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International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 05 Issue: 03 | Mar-2018 www.irjet.net p-ISSN: 2395-0072
© 2018, IRJET | Impact Factor value: 6.171 | ISO 9001:2008 Certified Journal | Page 3572
ENVIRONMENTAL IMPACT OF BIODIESEL DERIVED FROM ANIMAL FAT
& ITS BLEND
Kunal P. Patil1, Hemant D Sapkal1, Bhupesh K Lone1, Sumeet B Rahane1, Prof. Vinay More2
1Students, Department of Mechanical Engineering, Dilkap Research Institute of Engineering and Management
Studies Neral, Tal-Karjat, Dist-Raigad, Maharashtra, India.
2Professor, Department of mechanical engineering, Dilkap research institute of engineering and Management
studies,Neral, Tal-Karjat, Dist-Raigad, Maharashtra, India
----------------------------------------------------------------------***-------------------------------------------------------------------
Abstract—This research paper consist of attention to
acquiring knowledge of preparation of different blends of
biodiesel using catalyst methyl ester from unused animal fat,
and in this we assess engine analysis and performance of
respective blends. Need of preparation of biodiesel emerges
due to energy crisis. Energy crisis has become very serious
and significant problem all over the world and it is better
understand by more and more energy users. Bio-diesel can
be made from many vegetables like jatropha, soyabean,
sunflower, Mexicana seeds and waste cooking oil but This
vegetables oils are edible and useful for human being hence
we will look for another feedstock .We derived biodiesel
from waste chicken fat along with small percentage of low
fat oil.
Index Terms—Biodiesel, Waste chicken fat oil, Engine
testing, Biodiesel production.
1. INTRODUCTION
A .General Introduction-
In the 21st century world is facing day by day two major
conflicts, one is fossil fuel depletion and another one is bio-
degradability. Up to 2078 Diesel will be very limited
available source or it will be diminished.
So it became necessary to find alternative source so the
production of biodiesel In 19th century, it has main
advantage that the physical and chemical properties
similar to the pure diesel fuel. Main definition of biodiesel
is mono alkyl ester of long fatty acid and the process for
producing it is called trans esterification. Generally the
biodiesel is preparing from the vegetable oil which
ultimately effects increase the price in food market and
expected to increase more in future. Concentrating to that
condition production of biodiesel started in which the
vegetable oil or edible sources which can effect to human
routine.
Generally utilised feedstock for the production of biodiesel
contains soybean, rapeseed/canola, used (waste)
vegetable oils, and animal fat. Safflower, sunflower, and
hazelnut produce oil that could be used for biodiesel.
Warm climate tree oils such as palm oil and jatropha are
used as biodiesel feedstock in some parts of the world.
Feedstock for biodiesel are generally chosen based on
price and performance. Some are better for cold
temperature conditions. All the above feedstock have
alternative uses and markets, so the prices can fluctuate
depending on demand. But the waste chicken fat is low
cost raw material for preparing biodiesel and massively
available. This biodiesel from chicken fat is renewable,
nontoxic and also less harms to the environment.
Biodiesel is frequently blended with petroleum diesel in
ratio of 6%(B6) , 12%(B12), 18%(B18), 30%(B30),
36%(B36).
B. Problem Statement-
Recent studies show that oil is the main source of
energy for many countries. Due to increasing demand
from end customers for renewable fuel sources with low
negative environmental impacts biodiesel has become
greater relief source for the problem.
The use of biodiesel from reuse of cooking oil presents
a proposal for the minimization of waste to be disposed of
in sewage systems and contaminating rivers and
Groundwater, taking into account that litters of such
waste oil can contaminate thousands of litters of water
source. The development of this work aims at exploring
alternatives for the use of biofuels and evaluating the
environmental impacts as well as performance of engine.
Hence various alternative methods for production of
biodiesel must be searched which don’t leads to any
harmful impacts and no compromise in the energy
obtained. This led us to foundation of extraction of
biodiesel from waste fried oil.
C .Objectives-
 Identification of environment friendly and renewable
resources as alternative for petro diesel.
 This project aims to improve the energy balance, the
carbon performance, the sustainability and the overall
economics of biodiesel production, and to reduce the
sensitivity of biodiesel to volatile methanol and
glycerine spot prices.
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 05 Issue: 03 | Mar-2018 www.irjet.net p-ISSN: 2395-0072
© 2018, IRJET | Impact Factor value: 6.171 | ISO 9001:2008 Certified Journal | Page 3573
 Preparation of blends of biodiesel with diesel fuel
chicken fat by using esterification and Trans
esterification reaction.
