SlideShare a Scribd company logo
October 8th,2009
Science Café, Springfield MO
Headquarters
St. Louis, MO
Jordan Valley
Innovation
Center/MSU
Springfield, MO
Southern
Mississippi
University
Hattiesburg, MS
Crosslink Proprietary
2
Company Overview
Conductive coating technologies and
commercially-available inherently
conductive polymers (ICPs)
Coatings and printed ink systems using
these conductive polymer materials
 Light-emitting materials
 Energy Storage device
 Destruction of toxic/bad chemicals and
bacteria
 For the release of medicine for healing
cuts and burns
 Sensors for cracking within structures
Goal is to take these printed
conductive materials and make
everyday products that people can
use
0
20
40
60
80
100
120
140
2001 2002 2003 2004 2005 2006
Cumulative Patent Position
Issued Patents
Licensed IP
Crosslink Proprietary
3
The basics: Charge flow in a simple circuit using metals
 Negative particles (electrons) move from
the negative to the postive terminal of
the battery.
 Metals such as copper wires are used to
direct electricity because electrons move
freely through the metal.
Crosslink Proprietary
4
Charge flow in polymers (conductive)
+-
• Charge moves based on the
jumping of negative charge
along the chain of the
polymer;
• Conductivity is less than
metals because negative
jumps of site to site instead
of moving freely
• This type of conductive
polymer is called a n-type
(n=negative)
When charge moves
through the polymer,
this is called a
conductive polymer
Polyacetylene (n-type conductive polymer)
Crosslink Proprietary
5
Charge flow in polymers (polyelectrolytes)
Polyethylene Oxide
+ (Li+, K+)
+
+
++
+
+
+
+
+
+ +
+
 With out potassium chloride
salt (electrolyte), current
would not flow.
 Polymer is not charged in this
case.
 Charge moves along the
polymer chain so current can
flow
Electrochemical Cell (Battery)
Crosslink Proprietary
6
Production Process for polymer systems by XL
Screen Printing
Roll to Roll transfer printing
Easy to manufacture
Proprietary, patented process
Screen printing for Large Areas Roll to Roll Transfer Printing
Crosslink Proprietary
7
Screen printed coating for the destruction of toxic chemicals
and harmful bacteria
+ H2O2 Safe Products
Safe Oxidation/Hydrolysis
Products
Flexible or Rigid
Fabric or Substrate
Anode Electrode
Reaction
2H2O  O2 + 4e-
+ 4H+
Destruction through Oxidation
(addition of oxygen to agent)
Toxic agent + H2O2 
Safe Oxidation/Hydrolysis
Products
Toxic chemical or
Bacterial agent
Flexible or Rigid
Fabric or Substrate
Screen printed
Polymer gel electrolyte
(PGE)
Screen printed positive
electrode (carbon ink)
2H2O  O2 + 4e-
+ 4H+
Screen printed negative
electrode (carbon ink)
O2 + 2H+
+ 2e-
 H2O2O2 + 2H+
+ 2e-
 H2O2O2 + 2H+
+ 2e-
 H2O2
Can be used in
hospitals and clinics, homeland security and by the military
Crosslink Proprietary
8
Test samples designed for real-agent testing
Positive
Electrode
Negative
Electrode
Polymer
Gel
Electrolyte
Anthrax
spore
H2O2
Army Tent Fabric
Results!
A B
C D
A B
C D
Crosslink Proprietary
9
Supercapacitors as energy storage devices
separator
n-type
conductive
polymer
p-type
conductive
polymer
Standard electrolytic
capacitor
+
+
+
+
+
+
+
+ -
-
-
-
-
-
-
-
-
Capacitance (C)
depends on the
surface area (A)
being charged
Conductive polymer increases
surface area/capacitance by 10 to 100 times over
standard capacitors
Crosslink Proprietary
10
Energy Storage applications for supercapacitors
 Conventional rechargeable batteries
 Slow to charge and discharge (hours)
 Use metal foams/particles which are bulky and toxic (require
recycling)
 Limited charge storage
 Supercapacitors
 Fast to charge and discharge (seconds)
 Light weight and organic
 Large surface areas in a small volume
Supercapacitors are the ideal energy storage solution for storing
charge from solar panels and wind turbins!
Can handle large jumps in energy (wind gusts)
Can storage large amount energy so it can be used
when the sun is not shining or the wind is not
blowing
Ultimate Goal
ENERGY IN = ENERGY OUT
(100% Efficient)
~20% efficient
Crosslink Proprietary
11
SuperFlexTM
 Rugged, Flexible Electroluminescent (EL) Illumination System
SuperFlex™ is a set
of inks used to print a
multi-layer lamp
structure
Negative Terminal (-)
Positive Terminal (+)
The area, where the negative
charge from one conductive
polymer layer meets the positive
charge of the other conductive
layer,light is given off.
+
Crosslink Proprietary
12
Tent Prototypes
STAT 21 Shelter (by Vertigo)
Advanced Medical Shelter (ADMS,
by Vertigo
Modular Command
Post Prototype at
Crosslink
Test to make
sure fabric
lights when
crunched
Crosslink Proprietary
13
Conductive Polymers for Drug Delivery
+
+
+
+
+
+
+
+
+
+
+
+ +
+ +
+
+
+
+
+
+ +
+
+
+
+
+
+
+
+
+
+
+
+
+ +p-type
conductive
polymer
•Remove electrons leads to positive charge on chains
•Chains repel each other and move a part
•Drug particles are release into the skin
 Smart band-aids/patches for burn and wound healing
= antibiotic, anti-inflammatory, pain medication
Crosslink Proprietary
14
Demonstration of release of two different agents
Thank You!
