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NANOSCIENCE NANOTECHNOLOGY Walkiria Eyre [email_address]
TOPICS  ,[object Object],[object Object],[object Object],[object Object],Part 1 Part 2
Nanoscience Fisics Engeneering Biology Chemistry Basic life processes Chemical reactions Medicine Classical Fisics Quantum Fisics Smart materials Technological aplications
Nanotechnology ,[object Object],[object Object],[object Object],[object Object]
Nanostructures ,[object Object],[object Object],[object Object],[object Object]
 
 
NANO = 10 -9 ,[object Object],[object Object],[object Object],[object Object]
Nanofabrication techniques ,[object Object],[object Object]
Beginning of Nanoscience ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
[object Object],[object Object],[object Object]
IBM Logo xenon atoms on nickel substract
[object Object]
Instruments: ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],From:  http://en.wikipedia.org/wiki/Scanning_probe_microscopy
STM From:  http://en.wikipedia.org/wiki/Scanning_tunnelling_microscope
Piezoelectric effect ,[object Object],[object Object]
Images creation process ,[object Object],[object Object],From:  http://www.almaden.ibm.com/vis/stm/gallery.html
Continue... ,[object Object],From:  http://www.almaden.ibm.com/vis/stm/gallery.html
[object Object],From:  http://www.almaden.ibm.com/vis/stm/gallery.html
[object Object],From:  http://www.almaden.ibm.com/vis/stm/gallery.html
[object Object],From:  http://www.almaden.ibm.com/vis/stm/gallery.html
[object Object],[object Object],From:  http://www.almaden.ibm.com/vis/stm/gallery.html
[object Object],From:  http://www.almaden.ibm.com/vis/stm/gallery.html
Process: From:  http://www.almaden.ibm.com/vis/stm/gallery.html
Examples: From:  http://www.almaden.ibm.com/vis/stm/gallery.html
Nanostructures: ,[object Object],[object Object],[object Object],[object Object],[object Object]
Nanostructures and potencial aplications: ,[object Object],[object Object],[object Object],[object Object],From:  http://www.mct.gov.br/index.php/content/view/index.php
A typical configuration for a quantum well (AlIn)GaN LED on a sapphire substrate.  Epitaxial layer thicknesses are exaggerated for clarity and are not   to scale. From:  http://www.mtmi.vu.lt/pfk/funkc_dariniai/diod/led.htm
[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],From:  http://www.mct.gov.br/index.php/content/view/index.php
“ Lead selenide (PbSe) quantum dots like the ones in this image,  <10nm in size, emit light in the visible regime (~1 to 3eV).  The nanoparticles in this scanning tunneling electron  micrograph are similar to those in the  colorful photograph  of  CdSe quantum dot containing material. (Micrograph courtesy of Mick Thomas, Cornell University) ” From:   http://instruct1.cit.cornell.edu/courses/comm494-nano/working_version/3article.htm
The emission from quantum dots is tuned by changing the particle size. These quantum dot solids, containing CdSe nanocrystals dispersed in a polymer matrix, span the visible spectrum when excited with ultraviolet light. For scale, containers are ~ 1 cm in diameter.   From:   http://instruct1.cit.cornell.edu/courses/comm494-nano/working_version/3article.htm
[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],From:  http://www.mct.gov.br/index.php/content/view/index.php
“ Scanning tunneling microscope (STM) image of a silver surface with adsorbed potassium atoms and two C-60 buckyballs. Using the STM tip to drag one of the buckyballs around the surface, UC Berkeley researchers were able to pick up single potassium atoms at a time, subtly altering the buckyball's electronic properties with each addition. Credit: Michael Crommie/UC Berkeley. (Image courtesy of Science) ” From:  http://www.nanotech-now.com/ucb-release-03112004.htm
[object Object],[object Object],[object Object],[object Object],From:  http://www.mct.gov.br/index.php/content/view/index.php
[object Object],[object Object],[object Object],[object Object],From:  http://www.mct.gov.br/index.php/content/view/index.php
[object Object],From:  http://www.mtl.kyoto-u.ac.jp/english/laboratory/nanoscopic/nanoscopic.htm
[object Object],[object Object],[object Object],From:  http://www.mct.gov.br/index.php/content/view/index.php
CNT
 
 
 
 
 
