lattice relaxation
Raman spectroscopy
a b s t r a c t
The crystal structure and quality of ZnO thin films were enhanced
by high temperature vacuum annealing. High quality ZnO thin
films have been grown on a-plane sapphire substrate by radio
frequency (rf) magnetron sputtering method at a substrate
temperature of 600 C. A remarkable improvement in the epilayer
quality were established by in situ high temperature annealing.
The film quality, smoothness, the in plane stress, and the degree
of epitaxy of the films have been evaluated. The crystalline quality
was investigated by X-ray diffraction (XRD), scanning electron
microscopy (SEM), atomic force microscopy (AFM) and Raman
spectroscopy analyses. An extremely smooth ZnO films were
achieved at higher annealing temperatures with root mean square
roughness of 0.3 nm. The transverse optical mode A1(TO) observed
in all the samples and the longitudinal optical mode A1(LO)
appeared only at higher annealing temperatures over 800 C in
the micro-Raman scattering measurements. The strain of c-axis
were relaxed and the lattice parameter was comparable to that
of bulk ZnO at high annealing temperature of 900 C.
2014 Elsevier Ltd. All rights reserved.
1. Introduction
Zinc oxide has a wide band gap of 3.37 eV at room temperature. It has a potentially useful
properties including chemical stability, non-toxic (environmental friendly), catalytic activity,
⇑ Corresponding authors. Present address: Texas State University-San Marcos, Department of Chemistry and Biochemistry,
601 University Dr., San Marcos, TX 78666, USA. Tel.: +1 512 557 1495 (E.S.M. Duraia).
E-mail addresses: duraia_physics@yahoo.com, ed24@txstate.edu (E.S.M. Duraia).
http://dx.doi.org/10.1016/j.spmi.2014.05.022
0749-6036/ 2014 Elsevier Ltd. All rights reserved.
2. A.N. Fouda et al. / Superlattices and Microstructures 73 (2014) 268–274 269
piezoelectricity, low cost in production, commercial availability of large area single crystal ZnO sub-strates,
and bio-compatibility [1,2]. ZnO has a wide range of applications like gas sensors, photo-cat-alysts,
transparent electrodes, dilute magnetic semiconductors (DMS), photo-detectors, microsensors,
window layer for solar cells, and active channel layer of transparent thin film transistor (TTFT) wave-guides,
surface acoustic wave devices, and ultra-violet/blue emission devices [3,4].
Light emitting diodes and lasing development have been focused on GaN with exciton binding
energy of 24 meV. However, ZnO is more efficient emitter and promising in optoelectronic applica-tions
than GaN [5]. ZnO has a large exciton binding energy of 59 meV and the major challenge for
ZnO in optoelectronic device applications is the production of good quality and wide area ZnO films
by low cost method [6]. Based on Bose–Einstein condensation, Zamfirescu et al. proposed a model
for ZnO microcavity structure with a promising exciton oscillating strength toward the fabrication
of exciton–polariton laser in ZnO [7].
The epitaxial growth of ZnO have been conducted by a variety of methods, such as pulsed laser
deposition PLD [8], laser assisted molecular beam epitaxy L-MBE [9], plasma assisted MBE [10],
MBE [11], chemical vapor deposition CVD [12], MOCVD [13] chemical spraying [14], sol gel [15],
ion beam deposition [16] and sputtering [17–21]. Among these, sputtering method can produce wide
area films with controlled composition economically. However, the film quality and roughness do not
match the requirements of optoelectronic devices. Epitaxial growth of ZnO films can be established on
different kind of substrates like ZnO [22], GaN [11], AlN [23], ScAlMgO4 [5] and Al2O3 [24]. Al2O3 is one
of the most extensively adopted substrates for the growth of ZnO epilayers because of its hexagonal
symmetry, low cost and commercial availability. Many researchers try to grow high quality ZnO films
on sapphire substrate. Lin et al. [25] succeeded in the growth of high quality ZnO films on c-plane sap-phire
substrate without a buffer layer. However, for epitaxially grown (0001) ZnO on (0001) Al2O3
defects are easily generated, because of the large lattice mismatch 18.4% which decreases to 0.08%
for (0001) ZnO grown on (11–20) Al2O3 [26].
In the present paper, high quality ZnO films were grown by rf magnetron sputtering on a-plane
sapphire substrate. The influence of high temperature vacuum annealing on the epilayer quality,
microstructure and crystalline perfection has been investigated. We try to find out the optimum
growth and heat treatment conditions.
2. Experimental
150 nm thick ZnO thin films were deposited by rf magnetron sputtering, using radio frequency
source (RF, 13.56 MHz). High purity ZnO target (99.999) with 5.1 diameter has been used. Growth
temperature of 600 C were established by SiC heater. The films deposited at a bias voltage of
350 V, working pressure of 5 104 Torr, background pressure of 2 106 Torr and radio frequency
power of 700 W. High purity Ar (99.999), O2 (99.9999) with Ar to O2 ratio of (Ar/O2 = 4/1) were used.
