Particle technology involves the handling and processing of particles. Some key aspects covered in the document include:
1) Characterization of particles involves measuring their size, shape, and density. Size is an especially important property and can be measured using techniques like screen analysis.
2) Particles in industrial processes come in many forms and sizes, from hard abrasive particles to soft cohesive powders. Proper handling and processing requires understanding particle properties.
3) The course will cover topics ranging from particle characterization to separation techniques. It will provide useful knowledge for industries involving particulate solids like chemicals, minerals, foods, and more.
The first lecture in the module Particle Technology, delivered to second year students who have already studied basic fluid mechanics. Some applications of Particle Technology are described, in industry and nature, and particle size analysis and means of representing the data. The format for the laboratory classes for the module and their reports are covered.
The processing technique employing a suspension or fluidization of small solid particles in a vertically rising stream of fluid usually gas so that fluid and solid come into intimate contact. This is a tool with many applications in the petroleum and chemical process industries. Suspensions of solid particles by vertically rising liquid streams are of lesser interest in modern processing, but have been shown to be of use, particularly in liquid contacting of ion-exchange resins. However, they come in this same classification and their use involves techniques of liquid settling, both free and hindered (sedimentation), classification, and density flotation.
The first lecture in the module Particle Technology, delivered to second year students who have already studied basic fluid mechanics. Some applications of Particle Technology are described, in industry and nature, and particle size analysis and means of representing the data. The format for the laboratory classes for the module and their reports are covered.
The processing technique employing a suspension or fluidization of small solid particles in a vertically rising stream of fluid usually gas so that fluid and solid come into intimate contact. This is a tool with many applications in the petroleum and chemical process industries. Suspensions of solid particles by vertically rising liquid streams are of lesser interest in modern processing, but have been shown to be of use, particularly in liquid contacting of ion-exchange resins. However, they come in this same classification and their use involves techniques of liquid settling, both free and hindered (sedimentation), classification, and density flotation.
Types of Distillation & column internalsBharat Kumar
More:- https://chemicalengineeringworld.com
Distillation is a method of separating the components of a solution which depends upon distribution of the substances between a gas and liquid phase, applied to cases where all components are present in both phases.
* What is distillation ?
* Types of Distillation
* Batch Distillation
* Azeotropic Distillation
* Flooding
* Priming
* Coning
* Weeping
* Dumping
* Packed Column
* Tray column
* Reflux Ratio
* Relative volatility
* Distillation column
Distillation is a method of separating mixtures based on differences in volatility (volatility is the tendency of a substance to vaporize. Volatility is directly related to a substance's vapor pressure.) of components in a boiling liquid mixture. Distillation is a unit operation, or a physical separation process, and not a chemical reaction
An Overview to the most common Industrial Mass Transfer Operations & Process Separation Technologies
Course Description
In this course we will cover the most basic processes involved in Mass Transfer Operations. This is an overview of what type of processes, methods and units are used in the industry. This is mostly an introductory course which will allow you to learn, understand and know the approach towards separation processes involving mass transfer phenomena.
It is an excellent course before any Mass Transfer Process or Unit Operation Course such as Distillations, Extractions, Leaching, Membranes, Absorption, etc...
This course is extremely recommended if you will continue with the following:
Flash Distillation, Simple Distillation, Batch Distillation
Gas Absorption, Desorption & Stripping
Binary Distillation, Fractional Distillation
Scrubbers, Gas Treating
Sprayers / Spray Towers
Bubble Columns / Sparged Vessels
Agitation Vessels
Packed Towers, Tray Towers
Membranes
Liquid Extraction
Dryers / Humidifiers
Adsorbers
Evaporators/Sublimators
Crystallizers
Centrifugations
And many other Separation Technology!
At the end of the Course:
You will be able to understand the mass transfer operations concepts. You will be able to identify Mass Transfer Unit Operations. You will be also able to ensure the type of method of separation technology used.
You will be able to apply this theory in further Unit Operations.
Theory-Based Course
This is a very theoretical course, some calculations and exercises are present, but overall, expect mostly theoretical concepts.
Pin Mills are the mills used for grinding variety of things. The working, advantages, disadvantages, specifications and applications of Pin Mills have been well described in the presentation.
size reduction,laws involved in size reduction ,application & millsM Swetha
size reduction basic principles,laws&machanism of size reduction with all mills .I gave a note on size separation .it is very useful for the teaching staff &students of B.pharmacy
Slides for the eLearning course Separation and purification processes in biorefineries (https://open-learn.xamk.fi) in IMPRESS project.
Section: Distillation
Subject: 1.1 Vapor Liquid Equilibrium
Slides for the eLearning course Separation and purification processes in biorefineries (https://open-learn.xamk.fi) in IMPRESS project (https://www.spire2030.eu/impress).
Section: Mass transfer processes
Subject: 3.2 Equipment
Slides for the eLearning course Separation and purification processes in biorefineries (https://open-learn.xamk.fi) in IMPRESS project (https://www.spire2030.eu/impress).
Section: Distillation
Subject: 0.2 Introduction to distillation.
