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International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395 -0056
Volume: 03 Issue: 02 | Feb-2016 www.irjet.net p-ISSN: 2395-0072
© 2016, IRJET | Impact Factor value: 4.45 | ISO 9001:2008 Certified Journal | Page 1256
QUANTUM DOTS- SMART SEMICONDUTOR NANOMATERIALSLIGHTENING
THE OPTOELECTRONIS FIELDS
Irshad Ahamed. M1,Sundar Raj2
1 & 2 – Assistant Professor
1 & 2 – Department of ECE, E.G.S. Pillay Engineering College, Nagapattinam Tamilnadu, India.
--------------------------------------------------------------***-----------------------------------------------------------------
ABSTRACT
Light is the power of perception by vision. Due to
technological development, quantum dots are developed
into new, promising classes of material for superior
lighting and display systems. Quantum dots have many
interesting and important applications in nanotechnology.
They have remarkable optical properties, which can be
used for fabrication of quantum LEDs, white LEDs, photo
detector devices. Here, we will discuss the benefits,
applications and future trends of quantum dots.
Keywords: Quantum dots, LED light, Nano-technology,
Semi-conductors.
1. INTRODUCTION TO NANOTECHNOLOGY
Nanotechnology is the engineering of functional
system at the molecular scale[1]. It is the art and science of
manipulating matter at the nanoscale to create new and
unique materials and products with enormous potential to
change society. 1nanometer (nm) =1billionth of a meter.
There are two important approaches in nanotechnology.
Fig (1): micro, macro and Nano diagrammatic
representation
In top down approach, building something by starting with
a larger component and carving away material (like a
sculpture). In bottom up approach, building something by
assembling smaller components (like building a car
engine).
2.INTRODUCTION TO QUANTUM DOTS
Quantum dots may be the future of computing.
They are small devices that contain a tiny droplet of free
electrons. Typical dimensions are between nanometer to a
few microns. Quantum dot can have anything from a single
electron to a collection of several thousand [2]. The size,
shape and number of electrons can be precisely controlled.
As same as an atom, the energy levels are quantized due to
the confinement of electrons. The 3D spatial confinement
is observed in the quantum dots. In some of them even if
one electron leaves the structure there is a significant
change in properties. Unlike atoms however, quantum dots
can be easily connected to electrodes and are therefore
excellent tools to study atomic like properties. The
potential of nearby metal gate is changed. The atomic
structure might behave as a lead one minute and gold next
minute
.
Fig (2): TEM image of 3nm quantum dots
3. FABRICATION OF QUANTUM DOTS
There are three major fabrication methods for
quantum dots. The first method involves growing quantum
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395 -0056
Volume: 03 Issue: 02 | Feb-2016 www.irjet.net p-ISSN: 2395-0072
© 2016, IRJET | Impact Factor value: 4.45 | ISO 9001:2008 Certified Journal | Page 1257
dots in a beaker. This approach was introduced by Louis
Brus in the late 1970s when he was at Bell Labs. Originally,
the quantum dots grown were semiconductors such as
cadmium selenide or cadmium telluride, but now people
have made quantum dots of nearly every semiconductors
and also of many metals (gold, silver, nickel, cobalt, to
name a few) and insulators as well. The semiconductors
have the fascinating property that their color depends on
the size of the dot, thus it is possible to use one chemical
substance and yet make structures with a wide variety of
colors simply by varying the size of the dot. The metal dots
have a range of interesting electrical, magnetic and
catalytic properties [3]. The architecture of these
chemically grown dots is formed by coating one material
with another becoming more common. These structures
can be used to shield a chemically or electrically sensitive
dot from an unfriendly environment
.
Fig (3): Image of colloidal quantum dots
In second method, quantum dots create at or near the
surface of a semiconductor crystal. Originally, such
quantum dots were formed by growing a semiconductor
hetero structure (a plane of one semiconductor
sandwiched between two others). If the sandwiched layer
is thin enough, about ten nanometers or less, electrons can
no longer move vertically in a classical fashion, they are
effectively trapped in that dimensions. Such a structure is
called a quantum well. Quantum wells generate photons of
very specific wavelengths and can be found in lasers used
in laser pointers or key rings. Quantum wires can make
lasers that are switchable at very high speeds and can be
used as wave guides. Now rotate ninety degrees and do the
same again. The electrons are now ready to use in all three
dimensions and you have a quantum dot.
Fig (4): Sandwiched layer of InGaAs
Fig (5): GaN quantum dot preparation on AIN
In third method, researchers began to grow “self-
assembled” dots by depositing a semiconductor material
with a larger lattice constant onto a semiconductor with a
smaller lattice constant. Typical systems were germanium
on silicon and indium arsenide on gallium arsenide. These
self-assembled dots that have been used to fabricate
quantum dot lasers. This same method was used to create
a single photon detector [4].