 Extraction of oil from chicken fat by steam distillation
process.
 To perform engine analysis and exhaust analysis.
 Quality testing of all biodiesel blend along with diesel
fuel e.g. density, viscosity, flash point, fire point, cetane
number etc. (B00, B06, B12, B18, B24, B30, and B36.
 To find best blends for diesel fuel with no need of
modification in diesel engine.
2. MATERIALS AN D METHODOLOGY FOR BLEND
PREPARATION
A. Material & Chemicals:
 Waste chicken fat
 Small percentage of edible oil
 Sodium Chloride
 Methyl alcohol
 Sulphuric Acid
 Sodium Hydroxide
B. Equipment:
 Reactor flask
 Thermometer
 Magnetic stirrer
 Distillation Setup
 Beakers and Test tubes
C. Methodology:
PART A: EXTRACTION OF OIL
1. Take 2 kg chicken fat and add low fat oil (400 ml)
with 100 gm sodium chloride as an ingredients.
2. mixture is heated at medium flame for 16 hrs and
stirred so that it will not stick to the vessel.
3. After 16 hrs extraction of oil done from chicken
fat.
4. Extracted oil is taken in reactor flask set up which
consist of 4 inputs valves ,one for thermometer
,one for magnetic stirrer, and one for adding
additives and another for distillation setup.
5. Now in the flask 10% CH3OH and 0.5%
sulphuric acid is added as an solvent and
catalyst respectively. The temp is maintain at 60
degree centigrade.
PART B: ESTERIFICATION-TRANSESTERIFICATION
6. To get homogenous mixture with help of stirrer
rigorously stirring is done (mechanical stirrer )
for 2 hours at constant temperature 56-60 ’C
,process known as Esterification
7. After esterification one separate solution is
prepared of 0.5% sodium hydroxide & 10%
Methyl alcohol in separated beaker, that solution
will add to previous mixture in reactor flask and
stirring is continued for 2 hours process known
as Transesterification.
8. After 10 hours 2 layers will formed, upper will be
cloudy layer (impure biodiesel) and bottom is
glycerin which is byproduct. That high density
glycerin will be separated.
9. Obtained impure cloudy biodiesel contains
catalyst & solvent which is removed by washing
step by hot water (having temperature 64’C),
usually 3-4 steps are followed.
10. Finally moisturized Biodiesel will be formed, to
remove moisture pure biodiesel is heated and
pure biodiesel is obtained.
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 05 Issue: 03 | Mar-2018 www.irjet.net p-ISSN: 2395-0072
© 2018, IRJET | Impact Factor value: 6.171 | ISO 9001:2008 Certified Journal | Page 3574
Table 1.Properties of diesel & Biodiesel
Chicken fat oil biodiesel blends
B6% B12% B18% B24% B30%
0.833 0.384 0.836 0.838 0.841
42.41 42.2 42.09 41.96 41.86
49.44 49.7 49.88 49.95 50.11
_ _ 2.96 _
NA NA NA NA NA
75 89 96 102 110
_ _ _ 111 _
_ _ _ 3 _
_ _ _ -1 _
_ _ _ 0.1 _
Engine testing: Engine testing was carried out on IC
engine
with following specifications-
Fuel :Diesel
No. of cylinders :1
No. of strokes :4
Cylinder diameter :87.5mm
Stroke length :110mm
Connecting rod length :234mm
Orifice diameter :20mm
Dynamometer arm length :185mm
Power :3.5kW
Speed :1500RPM
CR :18:1
As above engine specifications keeping as C.R. 18
readings been taken. The fuel tank and pipe were cleaned
before inserting each blends of biodiesel. The emission
testings were carried on AVL 437 smoke meter Operating
Unit.
