pH value of soil
CourseTitle: ChemicalTechnology
II
Name: Shaikh Ashraful Alam
Applied Chemistry & Chemical
Engineering
Soil PH: What it Means
o Soil pH is a measure of the acidity and alkalinity in soils.
o The optimal pH range for most plants is between 5.5 and 7.0.
Range of PH
o The pH scale goes from 0 to 14 with
pH 7 as the neutral point.
o From pH 7 to 0 the soil is
increasingly more acidic and from
pH 7 to 14 the soil is increasingly
more alkaline or basic.
o Any soil above pH 10 and below pH
3 may be said sterile.
Sources of acidity
o Rainfall
o Fertilizer use
o Plant root activity
o Acid rain
o Mine spoil
Sources of alkalinity
o Alkaline soils have a high saturation of base cations (K+, Ca2+,
Mg2+ and Na+).
o Alkaline soils are characterized by the presence of carbonates.
o Soil in areas with limestone near the surface are alkaline from the
calcium carbonate in limestone constantly mixing with the soil.
Measuring Soil pH
o The most accurate method of determining soil pH is by a pH meter
o Using certain indicators or dyes.
pH Affects Nutrients, Minerals and Growth
o The effect of soil pH is great on the solubility of minerals or nutrients.
o Phosphorus is never readily soluble in the soil but is most available in soil with
a pH range centered around 6.5.
o Extremely and strongly acid soils (pH 4.0-5.0) can have high concentrations of
soluble aluminum, iron and manganese which may be toxic to the growth of
some plants.
o A pH range of approximately 6 to 7 promotes the most ready availability of
plant nutrients.
Changes in Soil pH
Increasing pH of acidic soil:
o Lime is usually added to acid soils to increase soil pH.
o The addition of lime not only replaces hydrogen ions and raises soil pH.
o Eliminating most major problems associated with acid soils but it also provides two
nutrients, calcium and magnesium to the soil. Lime also makes phosphorus that is
added to the soil more available for plant growth .
Decreasing pH of alkaline soil:
o The pH of an alkaline soil can be reduced by adding acidifying agents or organic
materials.
o Acidifying fertilizers, such as those containing ammonium, can help to reduce the
pH of a soil.
o Add elemental sulfur (90 or 99% sulfur material) annually at a rate of 6 to 10
pounds per 1000 square feet of area.
Ph valu of soil

Ph valu of soil

  • 1.
    pH value ofsoil CourseTitle: ChemicalTechnology II Name: Shaikh Ashraful Alam Applied Chemistry & Chemical Engineering
  • 2.
    Soil PH: Whatit Means o Soil pH is a measure of the acidity and alkalinity in soils. o The optimal pH range for most plants is between 5.5 and 7.0. Range of PH o The pH scale goes from 0 to 14 with pH 7 as the neutral point. o From pH 7 to 0 the soil is increasingly more acidic and from pH 7 to 14 the soil is increasingly more alkaline or basic. o Any soil above pH 10 and below pH 3 may be said sterile.
  • 3.
    Sources of acidity oRainfall o Fertilizer use o Plant root activity o Acid rain o Mine spoil Sources of alkalinity o Alkaline soils have a high saturation of base cations (K+, Ca2+, Mg2+ and Na+). o Alkaline soils are characterized by the presence of carbonates. o Soil in areas with limestone near the surface are alkaline from the calcium carbonate in limestone constantly mixing with the soil.
  • 4.
    Measuring Soil pH oThe most accurate method of determining soil pH is by a pH meter o Using certain indicators or dyes. pH Affects Nutrients, Minerals and Growth o The effect of soil pH is great on the solubility of minerals or nutrients. o Phosphorus is never readily soluble in the soil but is most available in soil with a pH range centered around 6.5. o Extremely and strongly acid soils (pH 4.0-5.0) can have high concentrations of soluble aluminum, iron and manganese which may be toxic to the growth of some plants. o A pH range of approximately 6 to 7 promotes the most ready availability of plant nutrients.
  • 5.
    Changes in SoilpH Increasing pH of acidic soil: o Lime is usually added to acid soils to increase soil pH. o The addition of lime not only replaces hydrogen ions and raises soil pH. o Eliminating most major problems associated with acid soils but it also provides two nutrients, calcium and magnesium to the soil. Lime also makes phosphorus that is added to the soil more available for plant growth . Decreasing pH of alkaline soil: o The pH of an alkaline soil can be reduced by adding acidifying agents or organic materials. o Acidifying fertilizers, such as those containing ammonium, can help to reduce the pH of a soil. o Add elemental sulfur (90 or 99% sulfur material) annually at a rate of 6 to 10 pounds per 1000 square feet of area.

Editor's Notes

  • #3 Denomination pH range Ultra acidic < 3.5 Extremely acidic 3.5–4.4 Very strongly acidic 4.5–5.0 Strongly acidic 5.1–5.5 Moderately acidic 5.6–6.0 Slightly acidic 6.1–6.5 Neutral 6.6–7.3 Slightly alkaline 7.4–7.8 Moderately alkaline 7.9–8.4 Strongly alkaline 8.5–9.0 Very strongly alkaline > 9.0
  • #4 Rainfall Rainfall contributes to a soil’s acidity. Water (H O) combines with carbon dioxide (CO ) to form a weak acid — carbonic acid (H CO ). The weak acid ionizes, releasing hydrogen (H ) and bicarbonate (HCO ). Fertilizer use: Ammonium (NH4+) fertilizers react in the soil in a process called nitrification to form nitrate (NO3−), and in the process release H+ ions Plant root activity:\ Plants take up nutrients in the form of ions (NO3−, NH4+, Ca2+, H2PO4−, etc.), and often, they take up more cations than anions. However plants must maintain a neutral charge in their roots. In order to compensate for the extra positive charge, they will release H+ ions from the root. Some plants will also exude organic acids into the soil to acidify the zone around their roots to help solubilize metal nutrients that are insoluble at neutral pH, such as iron (Fe). Mine spoil: Severely acidic conditions can form in soils near mine spoils due to the oxidation of pyrite. Potential acid sulfate soils naturally formed in waterlogged coastal and estuarine environments can become highly acidic when drained or excavated.