MAGNETIC NANOSTRUCTURES
Topics ,[object Object],[object Object],[object Object],[object Object],[object Object]
Spin ,[object Object],[object Object]
Magnetic moment SPIN ( angular   moment) *charge* Magnetic Moment
Magnetic Moment
Magnetization ,[object Object],[object Object]
MAGNETIZATION Alignment of electrons due to the field
[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Magnetic Behaviors ,[object Object],Metamagnetic *Superparamagnetics* Spin glass Speromagnetic Helimagnetic Diamagnetic Paramagnetic Ferromagnetic Ferrimagnetic Antiferromagnetic
Magnetic Susceptibility ,[object Object],[object Object]
Diamagnetism ,[object Object],[object Object],[object Object]
Examples of diamagnetic substances: ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Interesting effects: From:  http://en.wikipedia.org/wiki/Diamagnetism
Paramagnetism ,[object Object]
Examples of paramagnetic substances ,[object Object],[object Object],[object Object],[object Object],[object Object]
Ferromagnetism ,[object Object],[object Object],It generates regions called DOMAINS
Ferromagnetic materials examples ,[object Object],[object Object],[object Object],[object Object],[object Object]
FERROMAGNETISM ,[object Object]
Magnetic Domains The domains are delineated with colloidal iron oxide particles FOTOMICROGRAFY   (Bell Telephone Laboratories)  From:  http://www.feiradeciencias.com.br/sala13/13_38.asp
[object Object],MICROSCOPY From:  http://www.icmm.csic.es/eng/gallery/gall_omtp.htm
CURIE TEMPERATURE  ,[object Object],[object Object],16 o C  Gadolinium 358 o C Nickel 1131 o C Cobalt 770 o C Iron Curie point Element
Hysteresis loop ,[object Object],[object Object]
Hysteresis Loop ,[object Object]
Hysteresis Loop From:  http://hyperphysics.phy-astr.gsu.edu/Hbase/solids/imgsol/hyloop.gif
Definitions: From:  http://hyperphysics.phy-astr.gsu.edu/Hbase/solids/imgsol/coercivity.gif
[object Object],[object Object],[object Object],Magnetic nanostructured systems:
Magnetic Behavior Configuration of minimum potential energy Magnetic domains with random orientation size temperature
[object Object],[object Object],Random orientation is not energetically favorable **Spontaneous permanent magnetization** SINGLE-DOMAIN
Temperature variation: ,[object Object],[object Object],Temperature increase Rotation in the magnetization direction
Thus... ,[object Object],[object Object],Quantum force superparamagnetism
Thin films ,[object Object]
Some aplications: ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Fabrication Techniques ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
[object Object],From:  http://www.surfaces.lsu.edu/nioncu.html
Ph otomicrogra phy   of SBN -s trontium  b arium  n iobate -   thin films .
From:  http://www.liec.ufscar.br/ceramica/index.html
Thin films and giant magnetoresistance ,[object Object],[object Object],[object Object],[ iron – cobalt – nickel ] [ chromium – copper – ruthenium ] Giant magnetoresistance
[object Object],Transmission Electron Microscopy on an Fe/Si multilayer (photo courtesy of EPFL)  From:  http://www.gencoa.com/tech/f_multilayer.html
Giant Magnetoresistance: ,[object Object],[object Object]
Experiment: ,[object Object]
Results: ,[object Object],[object Object],[object Object],[object Object]
Applications of the giant magnetoresistance effect: ,[object Object],[object Object]
[object Object],From:  http://nano.gov/ e  http://www.mct.gov.br/ US$milions
T H E E N D !

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Nano-Science

  • 1. NANOSCIENCE NANOTECHNOLOGY Walkiria Eyre [email_address]
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  • 3. Nanoscience Fisics Engeneering Biology Chemistry Basic life processes Chemical reactions Medicine Classical Fisics Quantum Fisics Smart materials Technological aplications
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  • 12. IBM Logo xenon atoms on nickel substract
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  • 15. STM From: http://en.wikipedia.org/wiki/Scanning_tunnelling_microscope
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  • 24. Process: From: http://www.almaden.ibm.com/vis/stm/gallery.html
  • 25. Examples: From: http://www.almaden.ibm.com/vis/stm/gallery.html
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  • 28. A typical configuration for a quantum well (AlIn)GaN LED on a sapphire substrate. Epitaxial layer thicknesses are exaggerated for clarity and are not to scale. From: http://www.mtmi.vu.lt/pfk/funkc_dariniai/diod/led.htm
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  • 30. “ Lead selenide (PbSe) quantum dots like the ones in this image, <10nm in size, emit light in the visible regime (~1 to 3eV). The nanoparticles in this scanning tunneling electron micrograph are similar to those in the colorful photograph of CdSe quantum dot containing material. (Micrograph courtesy of Mick Thomas, Cornell University) ” From: http://instruct1.cit.cornell.edu/courses/comm494-nano/working_version/3article.htm
  • 31. The emission from quantum dots is tuned by changing the particle size. These quantum dot solids, containing CdSe nanocrystals dispersed in a polymer matrix, span the visible spectrum when excited with ultraviolet light. For scale, containers are ~ 1 cm in diameter. From: http://instruct1.cit.cornell.edu/courses/comm494-nano/working_version/3article.htm
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  • 33. “ Scanning tunneling microscope (STM) image of a silver surface with adsorbed potassium atoms and two C-60 buckyballs. Using the STM tip to drag one of the buckyballs around the surface, UC Berkeley researchers were able to pick up single potassium atoms at a time, subtly altering the buckyball's electronic properties with each addition. Credit: Michael Crommie/UC Berkeley. (Image courtesy of Science) ” From: http://www.nanotech-now.com/ucb-release-03112004.htm
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  • 38. CNT
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  • 47. Magnetic moment SPIN ( angular moment) *charge* Magnetic Moment
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  • 50. MAGNETIZATION Alignment of electrons due to the field
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  • 56. Interesting effects: From: http://en.wikipedia.org/wiki/Diamagnetism
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  • 62. Magnetic Domains The domains are delineated with colloidal iron oxide particles FOTOMICROGRAFY (Bell Telephone Laboratories) From: http://www.feiradeciencias.com.br/sala13/13_38.asp
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  • 67. Hysteresis Loop From: http://hyperphysics.phy-astr.gsu.edu/Hbase/solids/imgsol/hyloop.gif
  • 68. Definitions: From: http://hyperphysics.phy-astr.gsu.edu/Hbase/solids/imgsol/coercivity.gif
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  • 70. Magnetic Behavior Configuration of minimum potential energy Magnetic domains with random orientation size temperature
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  • 78. Ph otomicrogra phy of SBN -s trontium b arium n iobate - thin films .
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  • 87. T H E E N D !