Types of Distillation & column internalsBharat Kumar
More:- https://chemicalengineeringworld.com
Distillation is a method of separating the components of a solution which depends upon distribution of the substances between a gas and liquid phase, applied to cases where all components are present in both phases.
* What is distillation ?
* Types of Distillation
* Batch Distillation
* Azeotropic Distillation
* Flooding
* Priming
* Coning
* Weeping
* Dumping
* Packed Column
* Tray column
* Reflux Ratio
* Relative volatility
* Distillation column
Distillation is a method of separating mixtures based on differences in volatility (volatility is the tendency of a substance to vaporize. Volatility is directly related to a substance's vapor pressure.) of components in a boiling liquid mixture. Distillation is a unit operation, or a physical separation process, and not a chemical reaction
An Overview to the most common Industrial Mass Transfer Operations & Process Separation Technologies
Course Description
In this course we will cover the most basic processes involved in Mass Transfer Operations. This is an overview of what type of processes, methods and units are used in the industry. This is mostly an introductory course which will allow you to learn, understand and know the approach towards separation processes involving mass transfer phenomena.
It is an excellent course before any Mass Transfer Process or Unit Operation Course such as Distillations, Extractions, Leaching, Membranes, Absorption, etc...
This course is extremely recommended if you will continue with the following:
Flash Distillation, Simple Distillation, Batch Distillation
Gas Absorption, Desorption & Stripping
Binary Distillation, Fractional Distillation
Scrubbers, Gas Treating
Sprayers / Spray Towers
Bubble Columns / Sparged Vessels
Agitation Vessels
Packed Towers, Tray Towers
Membranes
Liquid Extraction
Dryers / Humidifiers
Adsorbers
Evaporators/Sublimators
Crystallizers
Centrifugations
And many other Separation Technology!
At the end of the Course:
You will be able to understand the mass transfer operations concepts. You will be able to identify Mass Transfer Unit Operations. You will be also able to ensure the type of method of separation technology used.
You will be able to apply this theory in further Unit Operations.
Theory-Based Course
This is a very theoretical course, some calculations and exercises are present, but overall, expect mostly theoretical concepts.
Pin Mills are the mills used for grinding variety of things. The working, advantages, disadvantages, specifications and applications of Pin Mills have been well described in the presentation.
size reduction,laws involved in size reduction ,application & millsM Swetha
size reduction basic principles,laws&machanism of size reduction with all mills .I gave a note on size separation .it is very useful for the teaching staff &students of B.pharmacy
Slides for the eLearning course Separation and purification processes in biorefineries (https://open-learn.xamk.fi) in IMPRESS project.
Section: Distillation
Subject: 1.1 Vapor Liquid Equilibrium
Slides for the eLearning course Separation and purification processes in biorefineries (https://open-learn.xamk.fi) in IMPRESS project (https://www.spire2030.eu/impress).
Section: Mass transfer processes
Subject: 3.2 Equipment
Slides for the eLearning course Separation and purification processes in biorefineries (https://open-learn.xamk.fi) in IMPRESS project (https://www.spire2030.eu/impress).
Section: Distillation
Subject: 0.2 Introduction to distillation.
This presentation includes characteristics of an individual particle in a powder or in a mixture, mean particle size of a mixture or a powder, particle size distribution, fineness modulus etc.
a complete description of the particle size distribution of particles in different categories. Sedimentation is a phenomenon that completely work with the size of particles.
Episode 37 : SAMPLING
SAMPLING
As most laboratory tests use only a small sample, this has to be taken from a production stream or from an existing, stored material and it has to be representative of the whole.
Representative sampling absolutely critical for the success and relevance of any subsequent testing.
SAJJAD KHUDHUR ABBAS
Ceo , Founder & Head of SHacademy
Chemical Engineering , Al-Muthanna University, Iraq
Oil & Gas Safety and Health Professional – OSHACADEMY
Trainer of Trainers (TOT) - Canadian Center of Human
Development
The word Micromeritics refers to a discipline of science and technology that deals with studies related to the fundamental as well derived properties of particles. The knowledge and control of the size of particles is of importance in pharmacy and materials science.
NUMERICAL SIMULATIONS OF HEAT AND MASS TRANSFER IN CONDENSING HEAT EXCHANGERS...ssuser7dcef0
Power plants release a large amount of water vapor into the
atmosphere through the stack. The flue gas can be a potential
source for obtaining much needed cooling water for a power
plant. If a power plant could recover and reuse a portion of this
moisture, it could reduce its total cooling water intake
requirement. One of the most practical way to recover water
from flue gas is to use a condensing heat exchanger. The power
plant could also recover latent heat due to condensation as well
as sensible heat due to lowering the flue gas exit temperature.
Additionally, harmful acids released from the stack can be
reduced in a condensing heat exchanger by acid condensation. reduced in a condensing heat exchanger by acid condensation.
Condensation of vapors in flue gas is a complicated
phenomenon since heat and mass transfer of water vapor and
various acids simultaneously occur in the presence of noncondensable
gases such as nitrogen and oxygen. Design of a
condenser depends on the knowledge and understanding of the
heat and mass transfer processes. A computer program for
numerical simulations of water (H2O) and sulfuric acid (H2SO4)
condensation in a flue gas condensing heat exchanger was
developed using MATLAB. Governing equations based on
mass and energy balances for the system were derived to
predict variables such as flue gas exit temperature, cooling
water outlet temperature, mole fraction and condensation rates
of water and sulfuric acid vapors. The equations were solved
using an iterative solution technique with calculations of heat
and mass transfer coefficients and physical properties.