Ar and O2 flow were controlled by mass flow controller. Pre-sputtering was performed to remove con-taminations
on the target. Smooth a-plane sapphire substrate were cleaned using organic solvents,
rinsed in DI-water and baking in high vacuum at 750 C before deposition. The smoothness of the sub-strate
is shown in Fig. 2e. In situ high temperature vacuum annealing of (0001) ZnO films was carried
out for an hour at 700 C, 800 C, 850 C and 900 C respectively.
The film thickness were measured using the cross-section profile of scanning electron microscopy
(Model JEOL JSM-840). XRD measurements were performed by using Burker-D8 diffractometer with
Cu Ka radiation. In non-contact mode, AFM was used to study the roughness and surface morphology
of the deposited films. The characterizations were extended by Raman spectroscopy measurements at
room temperature. Micro-Raman spectroscopy system (Model Renishaw system 2000) with Ar+ laser
at wavelength of 488 nm with power of 100 mW has been used to investigate the local vibration
modes from ZnO epilayers grown on a-plane sapphire substrates.
3. Results and discussion
SEM has been used to investigate the film thickness. Fig. 1 depicts the side view of the film at dif-ferent
locations. The growth rate was 73 nm/h and it can be seen that, the thickness of the grown films
3. 270 A.N. Fouda et al. / Superlattices and Microstructures 73 (2014) 268–274
Fig. 1. Side view of SEM image for c-plane ZnO on a-plane sapphire substrate.
was around 150 nm. The sharpness of the interface between film and substrate indicate the unifor-mity,
smoothness and homogeneity of the grown films.
Fig. 2 shows AFM images for the films annealed at 700 C (Fig. 2a), 800 C (Fig. 2b), 850 C (Fig. 2c),
and 900 C (Fig. 2d), respectively. Small grains can be observed in little rough surface in Fig. 2a and b
for the vacuum annealed films at 700 C and 800 C. In addition, with increasing the annealing tem-perature,
coalescence process of grains is extended. Atomically clearly flat ZnO epilayers exhibiting
z-axis height less than 3 nm were conducted and RMS value decreases to 0.3 nm. The variation of
RMS values with annealing temperature is shown in Fig. 2f. RMS values regularly decrease with
increasing the annealing temperature up to 850 C and the increment at 900 C is related to the for-mation
of intermediate hexagonal pits. Small typically hexagonal pits were observed for the films
annealed at 900 C, which illustrate the backing of ZnO on a nearly lattice matched substrate [26].
The formation of similar hexagonal pits was also reported by Wang et al. for ZnO films grown by
MBE [27]. The obtained small roughness is so much smaller than the values reported for sputtered
ZnO films [18–21] and even comparable to high quality films grown by MBE [11] and PLD [8]. To
our knowledge, this is one from the best result reported for sputtered ZnO films on sapphire
substrates. Such enhancement was attributed to the fact that thermal annealing enhances the mass
transport and coalescence of adjacent grains [28] besides selecting the optimum preparation
conditions on a smooth a-plane sapphire substrate as shown in Fig. 2e.
Micro-Raman measurements have been carried out to investigate the nature of crystalline quality.
Wurtzite ZnO belongs to the C6v symmetry group. According to the well-known selection rules, there
are the Raman active phonon modes E2(low), E2(high), A1(TO), A1(LO), E1(TO), and E1(LO). The E2
modes and the A1(LO) mode are expected to be observed in un polarized Raman spectra [29]. Fig. 3
represents the room temperature Raman spectrum of ZnO films at different annealing temperatures
and Optical surface images for the spots of incidence. From the figure, one can see that; The transverse
optical mode A1(TO) appears at 380 cm1 for all the samples. While the longitudinal optical mode
A1(LO) at 576 cm1 appears only at higher annealing temperatures over 800 C. The disappearance
of E1(LO) in all samples indicates that our samples have little defects such as Zn interstitials, oxygen
vacancies, and the free carrier lack [30,31]. The other peaks at 417, 650 and 750 cm1 are attributed to
the Al2O3 substrate [32,33]. The peaks are slightly asymmetric and broadening, this is due to the quan-tum
confinement of the phonons. Therefore, the contribution to the Raman spectrum will not only
from the phonons of Brillouin zone center but also from the other phonons that is confined due to
the nanoscale effect [34]. The low intensity E2 at 430 cm1 indicates the small stress due to the
difference in the thermal coefficients between sapphire and zinc oxide [35].
h–2h scan for ZnO thin films annealed at 700 C, 800 C, 850 C and 900 C are shown in Fig. 4a. The
dominant diffraction peak in all scans is the (0002) peak beside the substrate (11–20) Al2O3 peak.
(0002) ZnO peak arises from diffraction from basal ZnO planes with c-axis perpendicular to the sub-strate.