4. APPLICATIONS OF QUANTUM DOTS
Quantum dots have wide range of applications, some
of them are, and in different approach to creating white
light several Sandia researchers have developed the first
solid-state white light-emitting device using quantum dot
[5]. In future, the use of quantum dots as light-emitting
phosphors may represent a major application of
nanotechnology. In the field of nanophotonics IBM
announced that, future technology utilizing nanophotonics
will be silicon chips that use light instead of or in addition
to electrical signals. The most interesting thing in this
technology is, it will work in standard ninety nanometer
semiconductor form factor.
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395 -0056
Volume: 03 Issue: 02 | Feb-2016 www.irjet.net p-ISSN: 2395-0072
© 2016, IRJET | Impact Factor value: 4.45 | ISO 9001:2008 Certified Journal | Page 1258
Fig (6): IBM is circulating this shot of a 90nm silicon-
based nanophotonics chip cross section.
Quantum dots may someday light your homes,
offices, streets and entire cities. Quantum dot LED’s will
produce any color of light, including white. [3] These LED’s
are extremely energy efficient. They use only a few watts,
while a regular incandescent lamp uses 30 or more watts
for the same amount of light. Quantum dots may one day
power the world with clean, efficient energy. Solar cells
can use quantum dots to convert sunlight into electricity
more efficiently than conventional designs. Quantum dot
solar cells are difficult to make and not yet cost effective.
Quantum dots may one day save your life. Medical imaging
has begun to colloidal quantum dots much like the ones we
look today. Quantum dots last longer in the system and are
brighter than many organic dyes and fluorescent proteins
previously used to illuminate the interiors of cells.
They also have the advantage of monitoring changes in
cellular processes while most high-resolution techniques
like only provide images of cellular processes frozen at one
moment. Quantum dots may be the future of computing.
Lots of effort is currently being put into the field of
spintronics to progress toward quantum computers. A
quantum computer would use spin of the electron instead
of the charge like current computers. In this way it may
use considerably less energy than a regular computer
while being significantly faster.
5. FUTURE SCOPE OF QUANTUM DOTS
The future is bright for quantum dots, the usefulness
and application of quantum dot technology continues to
expand and research is striving to bring their benefits to
more and more technologically applied fields.
Anti-counterfeiting capabilities: In this technique, the
quantum dots are injected into liquid mixtures, fabrics and
polymer matrices. Ability to specifically control absorption
and emission spectra to produce unique validation
signatures, almost impossible to mimic with traditional
semi-conductors [6].
Counter-espionage/ Defense applications: Integrate
quantum dots into dust that tracks enemies. Protection
against friendly-fire events.
In future LED televisions using quantum dots will be
remarkable technology. Traditional solar cells are made of
semi-conductors and expensive to produce [7].
Fig (7): Quantum dots exhibiting different colors.
Theoretical upper limit 33% efficiency for conversion
of sunlight to electricity for these cells. Utilizing quantum
dots realization of third-generation solar cells at 60%
efficiency in electricity production.
Fig (8): Quantum dot solar cell
In the future, quantum dots could also be armed with
tumor-fighting toxic therapies to provide the diagnosis and
treatment. Quantum dots can be useful tool for monitoring
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395 -0056
Volume: 03 Issue: 02 | Feb-2016 www.irjet.net p-ISSN: 2395-0072
© 2016, IRJET | Impact Factor value: 4.45 | ISO 9001:2008 Certified Journal | Page 1259
cancerous cells and providing a means to better
understand its evolution.
Quantum dots offer a wide broadband absorption
spectrum while maintaining a distinct, static emission
wavelength.
6. CONCLUSION
In this paper we mainly focused on quantum dots
fabrication and its various applications. Quantum dot LEDs
are used for fiber optic communications and solar cell
fabrication. According to the market demand and higher
requirements of applications, future research directions
are figured out and needed to be realized soon. In future
we may expect quantum dots will rule the entire lightening
devices in the world.
REFERENCES
1.”Introduction to nanotechnology”, Michael Krause,
mkrause@veritox.com
2. “Quantum Dots: Assessing the Impact within Lighting
and Displays”, Seth Coe-Sullivan, March 27th, 2012.
3. “Cientifica”, Quantum Dots Technology white papers
nr.13, published by Cientifica, October 2003.
4. Novel method to Fabricate Quantum Dot-based Light
Emitting Device November 23, 2011 by CLARA
PICCIRILLO, PhD
5.”Sandia Lab News”, managed by Lockheed Martin for the
National Nuclear Security Administration, volume.55,
no.14, July 11, 2003.
6.“Quantum Dot Light-Emitting Devices with
Electroluminescence Tunable over the Entire Visible
Spectrum”, Polina O. Anikeeva, Jonathan E. Halpert.