Immunizing Image Classifiers Against Localized Adversary Attacksgerogepatton
This paper addresses the vulnerability of deep learning models, particularly convolutional neural networks
(CNN)s, to adversarial attacks and presents a proactive training technique designed to counter them. We
introduce a novel volumization algorithm, which transforms 2D images into 3D volumetric representations.
When combined with 3D convolution and deep curriculum learning optimization (CLO), itsignificantly improves
the immunity of models against localized universal attacks by up to 40%. We evaluate our proposed approach
using contemporary CNN architectures and the modified Canadian Institute for Advanced Research (CIFAR-10
and CIFAR-100) and ImageNet Large Scale Visual Recognition Challenge (ILSVRC12) datasets, showcasing
accuracy improvements over previous techniques. The results indicate that the combination of the volumetric
input and curriculum learning holds significant promise for mitigating adversarial attacks without necessitating
adversary training.
Final project report on grocery store management system..pdfKamal Acharya
In today’s fast-changing business environment, it’s extremely important to be able to respond to client needs in the most effective and timely manner. If your customers wish to see your business online and have instant access to your products or services.
Online Grocery Store is an e-commerce website, which retails various grocery products. This project allows viewing various products available enables registered users to purchase desired products instantly using Paytm, UPI payment processor (Instant Pay) and also can place order by using Cash on Delivery (Pay Later) option. This project provides an easy access to Administrators and Managers to view orders placed using Pay Later and Instant Pay options.
In order to develop an e-commerce website, a number of Technologies must be studied and understood. These include multi-tiered architecture, server and client-side scripting techniques, implementation technologies, programming language (such as PHP, HTML, CSS, JavaScript) and MySQL relational databases. This is a project with the objective to develop a basic website where a consumer is provided with a shopping cart website and also to know about the technologies used to develop such a website.
This document will discuss each of the underlying technologies to create and implement an e- commerce website.
Sachpazis:Terzaghi Bearing Capacity Estimation in simple terms with Calculati...Dr.Costas Sachpazis
Terzaghi's soil bearing capacity theory, developed by Karl Terzaghi, is a fundamental principle in geotechnical engineering used to determine the bearing capacity of shallow foundations. This theory provides a method to calculate the ultimate bearing capacity of soil, which is the maximum load per unit area that the soil can support without undergoing shear failure. The Calculation HTML Code included.
6th International Conference on Machine Learning & Applications (CMLA 2024)ClaraZara1
6th International Conference on Machine Learning & Applications (CMLA 2024) will provide an excellent international forum for sharing knowledge and results in theory, methodology and applications of on Machine Learning & Applications.
CW RADAR, FMCW RADAR, FMCW ALTIMETER, AND THEIR PARAMETERSveerababupersonal22
It consists of cw radar and fmcw radar ,range measurement,if amplifier and fmcw altimeterThe CW radar operates using continuous wave transmission, while the FMCW radar employs frequency-modulated continuous wave technology. Range measurement is a crucial aspect of radar systems, providing information about the distance to a target. The IF amplifier plays a key role in signal processing, amplifying intermediate frequency signals for further analysis. The FMCW altimeter utilizes frequency-modulated continuous wave technology to accurately measure altitude above a reference point.
Industrial Training at Shahjalal Fertilizer Company Limited (SFCL)MdTanvirMahtab2
This presentation is about the working procedure of Shahjalal Fertilizer Company Limited (SFCL). A Govt. owned Company of Bangladesh Chemical Industries Corporation under Ministry of Industries.
Hierarchical Digital Twin of a Naval Power SystemKerry Sado
A hierarchical digital twin of a Naval DC power system has been developed and experimentally verified. Similar to other state-of-the-art digital twins, this technology creates a digital replica of the physical system executed in real-time or faster, which can modify hardware controls. However, its advantage stems from distributing computational efforts by utilizing a hierarchical structure composed of lower-level digital twin blocks and a higher-level system digital twin. Each digital twin block is associated with a physical subsystem of the hardware and communicates with a singular system digital twin, which creates a system-level response. By extracting information from each level of the hierarchy, power system controls of the hardware were reconfigured autonomously. This hierarchical digital twin development offers several advantages over other digital twins, particularly in the field of naval power systems. The hierarchical structure allows for greater computational efficiency and scalability while the ability to autonomously reconfigure hardware controls offers increased flexibility and responsiveness. The hierarchical decomposition and models utilized were well aligned with the physical twin, as indicated by the maximum deviations between the developed digital twin hierarchy and the hardware.
Cosmetic shop management system project report.pdfKamal Acharya
Buying new cosmetic products is difficult. It can even be scary for those who have sensitive skin and are prone to skin trouble. The information needed to alleviate this problem is on the back of each product, but it's thought to interpret those ingredient lists unless you have a background in chemistry.