www.CrosslinkUSA.com
(636) 349-0050
Contacts:
Patrick J. Kinlen, CTO pkinlen@crosslinkusa.com
Donald S. Landy, VP – Operations/Govt Relations dlandy@crosslinkusa.com
Jill C. Simpson, Gen Mgr – Energy Materials jsimpson@crosslinkusa.com

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Science Cafe Springfield MO

  • 1. October 8th,2009 Science Café, Springfield MO Headquarters St. Louis, MO Jordan Valley Innovation Center/MSU Springfield, MO Southern Mississippi University Hattiesburg, MS
  • 2. Crosslink Proprietary 2 Company Overview Conductive coating technologies and commercially-available inherently conductive polymers (ICPs) Coatings and printed ink systems using these conductive polymer materials  Light-emitting materials  Energy Storage device  Destruction of toxic/bad chemicals and bacteria  For the release of medicine for healing cuts and burns  Sensors for cracking within structures Goal is to take these printed conductive materials and make everyday products that people can use 0 20 40 60 80 100 120 140 2001 2002 2003 2004 2005 2006 Cumulative Patent Position Issued Patents Licensed IP
  • 3. Crosslink Proprietary 3 The basics: Charge flow in a simple circuit using metals  Negative particles (electrons) move from the negative to the postive terminal of the battery.  Metals such as copper wires are used to direct electricity because electrons move freely through the metal.
  • 4. Crosslink Proprietary 4 Charge flow in polymers (conductive) +- • Charge moves based on the jumping of negative charge along the chain of the polymer; • Conductivity is less than metals because negative jumps of site to site instead of moving freely • This type of conductive polymer is called a n-type (n=negative) When charge moves through the polymer, this is called a conductive polymer Polyacetylene (n-type conductive polymer)
  • 5. Crosslink Proprietary 5 Charge flow in polymers (polyelectrolytes) Polyethylene Oxide + (Li+, K+) + + ++ + + + + + + + +  With out potassium chloride salt (electrolyte), current would not flow.  Polymer is not charged in this case.  Charge moves along the polymer chain so current can flow Electrochemical Cell (Battery)
  • 6. Crosslink Proprietary 6 Production Process for polymer systems by XL Screen Printing Roll to Roll transfer printing Easy to manufacture Proprietary, patented process Screen printing for Large Areas Roll to Roll Transfer Printing
  • 7. Crosslink Proprietary 7 Screen printed coating for the destruction of toxic chemicals and harmful bacteria + H2O2 Safe Products Safe Oxidation/Hydrolysis Products Flexible or Rigid Fabric or Substrate Anode Electrode Reaction 2H2O  O2 + 4e- + 4H+ Destruction through Oxidation (addition of oxygen to agent) Toxic agent + H2O2  Safe Oxidation/Hydrolysis Products Toxic chemical or Bacterial agent Flexible or Rigid Fabric or Substrate Screen printed Polymer gel electrolyte (PGE) Screen printed positive electrode (carbon ink) 2H2O  O2 + 4e- + 4H+ Screen printed negative electrode (carbon ink) O2 + 2H+ + 2e-  H2O2O2 + 2H+ + 2e-  H2O2O2 + 2H+ + 2e-  H2O2 Can be used in hospitals and clinics, homeland security and by the military
  • 8. Crosslink Proprietary 8 Test samples designed for real-agent testing Positive Electrode Negative Electrode Polymer Gel Electrolyte Anthrax spore H2O2 Army Tent Fabric Results! A B C D A B C D
  • 9. Crosslink Proprietary 9 Supercapacitors as energy storage devices separator n-type conductive polymer p-type conductive polymer Standard electrolytic capacitor + + + + + + + + - - - - - - - - - Capacitance (C) depends on the surface area (A) being charged Conductive polymer increases surface area/capacitance by 10 to 100 times over standard capacitors
  • 10. Crosslink Proprietary 10 Energy Storage applications for supercapacitors  Conventional rechargeable batteries  Slow to charge and discharge (hours)  Use metal foams/particles which are bulky and toxic (require recycling)  Limited charge storage  Supercapacitors  Fast to charge and discharge (seconds)  Light weight and organic  Large surface areas in a small volume Supercapacitors are the ideal energy storage solution for storing charge from solar panels and wind turbins! Can handle large jumps in energy (wind gusts) Can storage large amount energy so it can be used when the sun is not shining or the wind is not blowing Ultimate Goal ENERGY IN = ENERGY OUT (100% Efficient) ~20% efficient
  • 11. Crosslink Proprietary 11 SuperFlexTM  Rugged, Flexible Electroluminescent (EL) Illumination System SuperFlex™ is a set of inks used to print a multi-layer lamp structure Negative Terminal (-) Positive Terminal (+) The area, where the negative charge from one conductive polymer layer meets the positive charge of the other conductive layer,light is given off. +
  • 12. Crosslink Proprietary 12 Tent Prototypes STAT 21 Shelter (by Vertigo) Advanced Medical Shelter (ADMS, by Vertigo Modular Command Post Prototype at Crosslink Test to make sure fabric lights when crunched
  • 13. Crosslink Proprietary 13 Conductive Polymers for Drug Delivery + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + +p-type conductive polymer •Remove electrons leads to positive charge on chains •Chains repel each other and move a part •Drug particles are release into the skin  Smart band-aids/patches for burn and wound healing = antibiotic, anti-inflammatory, pain medication
  • 14. Crosslink Proprietary 14 Demonstration of release of two different agents
  • 15. Thank You! www.CrosslinkUSA.com (636) 349-0050 Contacts: Patrick J. Kinlen, CTO pkinlen@crosslinkusa.com Donald S. Landy, VP – Operations/Govt Relations dlandy@crosslinkusa.com Jill C. Simpson, Gen Mgr – Energy Materials jsimpson@crosslinkusa.com