7. Quantum Dots Science and Applications”, James MC
Daniel, Physics 3500, Nano chemistry.

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Quantum Dots- Smart Semicondutor Nanomaterialslightening the Optoelectronic Fields

  • 1. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395 -0056 Volume: 03 Issue: 02 | Feb-2016 www.irjet.net p-ISSN: 2395-0072 © 2016, IRJET | Impact Factor value: 4.45 | ISO 9001:2008 Certified Journal | Page 1256 QUANTUM DOTS- SMART SEMICONDUTOR NANOMATERIALSLIGHTENING THE OPTOELECTRONIS FIELDS Irshad Ahamed. M1,Sundar Raj2 1 & 2 – Assistant Professor 1 & 2 – Department of ECE, E.G.S. Pillay Engineering College, Nagapattinam Tamilnadu, India. --------------------------------------------------------------***----------------------------------------------------------------- ABSTRACT Light is the power of perception by vision. Due to technological development, quantum dots are developed into new, promising classes of material for superior lighting and display systems. Quantum dots have many interesting and important applications in nanotechnology. They have remarkable optical properties, which can be used for fabrication of quantum LEDs, white LEDs, photo detector devices. Here, we will discuss the benefits, applications and future trends of quantum dots. Keywords: Quantum dots, LED light, Nano-technology, Semi-conductors. 1. INTRODUCTION TO NANOTECHNOLOGY Nanotechnology is the engineering of functional system at the molecular scale[1]. It is the art and science of manipulating matter at the nanoscale to create new and unique materials and products with enormous potential to change society. 1nanometer (nm) =1billionth of a meter. There are two important approaches in nanotechnology. Fig (1): micro, macro and Nano diagrammatic representation In top down approach, building something by starting with a larger component and carving away material (like a sculpture). In bottom up approach, building something by assembling smaller components (like building a car engine). 2.INTRODUCTION TO QUANTUM DOTS Quantum dots may be the future of computing. They are small devices that contain a tiny droplet of free electrons. Typical dimensions are between nanometer to a few microns. Quantum dot can have anything from a single electron to a collection of several thousand [2]. The size, shape and number of electrons can be precisely controlled. As same as an atom, the energy levels are quantized due to the confinement of electrons. The 3D spatial confinement is observed in the quantum dots. In some of them even if one electron leaves the structure there is a significant change in properties. Unlike atoms however, quantum dots can be easily connected to electrodes and are therefore excellent tools to study atomic like properties. The potential of nearby metal gate is changed. The atomic structure might behave as a lead one minute and gold next minute . Fig (2): TEM image of 3nm quantum dots 3. FABRICATION OF QUANTUM DOTS There are three major fabrication methods for quantum dots. The first method involves growing quantum
  • 2. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395 -0056 Volume: 03 Issue: 02 | Feb-2016 www.irjet.net p-ISSN: 2395-0072 © 2016, IRJET | Impact Factor value: 4.45 | ISO 9001:2008 Certified Journal | Page 1257 dots in a beaker. This approach was introduced by Louis Brus in the late 1970s when he was at Bell Labs. Originally, the quantum dots grown were semiconductors such as cadmium selenide or cadmium telluride, but now people have made quantum dots of nearly every semiconductors and also of many metals (gold, silver, nickel, cobalt, to name a few) and insulators as well. The semiconductors have the fascinating property that their color depends on the size of the dot, thus it is possible to use one chemical substance and yet make structures with a wide variety of colors simply by varying the size of the dot. The metal dots have a range of interesting electrical, magnetic and catalytic properties [3]. The architecture of these chemically grown dots is formed by coating one material with another becoming more common. These structures can be used to shield a chemically or electrically sensitive dot from an unfriendly environment . Fig (3): Image of colloidal quantum dots In second method, quantum dots create at or near the surface of a semiconductor crystal. Originally, such quantum dots were formed by growing a semiconductor hetero structure (a plane of one semiconductor sandwiched between two others). If the sandwiched layer is thin enough, about ten nanometers or less, electrons can no longer move vertically in a classical fashion, they are effectively trapped in that dimensions. Such a structure is called a quantum well. Quantum wells generate photons of very specific wavelengths and can be found in lasers used in laser pointers or key rings. Quantum wires can make lasers that are switchable at very high speeds and can be used as wave guides. Now rotate ninety degrees and do the same again. The electrons are now ready to use in all three dimensions and you have a quantum dot. Fig (4): Sandwiched layer of InGaAs Fig (5): GaN quantum dot preparation on AIN In third method, researchers began to grow “self- assembled” dots by depositing a semiconductor material with a larger lattice constant onto a semiconductor with a smaller lattice constant. Typical systems were germanium on silicon and indium arsenide on gallium arsenide. These self-assembled dots that have been used to fabricate quantum dot lasers. This same method was used to create a single photon detector [4]. 4. APPLICATIONS OF QUANTUM DOTS Quantum dots have wide range of applications, some of them are, and in different approach to creating white light several Sandia researchers have developed the first solid-state white light-emitting device using quantum dot [5]. In future, the use of quantum dots as light-emitting phosphors may represent a major application of nanotechnology. In the field of nanophotonics IBM announced that, future technology utilizing nanophotonics will be silicon chips that use light instead of or in addition to electrical signals. The most interesting thing in this technology is, it will work in standard ninety nanometer semiconductor form factor.