Instead of buying and hoping for the best, we can use data science to help us predict which products may be good fits for us. It includes various function programs to do the above mentioned tasks.
Data file handling has been effectively used in the program.
The automated cosmetic shop management system should deal with the automation of general workflow and administration process of the shop. The main processes of the system focus on customer's request where the system is able to search the most appropriate products and deliver it to the customers. It should help the employees to quickly identify the list of cosmetic product that have reached the minimum quantity and also keep a track of expired date for each cosmetic product. It should help the employees to find the rack number in which the product is placed.It is also Faster and more efficient way.
2. Introduction
• Particle technology is a term used to refer to the science and
technology related to the handling and processing of particles.
• Particle technology is also often described as powder technology,
particle science and powder science.
• Particles are commonly referred to as bulk solids, particulate solids
and granular solids.
• Today particle technology includes the study of liquid drops,
emulsions and bubbles as well as solid particles.
• This course is however limited only to solid particles.
• The discipline of particle technology now includes topics as diverse
as the formation of aerosols to the design of bucket elevators,
crystallization to pneumatics transport, slurry filtration to silo
design.
3. Importance
• Solids used in chemical industries are most commonly in form of
particles.
• Solids in general are more difficult to handle then liquid and gases.
• In process industries solid appear in variety of forms, they may be
hard and abrasive, tough and rubbery, soft and fragile, dusty and
cohesive, Free flowing or sticky.
• Particulate materials, powders or bulk solids are used widely in all
areas of the process industries, for example in the food processing,
pharmaceutical, biotechnology, oil, chemical, mineral processing,
metallurgical, detergent, power generation, paint, plastics and
cosmetics industries.
• So the knowledge of their properties, handling, storage,
transportation, separation and processing is important from
chemical engineering point of view.
4. Course Content
• Introduction to the subject.
• Characterization of solid particles (size, shape and density).
• Fundamentals of solid handling (conveying and storage).
• Mixing
• Size reduction (crushing and grinding).
• Size enlargement (crystallization, pelletization, and
granualization).
• Motion of particles in a fluid.
• Separation techniques
• Screening and Sieving (for solid – solid separation)
• Sedimentation and Filtration (for solid – liquid separation)
• Gas cleaning (for solid – gas separation)
5. Books to be consult
• Coulson & Richardson’s Chemical Engineering
by J F Richardson & J H Harker with J R
Backhurst. Volume 2, Fifth Edition.
• Units Operations of Chemical Engineering by
Warren Lee McCabe, Julian Smith & Peter
Harriott. Seventh Edition.
• Introduction to Particle Technology by Martin
Rhodes. Second Edition.
7. 1. Characterization of Solid
Particle
Individual solid particles are characterized by
their size, shape and density.
Size and shape are easily specified for regular
particles, such as spheres and cubes, but for
irregular particles ?
8. Why measure particle properties?
• Better control of quality of product (cement, urea,
cosmetics etc)
• Better understanding of products, ingredients.
• Designing of equipment for different operations such
as crushing, grinding, conveying, separation, storage
etc.
9. Which particle properties are
important to measure?
• In addition to chemical composition, the behavior of particulate
materials is often dominated by the physical properties of the
constituent particles.
• These can influence a wide range of material properties including,
for example, reaction and dissolution rates, how easily ingredients
flow and mix, or compressibility and abrasivity.
• From a manufacturing and development perspective, some of the
most important physical properties to measure are:
– Particle size
– Particle shape
– Surface properties
– Mechanical properties
– Charge properties
– microstructure
10. 1.1. Particle shape
• The shape of an individual particle is expressed in terms of
the sphericity which is independent of particle size.
• Sphericity is the ratio of surface area of sphere of same
volume as particle to the surface area of particle.
• So for spherical particle sphericity is equal to one.
• For non-spherical particle it is defined by:
– Dp: equivalent diameter of particle
– Sp: surface area of one particle
– vp: volume of one particle
11. • The equivalent diameter is sometimes defined as the
diameter of a sphere of equal volume.
• For fine particles, Dp is usually taken to be the nominal
size based on screen analysis or microscopic analysis.
• The surface area is found from adsorption
measurements or from the pressure drop in a bed of
particles.
• For many crushed materials, Sphericity is between 0.6
and 0.8. For particles rounded by abrasion, their
sphericity may be as high as 0.95.
• Exercise: Determine the sphericity of a particle of
surface area 15 mm2 and volume 2 mm3.
12.
13. 1.2. Particle size
• By far the most important physical property of particulate samples
is particle size.
• Particle size measurement is routinely carried out across a wide
range of industries and is often a critical parameter in the
manufacturing of many products.
• Particle size has a direct influence on material properties such as:
– Reactivity or dissolution rate e.g. catalysts, tablets
– Stability in suspension e.g. sediments, paints
– Efficacy of delivery e.g. asthma inhalers
– Texture and feel e.g. food ingredients
– Appearance e.g. powder coatings and inks
– Flowability and handling e.g. granules
– Viscosity e.g. nasal sprays
– Packing density and porosity e.g. ceramics.
14. • In general "diameter" may be specified for any equidimensional
particles (e.g. emulsions or bubbles).
