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Hair Shampoos
M.Swetha
• Shampoos are the semi solid preparations whose primary function is to
cleanse the hair.
• General Composition
• Detergents
• Opacifying agent
• Clarifying agents
• Sequestering agents
• Conditioners agents
• Thickening agent
• Foam boosters
• Activators
• Preservatives
• Special additives
Detergents
• Surfactants
• Anionic Surfactants—
• They carry the negative charge when ionised.
• Very good foaming.
• Excellent cleansing
• Less expensive
• Major disadvantages is they can be harsh and irritating on scalp
• Alkaline Soaps—SLS .
• Alkyl sulphates
• Ammonium lauryl sulphate gives good foaming and solubility than sodium
salts.
• Sulpho succinates
Detergents
• Non-ionic Surfactants- no charge
• They are good cleansing agents but alone it can’t produce good foam
,so it is mixed with SLS to get good characters
• Fatty alkanol amides such as a mono ethanol amide's and isopropanol
amide .
• Sorbitol esters :
• poly ethylene Sorbitol monoesters(TWEENS) –tween 20 and 80 are
widely used.
• cationic Surfactants-positive charge
• They do not have very good cleansing and foaming properties.
• They should not be used at high concentration .
• Irritating to eyes but safe in small amonuts.
• Alkyl trimethyl ammonium salts
• Cetyl pyridinium salt
• Amphoteric Surfactants- negative & positive
• Mild shampoos –baby
• Stearic acid ,glycol mono sterates.
Opacifying agent
• Opaque and pearly look.
• Stearic acid ,glycol mono and di stearates.
Clarifying agents -it improve the solubility
• Ex: alcohols –Ethanol, iso propanol and PG.
Sequestering agents – form complex with hard water .
• EX: EDTA
Conditioners agents –manageable
• Ex : cetyl alcohol, lanolin , mineral oil.
• Thickening agent
• Increase viscosity
• Methyl cellulose ,cabopol 934 &941
• Foam boosters – improve foaming charecter
• Guar gum , Xanthum gum.
• Activators
Preservatives : Ex :methyl paraben
Special additives
odour ,colour , perfume
FDA approved dyes are accetable
Types of shampoos
• Clear liquid shampoo :
Tri Ethanolamine lauryl sulphates 30%-40%
Coconut monoethanolamide -2%
perfume q.s
Colour q.s
Water upto 100%
Cream shampoo
SLS
Coconut diethanolamide
Magnesium stearate
PEG
Lanolin
perfume q.s
• Gel shampoo
• SLS -20%
• Coconut monoethanolamide- 1%
• Propylene Glycol monostearate 2%
• Stearic acid -5%
• Sodium Hydroxide 0.75%
• Water q.s
• Powder shampoo dry shampoo
• SLS -25% Rice starch 30%
• Sodium bicarbonate 15% Boric Acid 5%
• Sodium sulphate -60% silica 20%
Talc 20%
perfume q.s
Thank you
• REFERENCES
Text book of INDUSTRIAL Pharmacy By Shobha Rani

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Shampoos,Formulation ,Types.

  • 2. • Shampoos are the semi solid preparations whose primary function is to cleanse the hair. • General Composition • Detergents • Opacifying agent • Clarifying agents • Sequestering agents • Conditioners agents • Thickening agent • Foam boosters • Activators • Preservatives • Special additives
  • 3. Detergents • Surfactants • Anionic Surfactants— • They carry the negative charge when ionised. • Very good foaming. • Excellent cleansing • Less expensive • Major disadvantages is they can be harsh and irritating on scalp • Alkaline Soaps—SLS . • Alkyl sulphates • Ammonium lauryl sulphate gives good foaming and solubility than sodium salts. • Sulpho succinates
  • 4. Detergents • Non-ionic Surfactants- no charge • They are good cleansing agents but alone it can’t produce good foam ,so it is mixed with SLS to get good characters • Fatty alkanol amides such as a mono ethanol amide's and isopropanol amide . • Sorbitol esters : • poly ethylene Sorbitol monoesters(TWEENS) –tween 20 and 80 are widely used.
  • 5. • cationic Surfactants-positive charge • They do not have very good cleansing and foaming properties. • They should not be used at high concentration . • Irritating to eyes but safe in small amonuts. • Alkyl trimethyl ammonium salts • Cetyl pyridinium salt • Amphoteric Surfactants- negative & positive • Mild shampoos –baby • Stearic acid ,glycol mono sterates.
  • 6. Opacifying agent • Opaque and pearly look. • Stearic acid ,glycol mono and di stearates. Clarifying agents -it improve the solubility • Ex: alcohols –Ethanol, iso propanol and PG. Sequestering agents – form complex with hard water . • EX: EDTA Conditioners agents –manageable • Ex : cetyl alcohol, lanolin , mineral oil. • Thickening agent • Increase viscosity • Methyl cellulose ,cabopol 934 &941
  • 7. • Foam boosters – improve foaming charecter • Guar gum , Xanthum gum. • Activators Preservatives : Ex :methyl paraben Special additives odour ,colour , perfume FDA approved dyes are accetable
  • 8. Types of shampoos • Clear liquid shampoo : Tri Ethanolamine lauryl sulphates 30%-40% Coconut monoethanolamide -2% perfume q.s Colour q.s Water upto 100% Cream shampoo SLS Coconut diethanolamide Magnesium stearate PEG Lanolin perfume q.s
  • 9. • Gel shampoo • SLS -20% • Coconut monoethanolamide- 1% • Propylene Glycol monostearate 2% • Stearic acid -5% • Sodium Hydroxide 0.75% • Water q.s • Powder shampoo dry shampoo • SLS -25% Rice starch 30% • Sodium bicarbonate 15% Boric Acid 5% • Sodium sulphate -60% silica 20% Talc 20% perfume q.s
  • 10. Thank you • REFERENCES Text book of INDUSTRIAL Pharmacy By Shobha Rani