3. RESULT EMISSION ANALYSIS
Blends Load(in kg) CO % CO2 %
B00 0.3 0.024 0.5
3 0.027 0.9
6 0.016 1.2
9 0.015 1.6
12 0.016 1.9
B06 0.3 0.046 0.98
3 0.043 1.2
6 0.042 1.5
9 0.036 1.8
12 0.031 2.2
B12 0.3 0.039 0.6
3 0.038 1
6 0.026 1.3
9 0.03 1.7
12 0.033 2.2
B18 0.3 0.036 1
3 0.026 1.4
6 0.021 1.7
9 0.02 2.09
12 0.02 2.2
B30 0.3 0.032 0.6
3 0.036 1
6 0.021 1.5
9 0.026 1.7
12 0.028 2.09
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 05 Issue: 03 | Mar-2018 www.irjet.net p-ISSN: 2395-0072
© 2018, IRJET | Impact Factor value: 6.171 | ISO 9001:2008 Certified Journal | Page 3575
0
1
2
3
0.3 3 6 9 12
CO2 emission
B6 B12 B18 B30 B00
4. CONCLUSION AND SCOPE FOR FUTURE WORK
Conclusion:
In this project we produced biodiesel from waste chicken
fat in the form of various blends viz., B6 B12, B18, B30,
B00. We Achieved biodiesel using method which has very
few difficulties to prepare biodiesel and make the best or
most effective use .After preparing this biodiesel we
analysed the properties of biodiesel and compared with
pure diesel along with that we did engine analysis (IC
engine) & emission analysis which showed us some
characteristic properties of this prepared blends. On the
basis of the obtained data we arrive at a judgement that
the blends B18 and B12 shows similar properties as the
pure diesel shows (According to ASTM Std ) and we can
use this as alternative source for pure diesel.
According to today’s circumstance of fossil fuel depletion
and bio-degradability biodiesel is best alternative source.
This biodiesel has very less harmful effect on
environment.
Reference:
[1]Turning Chicken Fat Into Biodiesel - Georgia Farm
Monitor
https://www.youtube.com/watch?v=0rRvAgzKEDw
[2] K Srinivasa Rao, Dr. A Ramakrishna and P V Rao,
“performance and emission characteristics of DI-CI Diesel
Engine with Preheated Chicken Fat Biodiesel”,
International Journal of Mechanical Engineering &
Technology (IJMET). Volume: 4, Issue: 3, Pages: 177-190.
2013
[3]Jugulkar L.M And Jagadale S.S, “Performance
Characteristics of Single Cylinder Diesel Engine Using
Blend of Chicken Fat Based Biodiesel”, International
Journal of Mechanical Engineering & Technology (IJMET).
Volume: 3, Issue:2, Pages: 754-768. 2012
[4] kambiz Tahvildari A, Nages Davari B and Mohammad
Reaza, “Biodiesel Production from Waste Chicken Fat Oil
based Sources”, world academy of science, Engineering
and Technology 55. 2011
[5] Ertan Alptekin, Mustafa Canakci and huseyin sanli,
“methyl ester production from chicken fat with high FFA”,
world renewable congress, 8-13 may, Sweden, pp.319-
326, 2011.

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IRJET- Environmental Impact of Biodiesel Derived from Animal Fat & Its Blend

  • 1. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 05 Issue: 03 | Mar-2018 www.irjet.net p-ISSN: 2395-0072 © 2018, IRJET | Impact Factor value: 6.171 | ISO 9001:2008 Certified Journal | Page 3572 ENVIRONMENTAL IMPACT OF BIODIESEL DERIVED FROM ANIMAL FAT & ITS BLEND Kunal P. Patil1, Hemant D Sapkal1, Bhupesh K Lone1, Sumeet B Rahane1, Prof. Vinay More2 1Students, Department of Mechanical Engineering, Dilkap Research Institute of Engineering and Management Studies Neral, Tal-Karjat, Dist-Raigad, Maharashtra, India. 2Professor, Department of mechanical engineering, Dilkap research institute of engineering and Management studies,Neral, Tal-Karjat, Dist-Raigad, Maharashtra, India ----------------------------------------------------------------------***------------------------------------------------------------------- Abstract—This research paper consist of attention to acquiring knowledge of preparation of different blends of biodiesel using catalyst methyl ester from unused animal fat, and in this we assess engine analysis and performance of respective blends. Need of preparation of biodiesel emerges due to energy crisis. Energy crisis has become very serious and significant problem all over the world and it is better understand by more and more energy users. Bio-diesel can be made from many vegetables like jatropha, soyabean, sunflower, Mexicana seeds and waste cooking oil but This vegetables oils are edible and useful for human being hence we will look for another feedstock .We derived biodiesel from waste chicken fat along with small percentage of low fat oil. Index Terms—Biodiesel, Waste chicken fat oil, Engine testing, Biodiesel production. 