• Most of the solid particles used in industries are not
equidimensional, therefore cannot be specified by a single
dimension i.e. “diameter”.
• In order to simplify the measurement process, it is often convenient
to define the particle size using the concept of equivalent spheres.
• In this case the particle size is defined by the diameter of an
equivalent sphere having the same property as the actual particle
such as volume or mass for example.
15. • The equivalent sphere concept works very well for regular
shaped particles.
• However, it may not always be appropriate for irregular
shaped particles, such as needles or plates, where the size
in at least one dimension can differ significantly from that
of the other dimensions.
• Such particles are often characterized by the second
longest major dimension. For example needle like particles,
Dp would refer to the thickness of the particle, not their
length.
• Units used for particle size depend on the size of particles.
– Coarse particles: inches or millimetres
– Fine particles: screen size
– Very fine particles: micrometers or nanometers
– Ultra fine particles: surface area per unit mass, m2/g
16. 1.3 Mixed particle sizes and size
analysis
• In a sample of uniform particles of diameter Dp, the total
volume of the particles is m/ρp, where m = mass of the
sample, ρp = density. Since the volume of one particle is vp,
the total number of particle in the sample is:
• The total surface area of the particles is:
17. • To apply the above two equations to mixtures of particles
having various size and densities, the mixture is sorted into
fractions, each of constant density and approximately
constant size.
• Each fraction can then be weighed, or the individual
particles in it can be counted or measured by any of the
number of methods.
• Information from such a particle size analysis is tabulated to
show the mass fraction in each size increment as a function
of average particle size. The analysis tabulated in this way is
called differential analysis.
• A second way to present the information is through a
cumulative analysis obtained by adding, consecutively, the
individual increments, starting with that containing the
smallest particles, and tabulating or plotting the cumulative
sums against the maximum particle diameter in the
increment.
22. 1.4. Specific surface of mixture
• If the particle density ρp and spericity Φs are known,
the surface area of particles in each fraction can be
calculated and added to give the specific surface, Aw
(The total surface area of the unit mass of particles):
• Where xi = mass fraction in a given increment,
Dpi = average diameter (taken as
arithmetic average of the smallest and largest
particle diameters in increment).
23. 1.5. Average particle size
• The average particle size for a mixture of particles is
defined in several different ways.
• Volume surface mean diameter Ds:
If number of particle Ni in each fraction is known,
instead of mass fraction xi, then:
24. • Arithmetic mean diameter:
NT = number of particles
in the entire sample
• Mass mean diameter:
• Volume mean diameter:
• For sample consisting of uniform particles these average
diameters are, of course, all the same. For mixture containing
particle of various sizes, however, the several average
diameters may differ widely from one another.
25. 1.6. Number of particles in mixture
The volume of any particle is proportional to
its "diameter" cubed.
a = volume shape factor
Assuming that a is independent of size, then:
26. 1.7 Screen analysis
•Testing sieves are made of woven
wire screens.
•Openings are square.
•Screens are identified by Mesh No.
•Mesh No. is the numbers of opening
per linear inch.
•Area of opening in any screen = 2 x
Area of opening in next smaller screen.
•Mesh dimension of any screen = 1.41
x Mesh dimension of next smaller
screen.
27. • Standard screens are used to measure the size (and size distribution) of
particles in the size range between about 3 and 0.0015in (76mm and
38m m).
• Testing sieves are made of woven wire screens, the mesh and dimensions
of which are carefully standardized.
• The openings are square.
• Each screen is identified in mesh per inch, e.g. 10mesh, Dpi = 1/10 = 0.1in.
• The actual openings are however smaller than those corresponding to the
mesh number, because of thickness of wire.
• The area of the openings in any one screen in the series is exactly twice to
that of the openings in the next smaller screen. The ratio of the actual
mesh dimension of any screen to that of the next smaller screen is =1.41.
• For close sizing, intermediate screen are available, each of which has a
mesh dimension = 1.189 times that of next smaller standard screen.
• Analysis using standard screen: Screens are arranged serially in a stack,
with the smallest mesh at the bottom and the largest at the top. Materials
are loaded at top and then shacked for a period of time (e.g. 20 minutes).
• The particles retained of each screen are removed, weighed and masses
of individual screen increments are converted into mass fraction of total
sample.
• Any particle that passed the finest screen are caught in the pan at the
bottom of stack.
28.
29.
30. • The results of screen analysis are tabulated to show the
mass fraction of each screen increment as a function of
the mesh size range of the increment.
• The notation 14/20 means “through 14 mesh and on
20 mesh”.
• Typical screen analysis is given in next slide.
– First column: mesh size,
– second column: width of opening of screen,
– third column: mass fraction of total sample that is retained
on that screen xi (where i is the number starting from the
bottom of the stack),
– fourth column: averaged particle size Dpi (since the particle
on any screen are passed immediately by the screen ahead
of it, the averaged of these two screen are needed to
specify the averaged size in that increment).
– Fifth column: cumulative fraction smaller than Dpi.
34. Size measurement with fine particles
• Dry screening is useful for sizing particles with diameter
greater than about 44 μm (325 mesh).
• Wet screen analysis can be used for diameters down to 10
μm.
• Optical microscopy and gravity sedimentation are used
with particles 1 – 100 μm.