  • 3. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395 -0056 Volume: 03 Issue: 02 | Feb-2016 www.irjet.net p-ISSN: 2395-0072 © 2016, IRJET | Impact Factor value: 4.45 | ISO 9001:2008 Certified Journal | Page 1258 Fig (6): IBM is circulating this shot of a 90nm silicon- based nanophotonics chip cross section. Quantum dots may someday light your homes, offices, streets and entire cities. Quantum dot LED’s will produce any color of light, including white. [3] These LED’s are extremely energy efficient. They use only a few watts, while a regular incandescent lamp uses 30 or more watts for the same amount of light. Quantum dots may one day power the world with clean, efficient energy. Solar cells can use quantum dots to convert sunlight into electricity more efficiently than conventional designs. Quantum dot solar cells are difficult to make and not yet cost effective. Quantum dots may one day save your life. Medical imaging has begun to colloidal quantum dots much like the ones we look today. Quantum dots last longer in the system and are brighter than many organic dyes and fluorescent proteins previously used to illuminate the interiors of cells. They also have the advantage of monitoring changes in cellular processes while most high-resolution techniques like only provide images of cellular processes frozen at one moment. Quantum dots may be the future of computing. Lots of effort is currently being put into the field of spintronics to progress toward quantum computers. A quantum computer would use spin of the electron instead of the charge like current computers. In this way it may use considerably less energy than a regular computer while being significantly faster. 5. FUTURE SCOPE OF QUANTUM DOTS The future is bright for quantum dots, the usefulness and application of quantum dot technology continues to expand and research is striving to bring their benefits to more and more technologically applied fields. Anti-counterfeiting capabilities: In this technique, the quantum dots are injected into liquid mixtures, fabrics and polymer matrices. Ability to specifically control absorption and emission spectra to produce unique validation signatures, almost impossible to mimic with traditional semi-conductors [6]. Counter-espionage/ Defense applications: Integrate quantum dots into dust that tracks enemies. Protection against friendly-fire events. In future LED televisions using quantum dots will be remarkable technology. Traditional solar cells are made of semi-conductors and expensive to produce [7]. Fig (7): Quantum dots exhibiting different colors. Theoretical upper limit 33% efficiency for conversion of sunlight to electricity for these cells. Utilizing quantum dots realization of third-generation solar cells at 60% efficiency in electricity production. Fig (8): Quantum dot solar cell In the future, quantum dots could also be armed with tumor-fighting toxic therapies to provide the diagnosis and treatment. Quantum dots can be useful tool for monitoring
  • 4. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395 -0056 Volume: 03 Issue: 02 | Feb-2016 www.irjet.net p-ISSN: 2395-0072 © 2016, IRJET | Impact Factor value: 4.45 | ISO 9001:2008 Certified Journal | Page 1259 cancerous cells and providing a means to better understand its evolution. Quantum dots offer a wide broadband absorption spectrum while maintaining a distinct, static emission wavelength. 6. CONCLUSION In this paper we mainly focused on quantum dots fabrication and its various applications. Quantum dot LEDs are used for fiber optic communications and solar cell fabrication. According to the market demand and higher requirements of applications, future research directions are figured out and needed to be realized soon. In future we may expect quantum dots will rule the entire lightening devices in the world. REFERENCES 1.”Introduction to nanotechnology”, Michael Krause, mkrause@veritox.com 2. “Quantum Dots: Assessing the Impact within Lighting and Displays”, Seth Coe-Sullivan, March 27th, 2012. 3. “Cientifica”, Quantum Dots Technology white papers nr.13, published by Cientifica, October 2003. 4. Novel method to Fabricate Quantum Dot-based Light Emitting Device November 23, 2011 by CLARA PICCIRILLO, PhD 5.”Sandia Lab News”, managed by Lockheed Martin for the National Nuclear Security Administration, volume.55, no.14, July 11, 2003. 6.“Quantum Dot Light-Emitting Devices with Electroluminescence Tunable over the Entire Visible Spectrum”, Polina O. Anikeeva, Jonathan E. Halpert. 7. Quantum Dots Science and Applications”, James MC Daniel, Physics 3500, Nano chemistry.