1. INTRODUCTION A .General Introduction- In the 21st century world is facing day by day two major conflicts, one is fossil fuel depletion and another one is bio- degradability. Up to 2078 Diesel will be very limited available source or it will be diminished. So it became necessary to find alternative source so the production of biodiesel In 19th century, it has main advantage that the physical and chemical properties similar to the pure diesel fuel. Main definition of biodiesel is mono alkyl ester of long fatty acid and the process for producing it is called trans esterification. Generally the biodiesel is preparing from the vegetable oil which ultimately effects increase the price in food market and expected to increase more in future. Concentrating to that condition production of biodiesel started in which the vegetable oil or edible sources which can effect to human routine. Generally utilised feedstock for the production of biodiesel contains soybean, rapeseed/canola, used (waste) vegetable oils, and animal fat. Safflower, sunflower, and hazelnut produce oil that could be used for biodiesel. Warm climate tree oils such as palm oil and jatropha are used as biodiesel feedstock in some parts of the world. Feedstock for biodiesel are generally chosen based on price and performance. Some are better for cold temperature conditions. All the above feedstock have alternative uses and markets, so the prices can fluctuate depending on demand. But the waste chicken fat is low cost raw material for preparing biodiesel and massively available. This biodiesel from chicken fat is renewable, nontoxic and also less harms to the environment. Biodiesel is frequently blended with petroleum diesel in ratio of 6%(B6) , 12%(B12), 18%(B18), 30%(B30), 36%(B36). B. Problem Statement- Recent studies show that oil is the main source of energy for many countries. Due to increasing demand from end customers for renewable fuel sources with low negative environmental impacts biodiesel has become greater relief source for the problem. The use of biodiesel from reuse of cooking oil presents a proposal for the minimization of waste to be disposed of in sewage systems and contaminating rivers and Groundwater, taking into account that litters of such waste oil can contaminate thousands of litters of water source. The development of this work aims at exploring alternatives for the use of biofuels and evaluating the environmental impacts as well as performance of engine. Hence various alternative methods for production of biodiesel must be searched which don’t leads to any harmful impacts and no compromise in the energy obtained. This led us to foundation of extraction of biodiesel from waste fried oil. C .Objectives-  Identification of environment friendly and renewable resources as alternative for petro diesel.  This project aims to improve the energy balance, the carbon performance, the sustainability and the overall economics of biodiesel production, and to reduce the sensitivity of biodiesel to volatile methanol and glycerine spot prices.
  • 2. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 05 Issue: 03 | Mar-2018 www.irjet.net p-ISSN: 2395-0072 © 2018, IRJET | Impact Factor value: 6.171 | ISO 9001:2008 Certified Journal | Page 3573  Preparation of blends of biodiesel with diesel fuel chicken fat by using esterification and Trans esterification reaction.  Extraction of oil from chicken fat by steam distillation process.  To perform engine analysis and exhaust analysis.  Quality testing of all biodiesel blend along with diesel fuel e.g. density, viscosity, flash point, fire point, cetane number etc. (B00, B06, B12, B18, B24, B30, and B36.  To find best blends for diesel fuel with no need of modification in diesel engine. 2. MATERIALS AN D METHODOLOGY FOR BLEND PREPARATION A. Material & Chemicals:  Waste chicken fat  Small percentage of edible oil  Sodium Chloride  Methyl alcohol  Sulphuric Acid  Sodium Hydroxide B. Equipment:  Reactor flask  Thermometer  Magnetic stirrer  Distillation Setup  Beakers and Test tubes C. Methodology: PART A: EXTRACTION OF OIL 1. Take 2 kg chicken fat and add low fat oil (400 ml) with 100 gm sodium chloride as an ingredients. 2. mixture is heated at medium flame for 16 hrs and stirred so that it will not stick to the vessel. 3. After 16 hrs extraction of oil done from chicken fat. 4. Extracted oil is taken in reactor flask set up which consist of 4 inputs valves ,one for thermometer ,one for magnetic stirrer, and one for adding additives and another for distillation setup. 5. Now in the flask 10% CH3OH and 0.5% sulphuric acid is added as an solvent and catalyst respectively. The temp is maintain at 60 degree centigrade. PART B: ESTERIFICATION-TRANSESTERIFICATION 6. To get homogenous mixture with help of stirrer rigorously stirring is done (mechanical stirrer ) for 2 hours at constant temperature 56-60 ’C ,process known as Esterification 7. After esterification one separate solution is prepared of 0.5% sodium hydroxide & 10% Methyl alcohol in separated beaker, that solution will add to previous mixture in reactor flask and stirring is continued for 2 hours process known as Transesterification. 8. After 10 hours 2 layers will formed, upper will be cloudy layer (impure biodiesel) and bottom is glycerin which is byproduct. That high density glycerin will be separated. 9. Obtained impure cloudy biodiesel contains catalyst & solvent which is removed by washing step by hot water (having temperature 64’C), usually 3-4 steps are followed. 10. Finally moisturized Biodiesel will be formed, to remove moisture pure biodiesel is heated and pure biodiesel is obtained.