• Coulter counter, a device used for sizing and measuring
particles by measuring change in resistivity of an electrolyte
as it carry particle one by one through a small orifice.
• Light scattering techniques, sedimentation in centrifuges
and electron microscopy are other useful method for
measuring size of even smaller particles.
35. PARTICULATE SOLIDS IN BULK
• Masses of solid particles, especially when they are dry and
not sticky, have many properties of a fluid.
• They exert pressure on sides of walls of container.
• They flow through opening or inclined plane / channel.
• Depending upon the flow property particulate solids are
divided into two classes, cohesive (wet clay, reluctant to
flow through opening) and non-cohesive (grains, dry sand,
plastic chips etc readily flow out of bin or silo).
• They differ from liquid and gasses in several ways because
of particles interlocked at high pressure.
• Before the mass of tightly packed particles can flow, it must
increased in volume to permit interlocking grains to move
past one another.
36. Voidage
Voidage is the fraction of the total volume which is made up of
the free space between the particles and is filled with fluid.
37. • One of the most important characteristics of any
particulate mass.
• Voidage is the fraction of the total volume which is made
up of the free space between the particles and is filled with
fluid.
• Voidage corresponds to density of packing of the particles.
• In general, isometric particles, will pack more densely than
long thin particles or plates.
• The more rapidly material is poured on to a surface or into
a vessel, the more densely will it pack.
• If it is then subjected to vibration, further consolidation
may occur.
• The packing density or voidage is important in that it
determines the bulk density of the material.
• It affects the tendency for agglomeration of the particles.
• It critically influences the resistance offers to the fluid
flowing through it as for example in filtration.
39. • The main mechanisms giving rise to agglomeration are:
– Mechanical interlocking: This can occur particularly if the particles are long
and thin in shape, in which case large masses may become completely
interlocked.
– Surface attraction: Surface forces, including van der Waals’ forces, may give
rise to substantial bonds between particles, particularly where particles are
very fine (<10 μm), with the result that their surface per unit volume is high. In
general, freshly formed surface, such as that resulting from particle fracture,
gives rise to high surface forces.
– Plastic welding: When irregular particles are in contact, the forces between
the particles will be applied on extremely small surfaces and the very high
pressures developed may give rise to plastic welding.
– Electrostatic attraction: Particles may become charged as they are fed into
equipment and significant electrostatic charges may be built up, particularly
on fine solids.
– Effect of moisture: Moisture may have two effects. Firstly, it will tend to
collect near the points of contact between particles and give rise to surface
tension effects. Secondly, it may dissolve a little of the solid, which then acts
as a bonding agent on subsequent evaporation.
– Temperature fluctuations: give rise to changes in particle structure and to
greater cohesiveness.
40. Pressure in particulate solids
• The exerted pressure is not same in all directions. In
general the pressure applied in one direction creates some
pressure in other directions.
• The minimum pressure in solid masses is in the direction
normal to that of applied pressure.
• In homogenous masses the ratio of normal pressure to
applied pressure is constant which is the characteristic of
material which depends on:
– shape and interlocking tendency of particles,
– stickiness of grain surfaces,
– and degree of packing.
• It is nearly independent of particle size until the grain
become very small and material is no loner free-flowing.
41. Angle of repose
When the granular solid are piled up on a flat surface, the sides
of the pile are at a definite reproducible angle with the
horizontal. This angle is called angle of repose of that material.
42. • If solid is poured from a nozzle on to a plane surface, it will form an
approximately conical heap and the angle between the sloping side
of the cone and the horizontal is the angle of repose. When this is
determined in this manner it is sometimes referred to as the
dynamic angle of repose or the poured angle.
• The angle of repose may also be measured using a plane sheet to
which is stuck a layer of particles from the powder. Loose powder is
then poured on to the sheet which is then tilted until the powder
slides. The angle of slide is known as the static angle of repose or
the drained angle.
• Angles of repose vary from about 20◦ with free-flowing solids, to
about 60◦ with solids with poor flow characteristics.
• Powders with low angles of repose tend to pack rapidly to give a
high packing density.
• An angle which is similar to the static angle of repose is the angle of
slide which is measured in the same manner as the drained angle
except that the surface is smooth and is not coated with a layer of
particles.
43. • A measure of the frictional forces within the particulate mass
is the angle of friction.
• The angle of friction is important in its effect on design of bin
and hoppers.
44. • If the pressure at the base of a column of solids is measured as a function
of depth, it is found to increase approximately linearly with height up to a
certain critical point beyond which it remains constant.
• For heights greater than Lc the mass of additional solids is supported by
frictional forces at the walls of the hopper.
45. Storage of Solids
Coarse solid like gravel, sand
and coal are stored outside
in large pile unprotected
from weather. Solids that are two valuable
and soluble on expose to
outdoor piles are stored in
bins, hoppers or silos.
46.
47. • When hundred and thousands of tons of solids are involved
then storing out door in a pile is the most economical
method.
• Valuable solids are stored in bins, hoppers or silos.
• These are cylindrical or rectangular vessel of concrete or
metal.
– Silo is tall relatively small in diameter.
– Bin is not very tall but fairly wide.