The sharpness and symmetric nature of the peak confirm the quality of the epilayers. FWHM
4. A.N. Fouda et al. / Superlattices and Microstructures 73 (2014) 268–274 271
2.5
2.0
1.5
1.0
0.5
decreases with increasing the annealing temperature and for the films annealed at 900 C, (0002) ZnO
peak with FWHM of 0.0672 was observed in Fig. 4a. No reflections corresponding to other planes
were observed except (0002) ZnO which is very symmetric. This indicates the absence of any other
phases. The sharpness of ZnO (0002) reflection shows a good c-axis orientation perpendicular to
a-plane sapphire substrate without the well-known rotation by 30 which ZnO films exhibited on
c-plane sapphire substrate [25,26]. x scan for the films annealed at 900 C is shown in Fig. 4b. The
value of FWHM for rocking curve scan has a very small value of 0.0026, implying the ordering and
little tilt in c-plane.
Fig. 5 shows the lattice constant obtained from ZnO (0002) reflection in comparison with bulk ZnO
lattice constant. A well identified lattice relaxation by high temperature annealing were confirmed.
This implies that the film was relaxed by increasing the annealing temperature and the lattice con-stant
is comparable to bulk ZnO [4]. High temperature annealing enhances the quality and orientation
of the grown ZnO epilayers.
700 750 800 850 900
0.0
RMS VALUE (nm)
ANNEALING
TEMPERATURE (°C)
a b
c d
e
1nm
0nm
f
Fig. 2. AFM images (2 lm 2 lm) and cross-sectional height profiles of atomically smooth ZnO films grown on a-plane
sapphire substrates which annealed at (a) 700 C, (b) 800 C, (c) 850 C and (d) 900 C. (e) AFM for the used smooth a-plane
sapphire substrate. (f) Graphical representation of annealing temperature dependence of RMS values for ZnO epilayers.
5. 272 A.N. Fouda et al. / Superlattices and Microstructures 73 (2014) 268–274
TA= 850οC
TA= 800οC
400 600 800 1000 1200
900
10 μm
850°
800°
700
TA= 900οC
TA= 700οC
INTENSITY (arb. units)
WAVE NUMBER (cm-1)
Fig. 3. Raman spectra of ZnO films on a-plane sapphire substrates measured at room temperature under various annealing
conditions and optical images for the measuring spot.
(11-20) Al2O3)
(0002) ZnO
T = 900°C
T =850°C
T = 800°C
T = 700°C
33 34 35 36 37 38 39
2θ (deg.)
INTENSITY (arb.units)
-1.0 -0.5 0.0 0.5 1.0
Δω (deg.)
(0002) ZnO
FWHM=0.0026°
INTENSITY (arb.units)
(a)
(b)
Fig. 4. (a) Shows h–2h scan of (0001) ZnO on (11–20) Al2O3 substrate, ZnO (0002) reflection is observed. (b) Shows x-scan
rocking curve recorded for the (0002) line with a width of only 0.0026.
6. A.N. Fouda et al. / Superlattices and Microstructures 73 (2014) 268–274 273
c - BULK (ZnO)
700 800 900
5.217
5.214
5.211
5.208
5.205
c - AXSIS STRAIN (%)
c - LATTICE CONSTANT (Å)
ANNEALING TEMPERATURE (C°)
0.18
0.12
0.06
0.00
Fig. 5. Relation between c-lattice parameter and strain for ZnO thin films under various annealing conditions.
700 750 800 850 900
5x109
4x109
3x109
2x109
1x109
0
IN PLANE STRESS (dyn/cm2)
ANNEALING TEMPERATURE (C°)
Fig. 6. The in plane stress of ZnO epilayers on a-plane sapphire substrates under different annealing temperatures.
The residual stress in the c-plane of annealed ZnO films can be calculated based on biaxial strain
model for hexagonal lattice [36]
r ¼ ð233 1010Þ
cfilm cbulk
cbulk
dyne=cm2
Here r is the in plane stress, cfilm is the lattice constant obtained from the (0002) reflection in the XRD
profile, cbulk is the corresponding bulk value [37,38]. The calculated in-plane stress values for thermally
annealed ZnO films are shown in Fig. 6. The value of stress in our samples is two order of magnitude
lower than the values reported by some other groups [36]. Generally, intrinsic stress and thermal
stress can be found in ZnO films. Due to the small lattice mismatch in our films, the intrinsic stress
induced by lattice mismatch is small. We believe that the resultant stress is mainly due to thermal
stress which is attributed to the difference in the thermal expansion coefficients of the substrate
and film [35]. High temperature annealing reduce the in plane stress in ZnO films and promote grain
growth.
7. 274 A.N. Fouda et al. / Superlattices and Microstructures 73 (2014) 268–274
4. Conclusions
The effect of vacuum annealing on the relaxation of ZnO films was illustrated. ZnO epilayer had a
smooth surface comparable to layer by layer films grown by MBE and PLD. As determined by XRD
measurements, the sharpness of ZnO (0002) reflection shows a good c-axis orientation perpendicular
to a-plane sapphire with a small FWHM. Our result suggests few threading dislocations which is
related to x-rocking curve of ZnO (0002) reflection and high temperature annealing improves the
ordering of the films. A well identified lattice relaxation by high temperature annealing were con-firmed.
This implies that the film was relaxed by increasing the annealing temperature and the lattice
constant is comparable to bulk ZnO. Micro-Raman analysis confirm the small stress in the films.
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