  • 3. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 05 Issue: 03 | Mar-2018 www.irjet.net p-ISSN: 2395-0072 © 2018, IRJET | Impact Factor value: 6.171 | ISO 9001:2008 Certified Journal | Page 3574 Table 1.Properties of diesel & Biodiesel Chicken fat oil biodiesel blends B6% B12% B18% B24% B30% 0.833 0.384 0.836 0.838 0.841 42.41 42.2 42.09 41.96 41.86 49.44 49.7 49.88 49.95 50.11 _ _ 2.96 _ NA NA NA NA NA 75 89 96 102 110 _ _ _ 111 _ _ _ _ 3 _ _ _ _ -1 _ _ _ _ 0.1 _ Engine testing: Engine testing was carried out on IC engine with following specifications- Fuel :Diesel No. of cylinders :1 No. of strokes :4 Cylinder diameter :87.5mm Stroke length :110mm Connecting rod length :234mm Orifice diameter :20mm Dynamometer arm length :185mm Power :3.5kW Speed :1500RPM CR :18:1 As above engine specifications keeping as C.R. 18 readings been taken. The fuel tank and pipe were cleaned before inserting each blends of biodiesel. The emission testings were carried on AVL 437 smoke meter Operating Unit. 3. RESULT EMISSION ANALYSIS Blends Load(in kg) CO % CO2 % B00 0.3 0.024 0.5 3 0.027 0.9 6 0.016 1.2 9 0.015 1.6 12 0.016 1.9 B06 0.3 0.046 0.98 3 0.043 1.2 6 0.042 1.5 9 0.036 1.8 12 0.031 2.2 B12 0.3 0.039 0.6 3 0.038 1 6 0.026 1.3 9 0.03 1.7 12 0.033 2.2 B18 0.3 0.036 1 3 0.026 1.4 6 0.021 1.7 9 0.02 2.09 12 0.02 2.2 B30 0.3 0.032 0.6 3 0.036 1 6 0.021 1.5 9 0.026 1.7 12 0.028 2.09
  • 4. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 05 Issue: 03 | Mar-2018 www.irjet.net p-ISSN: 2395-0072 © 2018, IRJET | Impact Factor value: 6.171 | ISO 9001:2008 Certified Journal | Page 3575 0 1 2 3 0.3 3 6 9 12 CO2 emission B6 B12 B18 B30 B00 4. CONCLUSION AND SCOPE FOR FUTURE WORK Conclusion: In this project we produced biodiesel from waste chicken fat in the form of various blends viz., B6 B12, B18, B30, B00. We Achieved biodiesel using method which has very few difficulties to prepare biodiesel and make the best or most effective use .After preparing this biodiesel we analysed the properties of biodiesel and compared with pure diesel along with that we did engine analysis (IC engine) & emission analysis which showed us some characteristic properties of this prepared blends. On the basis of the obtained data we arrive at a judgement that the blends B18 and B12 shows similar properties as the pure diesel shows (According to ASTM Std ) and we can use this as alternative source for pure diesel. According to today’s circumstance of fossil fuel depletion and bio-degradability biodiesel is best alternative source. This biodiesel has very less harmful effect on environment. Reference: [1]Turning Chicken Fat Into Biodiesel - Georgia Farm Monitor https://www.youtube.com/watch?v=0rRvAgzKEDw [2] K Srinivasa Rao, Dr. A Ramakrishna and P V Rao, “performance and emission characteristics of DI-CI Diesel Engine with Preheated Chicken Fat Biodiesel”, International Journal of Mechanical Engineering & Technology (IJMET). Volume: 4, Issue: 3, Pages: 177-190. 2013 [3]Jugulkar L.M And Jagadale S.S, “Performance Characteristics of Single Cylinder Diesel Engine Using Blend of Chicken Fat Based Biodiesel”, International Journal of Mechanical Engineering & Technology (IJMET). Volume: 3, Issue:2, Pages: 754-768. 2012 [4] kambiz Tahvildari A, Nages Davari B and Mohammad Reaza, “Biodiesel Production from Waste Chicken Fat Oil based Sources”, world academy of science, Engineering and Technology 55. 2011 [5] Ertan Alptekin, Mustafa Canakci and huseyin sanli, “methyl ester production from chicken fat with high FFA”, world renewable congress, 8-13 may, Sweden, pp.319- 326, 2011.