– Hopper is small vessel with sloping bottom.
• Silos and bins are used storage for some period of time
while hoppers are used for temporary storage before
feeding solid to the process.
• All these container are loaded from top by some kind of
elevator; discharging is from the bottom.
• The major problem in solid storage vessel design is to
provide satisfactory discharge.
49. • Discharge from the hopper takes place through an aperture at the bottom
of the cone, and difficulties are commonly experienced in obtaining a
regular, or sometimes, any flow.
• Commonly experienced types of behavior are shown in Figure 1.15.
• Bridging of particles may take place and sometimes stable arches (b) may
form inside the hopper. These can usually be broken down by vibrators
attached to the walls.
• A further problem which is commonly encountered is that of “piping” or
“rat-holing”(c), in which the central core of material is discharged leaving
a stagnant surrounding mass of solids. As a result some solids may be
retained for long periods in the hopper and may deteriorate.
• Ideally, “mass flow” (a) is required in which the solids are in plug flow and
move downwards in masse in the hopper. The residence time of all
particles in the hopper will then be the same.
• In general, tall thin hoppers give better flow characteristics than short
wide ones and the use of long small-angle conical sections at the base is
advantageous.
• The nature of the surface of the hopper is important and smooth surfaces
give improved discharge characteristics.
50. Discharge rate, measurement and
control of solids flowrate
• The discharge rate of solid particles is usually controlled by the size
of the orifice or the aperture at the base of the hopper.
• The rate of discharge of solids through the outlet orifice is
substantially independent of the depth of solids in the hopper,
provided this exceeds about four times the diameter of the hopper.
• BROWN has developed an equation for flow through an orifice
51. • The flowrate of solids can be measured either as they leave
the hopper or as they are conveyed. Methods include:
– Fitting an orifice plate at the discharge point from the hopper.
– Using a belt-type feeder in which the mass of material on the
belt is continuously measured, by load cells for example or by a
nuclear densitometer which measures the degree of absorption
of gamma rays transmitted vertically through the solids on the
belt which is travelling at a controlled speed.
– Applying an impulse method in which a solids stream impacts
vertically on a sensing plate orientated at an angle to the
vertical. The horizontal component of the resulting force is
measured by as load cell attached to the plate.
– Alternatively, the level of the solids in the hopper may be
continuously monitored using transducers covered by flexible
diaphragms flush with the walls of the hopper. The diaphragm
responds to the presence of the solids and thus indicates
whether there are solids present at a particular level.
53. • Belt conveyors—where the solids are conveyed
horizontally, or at small angles to the horizontal, on a
continuous moving belt.
• Screw conveyors—in which the solids are moved along a
pipe or channel by a rotating helical impeller, as in a screw
lift elevator.
• Bucket elevators—in which the particles are carried
upwards in buckets attached to a continuously moving
vertical belt.
• Vibrating conveyors—in which the particles are subjected
to an asymmetric vibration and travel in a series of steps
over a table. During the forward stroke of the table the
particles are carried forward in contact with it, but the
acceleration in the reverse stroke is so high that the table
slips under the particles. With fine powders, vibration of
sufficient intensity results in a fluid-like behavior.
• Pneumatic/hydraulic conveying installations—in which the
particles are transported in a stream of air/water.
54.
55. Mixing of solids
• Achieving good mixing of particulate solids of different size
and density is important in many processes for example in
pharmaceuticals.
• It is more art than science.
• One can never achieve perfect mixing unlike that in fluid
phase.
• In the mixing of solid particles, the following three
mechanisms may be involved:
– Convective mixing, in which groups of particles are moved from
one position to another,
– Diffusion mixing, where the particles are distributed over a
freshly developed interface, and
– Shear mixing, where slipping planes are formed.
• A trough mixer with a ribbon spiral involves almost pure
convective mixing, a simple barrel-mixer involves mainly a
form of diffusion mixing and a shear hoppers involves shear
mixing.
56. Through mixer with
ribbon spiral:
Convective mixing
Barrel mixer:
Diffusive mixing
Shear hopper:
Shear mixing
The performance of an
industrial mixer is judged by:
•The time required
•The power load
•The properties of the product.
Both the requirements of the mixing device and the
properties of desired material vary widely from one problem
to another.
•Sometime a very high degree of uniformity is required
•Sometime a rapid mixing action is necessary
•Sometime a minimum amount of power is needed.
57. Mixing Equipments
• For paste and heavy material
– Kneader mixer
– Mixing rolls
– Muller mixer
– Pug mill
– Dispersers
• For granular solids
– Paddle mixer
– Ribbon mixer
– Tumbling mixer
– Internal screw mixer
– Impact wheel
58. Kneader mixer
• Two arm kneader handles suspensions, pastes and light plastic
masses.
• Kneading is a method of mixing used with deformable solid or
pastes.
• It involve squashing the mass flat, holding it over itself and
squashing it once again.
• Sometime kneading machine tear the mass apart and shear it
between the moving blade and stationary surface.
• Considerable energy is required even with fairly thin materials and
as the mass becomes stiff and rubbery, the power requirements
become very large.
• Material to be kneaded is dropped into trough and mixed for 5 – 20
minutes.
• Sometime the mass is heated while in the machine.
• Trough is often unloaded by tilting it so that it content spill out.
• In many kneader mixer trough is open.
59.
60. Muller Mixer
• Mulling is the rubbing action similar to that in motor and pestle.
• At large scale processing this action is given by wide heavy wheel of
mixer as shown in figure.
• In this particular design of muller the pan is stationary causing the
central vertical shaft is driven, causing the muller wheel to roll in a
circular path over the layer of solid or paste on the pan floor.
• The rubbing action results from the slip of wheel on the solid.
• Plow guided the solid under the muller wheel or to the opening in
the pan floor at the end of cycle when the mixture is being
discharged.
61. Mixing effectiveness
• Quantitatively measured by analysis of number of spot samples taken
randomly from various location of a mixed product.
• Can be done by adding some kind of tracer material for easy analysis.
• If:
– ‘μ’ – be the overall average fraction of tracer in the mix.
– ‘N’ – be the number of small samples taken from various location of the mix.
– ‘xi’ – be the fraction of tracer in each sample.
– ‘x(bar)’ – be the averaged value of measured concentrations.
• Then:
– x(bar) = μ for large value of N
– xi = x(bar) for perfect mixing
• For incomplete mixing xi differ from x(bar) which is given by standard
deviation:
• The deviation ‘s’ is the relative measure of mixing.
• Low value of ‘s’ determines good mixing.
• Its significance varies with amount of tracer.
62. • One index that increase as the mixing improves could be the reciprocal of
the ratio of ‘s’ to the standard deviation at zero mixing ‘σ0’.
• For zero mixing the mix will be in two layer one in which xi = 0 and one in
which xi = 1 then:
• Mixing index of the pastes ‘Ip’ is the ratio of ‘σ0’ to ‘s’:
• For solid the mixing index is based on standard deviation that would be
observed with a fully blended mixture ‘σe’ (for pastes this factor is zero).
• Where ‘μp’ is the fraction measured by counting number of particles and
‘n’ is the number of particles in the spot sample.
63. • Ip is unity in start and
increases as the mixing
proceed.
• Theoretical Ip would have
become infinite for very
long mixing time.
• It does not happen in real
because mixing never quite
complete plus analytical
method are not
extraordinary precise.
• The Ip for sand rises rapidly
and then level off and for
other material the trend is
same but mixing is slow
and limiting value is lower.
• Ip typical fall in the range of
10 – 150.
64. • For granular solid mixing is initially rapid.
• In tumbling blender mixing is never perfect.
• Forces specially electrostatic are always at work which retard
mixing.
65. Mixing index at zero time for granular solid
• The standard deviation for complete mixing ‘σe’ is the used as a
reference with mixing of granular solids.
• The standard deviation for zero mixing ‘σo’ is used as a reference
with mixing of pastes.
• If ‘n’ is set equals to 1 then both equations become identical.
• When n = 1 then xi = 1 or xi = 0 which is the same as in completely
unmixed material.
• So for mixing index for granular solid for zero mixing willing be:
66. Rate of mixing
• In mixing as in other processes
the rate is directly
proportional to driving force.
• For the case of granular solid
where ‘Is’ is the mixing index
and ‘(1 – Is)’ is the driving
force because mixing index at
equilibrium will be 1.
• It is found that for short
mixing time the rate of change
of ‘Is’ is directly proportional
to ‘(1 – Is)’.
• By solving we can get the time
of mixing required for the
desire mixing.
70. CLASSIFICATION OF SOLID PARTICLES
• The problem of separating solid particles according to their
physical properties is of great importance.
• For examples:
– In the mining industry it is necessary to separate the valuable
constituents in a mineral from the adhering rocks which is
usually of lower density. In this case, it is first necessary to crush
the material so that each individual particle contains only one
constituent.
– In coal washing plants in which dirt is separated from the clean
coal.
– The processing industries are more usually concerned with
separating a single material, such as the product from a size
reduction plant or in obtaining a uniform material for
incorporation in a system in which a chemical reaction takes
place
71. • Separation depends on the selection of a process in which
the behavior of the material is influenced to a very marked
degree by some physical property.
– If a material is to be separated into various size fractions, a
sieving method may be used because this process depends
primarily on the size of the particles.
– Other methods of separation depend on the differences in the
behavior of the particles in a moving fluid, and in this case the
size and the density of the particles are the most important
factors.
– Other processes make use of differences in electrical or
magnetic properties of the materials.
• The maximum range of sizes that can be separated is
calculated from the ratio of the sizes of the particles of the
two materials which have the same terminal falling
velocities.
72.
73. • Gravity settling
– The settling tank
– The elutriator
– The Spitzkasten
– The double cone classifier
– The mechanical classifier
– The bowl classifier
– The hydraulic jig
– Riffled tables
• Centrifugal separators
– The hydrocyclone
• Sieves or screens
– Hummer electromagnetic
screen
– Trommel
• Magnetic separators
• Electrostatic separators
• Flotation machine
• Gas cleaning equipment
– Gravity separators
– Centrifugal separators
– Inertia or momentum
separators
– Fabric filters
– Electrostatic precipitators